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A General Strategy for Ordered Carrier Transport of Quasi‑2D and 3D Perovskite Films for Giant Self‑Powered Photoresponse and Ultrahigh Stability

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Nano-Micro Letters 2023年第8期15卷 128-140页

作者： Fei Zhu gang lian Deliang Cui Qilong Wang Haohai Yu Huaijin Zhang Qingbo Meng Ching‑Ping Wong State Key Laboratory of Crystal Materials Shandong UniversityJinan 250100People’s Republic of China Key Laboratory for Special Functional Aggregated Materials of Education Ministry School of Chemistry&Chemical EngineeringShandong UniversityJinan 250100People’s Republic of China Key Laboratory for Renewable Energy Chinese Academy of Sciences(CAS)BeijingPeople’s Republic of China Key Laboratory for New Energy Materials and Devices Beijing National Laboratory for Condensed Matter PhysicsInstitute of PhysicsCASBeijing 100190People’s Republic of China School of Materials Science and Engineering Georgia Institute of TechnologyAtlantaGA 30332USA

Organic–inorganic hybrid perovskite materials have been focusing more attention in the field of self-powered photodetectors due to their superb photoelectric properties.However,a universal growth approach is required and challenging to realize vertically oriented growth and grain boundary fusion of 2D and 3D perovskite grains to promote ordered carrier transport,which determines superior photoresponse and high stability.Herein,a general thermal-pressed(TP)strategy is designed to solve the above issues,achieving uniaxial orientation and single-grain penetration along the film thickness direction.It constructs the efficient channel for ordered carrier transport between two electrodes.Combining of the improved crystal quality and lower trap-state density,the quasi-2D and 3D perovskite-based self-powered photodetector devices(with/without hole transport layer)all exhibit giant and stable photoresponse in a wide spectrum range and specific wavelength laser.For the MAPbI_(3)-based self-powered photodetectors,the largest R_(λ) value is as high as 0.57 A W^(−1)at 760 nm,which is larger than most reported results.Meanwhile,under laser illumination(532 nm),the FPEA_(2)MA_(4)Pb_(5)I_(16)-based device exhibits a high responsivity(0.4 A W^(−1)) value,which is one of the best results in 2DRP self-powered photodetectors.In addition,fast response,ultralow detection limit,and markedly improved humidity,optical and heat stabilities are clearly demonstrated for these TP-based devices.

关键词： Perovskites Thermal-pressed strategy Uniaxial orientation Self-powered photodetectors Stability

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MoS2-intercalated carbon hetero-layers bonded on graphene as electrode materials for enhanced sodium/potassium ion storage

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Nano Research 2023年第1期16卷 473-480页

作者： Laiying Jing Junwei Sun Chaoyang Sun Di Wu gang lian Deliang Cui Qilong Wang Haohai Yu State Key Lab of Crystal Materials Shandong UniversityJinan 250100China School of Materials Science and Engineering Qilu University of Technology(Shandong Academy of Sciences)Jinan 250353China Key Laboratory for Special Functional Aggregated Materials of Education Ministry School of Chemistry&Chemical EngineeringShandong UniversityJinan 250100China

MoS2 is considered as an ideal electrode material in the field of energy storage due to high theoretical specific capacity and unique layered structure.However,limited interlayer distance and poor intrinsic electrical conductivity restrict its potential realworld application.Herein,an alternately intercalated structure of MoS2 monolayer and N-doped porous carbon(NC)layer is grown on reduced graphene oxide(rGO)via a chemical intercalated strategy.The expanded interlayer distance of MoS2(0.96 nm),enlarged by the intercalation of N-doped porous carbon layers,can enhance ion diffusion mobility,provide additional reactive sites for ion storage and maintain the stability of electrode structure.In addition,the hierarchical structures between rGO substrate and intercalated N-doped carbon layers construct a three-dimensional(3D)conductive network,which can significantly improve the electrical conductivity and the structural stability.As a result,the rGO-supported MoS2/NC electrode exhibits an ultrahigh reversible capacity and remarkable long cycling stability for sodium-ion batteries(SIBs)and potassium-ion(PIBs).Meanwhile,the as-obtained MoS2/NC@rGO electrode also delivers a superior cycle performance of 250 mAh·g−1 after 160 cycles at 0.5 A·g−1 when employed as an anode for sodium-ion full cells.

