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Atmospheric chemistry of trifluorodicarbonyls initiated by Cl atoms:Reactivity trends,mechanism,and acid formation yields

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Journal of Environmental Sciences 2025年第5期151卷 12-25页

作者： Pedro L.Lugo Vianni g.Straccia Cynthia b.Rivela Mariano A.Teruel María b.blanco Laboratorio Universitario de Química y Contaminación del Aire(L.U.Q.C.A) Instituto de Investigaciones en Fisicoquímica de Córdoba(I.N.F.I.Q.C.)Dpto.de Fisicoquímica.Facultad de Ciencias QuímicasUniversidad Nacional de Córdoba.Ciudad Universitaria5000 CórdobaArgentina Institute for Atmospheric and Environmental Research University of WuppertalDE-42097 WuppertalGermany

Rate coefficients of the gas-phase reactions of Cl atoms with a series of fluorinated diketones(FDKs):CF_(3)C(O)CH_(2)C(O)CH_(3)(TFP),CF_(3)C(O)CH_(2)C(O)CH_(2)CH_(3)(TFH)and CF_(3)C(O)CH_(2)C(O)CH(CH_(3))2(TFMH),have been measured at(298±2)K and under atmospheric *** experiments were performed using the relative-rate method with a gC-FID detection *** different determinations and references used,the following rate coefficients were obtained(in cm3/(molecule·sec)):k_(4)(TFP+Cl)=(1.75±0.21)×10^(−10),k_(5)(TFH+Cl)=(2.05±0.23)×10^(−10),k_(6)(TFMH+Cl)=(2.71±0.34)×10^(−10).Reactivity trends of FDKs were discussed and Free Energy Relationships analysis was *** expression lgkOH=1.68 lgkCl+5.71 was obtained for the reactivity of the studied FDKs together with similar unsaturated VOCs with Cl and OH radicals Additionally,acetic acid(CH_(3)C(O)OH)and trifluoroacetic acid(CF_(3)C(O)OH)were positively identified and quantified as degradation products using in situ FTIR *** to the identified products,atmospheric chemical mechanisms were *** atmospheric implications of the studied reactions were assessed by the estimation of the tropospheric lifetimes of TFP,TFH,and TFMH concerning their reaction with Cl atoms to be 48,41,and 31 hours,*** relatively short residence in the atmosphere of the fluorocarbons studied will have a local/regional impact with restricted *** warming potential(gWP(20 yr))calculated for the studied fluoro diketones were 0.014,0.003 and 0.001 for TFP,TFH and TFMH,respectively with a negligible contribution to the greenhouse effect.

关键词： Fluorinated diketones Kinetics SPME-gC-FID FTIR in situ SAR Free energy relationships

Hydrogen production from dry reforming of methane,using CO_(2)previously chemisorbed in the Li_(6)Zn_(1-x)ni_(x)O_(4)solid solution

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Journal of Environmental Sciences 2025年第3期149卷 535-550页

作者： Yocelin b.gonzález-gonzález Fernando Plascencia-Hernández Rubén Mendoza-Cruz Heriberto Pfeiffer Instituto de Investigaciones en Materiales Universidad Nacional Autónoma de MéxicoCircuito exterior s/nCiudad UniversitariaDel.CoyoacánCP 04510CdMxMexico

