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The energy-free purification of trace thallium(I)-contaminated potable water using a high-selective filter paper with multi-layered Prussian blue decoration

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Frontiers of Chemical Science and Engineering 2024年第2期18卷 1-12页

作者： Jiangyan Lu Zhu Xiong Yuhang Cheng Qingwu Long Kaige Dong Hongguo Zhang Dinggui Luo Li Yu wei Zhang gaosheng Zhang Key Laboratory for Water Quality and Conservation of the Pearl River Delta(Ministry of Education) School of Environmental Science and EngineeringGuangzhou UniversityGuangzhou 510006China College of Light Chemical Industry and Materials Engineering Shunde PolytechnicFoshan 528333China

Thallium is a highly toxic metal,and trace amount of thallium(I)(Tl+)in potable water could cause a severe water crisis,which arouses the exploitation of highly-effective technology for purification of Tl+contaminated water.This report proposes the multi-layered Prussian blue(PB)-decorated composite membranes(PBx@PDA/PEI-FP)based on the aminated filter papers for Tl+uptake.Extensively characterization by Fourier transform infrared spectrometer-attenuated total reflectance,scanning electron microscope,thermogravimetric analysis,X-ray photoelectron spectroscopy and X-ray diffraction were performed to confirm the in situ growth of cubic PB crystals on filter paper membrane surfaces via the aminated layers,and the successful fabrication of multi-layered PB overcoats via the increasing of aminated layers.The effect of PB layers on Tl+removal by PBx@PDA/PEI-FP from simulated drinking water was evaluated as well as the influence of different experimental conditions.A trade-off between PB decoration layer number and PB distribution sizes is existed in Tl+uptake by PBx@PDA/PEI-FP.The double-layered PB2@PDA/PEI-FP membrane showed the maximum sorption capacity,but its Tl+uptake performance was weakened by the acid,coexisting ions(K+and Na+)and powerful operation pressure,during filtrating a large volume of low-concentrated Tl+-containing water.However,the negative effect of coexisting ions on the Tl+uptake could be effectively eliminated in weak alkaline water,and the Tl+removal was increased up to 100%without any pressure driving for PB2@PDA/PEI-FP membrane.Most importantly,PB2@PDA/PEI-FP displayed the high-efficiency and high-selectivity in purifying the Tl+-spiked Pearl River water,in which the residual Tl+in filtrate was less than 2μg·L^(–1) to meet the drinking water standard of United States Environmental Protection Agency.This work provides a feasible avenue to safeguard the drinking water in remote and underdeveloped area via the energy-free operation.

关键词： membrane adsorption Prussian blue energy-free filtration potable water trace thallium(I)

CFD Analysis of an 800 kV HVDC Transformer Using Rapeseed Oil as the Cooling Fluid

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CSEE Journal of Power and Energy Systems 2022年第5期8卷 1508-1518页

作者： Edgardy M.Gutierrez Diaz gaosheng wei Liu Cui Key Laboratory of Power Station Energy Transfer Conversion and System(Ministry of Education) School of Energy Power and Mechanical EngineeringNorth China Electric Power UniversityBeijing 102206China Department of Power Engineering School of Electrical EngineeringBicentenary University of AraguaTurmero 2115Venezuela

This study aims to analyze rapeseed oil’s effectiveness as a coolant of a high-voltage direct current(HVDC)converter transformer while comparing it with mineral oil.We employed a numerical model,assisted by Computational Fluid Dynamics(CFD)tools,to simulate the convective heat transfer inside a HVDC converter transformer,which is an oil-directed air forced(ODAF)type.The model seeks to obtain the temperature and velocity fields at the critical points of the fluid domain.The simulation domain reproduces a 2D cross-sectional model in the center of the structure.The results show that rapeseed oil requires more time to gain heat from the core and windings due to its lower thermal conductivity.However,the average temperature of rapeseed and mineral oils will not significantly differ once the channel temperature reaches a stable value.It indicates that the rapeseed oil can effectively replace mineral oil under the same heating conditions.Also,a slower flow of the rapeseed oil allows the fluid to smoothly enter the cooling channel.Therefore,the rapeseed oil cools these channels by pushing the fluid in them and absorbs heat from the sources earlier than mineral oil.The improvement in cooling indicates that rapeseed oil is better than mineral oil as a coolant and electrical insulating fluid for power transformers.