关键词： MoS2 graphene expanded interlayer spacing sodium-ion batteries potassium-ion batteries

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“非洲独龙玉”的矿物成分及谱学特征

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光谱学与光谱分析 2024年第6期44卷 1676-1683页

作者：余炼钢郑金宇德宏师范高等专科学校艺术学院云南德宏678400 中国地质大学(武汉)珠宝学院湖北武汉430074

“非洲独龙玉”是近年来滇西珠宝市场上涌现的新兴玉石品种。其鲜艳绿色呈脉状和团絮状分布于无色至灰白色基体上,局部存在红褐色。品质优于云南怒江州“独龙玉”,市场前景引起业界广泛关注,但其宝石学特征及矿物种属尚不清楚。运用红... 详细信息

“非洲独龙玉”是近年来滇西珠宝市场上涌现的新兴玉石品种。其鲜艳绿色呈脉状和团絮状分布于无色至灰白色基体上,局部存在红褐色。品质优于云南怒江州“独龙玉”,市场前景引起业界广泛关注,但其宝石学特征及矿物种属尚不清楚。运用红外光谱仪、拉曼光谱仪、X射线粉晶衍射仪、扫描电子显微镜及能谱、X射线荧光光谱仪、紫外-可见光谱仪等测试方法对其矿物组成及结构特征、化学成分、谱学特征及颜色成因等进行了研究。红外光谱测试表明该玉石的绿色部分显示白云母与石英的红外特征混合谱,其中3623、694、1080和1619 cm^(-1)处特征吸收峰指示白云母。拉曼光谱测试显示玉石基体部分在204、262、355、395和463 cm^(-1)处具α-石英特征峰,绿色部分在261、395、694、3623 cm^(-1)处具白云母特征峰,表面金属光泽矿物在343、379和437 cm^(-1)处具黄铁矿特征峰,局部浸染状橙黄-红褐色矿物在224、295、409、493和610 cm^(-1)处具赤铁矿特征峰。X射线粉晶衍射测试在3.48、2.98、2.56处特征衍射峰指示为2M 1型白云母。扫描电子显微镜及能谱面扫描显示白云母呈纤柱状、鳞片状集合体,单颗粒长约25~40μm,宽约2~4μm;少量杂质矿物辉砷镍矿呈近似立方体晶形,粒径约为10~15μm,由黄铁矿蚀变作用形成,其中Fe、Co部分类质同像替代Ni,As含量高于S,指示为高温热液矿床成因。综合化学成分及紫外-可见光谱特征表明,致色矿物白云母含Ba、Cr,不含Fe,其中Cr为致色元素。除颜色特征外,利用多种谱学的方法揭示了“非洲独龙玉”与云南怒江“独龙玉”在杂质矿物、化学成分及致色元素方面的差异,可作为区分二者的有效证据,同时丰富了天然绿色石英质玉的成分信息和谱学特征数据,亦为进一步做“非洲独龙玉”的产地溯源及成矿地质条件背景研究奠定了理论基础。

关键词： “非洲独龙玉” 矿物组成辉砷镍矿颜色成因谱学特征

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Assembly of flower-like VS_(2)/N-doped porous carbon with expanded(001)plane on rGO for superior Na-ion and K-ion storage

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Nano Research 2022年第5期15卷 4108-4116页

作者： Junwei Sun gang lian Laiying Jing Di Wu Deliang Cui Qilong Wang Haohai Yu Huaijin Zhang Ching-Ping Wong State Key Lab of Crystal Materials Shandong UniversityJinan 250100China School of Materials Science and Engineering Qilu University of Technology(Shandong Academy of Sciences)Jinan 250353China Key Laboratory for Special Functional Aggregated Materials of Education Ministry School of Chemistry&Chemical EngineeringShandong UniversityJinan 250100China School of Materials Science and Engineering Georgia Institute of TechnologyAtlantaGeorgia 30332USA