Li_(6)ZnO_(4)was chemically modified by nickel addition,in order to develop different compositions of the solid solution Li_(6)Zn_(1-x)ni_(x)O_(4).These materials were evaluated bifunctionally;analyzing their CO_(2)capture performances,aswell as on their catalytic properties for H_(2)production via dry reforming of methane(DRM).The crystal structures of Li_(6)Zn_(1-x)ni_(x)O_(4)solid solution samples were determined through X-ray diffraction,which confirmed the integration of nickel ions up to a concentration around 20 mol%,meanwhile beyond this value,a secondary phase was *** results were supported by XPS and TEM ***,dynamic and isothermal thermogravimetric analyses of CO_(2)capture revealed that Li_(6)Zn_(1-x)ni_(x)O_(4)solid solution samples exhibited good CO_(2)chemisorption efficiencies,similarly to the pristine Li_(6)ZnO_(4)chemisorption trends ***,a kinetic analysis of CO_(2)isothermal chemisorptions,using the Avrami-Erofeev model,evidenced an increment of the constant rates as a function of the ni *** ni^(2+)ions incorporation did not reduce the CO_(2)capture efficiency and kinetics,the catalytic properties of thesematerialswere evaluated in the DRM *** demonstrated that nickel ions favored hydrogen(H_(2))production over the pristine Li_(6)ZnO_(4)phase,despite a second H2 production reaction was determined,methane ***,Li_(6)Zn_(1-x)ni_(x)O_(4)ceramics can be employed as bifunctional materials.

关键词： Dry reforming of methane(DRM) CO_(2)chemisorption H_(2)production Solid solution Li_(6)ZnO_(4)

Unveiling urbanization effects on trees outside forests along the urban-rural gradient in megacity bengaluru

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FOREST ECOSYSTEMS 2025年第1期12卷 56-65页

作者： Jiang, Tao Freudenberg, Maximilian Kleinn, Christoph Tewari, V. P. Diwakara, b. n. noelke, nils Univ gottingen Fac Forest Sci & Forest Ecol Forest Inventory & Remote Sensing Dept Gottingen Germany ICFRE Himalayan Forest Res Inst Shimla India IWST Inst Wood Sci & Technol Bengaluru India

Rapid urbanization has caused significant changes along the urban-rural gradient, leading to a variety of landscapes that are mainly shaped by human activities. This dynamic interplay also influences the distribution and characteristics of trees outside forests (TOF). Understanding the pattern of these trees will support informed decision-making in urban planning, in conservation strategies, and altogether in sustainable land management practices in the urban context. In this study, we employed a deep learning-based object detection model and high resolution satellite imagery to identify 1.3 million trees with bounding boxes within a 250 km2 research transect spanning the urban-rural gradient of bengaluru, a megacity in Southern India. Additionally, we developed an allometric equation to estimate diameter at breast height (DbH) from the tree crown diameter (CD) derived from the detected bounding boxes. Our study focused on analyzing variations in tree density and tree size along this gradient. The findings revealed distinct patterns: the urban domain displayed larger tree crown diameters (mean: 8.87 m) and DbH (mean: 43.78 cm) but having relatively low tree density (32 trees per hectare). Furthermore, with increasing distance from the city center, tree density increased, while the mean tree crown diameter and mean tree basal area decreased, showing clear differences of tree density and size between the urban and rural domains in bengaluru. This study offers an efficient methodology that helps generating instructive insights into the dynamics of TOF along the urban-rural gradient. This may inform urban planning and management strategies for enhancing green infrastructure and biodiversity conservation in rapidly urbanizing cities like bengaluru.

关键词： Individual tree detection Urbanization Tree density Tree crown diameter

Unveiling urbanization effects on trees outside forests along the urban-rural gradient in megacity bengaluru

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Forest Ecosystems 2025年第01期 56-65页

作者： Tao Jiang Maximilian Freudenberg Christoph Kleinn V.P.Tewari b.n.Diwakara nils n?lke Forest Inventory and Remote Sensing Department Faculty of Forest Sciences and Forest Ecology University of G?ttingen Himalayan Forest Research Institute ICFRE Institute of Wood Science and Technology IWST

