检索结果-南通市图书馆

Dual-Defect Engineering Strategy Enables High-Durability Rechargeable Magnesium-Metal Batteries

Nano-Micro Letters 2024年第9期16卷 449-461页

作者： Fuyu Chen Bai‑Qing Zhao Kaifeng huang Xiu‑Fen Ma Hong‑Yi Li Xie Zhang Jiang Diao Jili Yue guangsheng huang Jingfeng Wang Fusheng Pan National Innovation Center for Lndustry‑Education Integration of Energy Storage Technology School of Materials Science and EngineeringChongqing UniversityChongqing 400044People’s Republic of China National Magnesium Alloy Material Engineering Technology Research Center Chongqing UniversityChongqing 400044People’s Republic of China Materials and Energy Division Beijing Computational Science Research CenterBeijing 100193People’s Republic of China School of Materials Science and Engineering Northwestern Polytechnical UniversityXi’an 710072People’s Republic of China National Key Laboratory of Advanced Casting Technologies Chongqing UniversityChongqing 400044People’s Republic of China

Rechargeable magnesium-metal batteries(RMMBs)are promising next-generation secondary batteries;however,their development is inhibited by the low capacity and short cycle lifespan of cathodes.Although various strategies have been devised to enhance the Mg^(2+)migration kinetics and structural stability of cathodes,they fail to improve electronic conductivity,rendering the cathodes incompatible with magnesium-metal anodes.Herein,we propose a dual-defect engineering strategy,namely,the incorporation of Mg^(2+)pre-intercalation defect(P-Mgd)and oxygen defect(Od),to simultaneously improve the Mg^(2+)migration kinetics,structural stability,and electronic conductivity of the cathodes of RMMBs.Using lamellar V_(2)O_(5)·nH_(2)O as a demo cathode material,we prepare a cathode comprising Mg0.07V_(2)O_(5)·1.4H_(2)O nanobelts composited with reduced graphene oxide(MVOH/rGO)with P-Mgd and Od.The Od enlarges interlayer spacing,accelerates Mg^(2+)migration kinetics,and prevents structural collapse,while the P-Mgd stabilizes the lamellar structure and increases electronic conductivity.Consequently,the MVOH/rGO cathode exhibits a high capacity of 197 mAh g^(−1),and the developed Mg foil//MVOH/rGO full cell demonstrates an incredible lifespan of 850 cycles at 0.1 A g^(−1),capable of powering a light-emitting diode.The proposed dual-defect engineering strategy provides new insights into developing high-durability,high-capacity cathodes,advancing the practical application of RMMBs,and other new secondary batteries.

关键词： Rechargeable magnesium-metal batteries Dual-defect engineering Vanadium-based cathode High durability Lamellar structure

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

A perspective on the key factors of safety for rechargeable magnesium batteries

引用

Journal of Energy Chemistry 2024年第7期94卷 656-676页

作者： Shuangshuang Tan Jie Xu Rongrui Deng Qiannan Zhao Chaohe Xu guangsheng huang Jingfeng Wang Fusheng Pan National Engineering Research Center for Magnesium Alloys Chongqing UniversityChongqing 400044China National Innovation Center for Industry-Education Integration of Energy Storage Technology College of Materials Science and EngineeringChongqing UniversityChongqing 400044China Chongqing Institute of New Energy Storage Materials and Equipment Chongqing 401135China

Rechargeable Mg batteries(RMBs)have become one of the best subsitutes for lithium-ion batteries due to the high volumetric capacity,abundant resources,and uniform plating behavior of Mg metal anode.However,the safety hazard induced by the formation of high-modulue Mg dendrites under a high current density(10 mA cm^(-1))was still revealed in recent years.It has forced researchers to re-examine the safety of RMBs.In this review,the intrinsic safety factors of key components in RMBs,such as uneven plating,pitting and flammability of Mg anode,heat release and crystalline water decomposition of cathode,strong corrosion,low oxidition stability and flammability of electrolytes,and soforth,are systematacially summarized.Their origins,formation mechanisms,and possible safety hazards are deeply discussed.To develop high-performance Mg anode,current strategies including designing artificial SEl,three-dimensional substrates,and Mg alloys are summarized.For practical electrolytes,the configurations of boron-centered anions and simple Mg salts and the functionalized solvent with high boiling point and low flammability are suggested to comprehensively design.In addition,the future study should more focus on the investigation on the thermal runaway and decomposition of cathode materials and separa-tors.This review aims to provide fundamental insights into the relationship between electrochemistry and safety,further promoting the sustainable development of RMBs.

