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Effect of slag composition on kinetic behavior of deep deoxidation of 5 wt.% Si high-silicon austenitic stainless steel

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Journal of Iron and Steel Research International 2024年第8期31卷 1873-1885页

作者： guan-xiong Dou Han-jie Guo Jing Guo Xue-cheng Peng Qing-yun chen School of Metallurgical and Ecological Engineering University of Science and Technology Beijing(USTB)Beijing 100083China Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials Beijing 100083China

Based on a thermodynamic study of 5 wt.%Si high-silicon austenitic stainless steel(SS-5Si)smelting using CaF_(2)-CaO-Al_(2)0_(3)-Mg-Si0_(2) slag to obtain a low oxygen content of less than 10×10^(-4) wt.%,a kinetic mass transfer model for deep deoxidation was established through laboratory studies,and the effects of slag components and temperature on deoxidation during the slag-steel reaction process of sS-5Si were systematically *** experimental data verified the accuracy of the model *** results showed that the final oxygen content in the steel at 1873 K was mainly controlled by the oxygen content derived from the activity of SiO_(2) regulated by the[Si]-[O]equilibrium reaction in the slag system;in particular,when the slag basicity R(R=w(CaO)/w(SiO2),where w(CaO)and w(SiO_(2))are the contents of CaO and SiO_(2) in the slag,respectively)is 3,the Al2O3 content in the slag needs to be less than 2.7%.The mass transfer rate equation for the kinetics of the deoxidation reaction revealed that the mass transfer of oxygen in the liquid metal is the rate-controlling step under different slag conditions at 1873 K,and the oxygen transfer coefficient ko.m increases with increasing the slag basicity from 4.0×10^(-6)m s^(-1)(R=1)to 4.3×10^(-5) m s^(-1)(R=3).ko.m values at R=2 and R=3 are almost the same,indicating that high slag basicity has little *** integral of the mass transfer rate equation for the deoxidation reaction of SS-5Si under different slag conditions is *** total oxygen content of the molten steel decreases with increasing basicity from an initial content of 22×10^(-4) to 3.2×10^(-4) wt.%(R=3),consistent with the change in ko.m with slag *** R=2,the slag-steel reaction takes 15 min to reach equilibrium(w[O]=5.5×10^(-4) wt.%),whereas at R=3,the slag-steel reaction takes 30 min to reach equilibrium(w[0]=3.2×10^(-4) wt.%).Considering the depth of deoxidation and reaction time of SS-5Si smelting,it is recommended the slag b

关键词： Slag-steel reaction Kinetics Rate-controlling step Deep deoxidation Transfer coefficient

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Preparation and characteristic study of Schottky diodes based on Ga_(2)O_(3)thin films

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The Journal of China Universities of Posts and Telecommunications 2024年第2期31卷 28-37页

作者： Zhang Xuhui chen Haifeng Liu Xiangtai Lu Qin Wang Zhan cheng Hang Che Lujie guan Youyou Han Xiaocong School of Electronic Engineering Xi'an University of Posts and TelecommunicationsXi'an 710121China

This study uses atomic layer deposition(ALD)to grow Ga_(2)O_(3)films on SiO_(2)substrates and investigates the influence of film thickness and annealing temperature on film *** diode devices are fabricated based on the grown Ga_(2)O_(3)films,and the effects of annealing temperature,electrode size,and electrode spacing on the electrical characteristics of the devices are *** results show that as the film thickness increases,the breakdown voltage of the fabricated devices also increases.A Schottky diode with a thickness of 240 nm can achieve a reverse breakdown voltage of 300 *** film quality significantly improves as the annealing temperature of the film *** a voltage of 5 V,the current of the film annealed at 900℃is 64 times that of the film annealed at 700℃.The optimum annealing temperature for Ohmic contact electrodes is 450℃.At 550℃,the Ohmic contact metal tends to burn,and the performance of the device is *** the electrode spacing increases the forward current of the device but decreases the reverse breakdown *** the Schottky contact electrode size increases the forward current,but the change is not significant,and there is no significant change in the reverse breakdown *** device also performs well at high temperatures,with a reverse breakdown voltage of 220 V at 125℃.

