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Role of A-sites in pyrochlore lanthanide ruthenate for electrocatalysis of oxygen evolution reaction

Journal of Materiomics 2024年第6期10卷 1234-1242页

作者： Hengyu guo Zhengping Zhang feng Wang State Key Laboratory of Chemical Resource Engineering Beijing Key Laboratory of Electrochemical Process and Technology for MaterialsBeijing University of Chemical TechnologyBeijing100029China Beijing Advanced Innovation Center for Soft Matter Science and Engineering Beijing University of Chemical TechnologyBeijing100029China

Developing highly stable and efficient catalysts for oxygen evolution reaction(OER)is extremely important to sustainable energy conversion and storage,but improved efficiency is largely hindered by sluggish reaction *** and bimetal ruthenates have emerged as one of the promising substitutes to replace single-metal ruthenium or iridium oxides,but the fundamental understanding the role of A-site cations is still ***,a family of lanthanides(Ln=all the lanthanides except Pm)are applied to synthesize pyrochlore lanthanide ruthenates(Ln_(2)Ru_(2)O_(7)),and only Ln_(2)Ru_(2)O_(7)(Ln=Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,or Lu)with pure phase can be obtained by the ambient-pressure *** with the perovskite ruthenates(SrRuO_(3))and rutile RuO_(2),the[RuO_(6)]units in these Ln_(2)Ru_(2)O_(7) present the largely distorted configurations and different energy level splitting to prevent the excessive Ru oxidation and dissolution,which leads the primary improvement in the electrocatalytic OER *** the similar crystalline field split states,the charge transfer between[RuO6]units and Ln^(3+)cations also affect catalytic activities,even in the Ln_(2)Ru_(2)O_(7) surface reconstruction during the OER ***,Tb_(2)Ru_(2)O_(7) showed the highest OER performance among all the prepared Ln_(2)Ru_(2)O_(7) with similar morphologies and *** systematic work gives fundamental cognition to rational design of high-performance OER electrocatalysts in proper water electrolysis technologies.

关键词： Pyrochlores Lanthanides Ruthenates Electrocatalysts Oxygen evolution reaction

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A class of natural pinus koraiensis population system with time delay and diffusion term

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International Journal of Biomathematics 2024年第2期17卷 233-262页

作者： guo-feng feng Jiaqi Chen Bin Ge School of Mathematical Sciences Harbin Engineering University Harbin 150001 P.R.China

In this paper,we consider the long-term sustainability of the northeast Korean *** propose a class of natural Korean pine population system with time delay and diffusion ***,by analyzing the roots distribution of the characteristic equation,we study the stability of the model system with diffusion terms and prove the occurrence of Hopf ***,we introduce lactation time delay into a population model with a diffusion term,based on stability theory of ordinary differential equation,norm form methods and center manifold theorem,the stability of bifurcating periodic solutions and the relevant formula for the direction of Hopf bifurcation are ***,some numerical simulations are given.

关键词： Pinus koraiensis populations delay diffusion term Hopf bifurcation periodic solution

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Machine learning model based on non-convex penalized huberized-SVM

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Journal of Electronic Science and Technology 2024年第1期22卷 81-94页

作者： Peng Wang Ji guo Lin-feng Li School of Finance and Economics Xizang Minzu UniversityXianyang712082China Research Center for Quality Development of Xizang Special Industries Xianyang712082China School of Computer Science and Technology Xinjiang UniversityUrumqi830017China

The support vector machine(SVM)is a classical machine learning *** the hinge loss and least absolute shrinkage and selection operator(LASSO)penalty are usually used in traditional ***,the hinge loss is not differentiable,and the LASSO penalty does not have the Oracle *** this paper,the huberized loss is combined with non-convex penalties to obtain a model that has the advantages of both the computational simplicity and the Oracle property,contributing to higher accuracy than traditional *** is experimentally demonstrated that the two non-convex huberized-SVM methods,smoothly clipped absolute deviation huberized-SVM(SCAD-HSVM)and minimax concave penalty huberized-SVM(MCP-HSVM),outperform the traditional SVM method in terms of the prediction accuracy and classifier *** are also superior in terms of variable selection,especially when there is a high linear correlation between the *** they are applied to the prediction of listed companies,the variables that can affect and predict financial distress are accurately filtered *** all the indicators,the indicators per share have the greatest influence while those of solvency have the weakest *** companies can assess the financial situation with the indicators screened by our algorithm and make an early warning of their possible financial distress in advance with higher precision.