关键词： Rechargeable Mg batteries Battery safety Mg dendrites Electrolyte decomposition Intrinsic safety issues

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Strength-ductility balance of AZ31 magnesium alloy via accumulated extrusion bonding combined with two-stage artificial cooling Author links open overlay panel

引用

Journal of Magnesium and Alloys 2023年第5期11卷 1549-1555页

作者： Tingzhuang Han guangsheng huang Heng Li Lifei Wang Hua Zhang Fusheng Pan State Key Laboratory of Solidification Processing School of Materials Science&EngineeringNorthwestern Polytechnical UniversityXi'an 710072PR China Shaanxi Key Lab oratory of High-Performance Precision Forming Technology and Equipment Northwestern Polytechnical UniversityXi'an 710072PR China State Key Laboratory of Mechanical Transmission College of Materials Science and EngineeringChongqing UniversityChongqing 400044PR China College of Materials Science and Engineering Taiyuan University of TechnologyTaiyuan 030024PR China Institute for Advanced Studies in Precision Materials Yantai UniversityYantai 264005PR China

AZ31 Mg alloy with heterogeneous bimodal grain structure(smaller grain size of 5-20µm and coarser grain size of 100-200µm)was subjected to accumulated extrusion bonding(AEB)at 250℃combined with two-stage artificial cooling in this work,viz.local water cooling and artificial cooling.The microstructure developed consecutively as a result of discontinuous dynamic recrystallization(DDRX)for the AEBed samples.{10-12}tensile twinning also played an important role for the AEB with local water cooling at the initial extrusion stage in the container.Local water cooling could further reduce the DRXed grain size to~2.1µm comparing that without water cooling.And the grain growth rate was reduced by artificial cooling out of extrusion die.Under the combination of two-stage cooling,the fine DRXed grains at sizing band were almost retained with average grain size of~2.3µm after the sheet out of extrusion die,and the unDRXed grains with high residual dislocation density accumulation were also reserved.The tensile tests results indicated that a good strength-ductility balance with a high ultimate tensile strength(319 MPa vs.412 MPa)and fracture elongation(19.9%vs.30.3%)were obtained.The strength enhancement was mainly owing to the grain refinement and local residual plastic strain reserved by the artificial cooling.The excellent ductility originated from fine DRXed microstructure and ED-tilt double peak texture.

关键词： Magnesium alloy Accumulated extrusion bonding Local water cooling Artificial cooling Microstructure Mechanical properties

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Effect of initial orientation on microstructure and mechanical properties of AZ31 Mg alloy sheets via accumulated extrusion bonding

引用

Progress in Natural Science:Materials International 2023年第2期33卷 178-184页

作者： Xia Cao Tingzhuang Han Ji Xu guangsheng huang Hua Zhang Jianhui Bai Fusheng Pan Department of Mechanics and Surface Engineering Changzhou Institute of Technology Department of Aviation Manufacturing Engineering Changzhou Institute of Technology State Key Laboratory of Solidification Processing School of Materials Science & Engineering Northwestern Polytechnical University State Key Laboratory of Mechanical Transmission College of Materials Science and Engineering Chongqing University Institute for Advanced Studies in Precision Materials Yantai University

