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International Journal of Mining Science and Technology 2025年第2期35卷 249-264页

作者： Wei Zhang Dongxiao Zhang Weiyao guo Baoliang Zhang School of Architecture and Engineering Liaocheng UniversityLiaocheng 252000China College of Energy and Mining Engineering Shandong University of Science and TechnologyQingdao 266590China

It is important to analyze the damage evolution process of surrounding rock under different water content for the stability of engineering rock *** on digital speckle correlation(DSCM),acoustic emission(AE)and electromagnetic radiation(EMR),uniaxial hierarchical cyclic loading and unloading tests were carried out on sandstones with different fracture numbers under dry,natural and saturated water content,to explore the fracture propagation,failure precursor characteristics and damage response mechanism under the influence of water content *** results show that with the increase of water content,the peak stress and crack initiation stress decrease gradually,and the decreases are 15.28%-21.11%and 17.64%-23.04%,*** peak strain and crack initiation strain increase gradually,and the increases are 19.85%-44.53%and 19.15%-41.94%,*** precracked rock with different water content is mainly characterized by tensile failure at different loading ***,with the increase of water content,the proportion of shear cracks gradually increases,while acoustic emission events gradually decrease,the dissipative energy and energy storage limits of the rock under peak load gradually decrease,and the charge signal increases significantly,which is because the lubrication effect of water reduces the friction coefficient between crack surfaces.

关键词： Damage mechanisms Pre-cracked rocks Crack propagation Water-rock interaction Graded cyclic loading and unloading

Buried interface bridging for inverted cesium-formamidinium triiodide perovskite solar cells with long operational stability

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Science China Chemistry 2025年第1期68卷 163-173页

作者： Chenhui Zhang Chunjun Liang Fulin Sun Ting Zhu Xinghai Huang Yuzhu guo Xinyu guo Kunyang Ge Dan Li Fangtian You Zhiqun He Key Laboratory of Luminescence and Optical Information Ministry of EducationInstitute of Optoelectronic TechnologyBeijing Jiaotong UniversityBeijing 100044China Department of Physics School of Physical Science and EngineeringBeijing Jiaotong UniversityBeijing 100044China

In the field of perovskite solar cells(PSCs),the research on defects in the buried interface has been relatively limited due to its non-exposure;however,this interface significantly impacts the performance enhancement of inverted *** study employs phenylethylammonium chloride(PEACl)molecules as a buffer layer to modify the buried interface of p-i-n structured PSCs,aiming to enhance the uniformity of self-assembled monolayers(SAMs)and facilitate the uniform nucleation and growth of perovskite films on the ***,the introduction of the PEACl buffer layer effectively passivates defects at the bottom of the perovskite layer and notably enhances the crystal quality of the perovskite film by mitigating residual stress,thereby reducing nonradiative recombination *** these optimizations,the MA-free PSCs treated with PEACl achieve a power conversion efficiency(PCE)of 24.11%,with significant improvements in storage,thermal stability,and operational *** noteworthy is the device's performance in an unencapsulated state,whereas after 1,500 hours of continuous light operation stability testing,it retains 97%of its original *** study not only enriches the systematic understanding of the characteristics of the buried interface in PSCs but also contributes significantly to advancing the commercial production of perovskite photovoltaic technology.

关键词： defect-induced recombination buried interfaces inverted perovskite solar cells crystallization lattice mismatch

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Sulfur doping and oxygen vacancy in In2O3 nanotube co-regulate intermediates of CO2 electroreduction for efficient HCOOH production and rechargeable Zn-CO2 battery

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Journal of Energy Chemistry 2025年第2期101卷 474-484页

作者： Yu Li Zhengrong Xu Quanxin guo Qin Li Rui Liu Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education School of Materials Science and Engineering Tongji University

