检索结果-南通市图书馆

Griseofulvin enantiomers and bromine-containing griseofulvin derivatives with antifungal activity produced by the mangrove endophytic fungus Nigrospora ***1

引用

Marine Life Science & technology 2024年第1期6卷 102-114页

作者： ge Zou Wencong Yang Tao Chen Zhaoming Liu Yan Chen Taobo Li Gulab Said Bing Sun Bo Wang Zhigang She School of Chemistry Sun Yat-sen UniversityGuangzhou 510275China State Key Laboratory of applied Microbiology Southern china Guangdong Provincial Key Laboratory of Microbial Culture Collection and ApplicationInstitute of MicrobiologyGuangdong Academy of SciencesGuangzhou 510070China School of Pharmacy Anhui Medical UniversityHefei 230032China Department of Chemistry Women University SwabiSwabi 23430Pakistan

Marine microorganisms have long been recognized as potential sources for drug *** was one of the first antifungal natural products and has been used as an antifungal agent for *** this study,12 new griseofulvin derivatives[(±)-1-2,(+)-3,(±)-4,10-12,and 14-15]and two new griseofulvin natural products(9 and 16)together with six known analogues[(-)-3,5-8,and 13]were isolated from the mangrove-derived fungus Nigrospora ***1 treated with 0.3%NaCl or 2%NaBr in rice solid *** 2D structures and absolute configurations were established by extensive spectroscopic analysis(1D and 2D NMR,HRESIMS),ECD spectra,computational calculation,DP4+analysis,and X-ray single-crystal *** 1-4 represent the first griseofulvin enantiomers with four absolute configurations(2S,6'S;2R,6'R;2S,6'R;2R,6'S),and compounds 9-12 represent the first successful production of brominated griseofulvin derivatives from fungi via the addition of NaBr to the culture *** the antifungal assays,compounds 6 and 9 demonstrated significant inhibitory activities against the fungi Colletotrichum truncatum,Microsporum gypseum,and Trichophyton mentagrophyte with inhibition zones varying between 28 and 41 mm(10μg/disc).The structure-activity relationship(SAR)was analyzed,which showed that substituents at C-6,C-7,C-6'and the positions of the carbonyl and double bond of griseofulvin derivatives significantly affected the antifungal activity.

关键词： Mangrove endophytic fungus Nigrospora sp. Griseofulvin Antifungal activity

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Rock joint detection from borehole imaging logs using a convolutional neural networks model

引用

Journal of Earth Science 2024年

作者： Yunfeng ge geng Liu Haiyan Wang Huiming Tang Binbin Zhao Faculty of Engineering， china University of geosciences Hunan Earthquake Agency Badong National Observation and Research Station of geohazards， china University of geosciences Research institute of Transmission and Transformation Projects， china Electric Power Research institute Co.， Ltd， State Grid Corporation of china

To map the rock joints in the underground rock mass， a method was proposed to semi-automatically detect the rock joints from borehole imaging logs using a deep learning algorithm. First， 450 images containing rock joints were selected from borehole ZKZ01 in the Rumei hydropower station. These images were labeled to establish ground truth which was subdivided into training， validation， and testing data. Second， the YOLO v2 model with optimal parameter settings was constructed. Third， the training and validation data were used for model training， while the test data was used to generate the Precision-Recall curve for prediction evaluation. Fourth， the trained model was applied to a new borehole ZKZ02 to verify the feasibility of the model. There were 12 rock joints detected from the selected images in borehole ZKZ02 and four geometric parameters for each rock joint were determined by sinusoidal curve fitting. The average precision of the trained model reached 0.87.

