检索结果-南通市图书馆

Recent advances in 3D-printable aggregation-induced emission materials

在线全文

学校读者我要写书评

暂无评论

Materials Futures 2024年第4期3卷 22-40页

作者： Mingtao Zhang yu Li Guangmeng Ma Fawei Guo Haixin wu Han wu Qingxin Jin xin Luo Chunyi Luo Jiaqi Li yu Long State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Guangxi UniversityNanning 530004People’s Republic of China Institute of Laser Intelligent Manufacturing and Precision Processing School of Mechanical EngineeringGuangxi UniversityNanning 530004People’s Republic of China

Aggregation-induced emission(AIE)materials exhibit remarkable emission properties in the aggregated or solid states,offering numerous advantages such as high quantum yield,excellent photostability,and low background *** characteristics have led to their widespread application in optoelectronic devices,bio-detection markers,chemical sensing,and stimuli-responsive applications among *** contrast to traditional manufacturing processes,3D printing(3DP)enables rapid prototyping and large-scale customization with excellent flexibility in manufacturing techniques and material *** combination of AIE materials with 3DP can provide new strategies for fabricating materials and devices with complex ***,3DP is an ideal choice for processing AIE organic luminescent ***,3DP of AIE materials is still in the early stages of development and is facing many challenges including limited printable AIE materials,poor printing functionalities and limited application *** review aims to summarize the significant achievements in the field of 3DP of AIE ***,different types of AIE materials for 3DP are studied,and the factors that affect the printing effect and the luminescence mechanism are ***,the latest advancements made in various application domains using 3D printed AIE materials are ***,the existing challenges of this emerging field are discussed while the future prospects are prospected.

关键词： 3D printing aggregation-induced emission luminescent materials process monitoring

Photoinduced Dehalocyclization to Access Oxindoles Using Formate as a Reductant

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Chemistry 2024年第11期42卷 1203-1208页

作者： Wei ge Jia-xin Wang Ming-Chen Fu Yao Fu Hefei National Research Center for Physical Sciences at the Microscale iChEMCAS Key Laboratory of Urban Pollutant ConversionAnhui Province Key Laboratory of Biomass Clean EnergyUniversity of Science and Technology of ChinaHefeiAnhui230026 China Anhui Province Key Laboratory of Value-Added Catalytic Conversion and Reaction Engineering Hefei University of TechnologyHefeiAnhui230009 China

Herein,we report an efficient and practical protocol for the photoinduced dehalocyclization of ortho-halophenylacrylamides with formate by the engagement of a CO_(2) radical anion to access substituted *** method proceeds smoothly under mild conditions and exhibits a wide range of substrate as well as remarkable functional group compatibility.

关键词： Formate CO_(2)Radical ions Oxindole Photocatalysts Cyclization Organohalides

Controllable nucleation and deformation of skyrmions on surface of magnetic nanotubular monolayer

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Rare Metals 2024年第7期43卷 3250-3259页

作者： xin-xin Zhang Chen-yu Zhang Yi-xin xing Chao Man Jiao Liu Yong Hu Department of Physics College of SciencesNortheastern UniversityShenyang 110819China School of Materials and Mineral Resources Engineering Universiti Sains MalaysiaEngineering Campus14300 Nibong TebalPenangMalaysia State Key Laboratory of Rolling and Automation Northeastern UniversityShenyang110819China

Magnetic skyrmions emerge when the energy of ferromagnetic exchange interaction promoting parallel alignment of spins enters in competition with energies favoring non-collinear alignment of spins such as Dzy aloshinskii-Moriya interaction(DMI),long-rang dipole-dipole interaction(DDI),or higher-order exchange *** perform an unbiased Monte Carlo simulation to study the DMI-based skyrmion nucleation and stabilization on the surface of magnetic nanotubular monolayer controlled by tuning constants of DDI(g) and next-nearest-neighbor antiferromagnetic exchange interaction(j') with appropriate *** g and j',the loosely distributed skyrmions initially nucleate on the surface of nanotube approaching to the magnetic field(h) direction with increasing h in the intermediate ***,the skyrmion size,shape,density,distribution and crystal structure,as well as its driven field range,are tailored by g and j'.This work demonstrates the skyrmion nucleation mechanisms in three-dimensional magnetic nanostructures with curvature effect and multiple interactions,serving as a benchmark for a guide to experimentalists for preparation of samples in magnetic skyrmion states.

