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Effect of nucleating agents on the electrical properties of cross-linked polyethylene under tensile stress

High Voltage 2024年第2期9卷 429-439页

作者： Yunqi xing Jiahao Liu Jingang Su Junwei Zha guochang Li Ze guo Xiaozhen Zhao Mengjia Feng State Key Laboratory of Reliability and Intelligence of Electrical Equipment Hebei University of TechnologyTianjinChina Electric Power Research Institute of State Grid Hebei Electric Power Supply Co. Ltd.ShijiazhuangChina Beijing Advanced Innovation Center for Materials Genome Engineering School of Chemistry and Biological EngineeringUniversity of Science&Technology BeijingBeijingChina Institute of Advanced Electrical Materials Qingdao University of Science and TechnologyQingdaoChina

During the operation of high-voltage cables,external stress and residual stress can affect the aggregated structure of insulating materials and lead to significant deterioration in their electrical *** investigate the evolution characteristics of the electrical properties of cross-linked polyethylene(XLPE)under mechanical stress,this paper ex-plains the relationship between the aggregated structure of XLPE and its electrical properties and proposes a method for improving insulation performance under me-chanical *** results show that metallocene polyethylene used as a nucleating agent can promote crystallisation through heterogeneous nucleation and increase Young's modulus by non-uniform nucleation,increasing crystallinity and reducing interplanar spacing,resulting in more complete crystal forms and reduced damage to the aggregated structure during the tensile *** nucleating agent modification,the XLPE crystallisation becomes more uniform,and interfacial adhesion forces *** weakened interface damage process between the amorphous and crystalline regions under tensile stress effectively inhibits the process of molecular chain polarisation turning and reduces trap *** modified XLPE crystal structure shows a tendency towards densification and enhanced molecular chain interactions,which can reduce the damage to the aggregated structure under tensile stress,while the reduced free volume inside the material and the shortened average free path of carriers can weaken the damage of high-energy electrons to molecular chains,thereby inhibiting the process of electrical tree *** results show that nucleating agents have great potential for maintaining the stable operation of XLPE cables under mechanical stress.

关键词： stress electrical damage

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Effects of zeolite imidazole frameworks on rice seedlings (Oryza sativa L.): Phytotoxicity, transformation, and bioaccumulation

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Journal of Environmental Sciences 2024年第10期144卷 15-25页

作者： Chaofa Chen Yongqi Yao Chenghua xing Yunyu guo Luyi Cai Jianfang Yan Xi-Lin Wu Miaozhen Cai College of Geography and Environmental Science Zhejiang Normal UniversityJinhuaZhejiang 321004China College of Agriculture Jinhua PolytechnicJinhuaZhejiang 321007China

Zeolite imidazole frameworks(ZIFs),a class of the metal organic framework,have been extensively studied in environmental ***,their environmental fate and potential ecological impact on plants remain ***,we investigated the phytotoxicity,transformation,and bioaccumulation processes of two typical ZIFs(ZIF-8 and ZIF-67)in rice(Oryza sativa L.)under hydroponic ***-8 and ZIF-67 in the concentration of 50 mg/L decreased root and shoot dry weight maximally by 55.2%and 27.5%,53.5%and 37.5%,*** scanning electron microscopy(SEM)imaging combined with X-ray diffraction(XRD)patterns revealed that ZIFs on the root surface gradually collapsed and transformed into nanosheets with increasing cultivation *** fluorescein isothiocyanate(FITC)labeled ZIFs were applied to trace the uptake and translocation of ZIFs in *** results demonstrated that the transformed ZIFs were mainly distributed in the intercellular spaces of rice root,while they cannot be transported to culms and *** so,the Co and Zn contents of rice roots and shoots in the ZIFs treated groups were increased by 1145%and 1259%,145%and 259%,respectively,compared with the control *** findings suggested that the phytotoxicity of ZIFs are primarily attributed to the transformed ZIFs and to a less extent,the metal ions and their ligands,and they were internalized by rice root and increased the Co and Zn contents of *** study reported the transformation of ZIFs and their biological effectiveness in rice,highlighting the potential environmental hazards and risks of ZIFs to crop plants.