关键词：

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Engineering of Self-Supported Electrocatalysts on a Three-Dimensional Nickel Foam Platform for Efficient Water Electrolysis

引用

Transactions of Tianjin University 2024年第2期30卷 103-116页

作者： Ceneng Chen Xian Wang Zijun Huang Jiahui Mo Xiaoyan Zhang Chao Peng Mohamed Khairy Junjie ge Zhi Long Multiscale Crystal Materials Research Center Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China School of Chemistry and Materials Science University of Science and Technology of ChinaHefei 230026China Chemistry Department Faculty of ScienceSohag UniversitySohâg 82524Egypt Dalian National Laboratory for Clean Energy Dalian 116023China

Economical water electrolysis requires highly active non-noble electrocatalysts to overcome the sluggish kinetics of the two half-cell reactions,oxygen evolution reaction,and hydrogen evolution *** intensive efforts have been committed to achieve a hydrogen economy,the expensive noble metal-based catalysts remain under ***,the engineering of self-supported electrocatalysts prepared using a direct growth strategy on three-dimensional(3D)nickel foam(NF)as a conductive substrate has garnered significant *** is due to the large active surface area and 3D porous network offered by these electrocatalysts,which can enhance the synergistic eff ect between the catalyst and the substrate,as well as improve electrocatalytic ***-assisted growth,microwave heating,electrodeposition,and other physical methods(i.e.,chemical vapor deposition and plasma treatment)have been applied to NF to fabricate competitive electrocatalysts with low overpotential and high *** this review,recent advancements in the development of self-supported electrocatalysts on 3D NF are ***,we provide future perspectives of self-supported electrode platforms in electrochemical water splitting.

关键词： Nickel foam Water splitting Surface modification Hydrothermal method Microwave-assisted method Electrodeposition Chemical vapor deposition Plasma treatment

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Tumor microenvironment-responsive arsenic-loaded layered double hydroxides film with synergistic anticancer and bactericidal activity

引用

Rare Metals 2024年第3期43卷 1207-1221页

作者： Shun Xing Dong-Hui Wang Hai-Feng Zhang Li-Dan Liu Cheng-Ce Li Chao Wei Jun-Yu Liu Nai-Jian ge Xuan-Yong Liu State Key Laboratory of High Performance Ceramics and Superfine Microstructure Shanghai Institute of CeramicsChinese Academy of SciencesShanghai200050China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing100049China Intervention Center Eastern Hepatobiliary Surgery HospitalThe Third Affiliated Hospital of Naval Medical UniversityShanghai200438China School of Health Sciences and Biomedical Engineering Hebei University of TechnologyTianjin300130China

Malignant obstruction makes gallbladder cancer have a high mortality ***-titanium alloy(nitinol)stents are commonly used as a local intervention to maximize patient survival time,but the stents lack antitumor and antibacterial capacity and are vulnerable to secondary ***-based drugs show good therapeutic promise against gallbladder *** meet clinical *** layered double hydroxides(LDHs)film is constructed on the nitinol,whose arsenite loading amounts rose by 60%after simple heat treatment compared with the conventional anion-exchange *** addition,calcination promotes the dissolution of nickel ions from the LDHs lattice,resulting in a powerful synergistic killing effect on tumor cells together with the released *** importantly,the calcined arsenic-loaded LDHs are sensitive to the acidic microenvironment of tumor tissues,which presents a much lower arsenic and nickel release amount in the normal tissues,guaranteeing its ***,the vertically sharp LDHs nanosheets can synergize with arsenic to achieve effective physical cleavage and chemical killing of adherent and planktonic *** short,we attempt to use arsenic drugs for local interventions and reasonably avoid their toxic side effects,which provides a new design idea for nitinol stents applied in the treatment of gallbladder cancer.

关键词： Nitinol Layered double hydroxides Arsenic Gallbladder cancer

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Interface Engineering on Constructing Physical and Chemical Stable Solid-State Electrolyte Toward Practical Lithium Batteries

引用

Energy & Environmental Materials 2024年第4期7卷 28-47页

作者： Honggang He Litong Wang Malek Al-Abbasi Chunyan Cao Heng Li Zhu Xu Shi Chen Wei Zhang Ruiqing Li Yuekun Lai Yuxin Tang Mingzheng ge School of Textile and Clothing Nantong University School of Science Qingdao University of Technology Department of Biomedical Sciences City University of Hong Kong institute of applied Physics and Materials Engineering University of Macau College of Chemical Engineering Fuzhou University

Solid-state lithium batteries (SSLBs) with high safety have emerged to meet the increasing energy density demands of electric vehicles,hybrid electric vehicles,and portable electronic ***,the dendrite formation,high interfacial resistance,and deleterious interfacial reactions caused by solid-solid contact between electrode and electrolyte have hindered the commercialization of SSLBs.

