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Selective metal leaching from technosols based on synthetic root exudate composition

Journal of Environmental Sciences 2020年第10期32卷 85-92页

作者： Hussein Jaafar Kanbar Zeinab Matar ghina abed-alhadi safa Veronique Kazpard Research and Aralysis Platform for Enuironmental Sciences(PRASE) Doctoral School of Sciences and Techrology(EDST)The Lebanese UniversityP.O.5Rafic Hariri CampusHadatLebanon Department of Chemistry UmeàUniversitySE-90187UmeàSweden Department of Earth and Life Sciences Faculty of SciencesThe Lebanese UniversityRafic Hariri CampusHadatLebanon Laboratory of Georesources Geosciences and Enuironment(1.2GE)Faculty of SciencesThe Lebanese UniversityFanarLebanon

This study focused on metal release from technosols induced by synthetic root exudate(SRE).The effect of SRE composition on metal release was studied using six *** was done by treating the technosols with SRE solutions having varying concentrations of low molecular weight organic acids (LMWOAs),namely oxalic,citric,and malic ***,the physico-chemical parameters (p H and electric conductivity),Ca,Mg,Fe,Zn,and Cu release (by atomic absorption spectroscopy,AAS),chemical changes (by Fourier transform infrared,FT-IR),and organic parameters (by fluorescence) were *** release showed to be dependent on the SRE composition and technosol *** acid selectively released Ca,Mg,Zn,and Cu from technosols in a concentration-dependent manner;oxalic acid showed a significant role in the release of Mg and *** relatively high LMWOA concentrations,particulate organo-mineral complexes ***,technosol weathering was seen by the dissolution of humic substances and ferriallophanes,which in turn caused metal ***,re-precipitation of these phases showed to re-sorb metals,thus underestimating the role of LMWOAs in metal ***,the selective metal leaching was highly dependent on the SRE composition and LMWOA concentrations on one hand,and on the mineral,organic,and organo-mineral components of the technosols on the *** understanding of such processes is crucial for proposing and implementing environmental management strategies to reduce metal leaching or for the beneficial re-usage of metals (e.g.,for agromining) from technosols.

关键词： Technosols Oxalic acid Citric acid Metals Desorption Organo-mineral complexes

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