Rapid urbanization has caused significant changes along the urban-rural gradient, leading to a variety of landscapes that are mainly shaped by human activities. This dynamic interplay also influences the distribution and characteristics of trees outside forests(TOF). Understanding the pattern of these trees will support informed decision-making in urban planning, in conservation strategies, and altogether in sustainable land management practices in the urban context. In this study, we employed a deep learning-based object detection model and high resolution satellite imagery to identify 1.3 million trees with bounding boxes within a 250 km2research transect spanning the urban-rural gradient of bengaluru, a megacity in Southern India. Additionally, we developed an allometric equation to estimate diameter at breast height(DbH) from the tree crown diameter(CD) derived from the detected bounding boxes. Our study focused on analyzing variations in tree density and tree size along this gradient. The findings revealed distinct patterns: the urban domain displayed larger tree crown diameters(mean:8.87 m) and DbH(mean: 43.78 cm) but having relatively low tree density(32 trees per hectare). Furthermore,with increasing distance from the city center, tree density increased, while the mean tree crown diameter and mean tree basal area decreased, showing clear differences of tree density and size between the urban and rural domains in bengaluru. This study offers an efficient methodology that helps generating instructive insights into the dynamics of TOF along the urban-rural gradient. This may inform urban planning and management strategies for enhancing green infrastructure and biodiversity conservation in rapidly urbanizing cities like bengaluru.

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green ionic metal-organic frameworks as nanocatalysts for CO_(2)fixation

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nano Research 2025年第1期18卷 260-269页

作者： nuria Martín Miguel Maireles-Porcar Julián Sánchez Velandia belén Altava Francisco g.Cirujano Eduardo garcía-Verdugo Departamento de Química Inorgánica y Orgánica Universidad Jaume IAv.Sos Baynats/nCastellóde la PlanaCastellón 12071Spain

Co,ni,and Zn iso-reticular coordination polymers of 2,5-dihydroxyterphthalic acid(H_(2)dot)can be rapidly obtained under room temperature and aqueous conditions using either sodium or ammonium hydroxide as the bases to deprotonate the *** use of metal bromides and tetrabutylammonium hydroxide(TbAOH)as the base allows the green synthesis of ionic metal-organic frameworks(MOFs),characterized by X-ray diffraction(XRD),Fourier transform infrared(FTIR),scanning electron microscopy(SEM),thermo gravimetric analysis(TgA),H-nuclear magnetic resonance(nMR),elemental analysis,and X-ray photoelectron spectroscopy(XPS),and employed in the pressure,solvent,and additive-free CO_(2)fixation to epoxides by its cycloaddition to epichlorohydrin,exhibiting a cooperative behavior between the MOF and the ionic liquid formed within the framework,achieving TOns of the confined tetrabutylammonium bromide(TbAbr)up to 700.

关键词： metal-organic frameworks(MOFs) ionic liquids heterogeneous catalysis CO_(2)conversion

nano-Enhanced Dairy Scum biodiesel blends:Unleashing the Power of Aluminium Oxide for Sustainable and Efficient Engine Performance

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Journal of Thermal Science 2025年第1期34卷 283-302页

作者： Veeranna MODI Prasad b.RAMPURE Sunil Kumar SHETTY Madeva nAgARAL Channa Keshava nAIK n Johar MgM Muhammad Irsyad AbDULLAH Abdullah I.AL-MAnSOUR Shamshad ALAM KLE College of Engineering and Technology ChikodiVisvesvaraya Technological UniversityBelagavi 590018KarnatakaIndia nitte(Deemed to be University) NMAM Institute of Technology(NMAMIT)Department of Mechanical EngineeringNitte 574110India Aircraft Research and Design Centre HALBangalore 560037KarnatakaIndia Department of Mechanical Engineering BGS College of Engineering and TechnologyBengaluruAffiliated to Visvesvaraya Technological UniversityBelagaviIndia Management and Science University Selangor Darul EhsanMalaysia Department of Civil Engineering College of EngineeringKing Saud UniversityRiyadh-11421Saudi Arabia