关键词： dendrite formation high energy density interface instability interfacial resistance solid-state electrolyte

来源：

同方期刊数据库评论

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Hierarchical Self-assembly of Atomically Precise Au Nanoclusters with Molecular Rotor-based Ligands

引用

Chemical Research in Chinese Universities 2024年第4期40卷 670-674页

作者： WANG Guanzhong LU Hui LI Jiang WANG Lihua ZHU Ying SONG Shiping ge Zhilei LI Qian CHEN Jing FAN Chunhai Division of Physical Biology Shanghai Institute of Applied PhysicsChinese Academy of SciencesShanghai201800P.R.China University of Chinese Academy of Sciences Beijing100049P.R.China Zhangjiang Laboratory Shanghai201210P.R.China institute of Materiobiology Department of ChemistryCollege of SciencesShanghai UniversityShanghai200444P.R.China School of Chemistry and Chemical Engineering New Cornerstone Science LaboratoryFrontiers Science Center for Transformative MoleculesZhangjiang Institute for Advanced Study and National Center for Translational MedicineShanghai Jiao Tong UniversityShanghai200240P.R.China

The hierarchical assemblies of precise nanoparticles(NPs)have created materials with emergent properties and ***,the complex assemblies remain unclear at a precise ***,we show the hierarchical self-assembly of atomically precise gold nanoclusters(Au NCs)with molecular rotor-based ligands(MRL),featuring a double-layer *** to two other types of monolayer-protected(MLP)Au NCs,the significantly reduced surface density for MRL Au NCs profoundly influences their assembly behavior within the ***,the long length of rotor-based ligands and the rotational freedom of the phenyl-rings of rotor-based ligands also facilitate the assembly of *** works elucidate the hierarchical assembly on a precise scale,suggesting that the rotor-based ligand’s strategy offers promising potential for designing well-defined and more complex structures in supercrystals.

关键词： Gold nanocluster Molecular rotor Hierarchical assembly Double-layer surface

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Kac-系统与Morita等价

引用

数学学报（中文版） 2003年第5期46卷 943-950页

作者：张小霞郭懋正王永革烟台大学数学系北京大学数学系北京100871 北京航天航空大学应用数学系北京100083

本文讨论与Hilbert C*-模相关的Kac-系统在C*-代数上的作用的性质,给出了两个Morita等价的C*-代数(在Kac-系统的作用下得到的C*-代数的余交叉积是Morita等价的).从而,Baaj和Skandalis等人的结论是本文定理的特殊情况.

关键词： Hilbert C*-模 Kac-系统 Morita等价余交叉积

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

“嫦娥一号”任务全球地形实时仿真技术研究

引用

系统仿真学报 2009年第19期21卷 6135-6139页

作者：陈宏敏战守义刘涛唐歌实张伟北京理工大学计算机学院北京100081 北京航天飞行控制中心北京100094

针对"嫦娥一号"任务中航天器绕地球快速漫游的需求,设计了一种全球地形实时仿真技术。该技术采用建立静态层次细节模型和连续层次细节模型相结合的方法。运用逻辑四叉树结构组织全球海量数据的静态层次细节模型,满足海量地形数据的快速... 详细信息

针对"嫦娥一号"任务中航天器绕地球快速漫游的需求,设计了一种全球地形实时仿真技术。该技术采用建立静态层次细节模型和连续层次细节模型相结合的方法。运用逻辑四叉树结构组织全球海量数据的静态层次细节模型,满足海量地形数据的快速访问,并设计了数据更新算法,用以更新不同时相的地形数据;设计可见区域多细节层次数据块的快速确定算法实现全球地形的实时漫游,运用动态缓存调度策略提高了地形的绘制速度。实验表明,运用该技术实现了微机上全球地形的实时漫游。

