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QUANTUM CHEMICAL STUDY ON THE THERMOLYSES OF 1，5－CYCLOOCTADIENE AND 4－VINYLCYCLOHEXENE

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Chinese Chemical Letters 1995年第6期6卷 487-490页

作者： San guo HONG Shen WANG(Department of Chemistry,jiangxi Normal university.nanchang 830027) jiangxi Normal Univ Dept Chem Nanchang 330027 Peoples R China

MINDO/3 method *** used to study the thermolyses of 1,5-cyclooctadiene and *** results obtained show that the activation energies of the reta-determining ateps are 197.936and 225.534 ***.

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Journal of Hydrodynamics 1992年第2期4卷 10-23页

作者： Hu Zheng-yuan,jiangxi Polytechnic university, nanchang 330029, P.R.China jiangxi Polytechnic Univ Nanchang China

The water intake head installed with inclined boardings is called laminate sediment precipitation, which separates liquid and solid particles in two-phase flow by gravity. The paper presents the equations for calculating the distance H between two incllined boardings, indicating that H has a key effect on the particle precipitation velocity V_2. The paper focuses also on the cal- culation of hydraulic similarity of model with the theoretic model.

关键词： sediment reynolds number water intake head inclined boardings froude similarity criterion

Preparation of Co/S co-doped carbon catalysts for excellent methylene blue degradation

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 169-181页

作者： Haixu li Haobo He Tiannan Jiang Yunfei Du Zhichen wu liang Xu Xinjie Wang Xiaoguang liu Wanhua Yu Wendong Xue School of Materials Science and Engineering University of Science and Technology BeijingBeijing 100083China Beijing Jinyu Tongda Refractory Technologies Co. Ltd.Beijing 100085China

S and Co co-doped carbon catalysts were prepared via pyrolysis of MOF-71 and thiourea mixtures at 800℃at a mass ratio of MOF-71 to thiourea of 1:0.1 to effectively activate peroxymonosulfate(PMS)for methylene blue(MB)*** effects of two different mixing routes were identified on the MB degradation ***,the catalyst obtained by the alcohol solvent evaporation(MOF-AEP)mixing route could degrade 95.60%MB(50 mg/L)within 4 min(degradation rate:K=0.78 min^(-1)),which was faster than that derived from the direct grinding method(MOF-DGP,80.97%,K=0.39 min^(-1)).X-ray photoelectron spectroscopy revealed that the Co-S content of MOF-AEP(43.39at%)was less than that of MOF-DGP(54.73at%),and the proportion of C-S-C in MOF-AEP(13.56at%)was higher than that of MOF-DGP(10.67at%).Density functional theory calculations revealed that the adsorption energy of Co for PMS was -2.94 eV when sulfur was doped as C-S-C on the carbon skeleton,which was higher than that when sulfur was doped next to cobalt in the form of Co-S bond(-2.86 eV).Thus,the C-S-C sites might provide more contributions to activate PMS compared with ***,the degradation parameters,including pH and MOF-AEP dosage,were ***,radical quenching experiments and electron paramagnetic resonance(EPR)measurements revealed that ^(1)O_(2)might be the primary catalytic species,whereas·O~(2-)might be the secondary one in degrading MB.

关键词： advanced oxidation process alcohol solvent evaporation hydrogen bond S and Co co-doped carbon catalysts wastewater remediation

Substrate bias effects in p-channel GaN-on-Si transistors

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Science China(Information Sciences) 2025年第1期68卷 404-405页

作者： Mengyao ZHAO Jie MA Lanlan YANG chuanqi PAN Denggui WANG Jianjun ZHOU Sheng li Jiaxing WEI long ZHANG Siyang liu Weifeng SUN National ASIC System Engineering Research Center School of Integrated Circuits Southeast University National Center of Technology Innovation for Electronic Design Automation Southeast University National Key Laboratory of Solid-State Microwave Devices and Circuits

The drain current （ID） of the n-channel GaN field-effecttransistor （n-FET） is influenced by the substrate-to-source bias voltage (VBS)（substrate bias effect）[1].Actually,nonzero VBSis also likely to occur in p-FET in real application,because the source electrode of p-FET is usually connected to high *** study reports the dependency between IDand VBSin p-FET for the first time,and analyzes the underlying mechanisms from the perspective of vertical electric field （EF） distribution.

