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Chinese Chemical Letters 2024年第6期35卷 161-167页

作者： Ya Song Mingxia zhou Zhu Chen Huali Nie Jiao-Jing Shao guangmin zhou School of Materials and Metallurgy Guizhou UniversityGuiyang 550025China Medical College of Guizhou University Guiyang 550025China College of Biological Science and Medical Engineering Donghua UniversityShanghai 201620China Shenzhen Geim Graphene Center Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055China

The practical application of high-energy-density lithium-sulfur(Li-S)batteries have been highly praised for energy storage devices,while are largely hindered by the“shuttling effect”.Herein,core-shell carbon spheres composed of interlinked porous core and lamellar shell were designed to restrain the polysulfide *** microporous structure with pore size of around 1 nm effectively trap lithium ***,the interconnected porous core shortens the ion transfer distance and the lamellar carbon shell endows the carbon spheres with fast electron conduction,finally facilitating polysulfide conversion ***,the Li-S batteries with the carbon spheres as the interlayer show high discharge specific capacity of 1002 m Ah/g at 2 C with 574 m Ah/g remaining after 600 cycles,and high areal capacity of 5.48 m Ah/cm^(2) with sulfur loading of 4.67 mg/cm^(2) at 0.1 *** corresponding pouch cells also exhibit stable cycling stability with an initial discharge specific capacity of 1082 m Ah/g at 0.1 C.

关键词： Interlayer Shuttle effect Strong adsorption Porous carbon spheres Lithium-sulfur batteries

Two-dimensional silica enhanced solid polymer electrolyte for lithium metal batteries

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Particuology 2024年第2期85卷 146-154页

作者： Zhihong Luo Weiyong Li Chong Guo Ya Song Mingxia zhou Yan Shi Jing Xu Long Li Bin Shi Quansheng Ouyang Jiao-jing Shao guangmin zhou School of Materials and Metallurgy Guizhou UniversityGuiyang550025China State Key Laboratory of Advanced Chemical Power Sources Zunyi563003China Graphene Materials Engineering Research Center of Guizhou Colleges and Universities Guiyang550025China Tsinghua-Berkeley Shenzhen Institute&Tsinghua Shenzhen International Graduate Schoo Tsinghua UniversityShenzhen518055China

Solid polymer electrolytes(SPEs)are promising substitutes for current flammable liquid electrolytes to achieve high-safety and high-energy-density lithium metal *** oxide(PEO)based solid polymer electrolytes have attracted increasing attention because of their excellent flexibility,manufacturability,light weight,and low-cost processing,while they often suffer from low ionic con-ductivity at room temperature,low lithium transference number and unsatisfactory interfacial resis-tance,which largely restrain their practical ***,two-dimensional holey silica nanosheets(2D-HSN)as the fillers,together with LiNO_(3) as the electrolyte additive,are introduced in a PEO/poly(-vinylidene fiuoride-co-hexafluoropropylene)(PVDF-HFP)blended polymer matrix to obtain a *** incorporation of HSN filler creates supplementary channels for lithium ion migration and lowers the crystallinity of the polymer,thereby facilitating the movement of lithium *** HSN-based SPE demonstrates higher ionic conductivity up to 3.7 x 10-4 S cm-1 at 30℃,larger Li+transference number close to 0.34,and more stable lithium plating/stripping than that without the fillers,and HSN can promote the formation of more stable solid electrolyte interphase(SEI)*** as-assembled LiFePO4||Li batteries deliver a high specific capacity of 159 mA h g-1 with the capacity retention of 95.5%after 200 cycles at 30℃,as well as superior rate performance and cycling stability compared to that using the blank SPE.

关键词： Vermiculite nanosheets Two-dimensional silica Solid polymer electrolytes FillersLithium metal batteries

Recent development in electrode design for wide-temperature supercapacitors

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Science China Chemistry 2024年

作者： Jianhong Liu Qiang zhou Yuxiao Lin Xinsheng Zhao guangmin zhou Xiaoxiao Li School of Physics and Electronic Engineering Jiangsu Normal University Tsinghua-Berkeley Shenzhen Institute & Tsinghua Shenzhen International Graduate School Tsinghua University

An ever-increasing market demand has stimulated the soaring enthusiasm of researchers to develop wide-temperature supercapacitors (SCs). The active electrode is one of the most important parts of SC, which is directly related to the energy density,power transmission and long-term cyclability of the device in the wide-temperature environment. Compared with the SC electrodes aimed for room-temperature application, the SC electrodes for operating at wide-temperature scene often face greater challenges. In this review, the main challenges of SC electrodes under various temperature conditions, including low, high and cross-fade temperatures, are summarized. The relevant performance decay and failure mechanisms of wide-temperature SC electrodes are analyzed. In addition, this review deals with the recent studies and developments in robust wide-temperature SC electrodes with respect to the rational design of electrode structures and the exploitation of advanced active materials. Finally, the future directions for exploring reliable wide-temperature SCs are also proposed.

