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The component-activity interrelationship of cobalt-based bifunctional electrocatalysts for overall water splitting:Strategies and performance

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Journal of Energy Chemistry 2024年第4期91卷 453-474页

作者： Mingjie Sun Riyue ge Sean li liming Dai Yiran li bin liu Wenxian li School of Materials Science and Engineering Shanghai UniversityShanghai 200444China Institute of Textiles and Clothing The Hong Kong Polytechnic UniversityHong Kong SAR 999077China School of Materials Science and Engineering University of New South WalesSydneyNew South Wales 2052Australia UNSW Materials&Manufacturing Futures Institute UNSW SydneyNew South Wales 2052Australia School of Chemical Engineering University of New South WalesSydneyNew South Wales 2052Australia

Cobalt-based electrocatalysts take advantage of potentially harmonizable microstructure and flexible coupling effects compared to commercial noble metal-based catalytic ***,conventional water electrolysis systems based on cobalt-based monofunctional hydrogen evolution reaction(HER)or oxygen evolution reaction(OER)catalysts have certain shortcomings in terms of resource utilization and *** contrast,cobalt-based bifunctional catalysts(CBCs)have attracted much attention in recent years for overall water splitting systems because of their practicality and reduced preparation cost of *** review aims to address the latest development in CBCs for total *** main modification strategies of CBCs are systematically classified in water electrolysis to provide an overview of how to regulate their morphology and electronic ***,the catalytic performance of CBCs in total-hydrolysis is summarized according to the types of cobalt-based phosphides,sulfides and oxides,and the mechanism of strengthened electrocatalytic ability is emphasized through combining experiments and theoretical *** efforts are finally suggested to focus on exploring the dynamic conversion of reaction intermediates and building near-industrial CBCs,designing advanced CBC materials through micro-modulation,and addressing commercial applications.

关键词： Cobalt Bifunctional electrocatalysis Water splitting Modification strategies Electrocatalytic performances

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High-entropy catalysts for electrochemical water-electrolysis of hydrogen evolution and oxygen evolution reactions

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Frontiers in Energy 2024年第3期18卷 265-290页

作者： Simiao SHA Riyue ge Ying li Julie M.CAIRNEY Rongkun ZHENG Sean li bin liU Jiujun ZHANG Wenxian li School of Materials Science and Engineering Shanghai UniversityShanghai 200444China School of Chemical and Environmental Engineering Anhui Polytechnic UniversityWuhu 241000China Australian Centre for Microscopy and Microanalysis School of AerospaceMechanical and Mechatronic EngineeringThe University of SydneySydney NSW 2006Australia School of Physics The University of SydneySydney NSW 2006Australia School of Materials Science and Engineering UNSW Materials&Manufacturing Futures InstituteUniversity of New South WalesSydney NSW 2052Australia College of Materials Science and Engineering Fuzhou UniversityFuzhou 350108China

High entropy materials (HEMs) have developed rapidly in the field of electrocatalytic water-electrolysis for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) due to their unique properties. In particular, HEM catalysts are composed of many elements. Therefore, they have rich active sites and enhanced entropy stability relative to single atoms. In this paper, the preparation strategies and applications of HEM catalysts in electrochemical water-electrolysis are reviewed to explore the stabilization of HEMs and their catalytic mechanisms as well as their application in support green hydrogen production. First, the concept and four characteristics of HEMs are introduced based on entropy and composition. Then, synthetic strategies of HEM catalysts are systematically reviewed in terms of the categories of bottom-up and top-down. The application of HEMs as catalysts for electrochemical water-electrolysis in recent years is emphatically discussed, and the mechanisms of improving the performance of electrocatalysis is expounded by combining theoretical calculation technology and ex-situ/in situ characterization experiments. Finally, the application prospect of HEMs is proposed to conquer the challenges in HEM catalyst fabrications and applications.

