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Provenance of Conglomerate and Sandstone from Early Permian Shoushangou Formation in Xi Ujimqin,Inner Mongolia:Implications for Understanding Paleo-Asian Ocean Subduction

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Acta Geologica Sinica(English Edition) 2024年第1期98卷 10-31页

作者： ZHANG Yingli guo xianqing MA Shouxian MNR Key Laboratory of Metallogeny and Mineral Assessment Institute of Mineral ResourcesCAGSBeijing 100037China Chinese Academy of Geological Sciences Beijing 100037China

During the Late Carboniferous to Early Permian,a rift was formed by post-collisional extension after ocean closure or an island arc-related basin formed by Paleo-Asian Ocean(PAO)subduction in the Xi Ujimqin ***,the closure time of the PAO is still under ***,to identify the origin of the PAO,the geochemistry and U-Pb age of zircons were analyzed for the extra-large deep marine,polymict clastic boulders and sandstones in the Shoushangou Formation within the *** analyses revealed magmatic activity and tectonic *** conglomerates include megaclasts of granite(298.8±9.1 Ma)and granodiorite porphyry(297.1±3.1 Ma),which were deposited by muddy debris *** of this study demonstrated that the boulders of granitoids have the geochemistry of typical I-type granite,characterized by low Zr+Nb+Ce+Y and low Ga/Al *** granitoid boulders were formed in island arc setting,indicating the presence of arc magmatism in the area that is composed of the Late Carboniferous to Early Permian subduction-related granitoid in southern Xi *** diagrams for determining sedimentary provenance using major and trace elements indicate that Shoushangou sediments originated from continental island arc-related felsic *** zircon U-Pb age cluster of 330–280 Ma was obtained,indicating input from granite,ophiolite,Xilin Gol complex,and Carboniferous sources to the *** basin was geographically developed behind the arc during the Early Permian period because the outcropped intrusive rocks in the Late Carboniferous to Early Permian form a volcanic *** comprehensive analyses of source areas suggest that Shoushangou sediments developed in a backarc basin in response to the northward subduction of the *** backarc basin and intrusive rocks,in addition to previously published Late Carboniferous to Early Permian magmatic rocks of arc unit in Xilin Gol,confirm the presence of an Early Permian trencharc-basin system in the region,r

关键词： provenance analysis backarc basin Shoushangou Formation Early Permian Central Asian Orogenic Belt

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Geochemistry, Geochronology and Lu-Hf Isotopes of Peraluminous Granitic Porphyry from the Walegen Au Deposit, West Qinling Terrane

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Acta Geologica Sinica(English Edition) 2017年第6期91卷 2024-2040页

作者： guo xianqing YAN Zhen Jonathan C.AITCHISON FU Changlei WANG Zongqi MLR Key Laboratory of Metallogeny and Mineral Assessment Institute of Mineral ResourcesChinese Academy of Geological Sciences Institute of Geology Chinese Academy of Geological Sciences School of Earth and Environmental Sciences (SEES) Faculty of ScienceThe University of Queensland

Walegen Au deposit is closely correlated with granitic intrusions of Triassic age, which are composed of granite and quartz porphyries. Both granite porphyry and quartz porphyry consist of quartz, feldspar and muscovite as primary minerals. WeaMy peraluminous granite porphyry （A/ CNK=1.10-1.15） is enriched in LREE, depleted in HREE with Nb-Ta-Ti anomalies, and displays subduction-related geochemistry. Quartz porphyry is strongly peraluminous （A/CNK=1.64-2.81） with highly evolved components, characterized by lower TiO2, REE contents, Mg#, K/Rb, Nb/Ta, Zr/Hf ratios and higher Rb/Sr ratios than the granite porphyry. REE patterns of quartz porphyry exhibit lanthanide tetrad effect, resulting from mineral fractionation or participation of fluids with enriched F and CI. LA- ICP-MS zircon U-Pb dating indicates quartz porphyry formed at 233±3 Ma. The ages of relict zircons from Triassic magmatic rocks match well with the detrital zircons from regional area. In addition, εHf（t） values of Triassic magmatic zircons from the granite and quartz porphyries are -14.2 to -9.1 （with an exception of ＋4.1） and -10.8 to -8.6 respectively, indicating a crustal-dominant source. Regionally, numerous Middle Triassic granitoids were previously reported to be formed under the consumption of Paleotethyan Ocean. These facts indicate that the granitic porphyries from Walegen Au deposit may have been formed in the processes of the closing of Paleotethyan Ocean, which could correlate with the arc-related magmatism in the Kunlun orogen to the west and the Qinling orogen to the east.