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雷火灸联合人工泪液治疗泪液生成不足型干眼症的临床效果观察

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中国社区医师 2024年第8期40卷 82-84页

作者：白秋爽周广敏西安市中医医院眼科陕西西安710021

目的:分析雷火灸联合人工泪液治疗泪液生成不足型干眼症的临床效果。方法:选取2023年1—12月西安市中医医院眼科收治的106例泪液生成不足型干眼症患者作为研究对象,按照随机数字表法分为试验组和对照组,各53例。对照组实施人工泪液治疗... 详细信息

目的:分析雷火灸联合人工泪液治疗泪液生成不足型干眼症的临床效果。方法:选取2023年1—12月西安市中医医院眼科收治的106例泪液生成不足型干眼症患者作为研究对象,按照随机数字表法分为试验组和对照组,各53例。对照组实施人工泪液治疗,试验组在对照组基础上给予雷火灸治疗。比较两组泪液分泌试验、泪膜破裂时间(BUT)、角膜荧光素染色(FL)评分结果及临床疗效。结果:治疗前,两组滤纸润湿长度、BUT、FL评分比较,差异无统计学意义(P>0.05);治疗后,两组滤纸润湿长度、BUT长于治疗前,且试验组长于对照组,FL评分低于治疗前,且试验组低于对照组,差异有统计学意义(P<0.001)。试验组治疗有效率高于对照组,差异有统计学意义(P=0.034)。结论:雷火灸联合人工泪液可有效改善泪液生成不足型干眼症患者临床症状,增加泪液分泌量,延长泪膜破裂时间。

关键词：泪液生成不足型干眼症雷火灸人工泪液

Rationalizing the impact of oxygen vacancy on polysulfide conversion kinetics for highly efficient lithium-sulfur batteries

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Journal of Energy Chemistry 2023年第12期87卷 51-60,I0003页

作者： Ya Song Huan Li Junfeng Li Jinyu An Jiao-Jing Shao guangmin zhou School of Materials and Metallurgy Guizhou UniversityGuiyang 550025GuizhouChina School of Chemical Engineering and Advanced Materials The University of AdelaideAdelaideSA 5005Australia Shenzhen Geim Graphene Center Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055GuangdongChina College of Civil Engineering Guizhou UniversityGuiyang 550025GuizhouChina

The“shuttle effect”of lithium polysulfides(LiPSs)is a huge challenge for practical use of high-energydensity lithium-sulfur(Li-S)batteries,and one of the main reasons is the sluggish kinetics of sulfur *** oxides are able to expedite the sulfur electrochemistry,and the structural defects enhance the adsorption-conversion ability of metal oxides for ***,a significant research gap still remains regarding the relationship between the oxygen vacancy concentration and the adsorptivecatalytic performance of metal ***,we establish a correlation between oxygen vacancy concentration and adsorptive-catalytic properties by using tungsten oxide(WO_(x))as model *** is revealed that high-concentration oxygen vacancy is beneficial for enhancing the binding between tungsten oxide and LiPSs,reducing the energy barrier of Li_(2)S decomposition,and promoting polysulfide conversion ***,the Li-S batteries using the tungsten oxide with high-concentration oxygen vacancies deliver high initial discharge capacity of 1169 mA h g^(-1)at 0.2 C and 865 mA h g^(-1)at 2 C,low attenuation rate of 0.064%per cycle over 1100 cycles at 2 *** a high sulfur area loading of 5.34 mg cm^(-2),the Li-S batteries still exhibit high initial gravimetric capacity of 982 mA h g^(-1)at 0.1 C and areal capacity of 5.92 mA h cm^(-2).This work promotes the feasibility of defect engineering on metal oxides as an effective mean to enhance the practicality of Li-S batteries.