关键词： high-entropy electrocatalysis synthetic methods water-electrolysis hydrogen and oxygen evolutions

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lithium-induced graphene layer containing li_(3)P alloy phase to achieve ultra-stable electrode interface for lithium metal anode

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Rare Metals 2024年第2期43卷 562-574页

作者： Jia-Xin Chen Guo-Qiang Zhang Xian-Ying Qin Kui lin Zi-Jin Yang ge-Meng liang Yue Xia Guo-bin Zhang Hai-Kun Wu Qiu-Chan Cai Hai lin Bao-Hua li Shenzhen Key Laboratory on Power Battery Safety Research and Shenzhen geim Graphene Center Tsinghua Shenzhen International Graduate SchoolShenzhen518055China Shenzhen Graphene Innovation Center Co. Ltd.Shenzhen518107China School of Chemical Engineering and Advanced Materials The University of AdelaideAdelaideSA5005Australia Department of Chemistry City University of Hong KongHong Kong990077China

Uncontrolled growth of lithium dendrite will lead to low Coulombic efficiency and poor cycle stability,which hinders the commercialization of lithium metal ***,a novel modified lithium anode with reduced graphene oxide conductive network containing trace lithiophilic phosphorus(P-rGO/Cu)is prepared by electrospraying technique combined with heat treatment *** rGO layer has a concave and undulating conductive structure,which can significantly improve the effective electrical contact between lithium metal and the current collector,speed up the kinetics of interfacial electron transport and reaction,and improve the resistance of the negative electrode to the internal stress caused by volume change of the lithium,which is advantageous for the stability of the SEI *** extremely small and uniformly distributed red phosphorus element avoids the volume change caused by lithiation to the maximum *** two-phase compound li_(3)P obtained by alloying P with li can directionally induce the homogeneous nucleation and dense deposition of lithium metal,address the issue of lithium dendrites and extend the cycle life of the *** obtained P-rGO/Cu exhibits excellent electrochemical performance with an average Coulombic efficiency(CE)of 98%at a current density of 1 mA·cm^(−2) for 400 cycles,and the capacity retention rate of the full cell matched with lithium iron phosphate(LFP)is 83%after 400 cycles at 1C.

关键词： lithium anode Dendrite-free lithiophilicity Induced nucleation deposition

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Effect of V on high-temperature mechanical properties of Al-5Cu-1.5Ni alloy

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Journal of Iron and Steel Research(International) 2024年第7期31卷 1792-1810页

作者： Jun-ge Cui Yong-bin Chen Xiang-zhou Fu Hai-long Yang Han-zhang Wang An-min li li-wen Pan School of Resources Environment and MaterialsGuangxi UniversityNanning 530004GuangxiChina State Key Laboratory of Featured Metal Materials and life-Cycle Safety for Composite Structures Nanning 530004GuangxiChina Guangxi Higher Education Key Laboratory of Advanced Materials Nanning 530004GuangxiChina

The effects of V on microstructure,room temperature,and high-temperature(350℃)mechanical properties of Al-5Cu-1.5Ni alloy were *** results show that Al-5Cu-1.5Ni-xV alloys mainly compriseα-Al,Al_(2)Cu,Al_(3)(Ni,Cu)_(2),Al_(3)Ni,Al7Cu4Ni,and Al_(10)V *** addition of V can signally refineα-Al dendritic structure,which improves the mechanical properties of the as-cast alloys at room and high *** T6 heat treatment(540℃/12 h/WC+170℃/8 h/AC),α-Al,network skeleton structure Al_(3)(Ni,Cu)_(2),and Al_(10)V phases all show coarsening,while the fine nano-θ'-Al_(2)Cu precipitated from the matrix and dispersed *** introduction of V promotes the quantity of precipitatedθ'-Al_(2)Cu *** ultimate tensile strength of the heat-treated alloys at room and high temperatures is greatly improved compared to that of the as-cast *** highest high-temperature ultimate tensile strength of the alloys with V is 111.8 MPa,21.5%higher than that of the base *** analysis shows that the improvement of high-temperature mechanical properties after heat treatment is mainly due to the introduction of V,increasing the precipitated quantity of nano-θ'-Al_(2)Cu particles and improving its thermal *** dispersion strengthening effect ofθ'-Al_(2)Cu particles exceeds the weakening effect of other adverse microstructures on the mechanical properties.

关键词： Al-Cu-Ni-V alloy θ'-Al_(2)Cu phase Heat treatment Microstructure Mechanical property

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Flocking Effects of the Stochastic Cucker-Smale System with Noise

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Journal of Systems Science & Complexity 2024年第5期37卷 1978-1994页

作者： HAN Ning ge bin li lin School of Mathematical Sciences Harbin Engineering University

In this paper, the flocking behavior of a Cucker-Smale model with a leader and noise is studied in a finite time. The authors present a Cucker-Smale system with two nonlinear controls for a complex network with stochastic synchronization in probability. Based on the finite-time stability theory of stochastic differential equations, the sufficient conditions for the flocking of stochastic systems in a finite time are obtained by using the Lyapunov function method. Finally, the numerical simulation of the particle system is carried out for the leader and noise, and the correctness of the results is verified.