This study investigates the effect of aluminium oxide nanoparticlesaddition to biodiesel blends made from dairy milk scum on performance and combustion characteristics of the diesel *** dispersion of Al_(2)O_(3)nanoparticles in b20 blends at different concentrations was done with the help of *** number of blends were prepared for the *** Machine learning algorithms(Random Forest(RF)and Catboost)was used for the *** results show that in comparison to biodiesel blends without nanoparticles,the kinematic viscosity and density is higher for fuel blends with *** these Fuel blends have higher calorific *** blends exhibited reduced brake Specific Fuel Consumption(bSFC)of 2.85% than the blends without nano particles(Dairy Scum Methyl Ester biodiesel 20%+neat Diesel 80%(in volume),DSMEb20),57.14%less CO,40.8% less hydrocarbon,and increased nO_(x)emissions compared to conventional diesel,contributing to the development of environmentally friendly and renewable biofuel blends with *** b20nP30 is the optimal blend for performance and emission *** study concludes with findings on enhanced brake Thermal Efficiency(bTE)of 26.29% in 3×10^(-5)(in volume)Al_(2)O_(3)nanoparticle-blended DSME b20 and other DSME b20 fuel blends,emphasizing the importance of optimal nanoparticle *** correlation matrix shows how engine load,efficiency measures(bTE,bSFC),and emissions(CO,CO_(2),nO_(x),Smoke)are connected in complex *** results help us understand the complicated dynamics of engine performance and emission characteristics ***'s diagram for bTE and bSFC shows that Catboost-based bTE models perform superior to RF-based models during the training as well as testing *** results were obtained for CO and CO_(2)emission results.

关键词： Dairy Scum Methyl Ester biodiesel CI engine Al_(2)O_(3)concentration

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Silk-based nerve guidance conduits with macroscopic holes modulate the vascularization of regenerating rat sciatic nerve

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neural Regeneration Research 2025年第6期20卷 1789-1800页

作者： Carina Hromada Patrick Heimel Markus Kerbl Lászlógál Sylvia nürnberger barbara Schaedl James Ferguson nicole Swiadek Xavier Monforte Johannes C.Heinzel Antal nógrádi Andreas H.Teuschl-Woller David Hercher Department Life Science Engineering University of Applied Sciences Technikum WienViennaAustria Austrian Cluster for Tissue Regeneration ViennaAustria Ludwig boltzmann Institute for Traumatology The Research Center in Cooperation with AUVAViennaAustria University Clinic of Dentistry Medical University of ViennaViennaAustria Department of Plastic Reconstructive and Aesthetic SurgeryLandesklinikum Wiener Neustadt2700 Wiener NeustadtAustria Department of Anatomy Histology and EmbryologyAlbert Szent-Györgyi Medical SchoolUniversity of SzegedSzegedHungary Medical University of Vienna Department of Orthopedics and Trauma SurgeryDevision of Trauma SurgeryViennaAustria Department of Hand- PlasticReconstructive and Burn SurgeryBG Unfallklinik TuebingenUniversity of TuebingenTuebingenGermany

Peripheral nerve injuries induce a severe motor and sensory deficit. Since the availability of autologous nerve transplants for nerve repair is very limited, alternative treatment strategies are sought, including the use of tubular nerve guidance conduits(tngCs). However, the use of tngCs results in poor functional recovery and central necrosis of the regenerating tissue, which limits their application to short nerve lesion defects(typically shorter than 3 cm). given the importance of vascularization in nerve regeneration, we hypothesized that enabling the growth of blood vessels from the surrounding tissue into the regenerating nerve within the tngC would help eliminate necrotic processes and lead to improved regeneration. In this study, we reported the application of macroscopic holes into the tubular walls of silk-based tngCs and compared the various features of these improved silk^(+) tngCs with the tubes without holes(silk^(–) tngCs) and autologous nerve transplants in an 8-mm sciatic nerve defect in rats. Using a combination of micro-computed tomography and histological analyses, we were able to prove that the use of silk^(+) tngCs induced the growth of blood vessels from the adjacent tissue to the intraluminal neovascular formation. A significantly higher number of blood vessels in the silk^(+) group was found compared with autologous nerve transplants and silk^(–), accompanied by improved axon regeneration at the distal coaptation point compared with the silk^(–) tngCs at 7 weeks postoperatively. In the 15-mm(critical size) sciatic nerve defect model, we again observed a distinct ingrowth of blood vessels through the tubular walls of silk^(+) tngCs, but without improved functional recovery at 12 weeks postoperatively. Our data proves that macroporous tngCs increase the vascular supply of regenerating nerves and facilitate improved axonal regeneration in a short-defect model but not in a critical-size defect model. This study suggests that further optimizatio