关键词： Triassic granites lanthanide tetrad effect subduction-related magmatism Walegen Au deposit West Qinling terrane

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Innovations in metallurgical and materials processes:advancing liquid theory and honoring ***-jie guo's contributions to physical chemistry in metallurgy

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Journal of Iron and Steel Research International 2024年第1期31卷 1-2页

作者： Shuai Liu Jing guo Han-jie guo School of Artificial Intelligence Beijing Technology and Business UniversityBeijing100048China School of Metallurgical and Ecological Engineering University of Science and Technology Beijing(USTB)Beijing100083China

Spanning three decades,***-jie guo's research group has dedicated itself to exploring the fundamental theories and practical applications of physical chemistry within the realm of *** under the assumption that molecul... 详细信息

关键词： chemistry liquid complexes

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青海南山“金水口岩群”的时代与构造属性研究

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地质学报 2016年第3期90卷 589-606页

作者：郭现轻闫臻付长垒王宗起中国地质科学院矿产资源研究所北京100037 中国地质科学院地质研究所北京100037

在青海南山出露一套变质程度达角闪岩相的变沉积岩组合,被认为可与东昆仑造山带中的金水口岩群相对应,其形成时代和构造属性仍存争议。本文对该套组合中的矽线石云母石英片岩和花岗伟晶岩侵入体进行了LA-ICP-MS锆石U-Pb测年和Lu-Hf同位... 详细信息

在青海南山出露一套变质程度达角闪岩相的变沉积岩组合,被认为可与东昆仑造山带中的金水口岩群相对应,其形成时代和构造属性仍存争议。本文对该套组合中的矽线石云母石英片岩和花岗伟晶岩侵入体进行了LA-ICP-MS锆石U-Pb测年和Lu-Hf同位素分析,结果表明矽线石云母石英片岩碎屑锆石U-Pb年龄峰值为779Ma,明显年轻于东昆仑造山带金水口岩群物源区最小年龄峰值(>1.9(Ga);对应的ε_(Hf)(t)值主要为负值(-23.7^-11.8),T_(DM2)年龄为2436~3172Ma,来自于再循环的古元古代—太古代地壳物质,少量碎屑锆石年龄为1744~2819Ma。这些特征与南祁连构造带党河南山和化隆地区元古宙变沉积岩相一致,完全不同于东昆仑造山带中的金水口群。~779Ma碎屑锆石与中祁连和南祁连构造带中新元古代岩浆岩时代相近。花岗伟晶岩形成于439±2Ma,相对应的ε_(Hf)(t)和T_(DM2)分别为-14.2^-7.7Ma和1909~2316Ma,可能为形成于俯冲相关环境下古元古代地壳物质再循环形成的S型花岗岩;775Ma继承性锆石与矽线石云母石英片岩碎屑锆石年龄峰值一致,表明矽线石云母石英片岩为花岗伟晶岩的形成提供了部分物质来源。这些事实表明,青海南山所谓"金水口岩群"的形成时间应不早于779Ma,但不晚于439Ma,其沉积物源区应为~779Ma岩浆岩,在空间上与南祁连构造带党河南山地区以及拉脊山南侧化隆地区的同时期变沉积岩具有相似的沉积物源区和构造属性。

关键词：早志留世花岗岩金水口岩群新元古代青海南山南祁连构造带

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南秦岭中段宁陕地区绿柱石-铌铁矿型伟晶岩中磷灰石和铌铁矿族矿物的矿物地球化学研究