关键词： atomic layer deposition(ALD) Ga_(2)O_(3)film Schottky diode annealing temperature

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Photothermal catalysts for efficient and clean fuel production at atmospheric pressure

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Science China Chemistry 2024年第6期67卷 1762-1764页

作者： Xinwei guan Yang chen Tianyi Ma School of Science RMIT UniversityMelbourneVIC3000Australia Institute of Clean Energy Chemistry Key Laboratory for Green Synthesis and Preparative Chemistry of Advanced Materials of Liaoning ProvinceCollege of ChemistryLiaoning UniversityShenyang110036China

The use of waste carbon resources to produce valuable chemicals and hydrocarbon fuels has attracted great interest in recent *** a transformation not only maximises the utilisation of carbon resources but also plays a... 详细信息

关键词： thermal transformation clean

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The evolutionary trajectory of the rural settlements in Southern Jiangsu in the past 20 years:From the perspective of urbanization and land use

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Journal of Geographical Sciences 2024年第8期34卷 1615-1635页

作者： chen Feiyu chen cheng Key Laboratory of Watershed Geographic Sciences Nanjing Institute of Geography and LimnologyCASNanjing 210008China Nanjing College University of Chinese Academy of SciencesNanjing 211135China

For a long time,due to lack of accurate data covering large areas,it is difficult to capture the continuous spatial evolutionary trajectory of rural settlements shaped by rapid urbanization and rural land use *** fill this gap,based on theoretical analysis this paper systemically detected the changing characteristics of scale,spatial morphology,distribution,and land use pattern of rural settlements in Southern Jiangsu in the past 20 years depending on the data of land resource survey in 2009 and *** study suggests that the total area and per capita size of rural settlements declined by 30%and 2%respectively as a result of rural land consolidation and the influx of enormous immigrants from underdeveloped *** spatial density and average shape index dropped by 14%and 44%respectively in the recent decade,indicating an evident trend of decentralization in spatial distribution,and regularization in the spatial ***,residential land within rural settlements decreased by 33%over the past decade while the land for industry and commercial service steadily increased,demonstrating that the function for manufacturing and diversified services had been *** the emerging issue of the aging population and new business opportunities in rural Southern Jiangsu,rural settlements regeneration might be the focus offutureresearch.

关键词： rural settlements spatial morphology land use Southern Jiangsu

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Equalizer Zero-Determinant Strategy in Discounted Repeated Stackelberg Asymmetric Game

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Journal of Systems Science & Complexity 2024年第1期37卷 184-203页

作者： cheng Zhaoyang chen guanpu HONG Yiguang Key Laboratory of Systems and Control Academy of Mathematics and Systems ScienceChinese Academy of SciencesBeijing 100190China School of Mathematical Sciences University of Chinese Academy of SciencesBeijing 100049China School of Electrical Engineering and Computer Science KTH Royal Institute of Technology10044 StockholmSweden. Department of Control Science and Engineering Tongji UniversityShanghai 201804China Shanghai Research Institute for Intelligent Autonomous Systems Tongji UniversityShanghai 210201China

This paper focuses on the performance of equalizer zero-determinant(ZD)strategies in discounted repeated Stackelberg asymmetric *** the leader-follower adversarial scenario,the strong Stackelberg equilibrium(SSE)deriving from the opponents’best response(BR),is technically the optimal strategy for the ***,computing an SSE strategy may be difficult since it needs to solve a mixed-integer program and has exponential complexity in the number of *** this end,the authors propose an equalizer ZD strategy,which can unilaterally restrict the opponent’s expected *** authors first study the existence of an equalizer ZD strategy with one-to-one situations,and analyze an upper bound of its performance with the baseline SSE *** the authors turn to multi-player models,where there exists one player adopting an equalizer ZD *** authors give bounds of the weighted sum of opponents’s utilities,and compare it with the SSE ***,the authors give simulations on unmanned aerial vehicles(UAVs)and the moving target defense(MTD)to verify the effectiveness of the proposed approach.

关键词： Discounted repeated Stackelberg asymmetric game equalizer zero-determinant strategy strong Stackelberg equilibrium strategy

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Theoretical insights into thermal transport and structural stability mechanisms of triaxial compressed methane hydrate

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CHINESE PHYSICS B 2024年第9期33卷 494-504页

作者： chen, Dong-Sheng Miao, Tian-Ting Chang, cheng Guo, Xu-Yang guan, Meng-Yang Ji, Zhong-Li China Univ Petr Coll Mech & Transportat Engn Beijing Key Lab Proc Fluid Filtrat & Separat Beijing 102249 Peoples R China China Univ Petr State Key Lab Petr Resources & Prospecting Beijing 102249 Peoples R China

