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Enhancing insights into Global Cancer Statistics 2022: implications for cancer control

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Science China Life Sciences 2025年第1期 294-296页

作者： Jingtong Xu Runtian Wang Xiaoxiang guan Department of Oncology the First Affiliated Hospital of Nanjing Medical University Jiangsu Key Lab of Cancer Biomarkers Prevention and TreatmentCollaborative Innovation Center for Personalized Cancer MedicineNanjing Medical University

Globally, there has been a marked escalation in tumor morbidity and mortality,cementing tumors as the predominant cause of death in numerous *** the current tumor burden across various regions is imperative to discern potential risk factors and formulate efficacious strategies for tumor ***, the International Agency for Research on Cancer(IARC) provided a status report on the global tumor burden,estimating the incidence and mortality of 36 cancers in 185 countries(Bray et al.,2024).

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Mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

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Journal of Energy Chemistry 2025年第1期100卷 327-336页

作者： Mingdong Sun Wenwen guan Cailing Chen Chao Wu Xiaoling Liu Biao Meng Tao Chen Yu Han Jun Wang Shibo Xi Yu Zhou State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced Membranes and Porous Materials Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of Sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of Materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge X-ray absorption near-edge structure （XANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Single atom catalyst Synergy effect Carbon catalyst Electrocatalysis

Dielectric-ion-conductive ZnNb2O6 layer enabling rapid desolvation and diffusion for dendrite-free Zn metal batteries

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Journal of Energy Chemistry 2025年第1期100卷 693-701页

作者： Haifeng Yang Jian Wang Panpan Zhang Xiaomin Cheng Qinghua guan Jing Dong Bixian Chen Lujie Jia Jing Zhang Yongzheng Zhang Yunjian Liu Hongzhen Lin School of Materials Science and Engineering Jiangsu University i-Lab & CAS Key Laboratory of Nanophotonic Materials and Devices Suzhou Institute of Nano-Tech and Nano-Bionics Chinese Academy of Sciences Helmholtz Institute Ulm (HIU) Karlsruhe Institute of Technology (KIT) School of Materials Science and Engineering Xi'an University of Technology State Key Laboratory of Chemical Engineering East China University of Science and Technology

Rechargeable aqueous zinc-metal batteries （AZMBs） are promising candidates for large-scale energy storage systems due to their low cost and high ***,their performance and sustainability are significantly hindered by the sluggish desolvation kinetics at the electrode/electrolyte interface and the corresponding hydrogen evolution reaction where active water molecules tightly participate in the Zn（H2O）62+solvation ***,learnt from self-generated solid electrolyte interphase （SEI） in anodes,the dielectric but ion-conductive zinc niobate nanoparticles artificial layer is constructed on metallic Zn surface （ZNB@Zn）,acting as a rapid desolvation *** zincophilic and dielectric-conductive properties of ZNB layer accelerate interfacial desolvation/diffusion and suppress surface corrosion or dendrite formation,achieving uniform Zn plating/stripping behavior,as confirmed by electronic/optical microscopies and interface spectroscopical measurements together with theoretical ***,the as-prepared ZNB@Zn electrode exhibits excellent cycling stability of over 2000 h and robust reversibility （99.54%） even under high current density and depth of discharge ***,the assembled ZNB@Zn-based full cell displays high capacity-retention rate of 80.21%after 3000 cycles at 5 A g-1and outstanding rate performance up to 10 A *** large-areal pouch cell is stabilized for hundreds of cycles,highlighting the bright prospects of the dielectric but ion-conductive layer in further application of AZMBs.

关键词： Zn metal battery Dielectric artificial layer Rapid ion diffusion Zincophilic diffusion Active water inhibition

Neutron activation analysis and Mdssbauer spectroscopy research on coloring mechanism of ancient Chinese guan porcelain

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Chinese Science Bulletin 2000年第20期45卷 1840-1844页

作者： ZHAO Weijuan, LI Guoxia, GAO Zhengyao, ZHANG bin, LI Rongwu, WU Xiaoli, YAO Guifang, JIA Xiuqin, HAN Song & HUANG Zhongxiang1. Department of Physics, Zhengzhou University, Zhengzhou 450052, China 2. Department of Architecture, Zhengzhou Technology University, Zhengzhou 450002, China 3. Department of Physics, Beijing Normal University, Beijing 100875, China 4. Hangzhou Museum of guan kiln, Hangzhou 310008, China 5. Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100080, China

The content of 30 kinds of coloring elements in guan porcelain in the Southern Song Dynasty has been determined by neutron activation analysis (NAA). Iron is the major coloring element. Mossbauer spectroscopy has shown that the iron of the glaze exists in the form of structural iron (Fe2+, Fe3+). The quantitative relationship between the main wavelength of every color glaze and the relative content (Fe2+/Fe3+) of structural iron has been determined. Thus the coloring mechanism of guan porcelain in the Southern Song Dynasty has been revealed entirely.

