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Ammonia-induced CuO/13X for H_(2)S removal from simulated blast furnace gas at low temperature

Green Energy & Environment 2025年第1期10卷 139-149页

作者： Erping Cao Yuhua Zheng Hao zhang Jianshan Wang Yuran Li Tingyu Zhu zhan-guo zhang Guangwen Xu Yanbin Cui State Key Laboratory of Mesoscience and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing100190China State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization PanGang Group Research Institute Co.Ltd.Panzhihua Sichuan617000China Shenyang University of Chemical Technology Shenyang110142China University of Chinese Academy of Sciences Beijing 100049China

Blast furnace gas(BFG)is an important by-product energy for the iron and steel industry and has been widely used for heating or electricity ***,the undesirable contaminants in BFG(especially H_(2)S)generate harmful environmental *** desulfurization of BFG is urgent for integrated steel plants due to the stringent ultra-low emission *** with other desulfurization materials,zeolite-based adsorbents represent a viable option with low costs and long service *** this study,an ammonia-induced CuO modified 13X adsorbent(NH3–CuO/13X)was prepared for H_(2)S removal from simulated BFG at low *** XRD,H_(2)-TPR and TEM analysis proved that smaller CuO particles were formed and the dispersion of Cu on the surface of 13X zeolite was improved via the induction of *** on H_(2)S adsorption performance of the adsorbent was carried out using simulated BFG,and the results showed that NH3–CuO/13X-3 has better breakthrough sulfur capacity,which was more than twice the sulfur capacity of CuO/*** is proposed that the enhanced desulfurization performance of NH3–CuO/13X is attributed to an abundant pore of 13X,and combined action of 13X and *** work provided an effective way to improve the sulfur capacity of zeolite-based adsorbents via impregnation method by ammonia induction.

关键词： Blast furnace gas Desulfurization Ammonia-induced CuO 13X zeolite

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Insight into the particle shape on the impact of dry granular flow against a rigid barrier: A DEM study

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Journal of Earth Science 2025年

作者： Rui-Xiao zhan Dong Su Xiang-Sheng Chen Yuan-Jun Jiang guo-Ping Lei Jing-Jing Yu Key Laboratory for Resilient Infrastructures of Coastal Cities (MOE)， Shenzhen University College of Civil and Transportation Engineering， Shenzhen University School of Architecture and Urban Planning， Shenzhen University Shenzhen Key Laboratory of Green， Efficient and Intelligent Construction of Underground Metro Station， Shenzhen University Institute of Mountain Hazards and Environment， Chinese Academy of Sciences School of Transportation， Civil Engineering & Architecture， Foshan University

The effect of particle shape on the impact of dry granular flow remains an open area for further investigation. Five distinct particle shapes were examined in this study using discrete element simulations after calibrating the numerical model using a published work. The findings indicated that the particle shape had a significant influence on granular mobility. With negligible variations in normalized kinetic energy between particles of different shapes， the effect of particle shape on the increasing rate of kinetic energy became more obvious. All irregular particle scenarios had longer accumulated particle lengths down the channel than spherical particles. Variations in particle shape led to adjustments in the distribution of impact forces on the barrier. These findings substantially enhance our understanding of the distinctive effects of particle shapes on the impact mechanism of dry granular flow.

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Mechanical properties and microstructures of Mg-6Si alloys fabricated using the tungsten-inert-gas arc additive manufacturing

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China Foundry 2025年

作者： Peng-cheng Zhou guo-qiang You Jin-yu Feng Lei Wang Xiao Lin Bin Jiang College of Materials Science and Engineering Chongqing University National Engineering Research Center for Magnesium Alloys Chongqing University National Key Laboratory of Advanced Casting Technologies Chongqing University

Si-containing Mg alloys solidified at conventional rates often contain coarse and sharp Mg2Si phases,which can result in inferior material *** this study,Mg-6wt.%Si （Mg-6Si） alloy was prepared by wire arc additive manufacturing （WAAM）,employing the gas tungsten arc welding technique with rapid *** microstructures and mechanical properties of the WAAM alloy were investigated and compared with those of the as-cast samples produced using a metal *** results indicate that the WAAM Mg-6Si is harder and stronger than the as-cast *** microhardness of the WAAM Mg-6Si increases by 36.6%in comparison to that of as-cast Mg-6Si ***,the average tensile strengths at room temperature and 150°C increases by 63.4%and 21.3%,*** refines both the Mg2Si phase and the overall grains,resulting in a homogeneous morphology and improved mechanical *** granular Mg2Si phase,characterized by fine particles with a diffused distribution,shows a significant increase in *** acicular Mg2Si phase is distributed along the grain boundaries,and its concentration significantly *** average grain size of the Mg2Si phase is about 9.20μm,about 5 times *** refinement and distribution of the granular Mg2Si phase,as well as the reduction in the amount of needle-like Mg2Si particles,are the key factors for improving the mechanical properties of WAAM Mg-6Si alloy.