关键词： Cucker-Smale model flocking behavior leader noise

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Adaptive and augmented active anomaly detection on dynamic network traffic streams

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Frontiers of Information Technology & Electronic Engineering 2024年第3期25卷 446-460页

作者： bin li Yijie WANG li CHENG National Key Laboratory of Parallel and Distributed Computing College of ComputerNational University of Defense TechnologyChangsha 410073China College of System Engineering National University of Defense TechnologyChangsha 410073China

Active anomaly detection queries labels of sampled instances and uses them to incrementally update the detection model,and has been widely adopted in detecting network ***,existing methods cannot achieve desirable performance on dynamic network traffic streams because(1)their query strategies cannot sample informative instances to make the detection model adapt to the evolving stream and(2)their model updating relies on limited query instances only and fails to leverage the enormous unlabeled instances on *** address these issues,we propose an active tree based model,adaptive and augmented active prior-knowledge forest(A3PF),for anomaly detection on network trafic streams.A prior-knowledge forest is constructed using prior knowledge of network attacks to find feature subspaces that better distinguish network anomalies from normal *** one hand,to make the model adapt to the evolving stream,a novel adaptive query strategy is designed to sample informative instances from two aspects:the changes in dynamic data distribution and the uncertainty of *** the other hand,based on the similarity of instances in the neighborhood,we devise an augmented update method to generate pseudo labels for the unlabeled neighbors of query instances,which enables usage of the enormous unlabeled instances during model *** experiments on two benchmarks,CIC-IDS2017 and UNSW-NB15,demonstrate that A3PF achieves significant improvements over previous active methods in terms of the area under the receiver operating characteristic curve(AUC-ROC)(20.9%and 21.5%)and the area under the precision-recall curve(AUC-PR)(44.6%and 64.1%).

关键词： Active anomaly detection Network traffic streams Pseudo labels Prior knowledge of network attacks

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MULTIRATE TIME ITERATIVE SCHEME WITH MULTIPHYSICS FINITE ELEMENT METHOD FOR A NONliNEAR POROELASTICITY

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Journal of Computational Mathematics 2024年第2期42卷 597-616页

作者： Zhihao ge Hairun li Tingting li School of Mathematics and Statistics Henan UniversityKaifengHenan 475004China

In this paper,a multirate time iterative scheme with multiphysics finite element method is proposed and analyzed for the nonlinear poroelasticity *** original problem is reformulated into a generalized nonlinear Stokes problem coupled with a diffusion problem of a pseudo pressure field by a new multiphysics approach.A multiphysics finite element method is adopted for the spatial discretization,and the generalized nonlinear Stokes problem is solved in a coarse time step and the diffusion problem is solved in a finer time *** proposed algorithm is a decoupled algorithm,which is easily implemented in computation and reduces greatly computation *** stability analysis and the convergence analysis for the multirate iterative scheme with multiphysics finite element method are *** numerical tests are shown to demonstrate and validate the analysis results.

关键词： Nonlinear poroelasticity model Multiphysics finite element method Multirate iterative scheme

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An Electrochemical Perspective of Aqueous Zinc Metal Anode

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Nano-Micro Letters 2024年第1期16卷 274-312页

作者： Huibo Yan Songmei li Jinyan Zhong bin li School of Materials Science and Engineering Beihang UniversityBeijing 100191People’s Republic of China

Based on the attributes of nonflammability,environmental benignity,and cost-effectiveness of aqueous electrolytes,as well as the favorable compatibility of zinc metal with them,aqueous zinc ions batteries(AZIBs)become the leading energy storage candidate to meet the requirements of safety and low ***,aqueous electrolytes,acting as a double-edged sword,also play a negative role by directly or indirectly causing various parasitic reactions at the zinc anode *** reactions include hydrogen evolution reaction,passivation,and dendrites,resulting in poor Coulombic efficiency and short lifespan of AZIBs.A comprehensive review of aqueous electrolytes chemistry,zinc chemistry,mechanism and chemistry of parasitic reactions,and their relationship is ***,the understanding of strategies for suppressing parasitic reactions from an electrochemical perspective is not profound *** this review,firstly,the chemistry of electrolytes,zinc anodes,and parasitic reactions and their relationship in AZIBs are deeply ***,the strategies for suppressing parasitic reactions from the perspective of enhancing the inherent thermodynamic stability of electrolytes and anodes,and lowering the dynamics of parasitic reactions at Zn/electrolyte interfaces are ***,the perspectives on the future development direction of aqueous electrolytes,zinc anodes,and Zn/electrolyte interfaces are presented.