关键词：航天飞行实验全球地形仿真四叉树实时漫游

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

In situ TEM investigation of electron irradiation and aging-induced high-density nanoprecipitates in an Mg-10Gd-3Y-1Zn-0.5Zr alloy

引用

Journal of Magnesium and Alloys 2024年第5期12卷 1841-1853页

作者： M.Lv H.L.ge Q.Q.Jin X.H.Shao Y.T.Zhou B.Zhang X.L.Ma Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of Sciences72 Wenhua RoadShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China Materials Science and Engineering Research Center Guangxi University of Science and TechnologyLiuzhou 545006China

In-situ electron irradiation and aging are applied to introduce high-density precipitates in an Mg-10Gd-3Y-1Zn-0.5Zr(GWZ1031K,wt.%)alloy to improve the *** results show that the hardness of the Mg alloy after irradiation for 10 h and aging for 9 h at 250℃ is 1.64 GPa,which is approximately 64% higher than that of the samples before being *** is mainly attributed to γ'precipitates on the basal plane after irradiation and the high-density nanoscale β'precipitates on the prismatic plane after aging,which should be closely related to the irradiation-induced homogenous *** latter plays a key role in precipitation *** result paves a way to improve the mechanical properties of metallic materials by tailoring the precipitation through irradiation and aging.

关键词： Mg alloy Electron beam irradiation Hardening Precipitates In-situ TEM

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Remote estimates of suspended particulate matter in global lakes using machine learning models

引用

International Soil and Water Conservation Research 2024年第1期12卷 200-216页

作者： Zhidan Wen Qiang Wang Yue Ma Pierre Andre Jacinthe ge Liu Sijia Li Yingxin Shang Hui Tao Chong Fang Lili Lyu Baohua Zhang Kaishan Song Northeast institute of geography and Agroecology CASChangchunJilin130102China Department of geology Indiana University∼Purdue UniversityIndianapolisIN44602USA University of Chinese Academy of Sciences Beijing100100China College of geography and Urban Planning Liaocheng UniversityLiaochengChina

Suspended particulate matter(SPM)in lakes exerts strong impact on light propagation,aquatic ecosystem productivity,which co-varies with nutrients,heavy metal and micro-pollutant in *** lakes,SPM exerts strong absorption and backscattering,ultimately affects water leaving signals that can be detected by satellite *** regression models based on specific band or hand ratios have been widely used for SPM estimate in the past with moderate *** are still rooms for model accuracy improvements,and machine learning models may solve the non-linear relationships between spectral variable and SPM in *** assembled more than 16,400 in situ measured SPM in lakes from six continents(excluding the Antarctica continent),of which 9640 samples were matched with Landsat overpasses within±7 *** machine learning algorithms and two simple regression methods(linear and partial least squares models)were used to estimate SPM in lakes and the performance were *** overcome the problem of imbalance datasets in regression,a Synthetic Minority Over-Sampling technique for regression with Gaussian Noise(SMOGN)was adopted in this *** comparison,we found that gradient boosting decision tree(GBDT),random forest(RF),and extreme gradient boosting(XGBoost)models demonstrated good spatiotemporal transferability with SMOGN processed dataset,and has potential to map SPM at different year with good quality of Landsat land surface reflectance *** all the tested modeling approaches,the GBDT model has accurate calibration(n=6428,R^(2)=0.95,MAPE=29.8%)from SPM collected in 2235 lakes across the world,and the validation(n=3214,R^(2)=0.84,MAPE=38.8%)also exhibited stable ***,the good performances were also exhibited by RF model with calibration(R^(2)=0.93)and validation(R^(2)=0.86,MAPE=24.2%)*** applied GBDT and RF models to map SPM of typical lakes,and satisfactory result was *** addition,the GBDT model was evaluated b

关键词： Landsat imagery Remote estimation SPM Transferability

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：