关键词： Shuttl eeffect Oxygen vacancy Interlayer Lithium-sulfur batteries

Co_(3)O_(4)/Mn_(3)O_(4) hybrid catalysts with heterointerfaces as bifunctional catalysts for Zn-air batteries

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Journal of Energy Chemistry 2022年第5期31卷 679-687页

作者： Qikai Huang Xiongwei Zhong Qi Zhang Xin Wu Miaolun Jiao Biao Chen Jinzhi Sheng guangmin zhou Shenzhen Geim Graphene Center Tsinghua-Berkeley Shenzhen Institute&Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055GuangdongChina

Zinc-air batteries(ZABs) with high energy density and safety are promising as next-generation energy storage systems, while their applications are severely hindered by the sluggish reaction kinetic of air cathodes. Developing a bifunctional catalyst with high activity and durability is an effective strategy to address the above challenges. Herein, a Co_(3)O_(4)/Mn_(3)O_(4) nanohybrid with heterointerfaces is designed as advanced cathode catalyst for ZABs. Density functional theory calculations show the heterogeneous interface between Co_(3)O_(4)/Mn_(3)O_(4) can improve the dynamics of carrier transport and thus enhancing the catalytic activity and durability. The Co_(3)O_(4)/Mn_(3)O_(4) catalyst anchored on reduced graphene oxide(rGO)exhibits high oxygen reduction reaction(ORR) activity with a half-wave potential of 0.86 V, and excellent oxygen evolution reaction(OER) activity with the potential of 1.59 V at 10 mA cm^(-2) , which are comparable to the commercial noble metal catalysts. The improved ORR/OER catalytic activity is ascribed to the synergistic effect of heterointerfaces between Co_(3)O_(4) and Mn_(3)O_(4)as well as the improved conductivity and contact area of oxygen/catalysts/electrolytes three-phase interface by r GO. Furthermore, a home-made ZAB based on Co_(3)O_(4)/Mn_(3)O_(4)/r GO shows a high open circuit voltage of 1.54 V, a large power density of 194.6 mW cm^(-2) and good long-term cycling stability of nearly 400 h at 5 mA cm^(-2) , which affords a promising bifunctional oxygen catalyst for rechargeable ZABs.

关键词： Transition metal oxide Carbon-based catalyst Heterointerfaces Bifunctional catalyst Zn-air batteries

Fast Remaining Capacity Estimation for Lithium-ion Batteries Based on Short-time Pulse Test and Gaussian Process Regression

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Energy & Environmental Materials 2023年第3期6卷 238-246页

作者： Aihua Ran Ming Cheng Shuxiao Chen Zheng Liang Zihao zhou guangmin zhou Feiyu Kang Xuan Zhang Baohua Li Guodan Wei Tsinghua-Berkeley Shenzhen Institute(TBSI) Tsinghua UniversityShenzhen 518055China Tsinghua Shenzhen International Graduate School Tsinghua UniversityShenzhen 518055China

It remains challenging to effectively estimate the remaining capacity of the secondary lithium-ion batteries that have been widely adopted for consumer electronics,energy storage,and electric ***,by integrating regular real-time current short pulse tests with data-driven Gaussian process regression algorithm,an efficient battery estimation has been successfully developed and validated for batteries with capacity ranging from 100%of the state of health(SOH)to below 50%,reaching an average accuracy as high as 95%.Interestingly,the proposed pulse test strategy for battery capacity measurement could reduce test time by more than 80%compared with regular long charge/discharge *** short-term features of the current pulse test were selected for an optimal training *** at different voltage stages and state of charge(SOC)are collected and explored to find the most suitable estimation *** particular,we explore the validity of five different machine-learning methods for estimating capacity driven by pulse features,whereas Gaussian process regression with Matern kernel performs the best,providing guidance for future *** new strategy of combining short pulse tests with machine-learning algorithms could further open window for efficiently forecasting lithium-ion battery remaining capacity.

关键词： capacity estimation data-driven method Gaussian process regression lithium-ion battery pulse tests

Direct and green repairing of degraded LiCoO2 for reuse in lithium-ion batteries

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National Science Review 2022年第8期9卷 127-137页

作者： Junxiong Wang Qi Zhang Jinzhi Sheng Zheng Liang Jun Ma Yuanmao Chen guangmin zhou Hui-Ming Cheng Shenzhen Geim Graphene Center Tsinghua-Berkeley Shenzhen Institute&Tsinghua Shenzhen International Graduate SchoolTsinghua University Frontiers Science Center for Transformative Molecules School of Chemistry and Chemical EngineeringShanghai Jiao Tong University Faculty of Materials Science and Engineering/Institute of Technology for Carbon Neutrality Shenzhen Institute of Advanced TechnologyChinese Academy of Sciences