In this study, effects of initial orientation on microstructure evolution and mechanical properties of AZ31 Mg alloy sheets via accumulated extrusion bonding(AEB) was systematically studied. The samples with RD and TD parallel to extrusion direction(ED) were labeled as RED and TED, respectively. RD and TD pieces alternately stacked was named as RTED. The results revealed that under three-dimensional compressive stress, {10-12} tensile twinning dominated the first stage deformation in container. As the plunger continuous press down, dynamic recrystallization(DRX) occurred, and the newly fine DRXed grains along original and twin grain boundaries gradually consumed the matrix and twin grains. The microstructure was completely transformed into recrystallized grain structure at sizing band with an average grain size of ～0.9 μm in TED sample, smaller than that of RED sample.After the alloys extruded out of the die, DRXed grains significantly grew to ～4.5 μm and 3.5 μm for RED and TED samples, respectively. A laminated microstructure was obtained with average grain sizes of～4.4 μm in RD layers and 3.5 μm in TD layers for RTED sample. The AEB processed samples exhibited an ED-tilt double-peak basal texture with similar texture intensity. The tensile tests results indicated that attributed to the combined effect of grain refinement and texture evolution, the yield strength and fracture elongation of RED and TED samples was significantly improved. The heterogeneous microstructure in RTED sample induced an extra work hardening(HDI-work hardening) in tensile deformation and resulted in a further improved elongation of 32.0%.

关键词： Magnesium alloy Accumulated extrusion bonding Initial orientation Microstructure Texture Mechanical properties

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Effects of Li addition on the microstructure and tensile properties of the extruded Mg-1Zn-xLi alloy

引用

International Journal of Minerals,Metallurgy and Materials 2022年第7期29卷 1380-1387页

作者： Jun Zhao Bin Jiang Qinghang Wang Ming Yuan Yanfu Chai guangsheng huang Fusheng Pan School of Mechanical and Electrical Engineering Hunan City UniversityYiyang 413002China State Key Laboratory of Mechanical Transmissions College of Materials Science and EngineeringChongqing UniversityChongqing 400044China School of Mechanical Engineering Yangzhou UniversityYangzhou 225127China School of Mechanical and Electrical Engineering Shaoxing UniversityShaoxing 312000China

Li addition is verified to be an effective method to increase the room temperature ductility and formability of Mg alloys.In the present study,the microstructure,texture,and tensile properties of the extruded Mg-1Zn-xLi(wt%,x=0,1,3,5)alloy sheets were studied by X-ray diffraction(XRD),scanning electron microscope(SEM),and electron backscatter diffraction(EBSD).It was found that Li addition resulted in the grain coarsening and the development of new transverse direction(TD)-tilting and{101^(-)0}parallel to extrusion direction textures,which was related to the improved dynamic recrystallization and the increased prismatic slip during extrusion.The Mg-1 Zn-5 Li sheet showed the weakest texture,which contained both basal and TD-tilting oriented grains.No additional phase was formed with Li addition.The yield strength of Mg-1Zn-xLi sheets gradually decreased with increasing Li content,which was mainly related to the grain coarsening and texture weakening.In addition,the ductility of the Mg-1Zn-xLi sheet was remarkably enhanced by Li addition.The elongation of the Mg-1 Zn-5 Li sheet was 30.3%along the TD,which was three times than that of Mg-1 Zn sheet.Microstructural analysis implied that this significant ductility enhancement was associated with the improvement activation of prismatic and basal slips during the tensile tests.This study may provide insights into the development of high-ductility,low-density Mg-Zn-Li based alloys.

关键词： Mg-1Zn-xLi alloy texture prismatic slip tensile properties

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Preparation, structure and properties of Mg/Al laminated metal composites fabricated by roll-bonding, a review

引用

Journal of Magnesium and Alloys 2022年第8期10卷 2062-2093页

作者： Tingting Liu Bo Song guangsheng huang Xianquan Jiang Shengfeng Guo Kaihong Zheng Fusheng Pan School of Materials and Energy Southwest UniversityChongqing400715China School of Materials Science and Engineering Chongqing UniversityChongqing400044China Institute of New Materials Guangdong Academy of ScienceGuangzhou510650China

