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Building the Stable Oxygen Framework in High-Ni Layered Oxide Cathode for High-Energy-Density li-Ion Batteries

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Energy & Environmental Materials 2022年第4期5卷 1260-1269页

作者： Yang-Yang Wang Yu-Yang Wang Sheng liu guo-ran li Zhen Zhou Ning Xu Meng-Tao Wu Xue-Ping Gao Institute of New Energy Material Chemistry School of Materials Science and EngineeringRenewable Energy Conversion and Storage CenterNankai UniversityTianjin 300350China Tianjin Bamo Tech Co. Ltd.Tianjin 300384China

High-Ni layered oxide cathodes hold a great promise for fabricating highenergy lithium-ion ***,the oxygen evolution during cycling is a crucial factor in the structure deterioration,potential change,and capacity decay of cathodes,limiting the commercial application of high-Ni(Ni>0.9)layered oxides in ***,we demonstrate a feasible approach to enhance the stability of oxygen framework,through the surface oxygen immobilization with yttrium and bulk oxygen stabilization with aluminum in high-Ni layered *** expected,benefiting from the oxygen-stabilized framework,the bulk structure deterioration,and interfacial parasitic reaction are mitigated obviously during battery operation,along with the improved thermal stability of ***,the as-prepared high-Ni oxide delivers high reversible capacity,impressive cycle ability,and low potential polarization upon *** significant improvement on the electrochemical performance is primarily attributed to the strong oxygen affinities of both yttrium at the surface layer and aluminum in the bulk,which synergistically stabilizes the oxygen framework of high-Ni oxide via raising the energy barrier for oxygen ***,building the stable oxygen framework is critical for enhancing the energy density output,cycle operation,and thermal stability of high-Ni oxide cathodes.

关键词： li-ion batteries cathode high-Ni oxide oxygen evolution structure stability

Phosphotungstic acid immobilized on amino-functionalized TS-1 zeolite as a solid acid catalyst for the synthesis of tributyl citrate

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Chinese Journal of Chemical Engineering 2024年第6期70卷 199-210页

作者： Pei li Bianfang Shi Junyao Shen ran Cui Wenze guo ling Zhao Zhenhao Xi State Key Laboratory of Chemical Engineering East China University of Science and TechnologyShanghai 200237China Key Laboratory of Smart Manufacturing in Energy Chemical Process Ministry of EducationEast China University of Science and TechnologyShanghai 200237China

The amino-functionalization of TS-1 zeolite followed by immobilization of phosphotungstic acid(HPW)was presented to prepare a strong solid acid catalyst for the synthesis of bio-based tributyl citrate from the esterification of citric acid and n-butanol.γ-Aminopropyltriethoxysilane(APTES)was first grafted on the TS-1 zeolite via the condensation reactions with surface hydroxyl groups,and subsequently the HPW was immobilized via the reaction between the amino groups and the protons from HPW-forming strong ionic *** Keggin structure of HPW and MFI topology of TS-1 zeolite were well maintained after the *** amino-functionalization generated abundant uniformly distributed active sites on TS-1 for HPW immobilization,which promoted the dispersity,abundance,as well as the stability of the acid *** tetrahedrally coordinated framework titanium and non-framework titania behaved as weak Lewis acid sites,and the protons from the immobilized HPW acted as the moderate or strong Brønsted acid *** optimized TBC yield of 96.2%(mol)with a conversion of-COOH of 98.1%(mol)was achieved at 150℃for 6 h over the HPW immobilized on amino-functionalized *** catalyst exhibited good stability after four consecutive reaction runs,where the activity leveled off at still a relatively high level after somewhat deactivation possibly caused by the leaching of a small portion of weakly anchored APTES or HPW.