关键词： CFD analysis cooling fluid HVDC transformer rapeseed oil

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介孔二氧化硅导热特性的分子动力学研究

工程热物理学报 2024年第2期45卷 551-557页

作者：黄超魏高升崔柳杜小泽华北电力大学电站能量传递转化与系统教育部重点实验室北京102206

介孔二氧化硅作为一种人工合成纳米孔材料,其热性能调控对于材料的推广应用十分重要。本文基于典型介孔二氧化硅SBA-15建立了双尺度复合孔道模型,并采用逆非平衡态分子动力学方法模拟研究了其内部微尺度热输运行为。研究结果表明当体系... 详细信息

介孔二氧化硅作为一种人工合成纳米孔材料,其热性能调控对于材料的推广应用十分重要。本文基于典型介孔二氧化硅SBA-15建立了双尺度复合孔道模型,并采用逆非平衡态分子动力学方法模拟研究了其内部微尺度热输运行为。研究结果表明当体系长度大于12.84 nm时,无定形二氧化硅和介孔二氧化硅的尺寸效应不再明显。介孔二氧化硅的传热性能调节主要取决于孔径和孔隙率,且在相同孔隙率下,减小孔径可进一步增强材料的绝热性能。同时介孔间的微通道体系破坏了热流传输的连续性,并扩大了材料的比表面积,从而增强热载流子界面散射和热阻。此外,振动态密度分析表明介孔和微通道限制了纳米尺度的传热,降低了热载流子的平均频率,进而导致热导率降低。

关键词：介孔二氧化硅热导率逆非平衡态分子动力学微通道

Thermal Radiative Properties of Xonotlite Insulation Material

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Journal of Thermal Science 2005年第3期14卷 281-283,253页

作者： Xinxin ZHANG gaosheng wei Fan YU Department of Thermal Engineering University of Science ＆ Technology Beijing Beijing 100083 China

This paper presents experimental results of thermal radiative properties of xonotlite-type calcium silicate insulation material. Transmittance spectra were first taken using Fourier transform infrared spectrometer (FTIR) for the samples with ρ =234 kg/m3. Specific extinction coefficient spectra were then obtained by applying Beer’s law. Finally, by using the diffusion approximation, the specific Rossland mean extinction coefficients and radiative thermal conductivities were obtained for various temperatures. The results show that the specific spectral extinction coefficient of xonotlite is larger than 7 m2/kg in the whole measured spectra, and diffusion approximation equation is a reasonable description of radiative heat transfer in xonotlite insulation material. The specific Rossland mean extinction coefficient of xonotlite has a maximum value at 400 K and the radiative thermal conductivity is almost proportional to the cube of temperature.

关键词：热量辐射硬硅钙石绝热材料传导率

Humic acid-mediated transport of a typical soil passivation remediation product(chloropyromorphite)in saturated porous media

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Journal of Environmental Sciences 2024年第7期141卷 51-62页

作者： Xinying Li Mengjia Zhang Siyuan Li wei wei School of Environment Jiangsu Engineering Lab of Water and Soil Eco-remediationJiangsu Province Engineering Research Center of Environmental Risk Prevention and Emergency Response TechnologyNanjing Normal UniversityNanjing 210023China Jiangsu Center for Collaborative Innovation in Geographical Information Resource Development and Application Nanjing 210023China

Conversion of labile Pb species into chloropyromorphite(CPY)using phosphorus-bearing amendments was considered to be an ideal strategy in soil passivation remediation.However,the fate and transport of CPY in the soil are poorly understood.This study aims to fill the knowledge gap by evaluating the fate and transport of CPY under environmentally relevant conditions of humic acid(HA),pH,electrolyte concentration,and species through the saturated sandy medium.Results showed that bare CPY colloids are basically immobile in sandy porous media while the co-existence of HA made the transport of CPY improved by30%-93.5%.Facilitated transport of CPY was attributed to the increased stability of CPY and the repulsive interaction between CPY particles and sands due to HA adsorption.The mobility of CPY was also increased with increasing pH from 5.0 to 9.0.When the pH was 9 with a10 mmol/L NaCl background solution,the stronger energy barrier between CPY and sand led to enhanced transport behavior.The divalent Ca^(2+)had a more dramatic effect than monovalent Na^(+)on the aggregation and sedimentation of CPY colloids due to its effectivescreening of the surface charge of CPY and bridging interaction with CPY particles.Derjaguin-LandauVerwey-Overbeek theory and attachment efficiency calculation indicated that high energy barriers were responsible for the high mobility of CPY colloids,while the retention of CPY in sands was mainly caused by secondary energy minimum and physically straining.The findings of this work can help to evaluate the fate of soil passivation remediation products in natural water and soil.

关键词： Chloropyromorphite DLVO theory Stability Saturated porous medium Transport

Thermal conductivity measurements on xonotlite-type calcium silicate by the transient hot-strip method

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Journal of University of Science and Technology Beijing 2008年第6期15卷 791-795页

作者： gaosheng wei Xinxin Zhang Fan Yu Key Laboratory of the Ministry of Education of China of Condition Monitoring and Control for Power Plant Equipment School of Energy and Power Engineering North China Electric Power University Beijing 102206 China School of Mechanical Engineering University of Science and Technology Beijing Beijing 100083 China

The experimental results of the thermal conductivities of xonotlite-type calcium silicate insulation materials were presented at different temperatures and pressures. Two appropriative surroundings, i.e. an elevated temperature surrounding from ambient temperature to 1450 K and a vacuum surrounding from atmosphere pressure to 10-3 Pa, were designed for the transient hot-strip （THS） method. The thermal conductivities of xonotlite-type calcium silicate with four densities from ambient temperature to 1000 K and 0.045 Pa to atmospheric pressure were measured. The results show that the thermal conductivity of xonotlite-type calcium silicate decreases apparently with the fall of density, and decreases apparently with the drop of pressure, and reaches the least value at about 100 Pa. The thermal conductivity of xonotlite-type calcium silicate increases almost linearly with T0, and increases more abundantly with low density than with high density. The thermal conductivity measurement uncertainty is estimated to be approximately 3% at ambient temperature, and 6% at 800 K.