Laminated metal composites(LMCs) are a unique composite material and have great application prospects in automobiles, ships, aircraft,and other manufacturing industries. As lightweight materials, the Mg/Al LMCs are expected to combine the advantages of both Mg and Al alloys to broaden their application prospects. Roll-bonding is the most popular process for the fabrication of Mg/Al LMCs due to high production efficiency and good product quality stability. The roll-bonding process involves the deformation of the substrates and the formation of the interfacial diffusion layer. The latter will directly determine the interface bonding strength of Mg/Al LMCs. Bonding strength is very sensitive to the thickness of the reaction layer in the diffusion layer. When the thickness of the reaction layer exceeds 5 μm, the bonding strength decreases sharply. Therefore, controlling the thickness of the reaction layer is very important for the design of rolling parameters.The latest research also showed that the addition of intermediate layer metal and the construction of three-dimensional interfaces can further improve the interface bonding strength. How to apply these methods to roll-bonding is the focus of future research. Recently, a new rolling technique, corrugated roll/plat roll rolling+flat roll/flat roll rolling has been developed to fabricate Mg/Al LMCs. It can effectively promote the deformation of the hard layer and generate a wavy interface, resulting in the enhancement of the bonding quality and rolling quality.In the current review, the effects of rolling parameters and subsequent annealing on the interface structure of Mg/Al LMCs were elaborated in detail. The application of some special rolling techniques in the preparation of Mg/Al LMCs was also summarized. The latest research results on the relationship between interface structure and mechanical properties of Mg/Al LMCs were reviewed. Finally, further research directions in this field were proposed.

关键词： Mg/Al Laminated metal composites Roll-bonding Interface Mechanical properties

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Deformation Characterization,Twinning Behavior and Mechanical Properties of Dissimilar Friction-Stir-Welded AM60/AZ31 Alloys Joint During the Three-Point Bending

引用

Acta Metallurgica Sinica(English Letters) 2022年第5期35卷 727-744页

作者： Junlei Zhang Han Liu Xiang Chen Qin Zou guangsheng huang Bin Jiang Aitao Tang Fusheng Pan College of Materials Science and Engineering Kunming University of Science and TechnologyKunming650093China State Key Laboratory of Mechanical Transmission College of Materials Science and EngineeringChongqing UniversityChongqing400044China National Engineering Research Center for Mg Alloys Chongqing UniversityChongqing400044China

The AZ31 and AM60 alloys were used for dissimilar friction stir welding(FSW)in this study.The microstructure characteristics of the joint and its three-point bending performance were investigated.The electron backscattered diffraction results showed that the grains in the nugget zone(NZ)were more uniform and refined to a certain extent after FSW,but the grain size of AM60 in the NZ was larger than that of AZ31.The texture was strong locally in the NZ and presented a symmetric distribution characteristic from the advancing side to the retreating side.There were special texture features in the joint,resulting in the occurrence of severe strain localization during the bending process compared with the base materials,which can be well explained by the calculated Schmid factor in terms of the assumed stress state for bending.The bending tests revealed that the joint presented good bending properties compared with AZ31 BM.The bending fracture morphologies suggested that the fracture tended to the NZ interface on the AZ31 side,which was mainly due to the higher SF for basal slip and dislocation concentration degree in the region,and the relatively lower bending strength of AZ31 metal.

关键词： Friction stir welding(FSW) Dissimilar joint Microstructure evolution Bending properties Deformation

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Design of pure aluminum laminates with heterostructures for extraordinary strength-ductility synergy

引用

Journal of Materials Science & Technology 2022年第5期100卷 193-205页

作者： Xiang Chen Baoxuan Zhang Qin Zou guangsheng huang Shuaishuai Liu Junlei Zhang Aitao Tang Bin Jiang Fusheng Pan State Key Laboratory of Mechanical Transmission College of Materials Science and EngineeringChongqing UniversityChongqing 400044China National Engineering Research Center for Magnesium Alloys Chongqing UniversityChongqing 400044China

Heterogeneous metals and alloys are a new class of materials with superior mechanical properties.In this paper,we engineered sandwich-structured pure aluminum laminates composed of middle coarse-grained layer and outer fine-grained layer via extrusion,rolling and annealing.By controlling the post-annealing regimes,a larger degree of microstructure heterogeneities such as boundary spacing,misorientation and texture across the hetero-interface were obtained,which resulted in obvious mechanical differences.Tensile tests indicated that the 300℃/30 min annealed laminates enabled a relatively high tensile ductility while simultaneously retaining a high strength,which was better than prediction by the rule-of-mixture.To explain the reasons behind it,the evolution of geometrically necessary dislocations and strain gradient at the hetero-interface zone were detected using in-situ tension and microscopic digital image correlation technique.It was found that with the increasing applied strain,a significant strain gradient was developed near the interface,which was accommodated by geometrically necessary dislocations,thereby contributing to higher hetero-deformation induced(HDI)strengthening and hardening.