关键词： axon regeneration blood vessel functional recovery macroporous nerve lesion peripheral nerve repair sciatic nerve silk-based nerve guidance conduit vascularization

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Association of the glycemic background patterns and the diabetes management efficacy in poorly controlled type 2 diabetes

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World Journal of Diabetes 2025年第1期16卷 74-90页

作者： Ayşe n Erbakan Müzeyyen Arslan bahadır Fatoşn Kaya büşra güleç MiraçVural Keskinler Ümmügülsüm AktemurÇelik Özge Faydalıel banu Mesçi Aytekin Oğuz Department of Internal Medicine Prof Dr Suleyman Yalcin City HospitalIstanbul Medeniyet UniversityIstanbul 34722Türkiye Department of Family Medicine Istanbul Medeniyet UniversityIstanbul 34722Türkiye

bACKgROUnD Inadequate glycemic control in patients with type 2 diabetes(T2DM)is a major public health problem and a significant risk factor for the progression of diabetic *** To evaluate the effects of intensive and supportive glycemic management strategies over a 12-month period in individuals with T2DM with glycated hemoglobin(HbA1c)≥10%and varying backgrounds of glycemic *** This prospective observational study investigated glycemic control in patients with poorly controlled T2DM over 12 *** were categorized into four groups based on prior glycemic history:newly diagnosed,previously well controlled with recent worsening,previously off-target but now worsening,and HbA1c consistently above 10%.HbA1c levels were monitored quarterly,and patients received medical,educational,and dietary support as *** analysis focused on the success rates of good glycemic control and the associated factors within each *** The study showed significant improvements in HbA1c levels in all *** most significant improvement was observed in individuals newly diagnosed with diabetes:65%achieved an HbA1c target of≤7%.The results varied between participants with different glycemic control histories,followed by decreasing success rates:39%in participants with previously good glycemic control,21%in participants whose glycemic control had deteriorated compared to before,and only 10%in participants with persistently poor control,with mean HbA1c levels of 6.3%,7.7%,8.2%,and 9.7%,*** one year,65.2%of the“newly diagnosed patients”,39.3%in the“previously controlled group”,21.9%in the“previously off-target but now worsened'”group and 10%in the“poorly controlled from the start”group had achieved HbA1c levels of 7 and *** In poorly controlled diabetes,the rate at which treatment goals are achieved is associated with the glycemic background characteristics,emphasizing the need for tailored ***

关键词： Type 2 diabetes mellitus glycated hemoglobin glycemic control Patient-centered care Diabetes management glycemic background

Determination of Heavy Metal Adsorption Capacity of Water Contaminated by Metallurgical Tailings Leaching Using Carbohydrates Derived from Solanum tuberosum

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Advances in Chemical Engineering and Science 2025年第1期15卷 31-46页

作者： Walther b. Aparicio-Aragón Salomon Ttito-León Marleni Y. Valencia-Pacho School of Chemical Engineering Chemical Engineering Department Altiplano National University Puno Peru

Water contamination in areas of formal and informal polymetallic mining is a growing concern in the Peruvian highlands. At the same time, there are agricultural activities that use contaminated water from these rivers for irrigation. This could contaminate the agricultural products grown on these lands, such as potatoes. It is, therefore, necessary and a priority to determine the adsorption characteristics of these derivatives and to be able to use these natural adsorbents to decontaminate water contaminated with heavy metals.

关键词： Heavy Metals Adsorption Potato Derivatives Isotherm Polluted Water