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Ni-catalyzed cross-electrophile alkyl-alkyl coupling reactions

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Science China Chemistry 2025年

作者： Li-Xu You Lan Tian Chun-Ling guo Shun-Xi Li Yu-cheng Liu Yu-Long Li Wei Shu College of Chemistry and Environmental Engineering Key Laboratory of Green Catalysis of Higher Education Institutes of Sichuan Sichuan University of Science and Engineering Guangming Advanced Research Institute Shenzhen Grubbs Institute Department of Chemistry and Guangdong Provincial Key Laboratory of Catalysis Southern University of Science and Technology

Introducing saturated carbon-carbon bonds into organic molecules significantly increases the three-dimensional configuration,thus altering the physical and chemical properties as well as the functions of molecules. Transition-metal-catalyzed carboncarbon cross-couplings represent one of the most straightforward, efficient and modular alternatives to build saturation in a single step. However, the efficient construction of alkyl-alkyl bonds remains a formidable challenge due to the precise manipulation of multiple alkyl metallic intermediates as well as associated competitive side reactions and selectivity control. Over the past years, Ni-catalyzed cross-coupling under reductive conditions has gained more and more attention for alkyl-alkyl crosscoupling partially attributing to the low-valent state of metal centers under reducing conditions, which suppresses the competitive β-hydride elimination process, thus facilitating the formation of alkyl-alkyl bonds. In this review, the initiative and progress of Ni-catalyzed cross-electrophile alkyl-alkyl cross-coupling, including the efforts in racemic and enantioselective formation of alkyl-alkyl bonds, have been summarized and discussed. Moreover, the challenges and further opportunities in this area have also been discussed.

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Tunable non-Markovian and quantum coherence in the single-qubit dephasing noise channel

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Science China(Physics,Mechanics & Astronomy) 2025年

作者： Na-Na zhang Chao-Yi Wu Xu Zhou Qi-Yuan Liu cheng-Ge Liu Yong-Rui guo Ren-Pu Li School of Optoelectronic Engineering Chongqing University of Posts and Telecommunications Department of Physics Applied Optics Beijing Area Major Laboratory Beijing Normal University

In this paper, we construct a single-qubit dephasing noise channel based on the nuclear magnetic resonance（NMR） system by employing the bath-engineering technology, and achieve the construction of the tunable non-Markovian environment in the dephasing noise channel. Our findings indicate that for the single-qubit system, the transition of system dynamics from Markovian to non-Markovian can be achieved by adjusting the base frequency of the noise power spectrum. However, the base frequency corresponding to this phase transition point is not fixed, and there is a certain relationship between it and the total evolution time of the single-qubit system. Through our research, we discovered a fundamental relationship: if the single-qubit system dynamics undergoe a transition from Markovian to non-Markovian at ω0within 0-2t ms, shortening the evolution time to 0-t ms results in an increase of the phase transition point to 2ω0. This insight offers crucial guidance for artificially crafting non-Markovian environments across arbitrary time scales in single-qubit systems, and it is not limited by the type of noise. Apart from system dynamics, quantum coherence is also a focal point of our research. We find that when the system dynamics exhibit non-Markovian behavior, the quantum coherence of the single-qubit system experiences revivals. Notably, the timing of these coherence revivals aligns with the instants of the non-Markovianity enhancement. Therefore, our research also serves as a pivotal foundation for the artificial manipulation and realization of quantum coherence revivals within diverse single-qubit systems.

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长江经济带新型城镇化与空气污染的脱钩分析

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生态经济 2025年第1期41卷 140-148,194页

作者：詹成郭明晶周文潇陈嘉浩中国地质大学(武汉)经济管理学院湖北武汉430074

城市的快速发展带来了污染物的集中。为了协调经济发展与环境污染之间的关系,中国制定并实施了新型城镇化战略。但是,对新型城镇化与空气污染的具体关系的研究尚不充足,仍不清楚空气污染是否与新型城镇化脱钩。因此,基于2009—2021年长... 详细信息

城市的快速发展带来了污染物的集中。为了协调经济发展与环境污染之间的关系,中国制定并实施了新型城镇化战略。但是,对新型城镇化与空气污染的具体关系的研究尚不充足,仍不清楚空气污染是否与新型城镇化脱钩。因此,基于2009—2021年长江经济带108个城市的面板数据,构建了人口、经济、空间、社会和生态五个维度的新型城镇化评价指标体系。利用Tapio脱钩模型和追赶脱钩模型探讨了新型城镇化与PM_(2.5)浓度之间的脱钩关系和区域异质性。结果表明:(1)长江经济带PM_(2.5)浓度在2013年后持续减少。(2)新型城镇化的驱动力主要来自经济城镇化和社会城镇化。(3)PM_(2.5)浓度与新型城镇化之间长期保持脱钩状态,但在短期尺度内存在脱钩和负脱钩的交替现象。(4)大部分追赶城市对模范城市的追赶并不理想,地区间的不平衡现象还将长期持续。

关键词：新型城镇化空气质量 PM2.5 Tapio模型

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Flow Behavior in Z-Path Fluidized-Moving Bed with Inclined Perforated Plate

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Journal of Iron and Steel Research International 2002年第1期9卷 19-24页