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地学前缘 2023年第5期30卷 115-133页

作者：聂潇陈雷郭现轻于涛王宗起中国地质科学院北京100037 中国地质科学院地球深部探测中心北京100037 中国地质科学院矿产资源研究所自然资源部成矿作用与资源评价重点实验室北京100037 自然资源部矿产勘查技术指导中心北京100037

宁陕伟晶岩区分布于宁陕花岗岩基南侧的外接触带,是秦岭造山带内三大伟晶岩区之一,并分布有伟晶岩型铷-铍-铌-钽矿床。本研究利用扫描电镜和电子探针对宁陕地区的绿柱石-铌铁矿型伟晶岩进行了矿物学研究,同时对铌铁矿族矿物和晶质铀矿... 详细信息

宁陕伟晶岩区分布于宁陕花岗岩基南侧的外接触带,是秦岭造山带内三大伟晶岩区之一,并分布有伟晶岩型铷-铍-铌-钽矿床。本研究利用扫描电镜和电子探针对宁陕地区的绿柱石-铌铁矿型伟晶岩进行了矿物学研究,同时对铌铁矿族矿物和晶质铀矿进行了定年工作。矿物成分和结构特征显示伟晶岩内的磷灰石和铌铁矿族矿物均可分为两类。第一类磷灰石和第二类磷灰石分别具有相对低Mn、低Cl(MnO含量为0.41%~2.27%;Cl含量为0~0.06%)和高Mn、高Cl(MnO含量为14.51%~19.12%;Cl含量为0.12%~0.16%)的特征;第一类铌铁矿族矿物在分类图上集中在铌铁矿区域,第二类铌铁矿族矿物则分散于铌铁矿和钽铁矿区域。结合矿物组成和矿物相互交代关系,本研究认为第一类磷灰石和铌铁矿族矿物为岩浆分离结晶作用的产物,而第二类磷灰石和铌铁矿族矿物的形成则均与流体活动关系密切。第一类铌铁矿族矿物的U-Pb年龄((206.3±1.5) Ma)代表伟晶岩的侵位年龄,第一类磷灰石的原位Nd同位素结果(ε_(Nd)值的范围为-4.3~-2.5)与宁陕岩基内晚三叠世二长花岗岩的ε_(Nd)值基本一致,指示了其同源性。综合两类磷灰石和铌钽铁矿族矿物的成分和结构特征,本研究认为伟晶岩内流体活动具有多阶段性,次生晶质铀矿U-Pb年龄((199.2±1.5) Ma)与岩浆铌铁矿U-Pb年龄((206.3±1.5) Ma)相接近,暗示了早阶段流体活动与岩浆演化关系密切,属于岩浆-热液过渡阶段形成的残余流体;第二类铌铁矿族矿物中局部残留的高Mn含量和第二类磷灰石中较高的Mn、Cl含量共同指示了晚阶段流体中混合了来自围岩的外来流体。

关键词：磷灰石铌铁矿族矿物流体活动绿柱石-铌铁矿型伟晶岩宁陕伟晶岩区

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西秦岭与赛什塘铜矿床有关的花岗质岩石岩浆源区特征及大地构造背景探讨

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岩石学报 2016年第7期32卷 1997-2014页

作者：付长垒闫臻郭现轻牛漫兰陈雷夏文静中国地质科学院地质研究所北京100037 中国地质科学院矿产资源研究所北京100037 合肥工业大学资源与环境工程学院合肥230009 中国科学院大学地球科学学院北京100049

西秦岭赛什塘铜矿区内出露的三叠纪花岗质岩石有闪长玢岩、石英闪长岩、石英闪长玢岩、花岗斑岩和石英斑岩,其岩浆源区与形成构造环境可为古特提斯洋演化和区域成矿作用研究提供证据。岩石地球化学特征共同表明,这些花岗质岩石属于准铝... 详细信息