关键词： Magnetic nanotube Magnetic skyrmion Dzyaloshinskii-Moriya interaction Dipole-dipole interaction Monte Carlo simulation

EG-STC: An Efficient Secure Two-Party Computation Scheme Based on Embedded GPU for Artificial Intelligence Systems

在线全文

学校读者我要写书评

暂无评论

Computers, Materials & Continua 2024年第6期79卷 4021-4044页

作者： Zhenjiang Dong xin ge yuehua Huang Jiankuo Dong Jiang Xu School of Computer Science Nanjing University of Posts and TelecommunicationsNanjing210023China School of Computer Nanjing University of Information Science and TechnologyNanjing210044China

This paper presents a comprehensive exploration into the integration of Internet of Things(IoT),big data analysis,cloud computing,and Artificial Intelligence(AI),which has led to an unprecedented era of *** delve into the emerging trend of machine learning on embedded devices,enabling tasks in resource-limited ***,the widespread adoption of machine learning raises significant privacy concerns,necessitating the development of privacy-preserving *** such technique,secure multi-party computation(MPC),allows collaborative computations without exposing private *** its potential,complex protocols and communication interactions hinder performance,especially on resource-constrained *** to enhance efficiency have been made,but scalability remains a *** the success of GPUs in deep learning,lever-aging embedded GPUs,such as those offered by NVIDIA,emerges as a promising ***,we propose an Embedded GPU-based Secure Two-party Computation(EG-STC)framework for Artificial Intelligence(AI)*** the best of our knowledge,this work represents the first endeavor to fully implement machine learning model training based on secure two-party computing on the Embedded GPU *** experimental results demonstrate the effectiveness of *** an embedded GPU with a power draw of 5 W,our implementation achieved a secure two-party matrix multiplication throughput of 5881.5 kilo-operations per millisecond(kops/ms),with an energy efficiency ratio of 1176.3 kops/ms/***,leveraging our EG-STC framework,we achieved an overall time acceleration ratio of 5–6 times compared to solutions running on server-grade *** solution also exhibited a reduced runtime,requiring only 60%to 70%of the runtime of previously best-known methods on the same *** summary,our research contributes to the advancement of secure and efficient machine learning implementations on resource-constrained embedded

关键词： Secure two-party computation embedded GPU acceleration privacy-preserving machine learning edge computing

Novel high-voltage cathode for aqueous zinc ion batteries:Porous K_(0.5)VOPO_(4)·1.5H_(2)O with reversible solid-solution intercalation and conversion storage mechanism

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2024年第6期93卷 71-78,I0003页

作者： Liyu Wang Mingliang Zhao Xiaoyu Zhang Menghua wu yu Zong yu Chen xinliang Huang Mingjie xing xin Ning Wen Wen Daming Zhu Xiaochuan Ren Industrial Research Institute of Nonwovens&Technical Textiles College of Textiles&ClothingShandong Engineering Research Center for Specialty Nonwoven MaterialsQingdao UniversityQingdao 266071ShandongChina Shanghai Synchrotron Radiation Facility Shanghai Advanced Research InstituteChinese Academy of SciencesShanghai 201204China

Cathode materials that possess high output voltage,as well as those that can be mass-produced using facile techniques,are crucial for the advancement of aqueous zinc-ion battery(ZIBs)applications,Herein,we present for the first time a new porous K_(0.5)VOPO_(4)·1.5H_(2)O polyanionic cathode(P-KIVP)with high output voltage(above 1.2 V)that can be manufactured at room temperature using straightforward coprecipitation and etching *** P-KVP cathode experiences anisotropic crystal plane expansion via a sequential solid-solution intercalation and phase co nversion pathway throughout the Zn^(2+)storage process,as confirmed by in-situ synchrotron X-ray diffraction and ex-situ X-ray photoelectron *** to other layered vanadium-based polyanionic materials,the P-KVP cathode experiences a progressive decline in voltage during the cycle,which is demonstrated to be caused by the irreversible conversion into amorphous VO_(x).By introducing a new electrolyte containing Zn(OTF)_(2) to a mixed triethyl phosphate and water solution,it is possible to impede this irreversible conversion and obtain a high output voltage and longer cycle life by forming a P-rich cathode electrolyte interface *** a proof-of-concept,the flexible fiber-shaped ZIBs based on modified electrolyte woven into a fabric watch band can power an electronic watch,highlighting the application potential of P-KVP cathode.

关键词： Aqueous zinc ion battery Cathode Porous material High voltage platform In-situ synchrotron X-ray diffraction

Recent progress in ionic liquid-based electrolytes for nonaqueous and aqueous metal batteries

在线全文

学校读者我要写书评

暂无评论

eScience 2024年第2期4卷 57-69页

作者： xin wu Yao Dai Nian wu Li Xiao Chun Chen Le yu State Key Lab of Organic-Inorganic Composites Beijing University of Chemical TechnologyBeijing 100029PR China College of Chemical Engineering Beijing University of Chemical TechnologyBeijing 100029PR China

Nonaqueous Li metal batteries(LMBs)and aqueous Zn metal batteries(ZMBs)are promising next-generation secondary batteries owing to their high energy *** an appropriate electrolyte is critical for addressing the safety issues nonaqueous and aqueous metal batteries can *** liquids(ILs)have been widely used in secondary metal batteries because they are non-flammable,present good thermal stability,and have wide electrochemical *** review highlights the research progress on IL-based electrolytes for stable Li/Zn metal *** focus particularly on these electrolytes'electrochemistry and functionalities at the electrolyte/anode interface for inhibiting dendrite growth,preventing side reactions,and enhancing electrochemical *** is expected that this review will shed some light on the development of ILs for nextgeneration metal batteries.