关键词： Huberized loss Machine learning Non-convex penalties Support vector machine(SVM)

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A lithium–tin fluoride anode enabled by ionic/electronic conductive paths for garnet-based solid-state lithium metal batteries

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Rare Metals 2024年第2期43卷 575-587页

作者： Lei Zhang Qian-Kun Meng Xiang-Ping feng Ming Shen Yu-Qing Zhang Quan-Chao Zhuang Run-guo Zheng zhi-Yuan Wang Yan-Hua Cui Hong-Yu Sun Yan-guo Liu School of Materials Science and Engineering Northeastern UniversityShenyang110819China School of Resources and Materials Northeastern University at QinhuangdaoQinhuangdao066004China School of Materials and Physics China University of Mining&TechnologyXuzhou221116China Institute of Electronic Engineering China Academy of Engineering PhysicsMianyang621900China

The high energy density and stability of solid-state lithium metal batteries(SSLMBs)have garnered great ***-type oxides,especially Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO),with high ionic conductivity,wide electrochemical window,and stability to Li metal anode,are promising solid-state electrolyte(SSEs)materials for ***,Li/LLZTO interface issues including high interface resistance,inhomogeneous Li deposition,and Li dendrite growth have hindered the practical application of ***,a multi-functional Li–SnF_(2) composite anode with Li,LiF,and Li-Sn alloy was specifically designed and *** composite anode improves the wettability to LLZTO,constructing an intimate contact interface between it and ***,ionic/electronic conductive paths in situ formed at the interface can effectively uniform Li deposition and suppress Li *** solid-state symmetric cell exhibits low interface resistance(11Ω·cm^(2)) and high critical current density(1.3 mA·cm^(−2))at 25℃.The full SSLMB based on LiFePO_(4) or LiNi_(0.5)Co_(0.2)Mn_(0.3)O_(2) cathode also shows stable cycling performance and high rate *** work provides a new composite anode strategy for achieving high-energy density and high-safety SSLMBs.

关键词： Solid-state lithium metal batteries(SSLMBs) Lithium-tin fluoride anode Ionic/electronic conductive Interface resistance Lithium dendrite

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Axial enantiomers with donor-regulated TADF feature for multicolor circularly polarized electroluminescence

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Science China Chemistry 2024年第6期67卷 2039-2045页

作者： Chen-Hao guo Wen-Long Zhao Ke-Ke Tan Wei-Chen guo Liheng feng Chuan-feng Chen Meng Li School of Chemistry and Chemical Engineering Shanxi UniversityTaiyuan030006China Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and FunctionInstitute of ChemistryChinese Academy of SciencesBeijing100190China University of Chinese Academy of Sciences Beijing100049China

This study optimized the TADF feature of axial chiral enantiomers through precise donor engineering,and multicolor CP-TADFwas achieved in the axial chiral *** pairs of axial enantiomers with donor-regulated TADF feature,namely(R/S)-TPCBD,(R/S)-DPCBD,and(R/S)-DPACBD,were synthesized by introducing carbazole donors with different substituents onto biphenyl cyanide *** the electron-donating ability of donors increases,the emission of these axial enantiomers ranges from 455,476 to 552 nm,their singlet-triplet energy gaps(ΔE_(ST))gradually decrease from 0.30,0.22 to 0.02 e V,accompanied by an increasement in the transition rate(k_(RISC))of RISC process,and the k_(RISC)of DPACBD could reach up to 7.16×10^(5)s^(-1).These axial enantiomers also exhibit mirror-image CD and circularly polarized luminescence(CPL)***,OLEDs based on TPCBD,DPCBD,and DPACBD as emitter were then fabricated,which displayed blue,green,and orange electroluminescence with EQE_(max)of 13.0%,16.4%,and 25.0%,*** results also exhibited a phenomenon of device efficiency increasing with the enhancement of donor ***,the CP-OLEDs using(R/S)-TPCBD,(R/S)-DPCBD and(R/S)-DPACBD as emitters displayed intense CPEL signals with g_(EL)values of 3.4×10^(-3)/-4.1×10^(-3),3.2×10^(-3)/-3.1×10^(-3)and2.3×10^(-3)/-2.1×10^(-3),*** convenient molecular engineering of donor regulation in the same molecular skeleton,CP-TADF materials with multicolor CPEL and improved device performance could be conveniently achieved.