关键词： coloring mechanism of guan porcelain in Southern Song Dynasty characteristic spectrum NAA Mossbauer spectroscopy.

Geochemistry and origin of tektites from Guilin of guangxi,guangdong and Hainan

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Science China Earth Sciences 2011年第3期54卷 349-358页

作者： LIN Su guan YunBin HSU WeiBiao Purple Mountain Observatory Chinese Academy of Sciences Nanjing 210008 China Graduate School of Chinese Academy of Sciences Beijing 100049 China Division of Geological and Planetary Sciences California Institute of Technology Pasadena CA 91125 USA State Key Laboratory of Geological Processes and Mineral Resources and Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China

Six tektites from Guilin of guangxi, Hainan, and guangdong were analyzed for the abundances of major elements and 27 trace elements. All samples are splash-form tektites and have SiO2 contents ranging from 73.1wt% to 76.0wt% (74.6wt% on average). The chemical compositions, except Cr and Ni, of tektites from different areas, are similar. guangdong tektite shows enrichments of Ni and Cr contents by a factor of 3, and has slightly higher MgO and FeO than Hainan and Guilin tektites. It indicates that the tektites were formed by mixing several target rocks. The major and trace element concentrations of southern China tektites closely resemble previously reported data for average splash-form and Muong Nong-type indochinites, indicating that they have the same source. (La/Lu)CI (7.99), Zr/Hf (35.45 on average), Ba/Rb (3.59 on average), and the rare earth element (REE) contents of tektites are similar to those of typical post Archean upper crustal rocks. This study suggests that the best fit for the target source of southern China tektites could be a combination of 41% shale, 2% sandstone, 20% greywacke, and 37% quartzite.

关键词： tektites southern China Australasian source rock Post-Archean sedimentary rock

Heavy metal concentrations in plants and soils at roadside locations and parks of urban guangzhou

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Journal of Environmental Sciences 2006年第3期18卷 495-502页

作者： guan Dong-sheng M. R. Peart Department of Environmental Science Sun Yatsen University Guangzhou 510275 China Department of Geography University of Hong KongHong Kong China

Levels ofCu, Ni, Zn, Pb and Cr were measured in soils and trees in urban guangzhou, China. Tree and soil samples were collected from the roadside, urban parks and a university campus. Mean concentrations of Cu, Ni, Zn, Pb and Cr in tree leaves were 28.3, 7.7, 142.1, 23.4, and 195.1 mg/kg respectively. In a comparison of heavy metal concentrations in tree leaves between roads and park locations, only Pb concentrations were significantly higher in the former. Heavy metal concentrations were lower in the roots compared to leaves. It indicated that heavy metal pollution of trees is mainly from air pollution, For all top soil samples the mean concentrations of Cu, Ni, Zn, Pb and Cr were 24.3, 17.3, 121.5, 63.9 and 88.7 mg/kg, respectively. Heavy metal concentrations in roadside soils were higher and their coefficient of variation was higher than those in urban parks. Comparing heavy metal concentrations in trees and soil between urban guangzhou and Hainan Island, China, Cu, Ni, Zn, Pb and Cr levels in soils and plants in urban guangzhou were evidently affected by the human impact. However the heavy metal content in the soil compared to some international standards do not give cause for concern. Some observations on the implications of the data for environmental monitoring are made.

关键词： heavy metals roadside parks plants soil

Decreased levels of phosphorylated synuclein in plasma are correlated with poststroke cognitive impairment

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Neural Regeneration Research 2025年第9期20卷 2598-2610页

作者： Yi Wang Yuning Li Yakun Gu Wei Ma Yuying guan Mengyuan Guo Qianqian Shao Xunming Ji Jia Liu Department of Clinical Laboratory Beijing Bo’ai HospitalChina Rehabilitation Research CenterCapital Medical UniversityBeijingChina Beijing Institute of Brain Disorders Laboratory of Brain DisordersMinistry of Science and TechnologyCollaborative Innovation Center for Brain DisordersBeijing Advanced Innovation Center for Big Data-based Precision MedicineCapital Medical UniversityBeijingChina Department of Neurosurgery Xuanwu HospitalCapital Medical UniversityBeijingChina

Poststro ke cognitive impairment is a major secondary effect of ischemic stroke in many patients;however,few options are available for the early diagnosis and treatment of this *** aims of this study were to(1)determine the specific relationship between hypoxic andα-synuclein during the occur of poststroke cognitive impairment and(2)assess whether the serum phosphorylatedα-synuclein level can be used as a biomarker for poststro ke cognitive *** found that the phosphorylatedα-synuclein level was significantly increased and showed pathological aggregation around the cerebral infa rct area in a mouse model of ischemic *** addition,neuronalα-synuclein phosphorylation and aggregation were observed in the brain tissue of mice subjected to chronic hypoxia,suggesting that hypoxia is the underlying cause ofα-synuclein-mediated pathology in the brains of mice with ischemic *** phosphorylatedα-synuclein levels in patients with ischemic stroke were significantly lower than those in healt hy subjects,and were positively correlated with cognition levels in patients with ischemic ***,a decrease in serum high-density lipoprotein levels in stroke patie nts was significantly correlated with a decrease in phosphorylatedα-synuclein *** ischemic stroke mice did not show significant cognitive impairment or disrupted lipid metabolism 14 days after injury,some of them exhibited decreased cognitive function and reduced phosphorylatedα-synuclein *** together,our results suggest that serum phosphorylatedα-synuclein is a potential biomarker for poststroke cognitive impairment.