关键词： Zeolitic imidazolate frameworks (ZIFs) Rice(Oryza sativa L.) Phytotoxicity Transformed ZIFs ZIFs bioaccumulation

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Effects of antioxidant‑rich Lactiplantibacillus plantarum inoculated alfalfa silage on rumen fermentation, antioxidant and immunity status, and mammary gland gene expression in dairy goats

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Journal of Animal Science and Biotechnology 2024年第3期15卷 1227-1240页

作者： Yixin Zhang Samaila Usman qiang Li Fuhou Li Xia Zhang Luiz Gustavo Nussio Xusheng guo State Key Laboratory of Grassland Agro‑ecosystems School of Life SciencesLanzhou UniversityLanzhou 730000PR China Probiotics and Life Health Institute Lanzhou UniversityLanzhou 730000PR China Probiotics and Biological Feed Research Centre Lanzhou UniversityLanzhou 730000PR China Department of Animal Science Luiz de Queiroz College of AgricultureUniversity of Sao PauloPiracicaba 13418‑900Brazil

Background Milk synthesis in lactating animals demands high energy metabolism,which results in an increased production of reactive oxygen metabolites(ROM)causing an imbalance between oxidants and antioxidants thereby inducing oxidative stress(OS)on the *** mitigate OS and postpartum disorders in dairy goats and gain insight into the impact of dietary choices on redox status during lactation,a feeding trial was conducted using alfalfa silage inoculated with a high-antioxidant strain of Lactiplantibacillus *** Twenty-four Guanzhong dairy goats(38.1±1.20 kg)were randomly assigned to two dietary treatments:one containing silage inoculated with *** MTD/1(RSMTD-1),and the other containing silage inoculated with high antioxidant activity *** 24-7(ES24-7).Results ES24-7-inoculated silage exhibited better fermentation quality and antioxidant activity compared to *** ES24-7 diet elevated the total antioxidant capacity(T-AOC),superoxide dismutase(SOD),glutathione peroxi-dase(GSH-Px),and catalase(CAT)activities in milk,serum,and feces of lactating goats(with the exception of T-AOC in milk).Additionally,the diet containing ES24-7 inoculated silage enhanced casein yield,milk free fatty acid(FFA)content,and vitamin A level in the goats’***,an increase of immunoglobulin(Ig)A,IgG,IgM,inter-leukin(IL)-4,and IL-10 concentrations were observed,coupled with a reduction in IL-1β,IL-2,IL-6,interferon(IFN)-γ,and tumor necrosis factor(TNF)-αconcentrations in the serum of lactating goats fed *** concentrations of total volatile fatty acid(VFA),acetate,and propionate were observed in the rumen fluid of dairy goats fed ES24-7 inoculated ***,the diet containing ES24-7 inoculated silage significantly upregulated the expression of nuclear factor erythroid 2 like 2(NFE2L2),beta-carotene oxygenase 1(BCO1),SOD1,SOD2,SOD3,GPX2,CAT,glu-tathione-disulfide reductase(GSR),and heme oxygenase 1(HMOX1)genes in the mammary gland,

关键词： Alfalfa silage Antioxidant activity Gene expression Goats Immunity Lactation

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Design parameter optimization method for a prestressed steel structure driven by multi-factor coupling

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Frontiers of Structural and Civil Engineering 2024年第7期18卷 1066-1083页

作者： guo-Liang SHI Zhan-Sheng LIU De-Chun LU Qing-Wen ZHANG Majid DEZHKAM Ze-qiang WANG Faculty of Architecture Civil and Transportation EngineeringBeijing University of TechnologyBeijing 100124China The Key Laboratory of Urban Security and Disaster Engineering of the Ministry of Education Beijing University of TechnologyBeijing 100124China Beijing Building Construction Research Institute Co. Ltd.Beijing 100039China

To achieve efficient structural design,it is crucial to reduce the cost of materials while ensuring structural *** study proposes an optimization method for design parameters(DPs)in a prestressed steel structure driven by multi-factor *** accomplish this,a numerical proxy model of prestressed steel structures is established with integration of DPs and mechanical parameters(MPs).A data association-parameter analysis-optimization selection system is established.A correlation between DPs and MPs is established using a back propagation(BP)neural *** correlation provides samples for parameter analysis and optimization *** are used to characterize the safety of the *** on the safety grade analysis,the key DPs that affect the mechanical properties of the structure are obtained.A mapping function is created to match the MPs and the key *** optimal structural DPs are obtained by setting structural materials as the optimization objective and safety energy as the constraint *** theoretical model is applied to an 80-m-span gymnasium and verified with a scale test physical *** MPs obtained using the proposed method are in good agreement with the experimental *** with the traditional design method,the design cycle can be shortened by more than 90%.Driven by the optimal selection method,a saving of more than 20% can be achieved through reduction of structural material ***,the cross-sectional dimensions of radial cables have a substantial influence on vertical *** initial tension and cross-sectional size of the upper radial cable exhibit the most pronounced impact on the stress distribution in that *** initial tension and cross-sectional size of the lower radial cable hold the greatest sway over the stress distribution in that cable.