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Investigations into quantum correlation of coupled qubits in a squeezed vacuum reservoir

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Chinese Physics B 2013年第2期22卷 86-91页

作者：嵇英华刘咏梅 Department of Physics Jiangxi Normal University Key Laboratory of Photoelectronics and Telecommunication of jiangxi Province College of Mathematics and Information Science Jiangxi Normal University

In this paper,we investigate the quantum correlation of coupled qubits which are initially in maximally entangled mixed states in a squeezed vacuum *** compare and analyze the effects of squeezed parameters on quantum discord and quantum *** results show that in a squeezed vacuum reservoir,the quantum discord and quantum concurrence perform with completely opposite behaviors with the change of squeezed *** discord survives longer with the increase of squeezed amplitude parameter,but entanglement death is faster on the *** results also indicate that the classical correlation of the system is smaller than quantum discord in a vacuum reservoir,while it is bigger than quantum discord in a squeezed vacuum *** quantum discord and classical correlation are more robust than quantum concurrence in the two reservoir environments,which indicates that the entanglement actually is easily affected by decoherence and quantum discord has a stronger ability to avoid decoherence in a squeezed vacuum reservoir.

关键词： quantum correlation coupled qubits quantum discord concurrence

Highly mass activity electrocatalysts with ultralow Pt loading on carbon black for hydrogen evolution reaction

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 182-190页

作者： Shaorou Ke Yajing Zhao Xin Min Yanghong li Ruiyu Mi Yangai liu Xiaowen wu Minghao Fang Zhaohui Huang Engineering Research Center of Ministry of Education for Geological Carbon Storage and Low Carbon Utilization of Resources Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid WastersNational Laboratory of Mineral MaterialsSchool of Materials Science and TechnologyChina University of Geosciences(Beijing)Beijing 100083China

Pt-based nanocatalysts offer excellent prospects for various ***,the low loading of Pt with excellent performance for efficient and stable nanocatalysts still presents a considerable *** this study,nanocatalysts with ultralow Pt content,excellent performance,and carbon black as support were prepared through in-situ ***~2-nm particles uniformly and stably dispersed on carbon black because of the strong s-p-d orbital hybridizations between carbon black and Pt,which suppressed the agglomeration of Pt *** unique structure is beneficial for the hydrogen evolution *** catalysts exhibited remarkable catalytic activity for hydrogen evolution reaction,exhibiting a potential of 100 mV at 100 mA·cm^(-2),which is comparable to those of commercial Pt/C *** activity(1.61 A/mg)was four times that of a commercial Pt/C catalyst(0.37 A/mg).The ultralow Pt loading(6.84wt%)paves the way for the development of next-generation electrocatalysts.

关键词： hydrogen evolution reaction ultralow platinum in-situ synthesis ultrasound

Experimental Research on a Feasible Building Insulation Material Based Reed in China

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Journal of Thermal Science 2025年第1期34卷 176-187页

作者： liu Tiantian PENG Yizhe liu lifang CAI Chenghan WANG Shuang li Hongqiang College of Civil Engineering Hunan University College of Civil Engineering Hunan University of Science and Technology School of Energy and Power Jiangsu University of Science and Technology National Center for International Research Collaboration in Building Safety and Environment (NCIRCBSE) Hunan University Key Laboratory of Building Safety and Energy Efficiency of the Ministry of Education Hunan University