VS2 with natural layered structure and metallic conductivity is a prospective candidate for sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs).However,due to large radius of Na+and K+,the limited interlayer spacing(0.57 nm)of VS2 generally determines high ion diffusion barrier and large volume variation,resulting in unsatisfactory electrochemical performance of SIBs and PIBs.In this work,flower-like VS_(2)/N-doped carbon(VS_(2)/N-C)with expanded(001)plane is grown on reduced graphene oxide(rGO)via a solvothermal and subsequently carbonization strategy.In the VS_(2)/N-C@rGO nanohybrids,the ultrathin VS2"petals"are alternately intercalated by the N-doped porous carbon monolayers to achieve an expanded interlayer spacing(1.02 nm),which can effectively reduce ions diffusion barrier,expose abundant active sites for Na+/K+intercalation,and tolerate large volume variation.The N-C and rGO carbonous materials can significantly promote the electrical conductivity and structural stability.Benefited from the synergistic effect,the VS2/N-C@rGO electrode exhibits large reversible capacity(Na+:407 mAh·g^(-1) at 1 A·g^(-1);K^(+):334 mAh·g^(-1) at 0.2 A·g^(-1)),high rate capacity(Na+:273 mAh·g^(-1) at 8 A·g^(-1);K+:186 mAh·g^(-1) at 5 A·g^(-1)),and remarkable cycling stability(Na+:316 mAh·g^(-1) at 2 A·g^(-1) after 1,400 cycles;K^(+):216 mAh·g^(-1) at 1 A·g^(-1) after 500 cycles).

关键词： VS_(2) N-doped porous carbon,graphene substrate expanded interlayer spacing sodium-ion batteries potassium-ion batteries

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Water-soluble boron carbon oxynitride dots with excellent solid-state fluorescence and ultralong room-temperature phosphorescence

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Nano Research 2020年第12期13卷 3261-3267页

作者： Shenghui Han gang lian Xiaoliang Zeng Zhaozhen Cao Qilong Wang Deliang Cui Ching-Ping Wong State Key Lab of Crystal Materials Shandong UniversityJinan250100China Shenzhen Institutes of Advanced Technology Chinese Academy of SciencesShenzhen518055China Key Laboratory for Special Functional Aggregated Materials of Education Ministry School of Chemistry&Chemical EngineeringShandong UniversityJinan250100China School of Materials Science and Engineering Georgia Institute of TechnologyAtlantaGeorgia30332USA

Developing metal-free and long lifetime room-temperature phosphorescence(RTP)materials has received tremendous interest due to their numerous potential applications,of which stable triplet-excited state is the core challenge.Here,boron carbon oxynitride(BCNO)dots,emitting stable blue fluorescence and green RTP,are reported for the first time.The obtained BCNO dots exhibit an unexpected ultralong RTP lifetime of 1.57 s,lasting over 8 s to naked eyes.The effective doping of carbon and oxygen elements in boron nitride(BN)actually provides a small energy gap between singlet and triplet states,facilitating the intersystem crossing(ISC)and populating of triplet excitons.The formation of compact cores via crystallization and effective inter-/intra-dot hydrogen bonds further stabilizes the excited triplet states and reduces quenching of RTP by oxygen at room temperature.Based on the water-soluble feature of BCNO dots,a novel advanced security ink is developed toward anti-counterfeiting tag and confidential information encryption.This study extends BCNO dots to rarely exploited phosphorescence fields and also provides a facile strategy to prepare ultralong lifetime metal-free RTP materials.