关键词： Amino-functionalization Phosphotungstic acid TS-1 zeolite Esterification Tributyl citrate

Viral-mediated gene therapy in pediatric neurological disorders

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World Journal of Pediatrics 2024年第6期20卷 533-555页

作者： Jing Peng Wei-Wei Zou Xiao-Lei Wang Zhi-guo Zhang ran Huo li Yang Department of Pediatrics Clinical Research Center for Chidren Neurodevelopmental disablities of Hunan ProvinceXiangya HospitalCentral South UniversityChangsha 410008China Reproductive Medicine Center Department of Obstetrics and Gynecologythe First Affiliated Hospital of Anhui Medical UniversityHefeiChina State Key Laboratory of Reproductive Medicine Nanjing Medical UniversityNanjingChina

Background Due to the broad application of next-generation sequencing,the molecular diagnosis of genetic disorders in pediatric neurology is no longer an unachievable ***,treatments for neurological genetic disorders in children remain primarily *** the other hand,with the continuous evolution of therapeutic viral vectors,gene therapy is becoming a clinical *** this perspective,we wrote this review to illustrate the current state regarding viral-mediated gene therapy in childhood neurological *** sources We searched databases,including PubMed and Google Scholar,using the keywords"adenovirus vector,""lentivirus vector,"and"AAv"for gene therapy,and"immunoreaction induced by gene therapy vectors,""administration routes of gene therapy vectors,"and"gene therapy"with"NCL,""SMA,""DMD,""congenital myopathy,""MPS""leukodystrophy,"or"pediatric metabolic disorders".We also screened the database of *** using the keywords"gene therapy for children"and then filtered the results with the ones aimed at neurological *** time range of the search procedure was from the inception of the databases to the *** We presented the characteristics of commonly used viral vectors for gene therapy for pediatric neurological disorders and summarized their merits and drawbacks,the administration routes of each vector,the research progress,and the clinical application status of viral-mediated gene therapy on pediatric neurological *** Viral-mediated gene therapy is on the brink of broad clinical ***-mediated gene therapy will dramatically change the treatment pattern of childhood neurological disorders,and many children with incurable diseases will meet the dawn of a ***,the vectors must be optimized for better safety and efficacy.

关键词： Gene therapy Neurological disorders Pediatrics Viral vectors

Prescribed-time stabilization and inverse optimal control of stochastic high-order nonlinear systems

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Science China(Information Sciences) 2024年第2期67卷 144-156页

作者： ran liU Hui WANG Wuquan li School of Mathematics and Statistics Science Ludong University

This paper investigates the prescribed-time state-feedback stabilization and prescribed-time inverse optimality problems for stochastic high-order nonlinear systems. First, a time-varying controller is designed by developing scaled quartic Lyapunov functions, which can guarantee that the system has a unique strong solution almost surely on the prescribed interval for any system initial conditions and that the states and the control converge to the origin in a mean-square form within the prescribed time. Then, the controller is redesigned to address the problem of prescribed-time inverse optimal mean-square stabilization. Finally,a concrete example is provided to confirm the efficiency of the proposed design schemes.

关键词： stochastic high-order nonlinear systems prescribed-time stabilization the scaled design inverse optimality

Optimization study of spherical tuyere based on BP neural network and new evaluation index

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Building Simulation 2024年第2期17卷 223-234页

作者： Mengchao liu ran Gao Yi Wang Angui li School of Building Services Science and Engineering Xi’an University of Architecture and TechnologyXi’an710055China

The energy consumption of heating,ventilation,and air conditioning(HVAC)systems holds a significant position in building energy usage,accounting for about 65%of the total energy ***,with the advancement of building automation,the energy consumption of ventilation systems continues to *** study focuses on improving the performance of spherical tuyeres in HVAC *** primarily utilizes neural networks and multi-island genetic algorithms(MIGA)for multi-parameter *** employing methods such as structural parameterization,accurate and fast computational fluid dynamics(CFD)simulations,a minimized sample space,and a rational optimization strategy,the time cycle of the optimization process is ***,a new comprehensive evaluation index is proposed in this research to describe the performance of spherical tuyeres,which can be used to more accurately assess spherical tuyeres with different *** results show that by establishing a neural network prediction model and combining it with the multi-island genetic algorithm,a novel spherical tuyere design was successfully *** optimized novel spherical tuyeres achieved a 27.05%reduction in the spherical tuyeres effective index(STEI)compared to the traditional spherical ***,the resistance decreased by 15.68%,and the jet length increased by 7.57%.The experimental results demonstrate that our proposed optimization method exhibits high accuracy,good generalization capability,and excellent agreement at different Reynolds numbers.