The seemingly useless reeds are prepared as thermal insulation materials,which not only meet the requirements of environmental sustainability but also enhance the added value of reeds,creating new economic *** hydrophobicity of raw biomass surfaces leads to problems such as weak bonding strength and non-dense structure in the formed materials,as well as issues related to the residual insect infestations on the *** this study,reed straw was used as the raw material,and foamed geopolymer was used as the binder to prepare building insulation materials based *** improve the interfacial adhesion performance between reed straw and foamed geopolymer,a thermochemical modification method-thermal carbonization,was *** this study,the mechanical properties and hydraulic properties of the studied materials with different degrees of surface thermal modification were tested,especially the fire resistance performance,and weathering resistance performance rarely found in published *** the surface thermal modification condition of reed straw was 250℃（30 min）,the comprehensive performance of reed-based building insulation materials was the best,when the studied material density was 321.3 kg/m3;the compressive strength was 0.59 MPa;the thermal conductivity was 0.101 W/（m·K）;the pH was 11.27;the moisture absorption rate was 25.1%,and the compressive strength loss rate in wet-dry cycles was 18.5%.In addition,it had excellent fire resistance performance and weathering resistance *** new material can be widely used to improve the thermal insulation of traditional buildings and as sandwich filler in prefabricated buildings,such as preparing insulating walls.

关键词： building insulation material based reed fire resistance performance interface adhesion properties pre-treatment of reeds weathering resistance performance

Simulations of electron zebra stripes in the inner radiation belt using a composite empirical electric field model

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Science China Earth Sciences 2025年第1期68卷 27-38页

作者： Ziyang WANG Ying liu Qiugang ZONG Hong ZOU Yuguang YE Xuzhi ZHOU Chao yue Shan WANG Institute of Space Physics and Applied Technology Peking University State Key Laboratory of Lunar and Planetary Science Macau University of Science and Technology

The phenomenon termed “zebra stripes” manifests as regular patterns in the energy-space(L shell) spectrum of energetic electrons(ranging from tens to hundreds ke V) within the inner radiation belt. These structures exhibit drift-periodic behavior and commonly arise from large-scale electric field perturbations near the substorm onsets. In this study, we introduce a composite electric field model and replicate the formation, structure, and evolution of zebra stripes using a bounce-averaged test particle code under this electric field model. High-resolution measurements of energetic electrons obtained from the Van Allen Probes and the recently launched Macao Science Satellites-1 are used as initial conditions and served to validate our test particle simulations. Comparative analyses between observed data and simulations demonstrate our test particle method's efficacy in capturing zebra stripes' general behavior. Moreover, the composite model proves capable of reproducing realistic variations in the electric field within the inner radiation belt to a certain extent. Nevertheless, subtle differences emerge in the flux strength and the positions of stripes. These disparities primarily stem from limitations inherent in the electric field model and the initial conditions of the simulation. Acknowledging that the model represents an average case, it is conceivable that real-world scenarios may deviate from the average, thereby introducing variations in the observed phenomena.

关键词： Zebra stripes Inner radiation belt Large-scale electric fields Van Allen Probes Macao Science Satellite

A SEMI-ANALYTICAL SOLUTION FOR CHARACTERISTICS OF A DAMRESERVOIR SYSTEM WITH ABSORPTIVE RESERVOIR BOTTOM

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Journal of Hydrodynamics 2008年第6期20卷 727-734页

作者： li Shang-ming liANG Hong li Ai-min School of Civil Engineering and Architecture Nanchang University Nanchang 330031 China

In this study, a semi-analytical formulation based on the Scaled Boundary Finite Element Method （SBFEM） was proposed and used to obtain the solution for the characteristics of a two-dimensional dam-reservoir system with absorptive reservoir bottom in the frequency domain. For simplicity, the dam with arbitrary upstream faces was assumed to be rigid and was subjected to a horizontal ground acceleration, while the reservoir with absorptive bottom was assumed to be semi-infinite. The reservoir was divided into two sub-domains： a near-field sub-domain and a far-field sub-domain. The near-field sub-domain with arbitrary geometry was modelled by the Finite Element Method （FEM）, while the effects of the far-field sub-domain which was assumed to be horizontal were described by a semi-analytical formation. The semi-analytical formulation involved the effect of absorptive reservoir bottom, as well as the radiation damping effect of a semi-infinite reservoir. A FEM/SBFEM coupling formulation was presented to solve dam-reservoir coupled problems. The accuracy and efficiency of the coupling formulation were demonstrated by computing some benchmark examples. Highly accurate results are produced even if the near-field sub-domain is very small.

关键词： dam-reservoir interaction absorptive bottom SBFEM Hydraulic pressure FEM/SBFEM coupling formulation