关键词： axial chirality thermally activated delayed fluorescence circularly polarized luminescence electroluminescence organic light-emitting diodes

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Microstructure and texture evolution of Cu-Cr-Co-Ti alloys during the two-stage cryorolling

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Rare Metals 2024年第9期43卷 4535-4547页

作者： Jia-Jun Zhang Long-Jian Li zhi-feng Liu Zong-Ning Chen En-Yu guo Hui-Jun Kang Ren-Geng Li Tong-Min Wang Key Laboratory of Solidification Control and Digital Preparation Technology(Liaoning Province) School of Materials Science and EngineeringDalian University of TechnologyDalian 116024China Center of Hyper-Gravity Experimental and Interdisciplinary Research Zhejiang UniversityHangzhou 310058China Ningbo Institute of Dalian University of Technology Ningbo 315000China Key Laboratory for Light-Weight Materials Nanjing Tech UniversityNanjing 210009China

This study entailed an investigation of the mechanical properties,microstructural and texture orientation evolutions of Cu-Cr-Co-Ti alloys prepared via twostage cryorolling and intermediate aging *** this end,X-ray diffraction and electron backscatter diffraction were *** results indicate that the two-stage cryorolling and intermediate aging treatments led to the development of profuse twin bundles and significantly enhanced the mechanical *** initial cryorolling led to coplanar slip and developed a strong Y({111})orientation,accelerating the formation of Goss({011})orientation and a Brass-type *** intermediate aging treatment relieved the restriction on dislocation slip and reoriented the grains toward the Copper({112})and Z({111})*** Z orientation,with a relatively high volume fraction,dominated the *** cryorolling intensified twinning and shear banding,transforming the Copper-type shear bands into Brass-type shear bands with rhomboidal prism *** areas inside the Brasstype shear bands exhibited a Y orientation,and the areas outside the shear bands exhibited a stable Brass-type *** evident decrease in the weighted Schmid factors demonstrated that the two-stage cryorolling and intermediate aging treatment can modify the texture evolution and aid the design of high-performance Cu alloys.

关键词： Copper alloys Two-stage cryorolling Macrotexture evolution Electron backscatter diffraction Schmid factor

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Plant-derived nanovesicles as an emerging platform for cancer therapy

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Acta Pharmaceutica Sinica B 2024年第1期14卷 133-154页

作者： Hanzhe Liu guo-feng Luo Zhengjun Shang The State Key Laboratory Breeding Base of Basic Science of Stomatology(Hubei-MOST)&Key Laboratory of Oral Biomedicine Ministry of Education School and Hospital of StomatologyWuhan UniversityWuhan 430079China

Plant-derived nanovesicles(PDNVs)derived from natural green products have emerged as an attractive nanoplatform in biomedical *** are usually characterized by unique structural and biological functions,such as the bioactive lipids/proteins/nucleic acids as therapeutics and targeting groups,immune-modulation,and long-term *** the rapid development of nanotechnology,materials,and synthetic chemistry,PDNVs can be engineered with multiple functions for efficient drug delivery and specific killing of diseased cells,which represent an innovative biomaterial with high biocompatibility for fighting against *** this review,we provide an overview of the state-of-theart studies concerning the development of PDNVs for cancer *** original sources,methods for obtaining PDNVs,composition and structure are introduced *** an emphasis on the featured application,the inherent anticancer properties of PDNVs as well as the strategies in constructing multifunctional PDNVs-based nanomaterials will be discussed in ***,some scientific issues and technical challenges of PDNVs as promising options in improving anticancer therapy will be discussed,which are expected to promote the further development of PDNVs in clinical translation.