西秦岭赛什塘铜矿区内出露的三叠纪花岗质岩石有闪长玢岩、石英闪长岩、石英闪长玢岩、花岗斑岩和石英斑岩,其岩浆源区与形成构造环境可为古特提斯洋演化和区域成矿作用研究提供证据。岩石地球化学特征共同表明,这些花岗质岩石属于准铝质钙碱性-高钾钙碱性系列,为I型花岗岩;Mg#值变化较大(39~68),LREE富集,HREE亏损,(La/Yb)N比值介于8.50~22.9,具有Eu负异常,δEu介于0.28~0.78,同时富集大离子亲石元素Cs、Rb、K、Pb,亏损高场强元素Nb、Ta、Ti,呈现出与典型俯冲作用密切相关岛弧花岗岩相一致地球化学特征。石英闪长玢岩和石英斑岩SHRIMP锆石U-Pb年龄分别为219.0±2.3Ma和220.0±2.0Ma,锆石εHf(t)分别为-4.5^-2.1和-2.5^+1.0,对应二阶段模式年龄分别为1392~1544Ma和1190~1415Ma。结合前人对西秦岭三叠纪花岗岩以及其南侧阿尼玛卿蛇绿混杂带研究成果,本文认为赛什塘铜矿区花岗质岩石与西秦岭同时期花岗岩形成于与古特提斯洋向北俯冲密切相关的大陆边缘弧环境,其岩浆源区为中元古代下地壳变基性岩,且岩浆可能受到地幔物质混染。

关键词：花岗岩岩浆源区构造背景赛什塘铜矿床西秦岭

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独居石矿物地球化学对南秦岭宁陕地区Be-Nb伟晶岩成因的指示

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地质学报 2023年第11期97卷 3737-3749页

作者：聂潇陈雷于涛郭现轻王宗起中国地质科学院北京100037 中国地质科学院地球深部探测中心北京100037 中国地质科学院矿产资源研究所自然资源部成矿作用与资源评价重点实验室北京100037 自然资源部矿产勘查技术指导中心北京100037

近年来,在秦岭造山带宁陕伟晶岩区发现了数条Be-Nb稀有金属伟晶岩矿脉。本文通过扫描电镜和电子探针分析了Be-Nb伟晶岩中独居石的矿物学特征和矿物成分。研究结果表明,伟晶岩脉中的独居石可分为两类:Ⅰ类独居石主要分布在石英、长石等... 详细信息

近年来,在秦岭造山带宁陕伟晶岩区发现了数条Be-Nb稀有金属伟晶岩矿脉。本文通过扫描电镜和电子探针分析了Be-Nb伟晶岩中独居石的矿物学特征和矿物成分。研究结果表明,伟晶岩脉中的独居石可分为两类:Ⅰ类独居石主要分布在石英、长石等造岩矿物内部,在背散射图像中多数Ⅰ类独居石内部均匀,部分可见振荡环带,具有较高的Th O2含量(7.0%~13.9%,平均10.5%);Ⅱ类独居石单矿物在背散射图像下同样显示内部均匀,但亮度明显低于Ⅰ类独居石,且Th O2含量较低(0.9%~4.4%,平均2.2%)。这指示了Ⅰ类独居石的岩浆成因和Ⅱ类独居石的热液成因。岩浆成因独居石具有较高的Th O2含量与独居石中磷钙钍石的类质同象替代密切相关。岩浆成因独居石的U-Pb测年结果为200.8±2.1 Ma,代表伟晶岩的成岩年龄,该年龄结果接近宁陕岩基中的二长花岗岩。岩浆和热液成因独居石的εNd值的范围为4.6~3.0,这与二长花岗岩的εNd值范围基本一致,说明区内Be-Nb伟晶岩与上述二长花岗岩的同源性。综上所述,本研究认为宁陕地区Be-Nb伟晶岩的形成是宁陕岩基中二长花岗岩同源岩浆在早阶段结晶分异演化后的残留熔浆结晶所致。