关键词： boron carbon oxynitride dots room-temperature phosphorescence fluorescence colourless security ink anti-counterfeiting

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改性赤泥负载Pt催化剂催化氧化甲苯的性能

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中国环境科学 2024年第3期44卷 1244-1252页

作者：方宏萍梁文俊马琛马连刚李桂贤贵州理工学院资源与环境工程学院贵州贵阳550003 北京工业大学环境与生命学部区域大气复合污染防治北京市重点实验室北京100124

以改性赤泥为载体,采用浸渍方法制备低成本改性赤泥(MRM)负载Pt催化剂,并探究Pt含量对Pt/MRM催化剂催化氧化甲苯活性影响.结果表明0.4Pt/MRM表现出最佳的催化活性,在230℃时甲苯转化率为100%.当空速高达120000h^(-1)时0.4Pt/MRM催化剂... 详细信息

以改性赤泥为载体,采用浸渍方法制备低成本改性赤泥(MRM)负载Pt催化剂,并探究Pt含量对Pt/MRM催化剂催化氧化甲苯活性影响.结果表明0.4Pt/MRM表现出最佳的催化活性,在230℃时甲苯转化率为100%.当空速高达120000h^(-1)时0.4Pt/MRM催化剂依然能保持着较高的催化活性.当甲苯进口浓度为5000mg/m3时仍可以有效氧化甲苯.采用XRD、FT-IR、BET、H2-TPR和O2-TPD等手段进行表征测试分析发现,MRM的比表面积较RM大幅度提高,使MRM能够更好分散活性组分Pt,成为合适的活性组分Pt的催化剂载体.同时所制备的x Pt/MRM催化剂具有较高的比表面积和良好的孔结构.改性赤泥中Fe_(2)O_(3)与活性组分Pt物种相互作用,使催化剂的总氧解吸量增大,提高了催化剂表面氧的迁移率,从而提高了催化效率.

关键词：改性赤泥 Pt 催化燃烧甲苯

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Porous-hollow nanorods constructed from alternate intercalation of carbon and MoS2 monolayers for lithium and sodium storage

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Nano Research 2019年第8期12卷 1912-1920页

作者： Laiying Jing gang lian Junru Wang Mingwen Zhao Xizheng Liu Qilong Wang Deliang Cui Ching-Ping Wong State Key Lab of Crystal Materials Shandong UniversityJinan 250100China School of Physics Shandong UniversityJinan 250100China Tianjin Key Laboratory of Advanced Functional Porous Materials Institute for New Energy Materials and Low-Carbon TechnologiesSchool of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Key Laboratory for Special Functional Aggregated Materials of Education Ministry School of Chemistry and Chemical Engineering Shandong UniversityJinan 250100China School of Materials Science and Engineering Georgia Institute of Technology AtlantaGeorgia 30332USA

Weak ion diffusion and electron transport due to limited interlayer spacing and poor electrical conductivity have been identified as critical roadbacks for fast and abundant energy storage of both MoS2-based lithium ion batteries (LIBs) and sodium ion batteries (SIBs). In this work, MoS2 porous-hollow nanorods (MoS2/m-C800) have been designed and synthesized via an annealing-followed chemistry-intercalated strategy to solve the two issues. They are uniformly assembled from ultrathin MoS2 nanosheets, deviated to the rod-axis direction, with expanded interlayer spacing due to alternate intercalation of N-doped carbon monolayers between the adjacent MoS2 monolayers. Electrochemical studies of the MoS2/m-C800 sample, as an anode of LIBs, demonstrate that the superstructure can deliver a reversible discharge capacity of 1,170 mAh·g^-1 after 100 cycles at 0.2 A·g^-1 and maintain a reversible capacity of 951 mAh·g^-1 at 1.25 A·g^-1 after 350 cycles. While for SIBs, the superstructure also delivers a reversible discharge capacity of 350 mAh·g^-1 at 0.5 A-g-1 after 500 cycles and exhibits superior rate capacity of 238 mAh·g^-1 at 15 A·g^-1 .The excellent electrochemical performance is closely related with the hierarchical superstructures, including expanded interlayer spacing, alternate intercalation of carbon monolayers and mesoporous feature, which effectively reduce ion diffusion barrier, shorten ion diffusion paths and improve electrical conductivity.