By manipulating the distribution of surface electrons,defect engineering enables effective control over the adsorption energy between adsorbates and active sites in the CO2reduction reaction（CO2RR）.Herein,we report a hollow indium oxide nanotube containing both oxygen vacancy and sulfur doping（V_o-Sx-In2O3） for improved CO2-to-HCOOH electroreduction and *** componential synergy significantly reduces the*OCHO formation barrier to expedite protonation process and creates a favorable electronic micro-environment for*HCOOH *** a result,the CO2RR performance of Vo-Sx-In2O3outperforms Pure-In2O3and V_o-In2O3,where V_o-S53-In2O3exhibits a maximal HCOOH Faradaic efficiency of 92.4% at-1,2 V *** hydrogen electrode（RHE） in H-cell and above 92%over a wide window potential with high current density(119.1 mA cm-2at-1.1 V ***) in flow ***,the rechargeable Zn-CO2battery utilizing V_o-S53-In2O3as cathode shows a high power density of 2.29 mW cm-2and a long-term stability during charge-discharge *** work provides a valuable perspective to elucidate co-defective catalysts in regulating the intermediates for efficient CO2RR.

关键词： CO2 electroreduction In2O3 Intermediate Oxygen vacancy Sulfur doping Zn-CO2 battery

Distributed optimal consensus control for multiagent systems based on event-triggered and prioritized experience replay strategies

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Science China(Information Sciences) 2025年第1期68卷 306-321页

作者： Cuijuan ZHANG Lianghao JI Shasha YANG Xing guo Huaqing LI Chongqing Key Laboratory of Image Cognition Chongqing University of Posts and Telecommunications Key Laboratory of Intelligent Perception and Computing of Anhui Province Anqing Normal University College of Electronic and Information Engineering Southwest University

This study uses event-triggered(ET) and reinforcement learning methods to investigate the optimal consensus control problem for cooperative-competitive multiagent systems. It proposes a novel distributed ET control strategy, which relies on a prioritized experience replay(PER) policy. This strategy not only conserves communication resources but also ensures acceptable system performance. To implement the proposed method, actor-critic(AC) dual-structured neural networks(NNs) are used to approximate the value function and control policy. In the AC NNs, the weight estimates for the NNs are updated at the moment of event triggering, resulting in a nonperiodic weight adjustment pattern. This approach decreases the computational cost in comparison with the traditional ET mechanism. The PER-based ET mechanism makes full use of valid historical data and effectively establishes a balance between system performance and communication resource ***, it does not require the following two conditions in most existing studies:(1) requirement of the system dynamics model to be known, and(2) persistent excitation. In addition, Zeno behavior is excluded from this study. Finally, a simulation is conducted to confirm the validity of the suggested approach.

关键词： multiagent systems event-triggered mechanism prioritized experience replay dual-structured neural networks optimal consensus control

Absorption mechanism of SO_(3)on various alkaline absorbents in the presence of SO_(2)

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Journal of Environmental Sciences 2025年第3期149卷 268-277页

作者： Junxiang guo Jin Xiong Yuran Li Jirigele Qinggele Tingyu Zhu Shougang Group Research Institute of Technology Beijing 100043China Beijing Key Laboratory of Green Recyclable Process for Iron&Steel Production Technology Beijing 100043China CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringInnovation Academy for Green ManufactureChinese Academy of SciencesBeijing 100190China WISDRI City Environment Protection Engineering Limited Company Wuhan 430205China

Sulfur trioxide(SO_(3))as a condensable particle matter has a significant influence on atmospheric visibility,which easily arouses formation of *** is imperative to control the SO_(3)emission from the industrial flue *** commonly used basic absorbents,including Ca(OH)_(2),MgO and NaHCO_(3)were selected to explore the effects of temperature,SO_(2)concentration on the SO_(3)absorption,and the reaction mechanism of SO_(3)absorption was further *** suitable reaction temperature for various absorbents were proposed,Ca(OH)_(2)at the high temperatures above 500°C,MgO at the low temperatures below 320°C,and NaHCO_(3)at the temperature range of 320–500°*** competitive absorption between SO_(2)and SO_(3)was found that the addition of SO_(2)reduced the SO_(3)absorption on Ca(OH)_(2)and NaHCO_(3),while had no effect on *** order of the absorption selectivity of SO_(3)follows MgO,NaHCO_(3)and Ca(OH)_(2)under the given conditions in this *** absorption process of SO_(3)on NaHCO_(3)follows the shrinking core model,thus the absorption reaction continues until NaHCO_(3)was exhausted with the utilization rate of nearly 100%.The absorption process of SO_(3)on Ca(OH)_(2)and MgO follows the grain model,and the dense product layer hinders the further absorption reaction,resulting in low utilization of about 50%for Ca(OH)_(2)and *** research provides a favorable support for the selection of alkaline absorbent for SO_(3)removal in application.

