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Low-loading gold in situ doped with sulfur by biomolecule-assisted approach for promoted electrochemical carbon dioxide reduction

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Nano Research 2023年第2期16卷 2059-2064页

作者： Meijie Tan Xiaoqian Han Sen Ru Chao Zhang Zhouru Ji Zhaolin Shi guomeng qiao Yunying Wang Ruixue Cui Qiquan Luo Jiqing Jiao Yaguang Li Tongbu Lu MOE International Joint Laboratory of Materials Microstructure Institute for New Energy Materials and Low Carbon TechnologiesSchool of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Institutes of Physical Science and Information Technology Anhui UniversityHefei 230601China Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192China College of Materials Science and Engineering State Key Laboratory of Bio-Fibers and Eco-TextilesQingdao UniversityQingdao 266071China Hebei Key Lab of Optic-electronic Information and Materials College of Physics Science and TechnologyInstitute of Life Science and Green DevelopmentHebei UniversityBaoding 071002China

For electrochemical carbon dioxide reduction(CO_(2)RR),CO_(2)-to-CO conversion is considered an ideal route towards carbon neutrality for practical ***(Au)is known as a promising catalyst with high selectivity for CO;however,it suffers from high cost and low mass-specific *** this study,we design and prepare a catalyst featuring uniform S-doped Au nanoparticles on N-doped carbon support(denoted as S-Au/NC)by an in situ synthesis strategy using *** S-Au/NC displays high activity and selectivity for CO in CO_(2)RR with a Au loading as low as 0.4 wt.%.The Faradaic efficiency of CO(FECO)for S-Au/NC is above 95%at−0.75 V(***);by contrast,the FECO of Au/NC(without S)is only 58%.The Tafel slope is 77.4 mV·dec−1,revealing a favorable kinetics ***,S-Au/NC exhibits an excellent long-term stability for CO_(2)*** functional theory(DFT)calculations reveal that the S dopant can boost the activity by reducing the free energy change of the potential-limiting step(formation of the*COOH intermediate).This work not only demonstrates a model catalyst featuring significantly reduced use of noble metals,but also establishes an in situ synthesis strategy for preparing high-performance catalysts.

关键词： electrochemical CO_(2)reduction nanocomposites heterogeneous catalyst in situ sulfured heteroatoms

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A three dimensional visualized physical simulation for natural gas charging in the micro-nano pore system

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Petroleum Exploration and Development 2022年第2期49卷 349-362页

作者： qiao Juncheng ZENG Jianhui XIA Yuxuan CAI Jianchao CHEN Dongxia JIANG Shu HAN guomeng CAO Zhe FENG Xiao FENG Sen- State Key Laboratory of Petroleum Resources and Prospecting China University of PetroleumBeijing 102249.China College of Geosciences China University of PetroleumBeijing 102249China Institute of Geophysics and Geomatics China University of GeosciencesWuhan 430074China Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education China University of GeosciencesWuhan 430074China Dagang Oilfield Company PetroChinaTianjin 300280China Sinopec Petroleum Exploration and Production Research Institute Beijing 102206China CNPC Engineering Technology R&D Company Limited Beijing 102206China

A micro-nano pore three-dimensional visualized real-time physical simulation of natural gas charging, in-situ pore-scale computation, pore network modelling, and apparent permeability evaluation theory were used to investigate laws of gas and water flow and their distribution, and controlling factors during the gas charging process in low-permeability(tight) sandstone reservoir. By describing features of gas-water flow and distribution and their variations in the micro-nano pore system, it is found that the gas charging in the low permeability(tight) sandstone can be divided into two stages, expansion stage and stable stage. In the expansion stage, the gas flows continuously first into large-sized pores then small-sized pores, and first into centers of the pores then edges of pores;pore-throats greater than 20 μm in radius make up the major pathway for gas charging. With the increase of charging pressure, movable water in the edges of large-sized pores and in the centers of small pores is displaced out successively. Pore-throats of 20-50 μm in radius and pore-throats less than 20 μm in radius dominate the expansion of gas charging channels at different stages of charging in turn, leading to reductions in pore-throat radius, throat length and coordination number of the pathway, which is the main increase stage of gas permeability and gas saturation. Among which, pore-throats 30-50 μm in radius control the increase pattern of gas saturation. In the stable stage, gas charging pathways have expanded to the maximum, so the pathways keep stable in pore-throat radius, throat length, and coordination number, and irreducible water remains in the pore system, the gas phase is in concentrated clusters, while the water phase is in the form of dispersed thin film, and the gas saturation and gas permeability tend stable. Connected pore-throats less than 20 μm in radius control the expansion limit of the charging pathways, the formation of stable gas-water distribution, and the ma