关键词：独居石矿物成因 U-Pb测年 Be-Nb伟晶岩宁陕伟晶岩区

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Emerging direct current triboelectric nanogenerator for high-entropy mechanical energy harvesting

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Science China(Technological Sciences) 2024年第5期67卷 1297-1316页

作者： CHEN Jie guo RuiLong guo HengYu College of Physics and Electronic Engineering Chongqing Normal UniversityChongqing 401331China Department of Applied Physics Chongqing UniversityChongqing 401331China

In the era of the Internet of Things(IoT),the provision of sustainable power to distributed,mobile,and low-power-consumption electronic devices is a critical *** overcome this challenge,the triboelectric nanogenerator(TENG),a highly efficient high-entropy mechanical energy harvesting device,was developed in *** device enables the direct conversion of irregular and low-frequency mechanical energy into pulsed alternating current(AC)***,the incompatibility of most electronic devices with AC signals necessitates rectifier circuits or generators that deliver direct current(DC)*** recent years,DC-TENGs have undergone extensive development,achieving significant milestones in various application fields while also facing crucial challenges that require *** this review,three categories of DC-TENG devices with distinct operating mechanisms are comprehensively explored:multiphase coupling,mechanical rectification,and air *** typical structures and working mechanisms are thoroughly discussed,and specific output performance limitations,along with corresponding optimization strategies,are ***,the applications of DC-TENGs in various scenarios are ***,the challenges faced by DC-TENGs and potential solutions are analyzed to guide further advancements in this technology.

关键词： TENG direct current working mechanisms output performance limitations optimization strategies

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Physicochemical principles of hydrogen metallurgy in blast furnace

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Journal of Iron and Steel Research International 2024年第1期31卷 46-63页

作者： Han-jie guo School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing100083China Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials Beijing100083China

Based on the stoichiometric method and the free energy minimization method,an ideal model for the reduction of iron oxides by carbon and hydrogen under blast furnace conditions was established,and the reduction efficiency and theoretical energy consumption of the all-carbon blast furnace and the hydrogen-rich blast furnace were *** results show that after the reduction reaction is completed at the bottom of the blast furnace,the gas produced by reduction at 1600℃still has a certain excessive reduction capacity,which is due to the hydrogen brought in by the hydrogen-rich blast as well as the excess carbon monoxide generated by the reaction of the coke and the oxygen brought in by the *** the process of the gas with excessive reduction capacity rising from the bottom of the blast furnace and gas reduction process,the excessive reduction capacity of the gas gradually decreases with the increase in the dydrogen content in the *** the all-carbon blast furnace,the excess gas reduction capacity is the strongest,and the total energy consumption per ton of iron reduction is the *** shows that,for the current operation mode of the blast furnace,adding hydrogen in the blast furnace cannot reduce the consumption of carbon required for reduction per ton of iron,but rather increases the consumption of carbon.

关键词： Hydrogen metallurgy Excess gas reduction capacity Theoretical energy consumption Hydrogen-rich blast furnace Thermodynamic model Gibbs minimum free energy method

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Control Strategies for Digital Twin Systems

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IEEE/CAA Journal of Automatica Sinica 2024年第1期11卷 170-180页

作者： guo-Ping Liu IEEE the Center for Control Science and Technology Southern University of Science and TechnologyShenzhen 518055China

With the continuous breakthrough in information technology and its integration into practical applications, industrial digital twins are expected to accelerate their development in the near future. This paper studies various control strategies for digital twin systems from the viewpoint of practical *** make full use of advantages of digital twins for control systems, an architecture of digital twin control systems, adaptive model tracking scheme, performance prediction scheme, performance retention scheme, and fault tolerant control scheme are proposed. Those schemes are detailed to deal with different issues on model tracking, performance prediction, performance retention, and fault tolerant control of digital twin systems. Also, the stability of digital twin control systems is analysed. The proposed schemes for digital twin control systems are illustrated by examples.

关键词： Digital twin control systems fault tolerant control model tracking performance prediction performance retention

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