关键词： Alkali absorbent Sulfur trioxide Selectivity Shrinking core model Grain model

Effect of chlorination and ultraviolet on the adsorption of pefloxacin on polystyrene and polyvinyl chloride

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Journal of Environmental Sciences 2025年第3期149卷 21-34页

作者： Yanan Li Yaning Wu Kai guo Weiqin Wu Meijing Yao School of Environmental Science and Engineering Taiyuan University of TechnologyShanxi 030600China

During thewater treatment process,chlorination and ultraviolet(UV)sterilization can modify microplastics(MPs)and alter their physicochemical properties,causing various changes between MPs and other *** this study,the impact of chlorination and UV modification on the physicochemical properties of polystyrene(PS)and polyvinyl chloride(PVC)were investigated,and the adsorption behavior of pefloxacin(PEF)before and after modificationwas *** effect of pH,ionic strength,dissolved organicmatter,heavymetal ions and other water environmental conditions on adsorption behavior was *** results showed that PS had a higher adsorption capacity of PEF than PVC,and the modification increased the presence of O-containing functional groups in the MPs,thereby enhancing the adsorption capacity of both *** had a more significant impact on the physicochemical properties of MPs compared to UV irradiation within the same time period,leading to better adsorption performance of *** optimal pH for adsorption was found to be 6,and NaCl,sodium alginate and Cu2+would inhibit adsorption to varying degrees,among which the inhibition caused by pH was the *** and UV modification would weaken the inhibitory effect of environmental factors on the adsorption of PEF by *** main mechanisms of adsorption involved electrostatic interaction and hydrogen *** study clarified the effects of modification on the physicochemical properties of MPs,providing reference for subsequent biotoxicity analysis and environmental protection studies.

关键词： Microplastics Chlorination Ultraviolet Pefloxacin Adsorption mechanism

Upcycling of polyphenylene oxide into 2,6-dimethyl aniline via depolymerization and amination over a Pt/CeO_(2) catalyst

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Science China Chemistry 2025年第2期68卷 520-525页

作者： Shengchao Jia Wenke Zhao Xiaohui Liu Yong guo Yanqin Wang State Key Laboratory of Green Chemical Engineering and Industrial Catalysis Research Institute of Industrial CatalysisSchool of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China Shanghai Key Laboratory of Functional Materials Chemistry School of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China

Upcycling of plastic waste into N-containing compound is a novel and attractive strategy for its disposal and will opens up a promising direction for the production of value-added ***,an efficient strategy for the depolymerization-amination of polyphenylene oxide(PPO)into 2,6-dimethyl aniline is developed over a simple Pt/CeO_(2) *** C–O linkages of PPO can be selectively broken,producing 2,6-dimethyl phenol and then hydrogenated and aminated to 2,6-dimethyl cyclohexylamine over the Pt/CeO_(2) ***,2,6-dimethyl aniline was produced with high selectivity through the dehydrogenation of 2,6-dimethyl cyclohexylamine in the same *** can be used as the hydrogen-acceptor in the dehydrogenation step and enhance the selectivity of target *** N-containing compound,2,6-dimethyl aniline,is obtained and separated after HCl ***,the Pt/CeO_(2) catalyst exhibit remarkable stability and can sustainably catalyze the synthesis of 2,6-dimethyl aniline in several cycles.

