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Strong hetero-interface interaction in 2D/2D WSe_(2)/ZnIn_(2)S_(4) heterostructures for highly-efficient photocatalytic hydrogen generation

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Journal of Energy Chemistry 2024年第10期97卷 379-387,I0008页

作者： xu guo Xing Liu jing Shan Zhuo xu Zhiming Fang Lu Wang Shengzhong Liu School of Energy Powerand Mechanical EngineeringNorth China Electric Power UniversityBeijing 102206China Shaanxi Key Laboratory for Advanced Energy Devices School of Materials Science and EngineeringShanxi Normal UniversityXi'an 710119ShanxiChina Qinghai Advanced Energy Storage Laboratory SPIC Qinghai Photovoltaic Industry Innovation Center Co.Ltd.State Power Investment CorporationXining 810oo7QinghaiChina Key Laboratory of Photoelectric Conversion and Utilization of Solar Energy Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China

Green hydrogen is urgently required for sustainable development of human beings and rational construction of heterostructures holds great promising for photocatalytic hydrogen ***,2D/2D WSe_(2)/ZnIn_(2)S_(4) heterostructures with strong hetero-interface interaction and abundant contact were constructed via an impregnation-annealing *** charge transfer from ZnIn_(2)S_(4) to WSe_(2)was evidenced by transient absorption spectroscopy in crafted heterostructures owing to the tight and2D face-to-face *** a result,the prepared WSe_(2)/ZnIn_(2)S_(4) heterostructures exhibited boosted photocatalytic performance and a highest hydrogen evolution rate of 3.377 mmol/(g h)was achieved with an apparent quantum yield of 45.7%at 420 *** work not only provides new strategies to achieve efficient 2D/2D heterostructures but also paves the way for the development of green hydrogen in the future.

关键词： Strong hetero-interface interaction in 2D/2D WSe_(2)/ZnIn_(2)S_(4) heterostructures for highly-efficient photocatalytic hydrogen generation

Impaired pericyte-Müller glia interaction via PDGFRβsuppression aggravates photoreceptor loss in a rodent model of light-induced retinal injury

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International Journal of Ophthalmology(English edition) 2024年第10期17卷 1800-1808页

作者： Wei xu Li-Jin Cui Xiao-Ying Yang Xiao-Yuan Cui Jian guo guo-Xing xu Department of Ophthalmology the First Affiliated Hospital of Fujian Medical UniversityFuzhou 350001Fujian ProvinceChina Department of Ophthalmology National Regional Medical CenterBinhai Campus of the First Affiliated Hospital of Fujian Medical UniversityFuzhou 350212Fujian ProvinceChina Fujian Institute of Ophthalmology Fuzhou 350001Fujian ProvinceChina

AIM:To investigate the involvement of pericyte-Müller glia interaction in retinal damage repair and assess the influence of suppressing the platelet-derived growth factor receptorβ(PDGFRβ)signaling pathway in retinal pericytes on photoreceptor loss and Müller glial ***:Sprague-Dawley rats were exposed to intense light to induce retinal *** antibody against PDGFRβwere deployed to block the signaling pathway in retinal pericytes through intravitreal *** histology and Müller glial reaction were assessed following light *** vitro,normal and PDGFRβ-blocked retinal pericytes were cocultured with Müller cell line(rMC-1)to examine morphological and protein expression changes upon supplementation with light-injured supernatants of homogenized retinas(SHRs).RESULTS:PDGFRβblockage 24h prior to intense light exposure resulted in a significant exacerbation of photoreceptor *** upregulation of GFAP and p-STAT3,observed after intense light exposure,was significantly inhibited in the PDGFRβblockage *** ther upregulation of cytokines monocyte chemoattractant protein 1(MCP-1)and interleukin-1β(IL-1β)was also observed following PDGFRβ*** the in vitro coculture system,the addition of light-injured SHRs induced pericyte deformation and upregulation of proliferating cell nuclear antigen(PCNA)expression,while Müller cells exhibited neuron-like morphology and expressed ***,PDGFRβblockage in retinal pericytes abolished these cellular responses to light-induced damage,consistent with the in vivo PDGFRβblockage ***:Pericyte-Müller glia interaction plays a potential role in the endogenous repair process of retinal *** of this interaction exacerbates photoreceptor degeneration in light-induced retinal injury.