关键词： lithium/sodium ion batteries porous-hollow nanorods expanded interlayer spacing alternate intercalation ultrathin nanosheets

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苓桂泻心汤在结肠息肉术后的应用效果观察

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中国肛肠病杂志 2024年第4期44卷 38-40页

作者：高连刚刘艳山东省临沂市中医医院山东临沂276000

目的:观察苓桂泻心汤在结肠息肉电子结肠镜下治疗术后的应用效果。方法:将76例结肠息肉切除患者随机分为观察组和对照组,每组38例。对照组患者不予任何药物治疗,观察组患者予以苓桂泻心汤治疗,6个月后复查电子结肠镜。比较2组患者的临... 详细信息

目的:观察苓桂泻心汤在结肠息肉电子结肠镜下治疗术后的应用效果。方法:将76例结肠息肉切除患者随机分为观察组和对照组,每组38例。对照组患者不予任何药物治疗,观察组患者予以苓桂泻心汤治疗,6个月后复查电子结肠镜。比较2组患者的临床疗效以及治疗前后临床症状评分。结果:观察组患者总有效率明显高于对照组(P0.05),治疗后均下降,且观察组低于对照组(P<0.05)。结论:苓桂泻心汤可缓解结肠息肉镜下治疗术后患者的临床症状,防止复发,疗效显著。

关键词：结肠息肉电子结肠镜切除术苓桂泻心汤

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强化降压并改良填塞治疗隐蔽部位高血压鼻出血150例病例分析

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中国医药指南 2024年第5期22卷 33-36页

作者：连冈陈蕙菁福建省泉州市光前医院五官科泉州362321 福建省泉州市光前医院肿瘤内科泉州362321

目的探讨常规鼻内镜检查未发现明确的出血点的高血压鼻出血的有效治疗措施。方法对150例鼻内镜未发现出血点的高血压鼻出血患者,采用短期强化降压治疗,其中48例患者加用改良前鼻孔填塞法。观察鼻出血的止血治疗效果、并发症及复发情况... 详细信息

目的探讨常规鼻内镜检查未发现明确的出血点的高血压鼻出血的有效治疗措施。方法对150例鼻内镜未发现出血点的高血压鼻出血患者,采用短期强化降压治疗,其中48例患者加用改良前鼻孔填塞法。观察鼻出血的止血治疗效果、并发症及复发情况。结果150例患者中140例一次性止血。5例拔出填塞物后再出血,重新填塞并延长填塞时间并强化降压后治愈,5例最后通过手术止血,均未出现心、脑血管等并发症。随访半年未鼻出血复发。结论短期强化降压治疗并改良前鼻孔填塞法是治疗鼻内镜难定位的高血压鼻出血的安全有效的措施。

关键词：鼻出血高血压鼻腔填塞强化降压

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自制弯金属吸引管用于气管切开手术引导插管的临床效果

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中国医药指南 2024年第2期22卷 121-124页

作者：连冈陈蕙菁福建省泉州市光前医院五官科泉州362321 福建省泉州市光前医院肿瘤内科泉州362321

目的探讨在气管切开手术插管困难时,以自制的弯金属吸引管为引导进行插管的效果。方法对特定患者,先将气管套管套入弯制好的金属吸引管且靠近后端,然后在鼻内镜辅助观察或直视下,将吸引管前端插入气管内,随即将气管套管沿着吸引管身往前... 详细信息

目的探讨在气管切开手术插管困难时,以自制的弯金属吸引管为引导进行插管的效果。方法对特定患者,先将气管套管套入弯制好的金属吸引管且靠近后端,然后在鼻内镜辅助观察或直视下,将吸引管前端插入气管内,随即将气管套管沿着吸引管身往前推,插入气管。结果能确保气管套管插入气管内,减少了盲目插管失败引起窒息的风险。结论在鼻内镜辅助观察或直视下,使用自制弯金属吸引管用于气管切开手术插管困难患者的引导插管,可提高插管成功率。但手工弯制质量不稳定,期望未来医疗器械厂批量生产此器械。

关键词：气管切开吸引管插管困难

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