关键词： biomarker high-density lipoprotein ischemic stroke phosphorylatedα-synuclein poststroke cognitive impairment

Changing Concepts of City and Urban Planning Practices in guangzhou(1949–2010): An Approach to Sustainable Urban Development

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Chinese Geographical Science 2014年第5期24卷 607-619页

作者： XUE Desheng HUANG Gengzhi guan Jingwen LIN Jiarong School of Geography and Planning Sun Yat-sen University

By focusing on guangzhou, this paper examines how different concepts of city in terms of urban-rural relationships are shaped in transforming China since 1949, and explores how they influence the way in which urban planning are practiced. In the pre-reform era, the city was defined as a productive space under the system of urban-rural segregation established for securing rapid industrialization. Urban planning was thus only concerned with the development of urban areas. In the 1980 s and 1990 s after the reform, institutional change and economic transformation mobilized the urban-rural linkages. The development of suburban areas was then considered by urban planning, but this consideration was a passive response to urban problems such as population explosion and water resources protection. Since the new millennium, the agenda for sustainable development and problems of uneven urban-rural development have called for the development of urban-rural integration. In this context, the city is conceptualized as a complex of mountain, city, river, farmland and sea, reconstructing the ideology of urban-rural division in defining urban development. Urban planning has therefore sought in an active way to develop a sustainable city embracing rural and natural elements, and to balance economic growth and environmental protection. It is argued that developing the concept of city as a complex of urban and rural elements contributes to the urban planning for sustainable urban development, while this conceptualization relies on the recognition of the integrated urban-rural relationship.

关键词： urban-rural relationship concept of city urban planning sustainable urban development guangzhou

Endoplasmic reticulum stress and autophagy in cerebral ischemia/reperfusion injury:PERK as a potential target for intervention

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Neural Regeneration Research 2025年第5期20卷 1455-1466页

作者： Ju Zheng Yixin Li Ting Zhang Yanlin Fu Peiyan Long Xiao Gao Zhengwei Wang Zhizhong guan Xiaolan Qi Wei Hong Yan Xiao Key Laboratory of Endemic and Ethnic Diseases Ministry of Education&Key Laboratory of Medical Molecular Biology of Guizhou ProvinceGuizhou Medical UniversityGuiyangGuizhou ProvinceChina Guizhou Center for Disease Control and Prevention GuiyangGuizhou ProvinceChina Department of Histology and Embryology Guizhou Medical UniversityGuiyangGuizhou ProvinceChina Collaborative Innovation Center for Prevention and Control of Endemic and Ethnic Regional Diseases Co-constructed by the Province and Ministry GuiyangGuizhou ProvinceChina

Several studies have shown that activation of unfolded protein response and endoplasmic reticulum(ER)stress plays a crucial role in severe cerebral ischemia/reperfusion *** occurs within hours after cerebral ischemia,but the relationship between ER stress and autophagy remains *** this study,we established experimental models using oxygen-glucose deprivation/reoxygenation in PC12 cells and primary neurons to simulate cerebral ischemia/reperfusion *** found that prolongation of oxygen-glucose deprivation activated the ER stress pathway protein kinase-like endoplasmic reticulum kinase(PERK)/eukaryotic translation initiation factor 2 subunit alpha(e IF2α)-activating transcription factor 4(ATF4)-C/EBP homologous protein(CHOP),increased neuronal apoptosis,and induced ***,inhibition of ER stress using inhibitors or by si RNA knockdown of the PERK gene significantly attenuated excessive autophagy and neuronal apoptosis,indicating an interaction between autophagy and ER stress and suggesting PERK as an essential target for regulating *** autophagy with chloroquine exacerbated ER stress-induced apoptosis,indicating that normal levels of autophagy play a protective role in neuronal injury following cerebral ischemia/reperfusion *** from this study indicate that cerebral ischemia/reperfusion injury can trigger neuronal ER stress and promote autophagy,and suggest that PERK is a possible target for inhibiting excessive autophagy in cerebral ischemia/reperfusion injury.

关键词： apoptosis ATF4 autophagy C/EBP homologous protein cerebral ischemia/reperfusion injury eIF2α endoplasmic reticulum stress PERK