关键词： pericyte Müller glia light-induced retinal injury platelet-derived growth factor receptorβ signal pathway

Colo-colonic intussusception as a rare complication of colonoscopy with polypectomy: Two case reports

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World Journal of Gastrointestinal Surgery 2024年第6期16卷 1939-1947页

作者： Sai-Heng Xiang guo-Qiang xu Department of Gastroenterology The First Affiliated HospitalZhejiang University School of MedicineHangzhou 310003Zhejiang ProvinceChina

BACKGROUND Colonoscopy is the most frequently used diagnostic and therapeutic tool for the treatment of colorectal *** the complication rate is low,it can be potentially *** is a rare and severe complication often associated with *** a handful of post-colonoscopy intussusception cases have been reported,making this study a valuable addition to the medical *** SUMMARY Case 1:A 61-year-old man underwent colonoscopy with polypectomy for chronic abdominal *** patient experienced abdominal pain 11 hours later but was still discharged after pain *** was readmitted due to recurring *** tomography(CT)showed colo-colonic *** conservative management and attempts at endoscopic reduction failed;therefore,laparoscopic right hemicolectomy was *** examination revealed tubular adenomas in the polyps and inflammation in the resected *** 2:A 59-year-old woman underwent colonoscopy with polypectomy for a polyp in the transverse *** experienced upper abdominal pain,fever,nausea,and vomiting 9 hours after the *** CT and blood tests revealed a colo-colonic intussusception near the hepatic flexure and an elevated white blood cell *** attempts at endoscopic reduction failed and conservative treatment showed no *** underwent successful laparoscopic reduction and recovered *** examination of the resected polyp revealed *** Post-colonoscopy intussusception in adults is rare,and polypectomy may contribute to its *** diagnosis is crucial,with prompt CT examination serving as *** excluding malignancies,conservative management and reduction of intussusception should be considered before surgical bowel resection.

关键词： Intussusception Colonoscopy Polypectomy Complication Case report

Incorporating Lasso Regression to Physics-Informed Neural Network for Inverse PDE Problem

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Computer Modeling in Engineering & Sciences 2024年第10期141卷 385-399页

作者： Meng Ma Liu Fu xu guo Zhi Zhai National Key Lab of Aerospace Power System and Plasma Technology Xi’an Jiaotong UniversityXi’an710049China School of Mechanical Engineering Xi’an Jiaotong UniversityXi’an710049China Department of Electrical and Computer Engineering University of Massachusetts LowellLowellMA 01854USA

Partial Differential Equation(PDE)is among the most fundamental tools employed to model dynamic *** PDE modeling methods are typically derived from established knowledge and known phenomena,which are time-consuming and ***,discovering governing PDEs from collected actual data via Physics Informed Neural Networks(PINNs)provides a more efficient way to analyze fresh dynamic systems and establish *** study proposes Sequentially Threshold Least Squares-Lasso(STLasso),a module constructed by incorporating Lasso regression into the Sequentially Threshold Least Squares(STLS)algorithm,which can complete sparse regression of PDE coefficients with the constraints of l0 *** further introduces PINN-STLasso,a physics informed neural network combined with Lasso sparse regression,able to find underlying PDEs from data with reduced data requirements and better *** addition,this research conducts experiments on canonical inverse PDE problems and compares the results to several recent *** results demonstrated that the proposed PINN-STLasso outperforms other methods,achieving lower error rates even with less data.

关键词： Physics-informed neural network inverse partial differential equation Lasso regression scientific machine learning

Inverse design of mechanical metamaterial achieving a prescribedconstitutive curve

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Theoretical & Applied Mechanics Letters 2024年第1期14卷 16-22页

作者： Zongliang Du Tanghuai Bian Xiaoqiang Ren Yibo Jia Shan Tang Tianchen Cui xu guo State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentDepartment of Engineering MechanicsDalian University of TechnologyDalian 116023China Ningbo Institute of Dalian University of Technology Ningbo 315016China

Besides exhibiting excellent capabilities such as energy absorption,phase-transforming metamaterials offer a vast design space for achieving nonlinear constitutive *** is facilitated by switching between different patterns under ***,the related inverse design problem is quite challenging,due to the lack of appropriate mathematical formulation and the convergence issue in the post-buckling analysis of intermediate *** this work,periodic unit cells are explicitly described by the moving morphable voids method and effectively analyzed by eliminating the degrees of freedom in void ***,by exploring the Pareto frontiers between error and cost,an inverse design formulation is proposed for unit *** formulation aims to achieve a prescribed constitutive curve and is validated through numerical examples and experimental *** design approach presented here can be extended to the inverse design of other types of mechanical metamaterials with prescribed nonlinear effective properties.

关键词： Metamaterial Pattern-transformation Constitutive curve Inverse design

Discovery of scheelite in the Zaozigou gold deposit of West Qinling Orogen,Northwest China and its implications for ore genesis

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China Geology 2024年第3期7卷 586-588页

作者： Meng-xu guo Jia-jun Liu De-gao Zhai guo-ming Weng Rui Zhu State Key Laboratory of Geological Processes and Mineral Resources School of Earth Sciences and ResourcesChina University of Geosciences(Beijing)Beijing 100083China Zaozigou Gold Mine Zhaojin Mining Industry Co.Ltd.Hezuo 747000China

*** The West Qinling Orogen extends east-west over 1500 km and is endowed with dozens of large-super large scale gold *** Zaozigou gold deposit has a proven reserve of 134 t with an average grade of 3.08 g/t thus is one of the largest deposits in the West Qinling ***,whether the fluid type is metamorphic or magmatichydrothermal and ore-formation processes of the Zaozigou gold deposit are *** is a ubiquitous accessory mineral in geologically diverse ore-deposit types and attested to be a strong indicator of ore-forming conditions and oredeposit genesis.