关键词： Pure aluminum Laminates Annealing Heterostructures HDI strengthening and hardening

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Superior plating/stripping performance through constructing an artificial interphase layer on metallic Mg anode

引用

Journal of Materials Science & Technology 2023年第26期157卷 154-162页

作者： Bangpeng Yang Liuyan Xia Rong Li guangsheng huang Shuangshuang Tan Zhongting Wang Baihua Qu Jingfeng Wang Fusheng Pan College of Materials Science and Engineering Chongqing UniversityChongqing 400044China National Engineering Research Center for Magnesium Alloys College of Materials Science and EngineeringChongqing UniversityChongqing 400044China

Rechargeable magnesium batteries(RMBs)have attracted tremendous attention in energy storage ap-plications in term of high abundance,high specific capacity and remarkable safety of metallic magne-sium(Mg)anode.However,a serious passivation of Mg anode in the conventional electrolytes leads to extremely poor plating/stripping performance,further hindering its applications.Herein,we propose a convenient method to construct an artificial interphase layer on Mg anode by substitution and alloy-ing reactions between SbCl_(3) and Mg.This Sb-based artificial interphase layer containing mainly MgCl_(2) and Mg_(3) Sb_(2) endows the significantly improved interfacial kinetics and electrochemical performance of Mg anode.The overpotential of Mg plating/stripping in conventional Mg(TFSI)2/DME electrolytes is vastly reduced from over 2 V to 0.25-0.3 V.Combining experiments and calculations,we demonstrate that un-der the uniform distribution of MgCl_(2) and Mg_(3) Sb_(2),an electric field with a favorable potential gradient is formed on the anode surface,which enables swift Mg^(2+)migration.Meanwhile,this layer can inhibit the decomposition of electrolytes to protect anode.This work provides an in-depth exploration of the artificial solid-electrolyte interface(SEI)construction,and a more achievable and safe path to realize the application of metallic Mg anode in RMBs.

关键词： Rechargeable magnesium batteries Metallic Mg anode Artificial solid-electrolyte interface Interfacial modification Anode protection

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Effect of texture on deformation behavior of heterogeneous Mg-13Gd alloy with strength-ductility synergy

引用

Journal of Materials Science & Technology 2022年第18期113卷 271-286页

作者： Shuaishuai Liu Han Liu Xiang Chen guangsheng huang Qin Zou Aitao Tang Bin Jiang Yuntian Zhu Fusheng Pan State Key Laboratory of Mechanical Transmission College of Materials Science and EngineeringChongqing UniversityChongqing 400044China National Engineering Research Center for Magnesium Alloys Chongqing UniversityChongqing400044China Department of Materials Science and Engineering City University of Hong KongHong Kong999077China Nano and Heterogeneous Material Center Nanjing University of Science and TechnologyNanjing210094China

Heterostructure metals as a new class of materials can effectively break the traditional strength–ductility trade-off dilemma. In this study, the extruded sheet with the small extrusion ratio(ER) of 3.9(ER3.9)presented a heterogeneous lamella structure(HLS) and texture, where the fine dynamical recrystallized(DRXed) grains formed a random texture and coarse un-DRXed grains exhibited a strong basal texture.The ER3.9 sample presented an excellent combination of strength and ductility. The texture strengthening in coarse grains and hetero-deformation induced(HDI) strengthening contributed to the enhanced strength of the ER3.9 sample besides grain refinement. The improving ductility mainly stems from the weakened texture in fine grains. Interestingly, in coarse grains, the strong basal texture, the occurrence of cross slip, low stacking fault energy(SFE), and dislocation pinned by precipitates weaken the HDI hardening effect. While the traditional dislocation hardening mainly generated by fine grains dominates overall strain hardening. Meanwhile, the activation of non-basal slips, especially pyramidal slip,and the generation of cross slips in fine grains benefit for coordinating plastic deformation. The ability for coordinate plastic deformation in fine grains is higher than that of coarse grains, which was confirmed by the digital image correlation technology. This work will promote the development of the heterogeneous theory in textured Mg alloys.

关键词： Mg-Gd alloy Recrystallization Heterogeneous texture Mechanical properties HDI hardening

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：