关键词： Ionic liquids Electrolytes Li metal batteries Zn metal batteries Surface engineering

One more step to realistic CO_(2) reduction reactions——geometric structures evolutions at gas-solid interface

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Rare Metals 2024年第2期43卷 849-852页

作者： Ya-Qiang Xie xin yu Ting Wang College of the Environment and Ecology Xiamen UniversityXiamen361102China

A rational design of copper(Cu)nanocatalyst is critical to the efficient carbon dioxide(CO_(2))conversion toward C1/C2 chemical ***,the lack of actual information on the vicinal Cu interfaces hinders the intrinsic activitystructure correlation *** with atomic-scale in situ characterizations(AP-STM and synchrotron-based AP-XPS),Park and co-workers study and identify the adsorbate-driven morphological evolution of Cu nanoclusters on the Cu(997)surface,providing real-space evidence for the critical role of vicinal structures on Cu *** observed surface roughening trends caused by dissociated atomic oxygen and CO adsorbates subsequently affect the result of successive catalytic reactions to produce critical intermediates,such as carbonate and formate,during the CO_(2)reduction reaction.

关键词： reaction critical rational

Highly selective electrosynthesis of 3,4-dihydroisoquinoline accompanied with hydrogen production over three-dimensional hollow CoNi-based microarray electrocatalysts

在线全文

学校读者我要写书评

暂无评论

Nano Research 2024年第4期17卷 2509-2519页

作者： yu xin Liyu Chen Yingwei Li Kui Shen Guangdong Provincial Key Lab for Green Chemical Product Technology School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640China State Key Laboratory of Pulp and Paper Engineering School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhou 510640China

Electrocatalytic oxidation reaction of biomass-based derivatives is an excellent candidate to replace water oxidation for obtaining both value-added products and hydrogen(H_(2)),but the exploration of competent electrocatalysts is still highly ***,two new types of three-dimensional self-supported hollow microarrays containing CoNi layered double hydroxide(CoNi-LDH)and N-doped carbon nanosheets decorated with CoNi alloyed nanoparticles(CoNi-NC)on carbon cloth(CC)are prepared,which are further used as efficient electrocatalysts for tetrahydroisoquinoline(THIQ)electrooxidation and hydrogen evolution reaction(HER),*** demonstrate that the Co-modulated electronic environment for Ni(II)/Ni(Ⅲ)redox-looping in CoNi-LDH is the main factor to boost the selectivity of 3,4-dihydroisoquinoline(DHIQ)for the indirect electrooxidation process of *** functional theory(DFT)calculations reveal that the Ni(Ⅲ)/Co(Ⅲ)dual sites of CoNi-LDH exhibit enhanced adsorption for THIQ but poorer adsorption for DHIQ compared to pure Co(Ⅲ)or Ni(Ⅲ).Therefore,the Ni(Ⅲ)/Co(Ⅲ)dual sites can effectively inhibit the peroxidation of DHIQ to isoquinoline(IQ)over CoNi-LDH,thus improving the selectivity of DHIQ to nearly 100%,much higher than that of its pure Ni ***,CC@CoNi-NC can deliver high HER activity with low overpotential(40 mV@10 mA·cm^(-2))and high exchange current density(3.08 mA·cm^(-2)).Impressively,the assembled flow-cell device with CC@CoNi-LDH anode and CC@CoNi-NC cathode only requires low cell voltage and electricity consumption of 1.6 V and 3.50 kWh per cubic meter of H_(2)(@25 mA·cm^(-2)).

关键词： highly selective electrosynthesis dihydroisoquinolines hydrogen evolution reaction metal-organic frameworks hollow microarrays

Nonlinear metamaterial enabled aeroelastic vibration reduction of a supersonic cantilever wing plate

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Applied Mathematics and Mechanics(English Edition) 2024年第10期45卷 1749-1772页

作者： Peng SHENG xin FANG Dianlong yu Jihong WEN Laboratory of Science and Technology on Integrated Logistics Support College of Intelligence Science and TechnologyNational University of Defense TechnologyChangsha 410073China

The violent vibration of supersonic wings threatens aircraft *** paper proposes the strongly nonlinear acoustic metamaterial(NAM)method to mitigate aeroelastic vibration in supersonic wing *** employ the cantilever plate to simulate the practical behavior of a *** aeroelastic vibration model of the NAM cantilever plate is established based on the mode superposition method and a modified third-order piston *** aerodynamic properties are systematically studied using both the timedomain integration and frequency-domain harmonic balance *** presenting the flutter and post-flutter behaviors of the NAM wing,we emphasize more on the preflutter broadband vibration that is prevalent in *** results show that the NAM method can reduce the low-frequency and broadband pre-flutter steady vibration by 50%-90%,while the post-flutter vibration is reduced by over 95%,and the critical flutter velocity is also slightly *** clarified,the significant reduction arises from the bandgap,chaotic band,and nonlinear resonances of the NAM *** reduction effect is robust across a broad range of parameters,with optimal performance achieved with only 10%attached *** work offers a novel approach for reducing aeroelastic vibration in aircraft,and it expands the study of nonlinear acoustic/elastic metamaterials.

关键词： nonlinear acoustic metamaterial(NAM) hypersonic aeroelastic vibration vibration reduction fluid-structure interaction