关键词： deposit gold Qinling

Heteroepitaxial growth of Au@Pd core–shell nanocrystals with intrinsic chiral surfaces for enantiomeric recognition

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Rare Metals 2024年第1期43卷 225-235页

作者： Feng-Xia Wu Feng-Hua Li Xia-Li Lv Qi-Xian Zhang guo-Bao xu Wen-Xin Niu State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China Shaoxing Institute of Technology Shanghai UniversityShaoxing 312000China University of Science and Technology of China Hefei 230026China School of Materials Science and Engineering Shanghai UniversityShanghai 200436China Zhejiang Institute of Advanced Materials Shanghai UniversityJiashan 314113China University of Chinese Academy of Sciences Beijing 100039China

Noble metal surfaces with intrinsic chirality serve as an ideal candidate for investigating enantioselective chemistry due to their superior chemical durability and high catalytic ***,significant advance has been made in synthesizing metal nanocrystals with intrinsic ***,the majority reports are limited to ***,through a heteroepitaxial growth strategy,the synthesis of metal nanocrystals with intrinsic chirality to palladium was extended for the first time and their application in enantioselective recognition was *** heteroepitaxial growth strategy allows for transferring the chirality of homochiral Au nanocrystals to Au@Pd core–shell *** employing the chiral Au@Pd nanocrystals as enantiomeric recognizing elements,a series of electrochemical sensors for chiral discrimination were *** optimal conditions,the peak potential between D-dihydroxyphenylalanine(D-DOPA)and L-dihydroxyphenylalanine(L-DOPA)is about 80 m V,and the peak current of D-DOPA is 2 times as much as that of L-DOPA,which enables the determination of the enantiomeric excess(EE,%)of ***,this report not only introduces a heteroepitaxial growth strategy to synthesize metal nanocrystals with intrinsic chirality,but also demonstrates the superior capability of integrating intrinsic chirality and catalytic properties into metal nanocrystals for chiral recognition.

关键词： Core–shell nanostructures Chirality transfer Electrochemical sensors Chiral recognition Chiroplasmonics

Endoscopic ultrasound-guided lauromacrogol injection for treatment of colorectal cavernous hemangioma:Two case reports

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World Journal of Gastrointestinal Surgery 2024年第3期16卷 966-973页

作者： Hua-Tuo Zhu Wen-guo Chen Jing-Jie Wang Jia-Nan guo Fen-Ming Zhang guo-Qiang xu Hong-Tan Chen Department of Gastroenterology The First Affiliated HospitalZhejiang University School of MedicineHangzhou 310003Zhejiang ProvinceChina

BACKGROUND Colorectal cavernous hemangioma is a rare vascular malformation resulting in recurrent lower gastrointestinal hemorrhage,and can be misinterpreted as *** resection is currently the mainstay of treatment,with an emphasis on sphincter *** SUMMARY We present details of two young patients with a history of persistent hematochezia diagnosed with colorectal cavernous hemangioma by endoscopic ultrasound(EUS).Cavernous hemangioma was relieved by several EUS-guided lauromacrogol injections and the patients achieved favorable clinical *** Multiple sequential EUS-guided injections of lauromacrogol is a safe,effective,cost-efficient,and minimally invasive alternative for colorectal cavernous hemangioma.

关键词： Endoscopic ultrasound Lauromacrogol injection Colorectal cavernous hemangioma Case report

In-situ deposited anti-aging TiN capping layer for Nb superconducting quantum circuits

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Chinese Physics B 2024年第9期33卷 133-137页

作者： Hao-Ran Tao Lei Du Liang-Liang guo Yong Chen Hai-Feng Zhang Xiao-Yan Yang guo-Liang xu Chi Zhang Zhi-Long Jia Peng Duan guo-Ping guo CAS Key Laboratory of Quantum Information University of Science and Technology of ChinaHefei 230026China CAS Center for Excellence and Synergetic Innovation Center in Quantum Information and Quantum Physics University of Science and Technology of ChinaHefei 230026China Origin Quantum Computing Company Limited Hefei 230088China

The performance of Nb superconducting quantum devices is predominantly limited by dielectric loss at the metal–air interface,where Nb2O5 is considered the main loss ***,we suppress the formation of native oxides by in-situ deposition of a TiN capping layer on the Nb *** TiN capping layers,no Nb2O5 forms on the surface of the Nb *** quality factor Qi of the Nb resonator increases from 5.6×10^(5) to 7.9×10^(5) at low input power and from 6.8×10^(6) to 1.1×10^(7)at high input ***,the TiN capping layer also shows good aging resistance in Nb resonator devices,with no significant performance fluctuations after one month of *** findings highlight the effectiveness of TiN capping layers in enhancing the performance and longevity of Nb superconducting quantum devices.

关键词： anti-aging oxidation dielectric loss Nb superconducting quantum circuits