关键词： structure design association relationship performance analysis optimum selection experimental verification

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TSC prediction and dynamic control of BOF steelmaking with state-of-the-art machine learning and deep learning methods

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Journal of Iron and Steel Research International 2024年第1期31卷 174-194页

作者： Tian-yi Xie Cai-dong Zhang Quan-lin Zhou Zhi-qiang Tian Shuai Liu Han-jie guo Material Technology Research Institute Hesteel GroupShijiazhuang050023HebeiChina Tangsteel Company Hesteel GroupTangshan063611HebeiChina School of Artificial Intelligence Beijing Technology and Business UniversityBeijing100048China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China

Mathematical(data-driven)models based on state-of-the-art(SOTA)machine learning and deep learning models and data collected from 12,786 heats were established to predict the values of temperature,sample,and carbon(TSC)test,including temperature of molten steel(TSC-Temp),carbon content(TSC-C)and phosphorus content(TSC-P),which made prepa-ration for eliminating the TSC *** maximize the prediction accuracy of the proposed approach,various models with different inputs were implemented and compared,and the best models were applied to the production process of a Hesteel Group steelmaking plant in China in the *** number of tabular features(hot metal information,scrap,additives,blowing practices,and preset values)was expanded,and time series(off-gas profiles and blowing practice curves)that could reflect the entire steelmaking process were introduced as ***,the latest machine learning models(LightGBM,CatBoost,TabNet,and NODE)were used to make predictions with tabular features,and the best coefficient of determination R^(2)values obtained for TSC-P,TSC-C and TSC-Temp predictions were 0.435(LightGBM),0.857(Cat-Boost)and 0.678(LightGBM),respectively,which were higher than those of classic models(backpropagation and support vector machine).Then,making predictions was performed by using SOTA time series regression models(SCINet,DLinear,Informer,and MLSTM-FCN)with original time series,SOTA image regression models(NesT,CaiT,ResNeXt,and GoogLeNet)with resized time series,and the proposed Concatenate-Model and Parallel-Model with both tabular features and time *** optimization and comparisons,it was finally determined that the Concatenate-Model with MLSTM-FCN,SCINet and Informer as feature extractors performed the best,and its R^(2)values for predicting TSC-P,TSC-C and TSC-Temp reached 0.470,0.858 and 0.710,*** field test accuracies for TSC-P,TSC-C and TSC-Temp were 0.459,0.850 and 0.685,respectively.A related importance analysis was carri

关键词： BOF steelmaking In-blow prediction TSC test Machine learning Deep learning Field application

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Unimolecular Self-Assembled Hemicyanine-Oleic Acid Conjugate Acts as a Novel Succinate Dehydrogenase Inhibitor to Amplify Photodynamic Therapy and Eliminate Cancer Stem Cells

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Research 2024年第2期6卷 449-461页

作者： qiang Wang Tian Yang Shiyou Li Chen Xu Chong Wang Yuxuan Xiong xing Wang Jiangling Wan Xiangliang Yang Zifu Li National Engineering Research Center for Nanomedicine College of Life Science and Technology.Huazhong University of Science and TechnologyWuhan 430074P.R.China Key Laboratory of Molecular Biophysics of Ministry of Education College of Life Science and TechnologyHuazhong University of Science and TechnologyWuhan 430074P.R.China .3Hubei Key Laboratory of Bioinorganic Chemistry and Materia Medical Huazhong University of Science and TechnologyWuhan 430074P.R.China Hubei Engineering Research Center for Biomaterials and Medical Protective Materials Huazhong University of Science and TechnologyWuhan 430074P.R.China Hubei Bioinformatics and Molecular Imaging Key Laboratory College of Life Science and TechnologyHuazhong University of Science and TechnologyWuhan 430074P.R.China