Traditional recycling processes of LiCoO2rely on destructive decomposition, requiring high-temperature roasting or acid leaching to extract valuable Li and Co, which have significant environmental and economic concerns. Herein, a direct repairing method for degraded LiCoO2using a LiCl–CH4N2O deep eutectic solvent（DES） was established. The DES is not used to dissolve LiCoO2but directly serves as a carrier for the selective replenishment of lithium and cobalt. Replenishment of lithium restores LiCoO2at different states of charge to a capacity of 130 m Ah/g（at 0.1 C rate）, while replenishing the cobalt increases the capacity retention rate of 90% after 100 cycles, which is comparable to pristine LiCoO2. The DES is collected and reused multiple times with a high repair efficiency. This process reduces energy consumption by 37.1% and greenhouse gas emissions by 34.8% compared with the current production process of LiCoO2, demonstrating excellent environmental and economic viability.

关键词： spent cathodes lithium-ion batteries LiCoO2 direct repair deep eutectic solvent lattice distortion

A novel battery scheme:Coupling nanostructured phosphorus anodes with lithium sulfide cathodes

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Nano Research 2020年第5期13卷 1383-1388页

作者： David Sichen Wu guangmin zhou Eryang Mao Yongming Sun Bofei Liu Li Wang Jiangyan Wang Feifei Shi Yi Cui Department of Materials Science and Engineering Stanford UniversityStanfordCalifornia 94305USA Wuhan National Laboratory for Optoelectronics and School of Optical and Electronic Information Huazhong University of Science and TechnologyWuhan 430074China Institute of Nuclear and New Energy Technology Tsinghua UniversityBeijing 100084China Stanford Institute for Materials and Energy Sciences SLAC National Accelerator Laboratory2575 Sand Hill RoadMenlo ParkCalifornia 94025USA

Lithium-ion batteries are approaching their theoretical limit and can no longer keep up with the increasing demands of human ***-sulfur batteries,with a high theoretical specific energy,are promising candidates for next generation energy ***,the use of Li metal in Li-S batteries compromises both safety and performance,enabling dendrite formation and causing fast capacity *** studies have probed alternative battery systems to replace the metallic Li in Li-S system,such as a Si/Li2S couple,with limited success in ***,there is a focus on red P as a favorable anode material to host ***,we establish a novel battery scheme by utilizing a P/C nanocomposite anode and pairing it with a Li2S coated carbon nanofiber *** find that red P anode can be compatible in ether-based electrolyte systems and can be successfully coupled to a Li2S *** proof of concept full-cell displays remarkable specific capacity,rate and cycling *** expect our work will provide a useful alternative system and valuable insight in the quest for next generation energy storage devices.

关键词： lithium sulfur batteries red phosphorus lithium sulfide

A high-volumetric-capacity bismuth nanosheet/graphene electrode for potassium ion batteries

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Science China Materials 2020年第10期63卷 1920-1928页

作者： Linchao Zeng Minsu Liu Peipei Li guangmin zhou Peixin Zhang Ling Qiu Shenzhen Geim Graphene Center Tsinghua-Berkeley Shenzhen InstituteTsinghua UniversityShenzhen 518055China College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060China School of Materials Science and Engineering Hefei University of TechnologyHefei 230009China

Potassium ion batteries(PIBs)with high-volumetric energy densities are promising for next-generation low-cost energy storage *** bismuth(Bi)with a structure similar to graphite,is a promising anode material for PIBs due to its high theoretical volumetric capacity(3763 mA h cm^−3)and relatively low working potential(−2.93 V *** hydrogen electrode).However,it experiences severe capacity decay caused by a huge volume expansion of Bi when alloying with *** study reports a flexible and free-standing Bi nanosheet(BiNS)/reduced graphene oxide composite membrane with designed porosity close to the expansion ratio of BiNS after *** controlled pore structure improves the electron and ion transport during cycling,and strengthens the structural stability of the electrode during potassiation and depotassiation,leading to excellent electrochemical performance for potassium-ion *** particular,it delivers a high reversible volumetric capacity of 451 mA h cm^−3 at the current density of 0.5 A g^−1,which is much higher than the previously reported commercial graphite material.

关键词： potassium ion batteries high volumetric energy density bismuth nanosheet controlled pore structure graphite