The heat transfer and stability of methane hydrate in reservoirs have a direct impact on the drilling and production efficiency of hydrate resources, especially in complex stress environments caused by formation subsidence. In this study, we investigated the thermal transport and structural stability of methane hydrate under triaxial compression using molecular dynamics simulations. The results suggest that the thermal conductivity of methane hydrate increases with increasing compression strain. Two phonon transport mechanisms were identified as factors enhancing thermal conductivity. At low compressive strains, a low-frequency phonon transport channel was established due to the overlap of phonon vibration peaks between methane and water molecules. At high compressive strains, the filling of larger phonon bandgaps facilitated the opening of more phonon transport channels. Additionally, we found that a strain of -0.04 is a watershed point, where methane hydrate transitions from stable to unstable. Furthermore, a strain of -0.06 marks the threshold at which the diffusion capacities of methane and water molecules are at their peaks. At a higher strain of -0.08, the increased volume compression reduces the available space, limiting the diffusion ability of water and methane molecules within the hydrate. The synergistic effect of the strong diffusion ability and high probability of collision between atoms increases the thermal conductivity of hydrates during the unstable period compared to the stable period. Our findings offer valuable theoretical insights into the thermal conductivity and stability of methane hydrates in reservoir stress environments.

关键词： methane hydrate molecular dynamics thermal transport triaxial compression structural stability 65.40.-b 64.60.-i 91.50.Hc 31.15.xv MOLECULAR-DYNAMICS

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Inferring the Effects of Protein Variants on Protein-Protein Interactions with Interpretable Transformer Representations

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Research 2024年第2期2023卷 473-489页

作者： Zhe Liu Wei Qian Wenxiang Cai Weichen Song Weidi Wang Dhruba Tara Maharjan Wenhong cheng Jue chen Han Wang Dong Xu guan Ning Lin Shanghai Mental Health Center Shanghai Jiao Tong University School of MedicineSchool of Biomedical EngineeringShanghai Jiao Tong UniversityShanghaiChina Shanghai Key Laboratory of Psychotic Disorders ShanghaiChina School of Information Science and Technology Institute of Computational BiologyNortheast Normal UniversityChangchunChina Department of Electrical Engineering and Computer Science University of MissouriColumbiaMO 65211USA Christopher S.Bond Life Sciences Center University of MissouriColumbiaMO 65211USA

Identifying pathogenetic variants and inferring their impact on protein-protein interactions sheds light on their functional consequences on *** by the availability of experimental data on the consequences of protein interaction,most existing methods focus on building models to predict changes in protein binding ***,we introduced MIPPI,an end-to-end,interpretable transformer-based deep learning model that learns features directly from sequences by leveraging the interaction data from *** was specifically trained to determine the types of variant impact(increasing,decreasing,disrupting,and no effect)on protein-protein *** demonstrate the accuracy of MIPPI and provide interpretation through the analysis of learned attention weights,which exhibit correlations with the amino acids interacting with the ***,we showed the practicality of MIPPI in prioritizing de novo mutations associated with complex neurodevelopmental disorders and the potential to determine the pathogenic and driving ***,we experimentally validated the functional impact of several variants identified in patients with such ***,MIPPI emerges as a versatile,robust,and interpretable model,capable of effectively predicting mutation impacts on protein-protein interactions and facilitating the discovery of clinically actionable variants.

关键词： consequences weights versatile

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Performance study of vertical MSM solar-blind photodetectorsbased onβ-Ga_(2)O_(3)thin film

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The Journal of China Universities of Posts and Telecommunications 2024年第2期31卷 17-27页

作者： chen Haifeng Che Lujie Lu Qin Wang Shaoqing Liu Xiangtai Liu Zhanhang guan Youyou Zhao Xu cheng Hang Han Xiaocong Zhang Xuhui School of Electronic Engineering Xi'an University of Posts and TelecommunicationsXi'an 710121China

In this work,β-Ga_(2)O_(3)thin films were grown on SiO_(2)substrate by atomic layer deposition(ALD)and annealed in N_(2)atmosphere to enhance the crystallization quality of the thin films,which were verified from X-rays diffraction(XRD).Based on the grownβ-Ga_(2)O_(3)thin films,vertical metal-semiconductor-metal(MSM)interdigital photodetectors(PDs)were fabricated and *** PDs have an ultralow dark current of 1.92 pA,ultra-high photo-to-dark current ratio(PDCR)of 1.7×10^(6),and ultra-high detectivity of 4.25×10^(14)Jones at a bias voltage of 10 V under 254 nm deep ultraviolet(DUV).Compared with the horizontal MSM PDs under the same process,the PDCR and detectivity of the fabricated vertical PDs are increased by 1000 times and 100 times,*** addition,the vertical PDs possess a high responsivity of 34.24 A/W and an external quantum efficiency of 1.67×10^(4)%,and also exhibit robustness and repeatability,which indicate excellent *** the effects of electrode size and external irradiation conditions on the performance of the vertical PDs continued to be investigated.