关键词： spherical tuyeres STEI CFD ventilation

Enhanced electrochemical performance of li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3) solid electrolyte by anion doping

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Nano Research 2024年第3期17卷 1465-1472页

作者： Jingrui Kang Xu guo Rui Gu Honglei Hao Yi Tang Jiahui Wang li Jin Hongfei li Xiaoyong Wei Electronic Materials Research Laboratory Key Laboratory of the Ministry of Education&International Center for Dielectric ResearchSchool of Electronic and Information EngineeringXi’an Jiaotong UniversityXi’an 710049China School of Energy and Materials Shanghai Key Laboratory of Engineering Materials Application and EvaluationShanghai Polytechnic UniversityShanghai 201209China

Nowadays,the majority of the studies on the substitution are focused on cations(such as Y^(3+),Ti^(4+),P^(5+),etc.)in li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP),while there are few studies on the substitution of anion O^(2-).In this work,the modified LATP with a series of liCl(LATPClx,x=0.1,0.2,0.3,0.4)additives is prepared to enhance ionic *** successful introduction of Cl-makes the length of the c axis decrease from 20.822(2)to 20.792(1)Å,and the bulk conductivity of 2.13×10^(-3) S·cm^(-1) is achieved in LATPCl_(0.3).Moreover,the Al/Ti-O1/Cl1 and Al/Ti-O_(2)/Cl_(2) distance decrease,while the li1-O_(2)/Cl_(2) distance *** ions migrate more easily in the nanochannel of *** addition,the liCl additive increases the relative density and the grain boundary conductivity of LATPClx ***,a higher ionic conductivity of 2.12×10^(–4) S·cm^(-1) and a low activation energy of 0.30 eV are obtained in LATPCl_(0.3).Correspondingly,the symmetric cell exhibits a low overpotential of±50 mV for over 200 h in LATPCl_(0.3).The solid-state li|LATPCl_(0.3)|NCM811(NCM811=liNi0.8Co0.1Mn0.1O_(2))battery exhibits high initial capacity 185.1 mAh·g^(-1) with a capacity retention rate of 95.4%after 100 cycles at 0.5 *** result suggests that liCl additive is an effective strategy to promote electrochemical properties of LATP solid electrolyte and can be considered for reference to other inorganic solid electrolytes systems.

关键词： li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP)solid electrolyte anion doping ionic conductivity cyclic performance

Neighboring optimal guidance using higher-order dynamics approximation with application to orbital injection problem

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Chinese Journal of Aeronautics 2024年第5期37卷 426-440页

作者： Xinglun CHEN ran ZHANG Huifeng li School of Astronautics Beihang UniversityBeijing 100191China

Neighboring optimal guidance,a method to obtain a suboptimal guidance law by approximately solving the first-order necessary conditions based on a nominal trajectory,is widely used in the aerospace field due to its high computational efficiency and low resource *** more advanced scenarios,the existing methods still have a problem that the guidance accuracy and optimality will seriously degrade when the actual state largely deviates from the nominal *** is mainly caused by the approximate description of the first-order conditions in terms of total flight time and nonlinear *** address this problem,a higher-order neighboring optimal guidance method is ***,a novel total flight time updating strategy,together with a normalized time scale,is presented that transforms the optimal problem with free total flight time into a more tractable optimal problem with fixed total flight ***,using the vector partial derivative method,a higher-order approximation is adopted,instead of the first-order approximation,to accurately describe the nonlinear dynamical and terminal constraints,thus obtaining a polynomially constrained quadratic optimal ***,to numerically solve the polynomially constrained quadratic optimal problem,a Newton-type iterative algorithm based on the orthogonal decomposition is *** the iterative solution within each guidance period,the corrections to control quantities and total flight time are *** proposed method is applied to a launch vehicle orbital injection problem,and simulation results show that it achieves high accuracy of orbital injection and optimality of performance index.