关键词： PPO depolymerization-amination 2,6-dimethyl aniline Pt/CeO_(2)

Regulating local electron transfer environment of covalent triazine frameworks through F,N co-modification towards optimized oxygen reduction reaction

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Chinese Chemical Letters 2025年第1期36卷 344-348页

作者： Quanyou guo Yue Yang Tingting Hu Hongqi Chu Lijun Liao Xuepeng Wang Zhenzi Li Liping guo Wei Zhou Shandong Provincial Key Laboratory of Molecular Engineering School of Chemistry and Chemical EngineeringQilu University of Technology(Shandong Academy of Sciences)Ji’nan 250353China

The high conductivity of electrocatalyst can eliminate the Schottky energy barrier at the interface of heterogeneous phases during an electrocatalytic reaction and accelerate the rapid electron transfer to the catalytic active ***,the electronic conductivity is a vital parameter for oxygen reduction reaction(ORR).Covalent triazine frameworks(CTFs)have shown great potential application as electrocatalysts in ORR with a merit of the diverse building ***,the intrinsic low conductivity and high impedance of CTFs could be significant setbacks in electrocatalytic ***,CTFs were constructed by introducing F and N co-modification for efficient 2e^(-)*** with the pristine CTF,the co-presence of F,N could increase the conductivity obviously by *** a result,F-N-CTF exhibits enhanced catalytic performance of H_(2)O_(2)generation and selectivity towards reaction *** work reveals the importance of conductivity optimization for CTFs and provides guidance for designing high conductivity non-metallic organic semiconductor catalysts for 2e^(-)ORR.

关键词： Covalent triazine frameworks Conductivity Co-modification Electrocatalysis Oxygen reduction reaction

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Paradigm shifts from data-intensive science to robot scientists

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Science Bulletin 2025年第1期70卷 14-18页

作者： Xin Li Yanlong guo National Tibetan Plateau Data Center State Key Laboratory of Tibetan Plateau Earth SystemEnvironment and ResourcesInstitute of Tibetan Plateau ResearchChinese Academy of SciencesBeijing 100101China University of the Chinese Academy of Sciences Beijing 100049China

The advent of big data concepts and artificial intelligence(AI)has triggered a paradigm shift in scientific *** we move beyond the traditional paradigm,a significant and widespread debate revolves around determining whether the“correlation supersedes causation”paradigm or the“data-intensive scientific discovery”paradigm better aligns with the scientific research landscape in the era of big data[1].

关键词： robot artificial landscape

Influence of ecological restoration on regional temperature-vegetation-precipitation dryness index in the middle Yellow River of China

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Journal of Mountain Science 2025年第2期22卷 636-651页

作者： CHEN Wei guo Yuxing SUN Congjian School of Geographical Science Shanxi Normal UniversityTaiyuan 030031China Research Center for Ecological Environment in the Middle Reaches of the Yellow River Shanxi Normal UniversityTaiyuan 030031China

Drought is an important disaster factor disturbing the stability of the ecosystem in the middle reaches of the Yellow River(YRM).In this study,the spatiotemporal distribution of drought in the YRM from 2000 to 2021 was quantitatively investigated by constructing the TVPDI(Temperature-VegetationPrecipitation Dryness Index),and its driving mechanism was *** results show that:(1)a significant decreasing trend was observed in the regional annual TVPDI of the YRM,while the autumn TVPDI index showed an increasing trend during 2000-2021.(2)Plants are more susceptible to drought during the growing season.(3)Drought in YRM showed significant spatial heterogeneity,and the high gully area in the Loess Plateau and the earth-rocky mountain areas were less affected by drought than other regions.(4)The Structural Equation Model(SEM)indicated that regional soil moisture and vegetation coverage have a direct influence on regional TVPDI *** study has explored the regional differences of drought in different seasons and landforms in the YRM,providing a basis for carrying out targeted seasonal ecological management and refining regional environmental governance,as well as a reference for formulating differentiated ecological restoration and water resource allocation strategies according to local conditions.

关键词： Temperature Vegetation-Precipitation Dryness Index The middle reaches of the Yellow River Seasonal drought Regional drought

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