关键词： thermal conductivity hot-strip method xonotlite-type calcium silicate insulation

From Liquid to Solid‑State Lithium Metal Batteries:Fundamental Issues and Recent Developments

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Nano-Micro Letters 2024年第2期16卷 68-125页

作者： Zhao Zhang wei‑Qiang Han School of Materials Science and Engineering Zhejiang UniversityHangzhou 310027People’s Republic of China

The widespread adoption of lithium-ion batteries has been driven by the proliferation of portable electronic devices and electric vehicles,which have increasingly stringent energy density requirements.Lithium metal batteries(LMBs),with their ultralow reduction potential and high theoretical capacity,are widely regarded as the most promising technical pathway for achieving high energy density batteries.In this review,we provide a comprehensive overview of fundamental issues related to high reactivity and migrated interfaces in LMBs.Furthermore,we propose improved strategies involving interface engineering,3D current collector design,electrolyte optimization,separator modification,application of alloyed anodes,and external field regulation to address these challenges.The utilization of solid-state electrolytes can significantly enhance the safety of LMBs and represents the only viable approach for advancing them.This review also encompasses the variation in fundamental issues and design strategies for the transition from liquid to solid electrolytes.Particularly noteworthy is that the introduction of SSEs will exacerbate differences in electrochemical and mechanical properties at the interface,leading to increased interface inhomogeneity—a critical factor contributing to failure in all-solidstate lithium metal batteries.Based on recent research works,this perspective highlights the current status of research on developing high-performance LMBs.

关键词： Lithium metal batteries All-solid-state lithium metal battery Li dendrite Solid electrolyte Interface

On-surface synthesis and characterization of polyynic carbon chains

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National Science Review 2024年第3期11卷 192-199页

作者： Wenze Gao wei Zheng Luye Sun Faming Kang Zheng Zhou wei Xu Interdisciplinary Materials Research Center School of Materials Science and Engineering Tongji University

Carbyne, an elusive sp-hybridized linear carbon allotrope, has fascinated chemists and physicists for decades. Due to its high chemical reactivity and extreme instability, carbyne was much less explored in contrast to the sp2-hybridized carbon allotropes such as graphene. Herein, we report the on-surface synthesis of polyynic carbon chains by demetallization of organometallic polyynes on the Au（111） surface;the longest one observed consists of ～60 alkyne units（120 carbon atoms）. The polyynic structure of carbon chains with alternating triple and single bonds was unambiguously revealed by bond-resolved atomic force microscopy. Moreover, an atomically precise polyyne, C14, was successfully produced via tip-induced dehalogenation and ring-opening of the decachloroanthracene molecule(C14Cl10) on a bilayer NaCl/Au（111） surface at 4.7 K, and a band gap of 5.8 eV was measured by scanning tunnelling spectroscopy,in a good agreement with the theoretical HOMO–LUMO gap（5.48 eV）.

关键词： polyyne scanning probe microscopy carbon allotrope on-surface synthesis organometallic polyyne

A review of concentrated photovoltaic-thermal(CPVT) hybrid solar systems with waste heat recovery(WHR)

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Science Bulletin 2017年第20期62卷 1388-1426页

作者： Xing Ju Chao Xu Zhirong Liao Xiaoze Du gaosheng wei Zhifeng Wang Yongping Yang Key Laboratory of Condition Monitoring and Control for Power Plant Equipment of Ministry of Education School of Energy Power and Mechanical Engineering North China Electric Power University Key Laboratory of Solar Thermal Energy and Photovoltaic Systems Institute of Electrical Engineering Chinese Academy of Sciences

In conventional photovoltaic(PV) systems, a large portion of solar energy is dissipated as waste heat since the generating efficiency is usually less than 30%. As the dissipated heat can be recovered for various applications, the wasted heat recovery concentrator PV/thermal(WHR CPVT) hybrid systems have been developed. They can provide both electricity and usable heat by combining thermal systems with concentrator PV(CPV) module, which dramatically improves the overall conversion efficiency of solar energy.This paper systematically and comprehensively reviews the research and development of WHR CPVT systems. WHR CPVT systems with innovative design configurations, different theoretical evaluation models and experimental test processes for several implementations are presented in an integrated manner. We aim to provide a global point of view on the research trends, market potential, technical obstacles, and the future work which is required in the development of WHR CPVT technology. Possibly, it will offer a generic guide to the investigators who are interested in the study of WHR CPVT systems.

关键词： Hybrid solar system Waste heat recovery Photovoltaic/thermal Concentration Concentrator photovoltaic/thermal