Photodynamic therapy with reactive oxygen species production is a prospective treatment to combat cancer stem cells(CSCs).However,the innate drawbacks,including short lifetime and diffusion distance of reactive oxygen species and hypoxia within solid tumors,have become bottlenecks for clinical applications of photodynamic ***,we develop a mitochondria-targeting hemicyanine-oleic acid conjugate(CyOA),which can self-assemble into supramolecular nanoparticles(NPs)without any exogenous *** is also shown for targeting the mitochondrial complex II protein succinate dehydrogenase to inhibit oxidative phosphorylation and reverse tumor hypoxia,resulting in 50.4-fold higher phototoxicity against breast cancer stem cells(BCSCs)compared to SO_(3)-CyOA NPs that cannot target to *** 4T1 and BCSC tumor models,CyOA NPs achieve higher tumor inhibition and less lung metastasis nodules compared to the clinically used photosensitizer *** study develops a self-assembled small molecule that can serve as both oxidative phosphorylation inhibitor and photosensitizer for eradication of CSCs and treatment of solid tumors.

关键词： cyanine oxidative treatment

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New insights into the deposition of natural gas hydrate on pipeline surfaces:A molecular dynamics simulation study

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Petroleum Science 2024年第1期21卷 694-704页

作者： Jun Zhang Hai-qiang Fu Mu-Zhi guo Zhao Wang Li-Wen Li Qi Yin You-guo Yan Wei Wei Wei-Feng Han Jie Zhong School of Materials Science and Engineering China University of Petroleum(East China)Qingdao 266580ShandongChina School of Petroleum Engineering China University of Petroleum(East China)Qingdao 266580ShandongChina Department of Alternative Energy PetroChina Research Institute of Petroleum Exploration&DevelopmentLangfang 065007HebeiChina

Natural gas hydrate(NGH)can cause pipeline blockages during the transportation of oil and gas under high pressures and low *** hydrate adhesion on pipelines is viewed as an efficient way to prevent NGH *** studies suggested the water film can greatly increase hydrate adhesion in gas-dominant ***,by performing the molecular dynamics simulations,we find in water-dominant system,the water film plays different roles in hydrate deposition on Fe and its corrosion ***,due to the strong affinity of water on Fe surface,the deposited hydrate cannot convert the adsorbed water into hydrate,thus,a water film *** water affinities decrease(Fe>Fe_(2)O_(3)>FeO>Fe_(3)O_(4)),adsorbed water would convert to amorphous hydrate on Fe_(2)O_(3)and form the ordered hydrate on FeO and Fe_(3)O_(4)after hydrate *** absorbed water film converts to amorphous or to hydrate,the adhesion strength of hydrate continuously increases(Fe

关键词： Deposition Natural gas hydrate Pipelines Water affinity Adhesion strength

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Productivity Prediction Model of Perforated Horizontal Well Based on Permeability Calculation in Near-Well High Permeability Reservoir Area

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Energy Engineering 2024年第1期121卷 59-75页

作者： Shuangshuang Zhang Kangliang guo Xinchen Gao Haoran Yang Jinfeng Zhang xing Han College of the Earth Science Yangtze UniversityWuhan430100China PetroChina Changqing Oilfield Fifth Oil Production Plant Xi’an710201China Sinopec Jianghan Oilfield Information Center Wuhan430100China

To improve the productivity of oil wells,perforation technology is usually used to improve the productivity of horizontal wells in oilfield *** the perforation operation,the perforation channel around the wellbore will form a near-well high-permeability reservoir area with the penetration depth as the radius,that is,the formation has different permeability characteristics with the perforation depth as the dividing ***,the permeability is measured by the permeability tester,but this approach has a high workload and limited *** this paper,according to the reservoir characteristics of perforated horizontal wells,the reservoir is divided into two areas:the original reservoir area and the near-well high permeability reservoir *** on the theory of seepage mechanics and the formula of open hole productivity,the permeability calculation formula of near-well high permeability reservoir area with perforation parameters is *** to the principle of seepage continuity,the seepage is regarded as the synthesis of two directions:the horizontal plane elliptic seepage field and the vertical plane radial seepage field,and the oil well productivity prediction model of the perforated horizontal well is established by *** model comparison demonstrates that the model is reasonable and *** calculate and analyze the effect of oil well production and the law of influencing factors,actual production data of the oilfield are substituted into the oil well productivity *** can effectively guide the technical process design and effect prediction of perforated horizontal wells.