关键词： Naturally occurring nanovesicles Plant Nanotechnology Drug delivery Cancer therapy

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Chemical Synthesis of Globo H and Mannobiose Glycopolymers and their Immunological Stimulation

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Chinese Journal of Polymer Science 2024年第11期 1661-1667页

作者： zhi Zhang Ce-Ce Xue Ying-Le feng guo-Song Chen The State Key Laboratory of Molecular Engineering of Polymers and Department of Macromolecular Science Fudan University School of Chemistry and Chemical Engineering Shaanxi Normal University

Tumor-associated carbohydrate antigens(TACAs) provide a special class of tumor-specific antigens that show promising applications in cancer immunotherapy. However, the weak immunogenicity and structural complexity of TACAs are obstacles to their clinical ***, based on a fast and low-cost purification strategy for oligosaccharide synthesis, the synthesis of tumour-associated carbohydrate antigens Globo H and mannobiose which resembles repeat unit of mannan was achieved. To enhance the immunogenicity and multivalent effect, Globo H and mannobiose were covalently attached to degradable polymer backbones. 2D spindle-like lamellar micelle and globular micelle were obtained from glycopolymer through a solvent-exchange method of self-assembly. The glyconanoparticle showed good biocompatibility and degradability. Immunological functions of these glyconanoparticles such as stimulation of BMDC to cause upregulation of inflammatory factors were preliminarily explored.

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Design and implementation of a multi-tile parallel scanning rasterization accelerator

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The Journal of China Universities of Posts and Telecommunications 2024年第2期31卷 94-104页

作者： Xing Lidong guo Qiang Peng Xinlong feng Zhenfu School of Electronic Engineering Xi'an University of Posts and TelecommunicationsXi'an 710121China

In the design of a graphic processing unit(GPU),the processing speed of triangle rasterization is an important factor that determines the performance of the *** architecture of a multi-tile parallel-scan rasterization accelerator was proposed in this *** accelerator uses a bounding box algorithm to improve scanning *** rasterizes multiple tiles in parallel and scans multiple lines at the same time within each *** highly parallel approach drastically improves the performance of *** the 65 nm process standard cell library of Semiconductor Manufacturing International Corporation(SMIC),the accelerator can be synthesized to a maximum clock frequency of 220 *** implementation on the Genesys2 field programmable gate array(FPGA)board fully verifies the functionality of the *** implementation shows a significant improvement in rendering speed and efficiency and proves its suitability for high-performance rasterization.

关键词： graphic processing unit(GPU) rasterization multi-tile parallelism

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Accuracy improvement of geometric correction for CHRIS data

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Journal of Forestry Research 2008年第3期19卷 260-262页

作者： WANG Dian-zhong PANG Yong guo zhi-feng State Key Laboratory of Remote Sensing Science Jointly Sponsored by the Institute of Remote Sensing Applications of Chinese Academy of Sciences and Beijing Normal UniversityNo.3 Datun RoadBeijing 1O0101P.R.China Graduate School of Chinese Academy of Sciences Beijing 1O0039 P.R.China Institute of Forest Resource Information Technique Chinese Academy ofForestryBeijing 100091P.R.China

This paper deals with a new type of multi-angle remotely sensed data--CHRIS(the Compact High Resolution Imaging Spec-trometer),by using rational function models(RFM)and rigorous sensor models(RSM).For ortho-rectifying an image set,a rigorous sen-sor model-Toutin's model was employed and a set of reported parameters including across track angle,along track angle,IFOV,altitude,period,eccentricity and orbit inclination were input,then,the orbit calculation was started and the track information was given to the raw *** images were ortho-rectified with geocoded ASTER images and digital elevation(DEM)*** showed that with 16 ground control points(GCPs),the correction accuracy decreased with view zenith angle,and the RMSE value increased to be over one pixel at 36 degree *** the GCPs were approximately chosen as in Toutin's model,a RFM with three coefficients produced the same accuracy trend versus view zenith angle while the RMSEs for all angles were improved and within about one pixel.

关键词： CHRIS ortho-rectify rigorous sensor model rational function model

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