关键词： Optimal control Neighboring optimal guidance Launch vehicles Orbital injection Higher-order approximation

On m-ovoids of finite classical polar spaces with an irreducible transitive automorphism group

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Science China Mathematics 2024年第3期67卷 683-712页

作者： Tao Feng Weicong li ran Tao School of Mathematical Sciences Zhejiang UniversityHangzhou 310027China Department of Mathematics and National Center for Applied Mathematics Shenzhen Southern University of Science and TechnologyShenzhen 518055China Key Laboratory of Cryptologic Technology and Information Security Ministry of EducationShandong UniversityQingdao 266237China School of Cyber Science and Technology Shandong UniversityQingdao 266237China

In this paper, we classify the m-ovoids of finite classical polar spaces that admit a transitive automorphism group acting irreducibly on the ambient vector space. In particular, we obtain several new infinite familie... 详细信息

关键词： transitive m-ovoids irreducible action finite classical polar spaces primitive divisor

Double-confined nanoheterostructure Sb/Sb_(2)S_(3)@Ti_(3)C_(2)T_(x)@C toward ultra-stable li-/Na-ion batteries

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Rare Metals 2024年第5期43卷 2067-2079页

作者： Dan Wang Qun Ma Huan He Zhi-Yuan Wang Run-guo Zheng Hong-Yu Sun Yan-guo liu Chun-li liu School of Materials Science and Engineering Northeastern UniversityShenyang110819China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao 066004China Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province Qinhuangdao 066004China Department of Physics and Oxide Research Center Hankuk University of Foreign StudiesYongin 17035Korea

Antimony-based materials with high capacities and moderate potentials are promising anodes for lithium-/-sodium-ion ***,their tremendous volume expansion and inferior conductivity lead to poor structural stability and sluggish reaction ***,a doubleconfined nanoheterostructure Sb/Sb_(2)S_(3)@Ti_(3)C_(2)T_(x)@C has been fabricated through a solvothermal method followed by low-temperature heat *** dual protection of“MXene”and“carbon”can better accommodate the volume expansion of Sb/Sb_(2)S_(3).The strong covalent bond(Ti-S,Ti-O-Sb,C-O-Sb)can firmly integrate Sb-based material with Ti_(3)C_(2)T_(x)and carbon,which significantly improves the structure *** addition,the carbon layer can restrain the oxidation of MXenes,and the nano-Sb/Sb_(2)S_(3)can facilitate electron/ion transport and suppress the restacking of *** heterogeneous interface between Sb and Sb_(2)S_(3)can further promote interfacial charge *** MXene-Sb/Sb_(2)S_(3)@C-1 with the optimal Sb content shows high specific capacities,comparable rate properties and ultra-stable cycling performances(250 m Ah·g^(-1)after 2500 cycles at 1 A·g^(-1)for sodium-ion batteries).Ex situ X-ray diffractometer(XRD)test reveals the storage mechanism including the conversion and alloying process of MXene-Sb/Sb_(2)S_(3)@*** voltammetry(CV)test results demonstrate that the pseudocapacitance behavior is dominant in MXene-Sb/Sb_(2)S_(3)@C-1,especially at large *** design paves the way for exploring high-performance alloy-based/conversion-type anode for energy storage devices.

关键词： Sb/Sb_(2)S_(3) MXene Carbon Anode lithium-ion batteries Sodium-ion batteries