关键词： Aqueous zinc ions batteries Parasitic reactions Aqueous electrolyte Zinc anode

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Revisiting aluminum current collector in lithium-ion batteries:Corrosion and countermeasures

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Journal of Energy Chemistry 2024年第2期89卷 610-634,I0014页

作者： Shanglin Yang Jinyan Zhong Songmei li bin li Key Laboratory of Aerospace Advanced Materials and Performance of Ministry of Education School of Materials Science&EngineeringBeihang UniversityBeijing 100191China

With the large-scale service of lithium-ion batteries(liBs),their failures have attracted significant *** the decay of active materials is the primary cause for liB failures,the degradation of auxiliary materials,such as current collector corrosion,should not be ***,it is necessary to conduct a comprehensive review in this *** this review,from the perspectives of electrochemistry and materials,we systematically summarize the corrosion behavior of aluminum cathode current collector and propose corresponding ***,the corrosion type is clarified based on the properties of passivation layers in different organic electrolyte ***,a thoroughgoing analysis is presented to examine the impact of various factors on aluminum corrosion,including lithium salts,organic solvents,water impurities,and operating ***,strategies for electrolyte and protection layer employed to suppress corrosion are discussed in *** and most importantly,we provide insights and recommendations to prevent corrosion of current collectors,facilitate the development of advanced current collectors and the implementation of next-generation high-voltage stable liBs.

关键词： lithium-ion battery Aluminum current collector Corrosion Electrochemical performance Electrolyte Protective layer

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Mortality from cerebrovascular diseases in China:Exploration of recent and future trends

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Chinese Medical Journal 2024年第5期137卷 588-595页

作者： bin Lv ge Song Feng Jing Mingyu li Hua Zhou Wanjun li Jiacai lin Shengyuan Yu Jun Wang Xiangyu Cao Chenglin Tian Department of Neurology The First Medical CenterChinese PLA General HospitalBeijing 100853China Department of Neurology the 305 Hospital of Chinese PLABeijing 100017China Department of Internal Medicine Gucheng County Hospital of Traditional Chinese MedicineHengshuiHebei 253800China Department of Neurology Tangshan Hospital of Traditional Chinese MedicineTangshanHebei 063000China Department of Neurology Hainan Hospital of Chinese PLA General HospitalSanyaHainan 572013China

Background:Cerebrovascular disease(CVD)ranks among the foremost factors responsible for mortality on a global *** mortality patterns of CVDs and temporal trends in China need to be well-illustrated and ***:We collected mortality data on patients with CVD from Chinese Center for Disease Control and Prevention’s Disease Surveillance Points(CDC-DSP)*** mortality of CVD in 2020 was described by age,sex,residence,and *** temporal trend from 2013 to 2019 was evaluated using joinpoint regression,and estimated rates of decline were extrapolated until 2030 using time series ***:In 2019,the age-standardized mortality in China(ASMRC)per 100,000 individuals was *** ASMRC for males(137.7/10^(5))and rural areas(123.0/10^(5))were both higher when stratified by gender and urban/rural *** central region had the highest mortality(126.5/10^(5)),the western region had a slightly lower mortality(123.5/10^(5)),and the eastern region had the lowest mortality(97.3/10^(5)).The age-specific mortality showed an accelerated upward trend from aged 55-59 years,with maximum mortality observed in individuals over 85 years of *** age-standardized mortality of CVD decreased by 2.43%(95%confidence interval,1.02-3.81%)annually from 2013 to ***,the age-specific mortality of CVD increased from 2013 to 2019 for the age group of over 85 *** 2020,both the absolute number of CVD cases and the crude mortality of CVD have increased compared to their values in *** estimated total deaths due to CVD were estimated to reach 2.3 million in 2025 and 2.4 million in ***:The heightened focus on the burden of CVD among males,rural areas,the central and western of China,and individuals aged 75 years and above has emerged as a pivotal determinant in further decreasing mortalities,consequently presenting novel challenges to strategies for disease prevention and control.

关键词： Cerebrovascular diseases Mortality Epidemiology Global Burden of Disease China COVID-19 pandemic

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