关键词： low permeability(tight)sandstone gas charging three-dimensional visualization physical simulation micro-nanometer pore network gas and water flow and distribution

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英诗的声韵探析

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内蒙古工业大学学报（社会科学版） 2005年第1期14卷 72-75页

作者：乔晓燕郭萌内蒙古工业大学外国语学院内蒙古呼和浩特010062

英语诗歌是英语文学中占主导地位的文学形式之一。作为吟诵性很强的文学体裁,了解英诗的音韵对于欣赏英诗至关重要。本文的目的不在于尽述英诗的韵式和各种传统诗体,而是以几首耳熟能详的短诗为例,从语音能够给读者带来的联想和感受入手... 详细信息

英语诗歌是英语文学中占主导地位的文学形式之一。作为吟诵性很强的文学体裁,了解英诗的音韵对于欣赏英诗至关重要。本文的目的不在于尽述英诗的韵式和各种传统诗体,而是以几首耳熟能详的短诗为例,从语音能够给读者带来的联想和感受入手,分析具体的元音、辅音、以及能够激发特殊情感效果的语音运用到诗歌中所起到的作用。

关键词：语音联想感受押韵

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微纳米孔隙网络中天然气充注的三维可视化物理模拟

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石油勘探与开发 2022年第2期49卷 306-318页

作者：乔俊程曾溅辉夏宇轩蔡建超陈冬霞蒋恕韩国猛曹喆冯枭冯森中国石油大学(北京)油气资源与探测国家重点实验室北京102249 中国石油大学(北京)地球科学学院北京102249 中国地质大学(武汉)地球物理与空间信息学院武汉430074 中国地质大学(武汉)构造与油气资源教育部重点实验室武汉430074 中国石油大港油田公司天津300280 中国石油化工股份有限公司石油勘探开发研究院北京102206 中国石油集团工程技术研究院有限公司北京102206

利用微纳米孔隙三维可视化在线天然气充注物理模拟实验,结合孔隙尺度原位叠算技术、孔隙网络模拟技术和视渗透率理论,研究低渗(致密)气充注过程中气水流动与分布规律及其影响因素。通过精确刻画分析微纳米孔隙网络中的气水流动与分布特... 详细信息

利用微纳米孔隙三维可视化在线天然气充注物理模拟实验,结合孔隙尺度原位叠算技术、孔隙网络模拟技术和视渗透率理论,研究低渗(致密)气充注过程中气水流动与分布规律及其影响因素。通过精确刻画分析微纳米孔隙网络中的气水流动与分布特征及其变化可以发现,低渗(致密)气充注过程分为扩张和稳定两个阶段:扩张阶段形成了大孔喉先于小孔喉,孔喉中央先于边缘的气驱水连续流动模式,半径大于20μm的孔喉是气相充注的主要通道;随充注动力增加,孔隙边缘和更小孔隙中央的可动水持续被驱出,半径为20~50μm和半径小于20μm的孔喉先后主导了气相充注通道的扩张,充注通道的孔喉半径、喉道长度和配位数递减,是气相渗透率与含气饱和度的主要增长阶段;半径为30~50μm的孔喉控制了含气饱和度的增长模式。稳定阶段,气相充注通道扩张至极限,通道的孔喉半径、喉道长度和配位数保持稳定,孔喉网络中形成稳定的不可动束缚水,气相呈集中网簇状、水相呈分散薄膜状分布,含气饱和度和气相渗透率趋于稳定。半径小于20μm的连通孔喉控制了气相充注通道的极限规模,控制了稳定气水分布的形成及最大含气饱和度。连通孔喉非均质性影响了孔喉中气相充注和气水分布的动态变化过程。微纳米孔喉配置及其非均质性控制了低渗(致密)砂岩气充注动态过程及气水分布特征。

关键词：低渗(致密)砂岩天然气充注机理三维可视化物理模拟微纳米孔喉网络气水流动

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