作者： guo zhan.cheng TOKUDA Masanori Institute of Process Engineering CAS Center for Northeast Asia Studies Tohoku University

Much researches on the operation and structure of tundish were carried out at Xiangtan Iron and Steel Co Ltd to increase the yield of grade 20 carbon steel on the continuous casting production line. Through analyzing formation mechanism of pinholes and non metallic inclusions in billets and describing pattern of the flow of molten steel in tundish by a mathematic model, it was shown that the structure and operation of tundishes play an important part in product quality. So some measures were taken as follows: (1) Optimizing the tundish construction to decrease the impact of liquid steel and lengthening the residence time of liquid steel for homogenization of liquid steel; (2) Improving the influent and effluent operation of liquid steel to avoid the contact of liquid steel with air in order to decrease reoxidation; (3) Reducing over heat during continuous casting. After above measures being taken, the yield of grade 20 carbon steel and the service life of equipment were improved remarkably.

关键词： carbon steel continuous casting quality tundish

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Recovery of zinc from Zn-Al-Fe alloys by gas pressure filtration

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Journal of Iron and Steel Research International 2020年第11期27卷 1322-1330页

作者： Tian-yang Li Zhe Wang Lei guo zhan.cheng guo State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China

The recovery of zinc from galvanizing dross and the removal of iron contained dross particles by gas pressure filtration were investigated using the model of Zn-Fe-Al *** majority of molten zinc was separated after filtration,and the residue intercepted by the filter consisting mostly of dross *** effects of the pressure differential(p),separation temperature(T)and alloy composition on the zinc recovery and iron removal were *** p=0.30 MPa and T=723 K,86.2 wt.%zinc was recovered from the Zn-4Al-2Fe alloy,and up to 99.9 wt.%of the iron was concentrated in the *** a higher pressure differential led to the improved filtration efficiency,and the desired separation temperature was about 723 *** aluminum content in the Zn-Al-Fe alloy had little effect on separation efficiency,whereas increasing the iron content led to a decrease in the separation *** findings demonstrate the potential of the gas pressure filtration method for the recovery of zinc from galvanizing dross.

关键词： Galvanizing dross Gas pressure filtration Zinc recovery Iron removal Separation

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FHL2 deficiency aggravates Candida albicans infection through decreased myelopoiesis

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Science China Life Sciences 2025年

作者： Rongmei Gao Kanchao Chen Yimin Wang Rongxia guo Xiaoyu zhang Peng Wu Weili Wang Qingxiang Huang Xuemei Xie Shangda Yang Yanling Lü Qian Ren Fei Liu Song Chen Fengxia Ma Tao cheng Hui cheng State Key Laboratory of Experimental Hematology National Clinical Research Center for Blood Diseases Haihe Laboratory of Cell Ecosystem Institute of Hematology & Blood Diseases Hospital Chinese Academy of Medical Sciences & Peking Union Medical College CAMS Center for Stem Cell Medicine PUMC Department of Stem Cell and Regenerative Medicine

Hematopoiesis is a finely tuned process that generates all blood cell types through self-renewal and differentiation, which is crucial for maintaining homeostasis. Acute infections can prompt a hematopoietic response known as emergency myelopoiesis. In this study, using a Candida albicans (C. albicans) infection model, we demonstrated for the first time that disruption of Fhl2 led to increased fungal burden,heightened inflammatory response and reduced survival rates. Impaired myeloid hematopoiesis and immune cell production were evident, as proved by the decreased numbers of hematopoietic stem and progenitor cells (HSPCs) and granulocytes in the bone marrow of Fhl2-deficient mice. In conclusion, FHL2 regulated emergency myelopoiesis in response to C. albicans, affecting the host’s defense against pathogens.

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Effect of Al_(2)O_(3)/SiO_(2) mass ratio and CaO content on viscosity and structure of slag for pyrometallurgical processing of spent automotive catalysts

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Journal of Iron and Steel Research International 2024年第3期31卷 608-621页

作者： Zhe Wang Qi-long Wei cheng-bin Shi zhan.cheng guo State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China

The effect of Al_(2)O_(3)/SiO_(2) mass ratio and CaO content on the viscosity and structure of the CaO-Al_(2)O_(3)-SiO_(2)-6MgO-1.5ZrO_(2)-1.5CeO_(2) slag was *** results show that with the increase in Al_(2)O_(3)/SiO_(2) mass ratio,the viscous flow units within the slag gradually change from Si-O-Si to Al-O-Al and ***,the substitution of Al_(2)O_(3) for SiO_(2) leads to the transformation of Si-O bonds towards weaker Al-O bonds,which weaken the bond strength of the aluminosilicate networks,thus leading to a decrease in the viscosity of *** increase in CaO content effectively promotes the depolymerization of the aluminosilicate networks,resulting in a significant decrease in the viscosity of the *** slag with Al_(2)O_(3)/SiO_(2) of 0.7-1.5 and CaO of 30 wt.%shows promise as the reference slag system for the Fe-collection smelting of spent automotive catalysts due to its good comprehensive performance.

关键词： Aluminosilicate slag Al_(2)O_(3)/SiO_(2)mass ratio CaO content Viscosity Slag structure

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