关键词： Perforated horizontal well permeability productivity model sensitivity analysis

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Enhanced Cooling Efficiency of Urban Trees on Hotter Summer Days in 70 Cities of China

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Advances in Atmospheric Sciences 2024年第11期41卷 2259-2275页

作者： Limei YANG Jun GE Yipeng CAO Yu LIU xing LUO Shiyao WANG Weidong guo School of Atmospheric Sciences Nanjing UniversityNanjing 210023China Joint International Research Laboratory of Atmospheric and Earth System Sciences Nanjing UniversityNanjing 210023China Frontiers Science Center for Critical Earth Material Cycling Nanjing UniversityNanjing 210023China

Increasing the urban tree cover percentage(TCP) is widely recognized as an efficient way to mitigate the urban heat island effect. The cooling efficiency of urban trees can be either enhanced or attenuated on hotter days, depending on the physiological response of urban trees to rising ambient temperature. However, the response of urban trees' cooling efficiency to rising urban temperature remains poorly quantified for China's cities. In this study, we quantify the response of urban trees' cooling efficiency to rising urban temperature at noontime [~1330 LT(local time), LT=UTC+8] in 17summers(June, July, and August) from 2003–19 in 70 economically developed cities of China based on satellite observations. The results show that urban trees have stronger cooling efficiency with increasing temperature, suggesting additional cooling benefits provided by urban trees on hotter days. The enhanced cooling efficiency values of urban trees range from 0.002 to 0.055℃ %-1 per 1℃ increase in temperature across the selected cities, with larger values for the lowTCP-level cities. The response is also regulated by background temperature and precipitation, as the additional cooling benefit tends to be larger in warmer and wetter cities at the same TCP level. The positive response of urban trees' cooling efficiency to rising urban temperature is explained mainly by the stronger evapotranspiration of urban trees on hotter *** results have important implications for alleviating urban heat risk by utilizing urban trees, particularly considering that extreme hot days are becoming more frequent in cities under global warming.

关键词： urban trees cooling efficiency China's cities evapotranspiration summer hot days

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Constructing orthogonally structured graphene nanointerface on SiC nanowires reinforced carbon/carbon composites to boost mechanical strength and strength retention rate

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Journal of Materiomics 2024年第3期10卷 615-623页

作者： Yao guo Shouyang Zhang qiang Song Fei Zhao Longkang Cong Wei Li Ruimei Yuan State Key Laboratory of Solidification Processing Shaanxi Key Laboratory of Fiber Reinforced Light Composite MaterialsNorthwestern Polytechnical UniversityXi'an 710072China Advanced Interdisciplinary Research Center for Flexible Electronics Academy of Advanced Interdisciplinary ResearchXidian UniversityXi'an 710072China

Carbon/carbon composites with higher mechanical strength and better reliability at elevated tempera-tures are urgently needed to satisfy the practical applications *** nanowires(SiCNWs)modified C/C(SC-CC)composites have attracted an abundance of attention for their excellent mechanical *** further boost the mechanical strengths of composites and maximize the reinforcing efficiency of SiCNWs,we introduce orthogonally structured graphene nanosheets(OGNs)into SC-CC composites,in which OGNs are grafted on the SiCNWs via chemical vapor deposition(CVD)method,forming SC-G-CC *** from the nano-interface effects,uniform stress distribution,strong SiCNWs/PyC interfacial bonding and elevated stress propagation efficiency in the PyC matrix are achieved,thus SC-G-CC composites accomplish brilliant mechanical properties before and after 1,600℃ heat *** temperature rises to 2,100℃,SiCNWs lose efficacy,whereas OGNs with excellent thermal stability continue to play the nano-interface role in the PyC ***,SC-G-CC com-posites show better mechanical performance after 2,100℃ heat treatment,and the mechanical strength retention rate(MSR)of interlaminar shear strength,out-of-plane and in-plane compressive strength of SC-G-CC composites reach 61.0%,55.7%and 55.3%,*** work proposes an alternative thought for maximizing the potentiality of nanomaterials and edifies the mechanical modification of composites.

关键词： SiC nanowires Orthogonally structured graphene nanosheets Carbon/carbon composites Mechanical properties Heat treatment

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