关键词： Ga_(2)O_(3) atomic layer deposition(ALD) annealing vertical metal-semiconductor-metal(MSM)interdigital photodetectors

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Safety and effectiveness of butorphanol in epidural labor analgesia:A protocol for a systematic review and meta-analysis

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World Journal of Clinical Cases 2024年第8期12卷 1416-1421页

作者： guan-cheng Tang Man He Zhen-Zhao Huang Yan cheng Department of Anesthesiology Yongkang Hospital of Traditional Chinese MedicineJinhua 321301Zhejiang ProvinceChina Department of Gynecology and Obstetrics Yongkang Hospital of Traditional Chinese MedicineJinhua 321301Zhejiang ProvinceChina Department of Anesthesiology Hangzhou United Liger Sixth Medical Beauty HospitalHangzhou 311215Zhejiang ProvinceChina Department of Ultrasound Hangzhou Women’s HospitalHangzhou 310008Zhejiang ProvinceChina

BACKGROUND Epidural analgesia is the most effective analgesic method during *** administered epidurally has been shown to be a successful analgesic method during ***,no comprehensive study has examined the safety and efficacy of using butorphanol as an epidural analgesic during *** To assess butorphanol's safety and efficacy for epidural labor *** The PubMed,Cochrane Library,EMBASE,Web of Science,China National Knowledge Infrastructure,and Google Scholar databases will be searched from *** types of literature,such as conference abstracts and references to pertinent reviews,will also be *** will include randomized controlled trials comparing butorphanol with other opioids combined with local anesthetics for epidural analgesia during *** will be no language *** primary outcomes will include the visual analog scale score for the first stage of labor,fetal effects,and Apgar *** independent reviewers will evaluate the full texts,extract data,and assess the risk of *** bias will be evaluated using Egger's or Begg's tests as well as visual analysis of a funnel plot,and heterogeneity will be evaluated using the Cochran Q test,P values,and I2 ***-analysis,subgroup analysis,and sensitivity analysis will be performed using RevMan software version *** protocol was developed in accordance with the Preferred Reporting Items for Systematic Reviews and Meta-Analyses(PRISMA)Protocols statement,and the PRISMA statement will be used for the systematic *** This study provides reliable information regarding the safety and efficacy of using butorphanol as an epidural analgesic during *** To support clinical practice and development,this study provides evidence-based findings regarding the safety and efficacy of using butorphanol as an epidural analgesic during labor.

关键词： Epidural analgesia during labor Butorphanol Safety Protocol Meta-analysis

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A refined representation method of the particle size distribution curve based on grading entropy

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Particuology 2024年第5期88卷 302-311页

作者： Xing Li Qun chen Zhaozhao Liu cheng Zhou chen Wang chen chen State Key Laboratory of Hydraulics and Mountain River Engineering College of Water Resource and HydropowerSichuan UniversityChengdu610065China

The particle size distribution(PSD)curve is an important expression of the basic properties of the *** characteristic parameters such as median particle size D_(50),effective particle size D_(10),and some combinations of characteristic parameters can only represent some points of the PSD curve,failing to represent all information of the PSD *** this paper,a fraction characteristic parameter F that could reflect the fraction size variation of the PSD curve was introduced based on grading *** a new presentation method of the A-B-F three parameters was proposed for a refined representation of the PSD *** was found that the newly constructed model not only better represents the differences in the width of PSD curves but also has a higher sensitivity than the A-B two-parameter model proposed by Lő*** PSD curves with similar distributions,the new presentation method has a higher degree of discrimination than that of the D_(50)-C_(u)-C_(c) three-parameter or the four-parameter combination G_(c) proposed by ***,the application of this new method in describing the spatial nonuniformity distribution of depositions and predicting the soil hydraulic conductivity was *** research results can provide a reference for the refined representation of PSD curves.

关键词： Grading entropy Particle size distribution curve Refined representation

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