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In-situ construction of grass-like hybrid architecture responsible for extraordinary corrosion performance: Experimental and theoretical approach

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nano materials Science 2024年第1期6卷 44-59页

作者： T.Suhartono F.Hazmatulhaq Y.Sheng A.Chaouiki m.p.Kamil Y.g.Ko materials Electrochemistry group School of Materials Science and EngineeringYeungnam UniversityGyeongsan38541Republic of Korea Research Center for Advanced materials National Research and Innovation Agency(BRIN)South TangerangBanten15314Indonesia

Despite the engineering potential by the co-existence of inorganic and organic substances to protect vulnerable metallic materials from corrosive environments,both their interaction and in-situ formation mechanism to induce the nature-inspired composite remained less *** present work used three distinctive mercaptobenzazole(mB)compounds working as corrosion inhibitors,such as 2-mercaptobenzoxazole(mBO),2-mercaptobenzothiazole(mBT),and 2-mercaptobenzimidazole(mBI)in a bid to understand how the geometrical structure arising from O,S,and n atoms affected the interaction toward inorganic *** compounds that were used here to control the corrosion kinetics would be interacted readily with the pre-existing mgO layer fabricated by plasma *** phenomenon triggered the nucleation of the root network since mB compounds were seen to be adsorbed actively on the defective surface through the active sites in mB ***,the molecule with twin donor atoms adjacent to the mercapto-sites affected the facile growth of the grass-like structures with‘uniform’distribution via molecular self-assembly,which showed better corrosion performance than those with having dissimilar donor atoms with the inhibition efficiency(η)of 97%*** formation mechanism underlying nucleation and growth behavior of mB molecule was discussed concerning the theoretical calculation of density functional theory.

关键词： nature-inspired composite Organic-inorganic interaction Corrosion inhibitor Density functional theory Electrochemistry

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Ferroelectricity Induced by Oxygen vacancies in Rhombohedral ZrO_(2) Thin Films

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Energy & Environmental materials 2024年第1期7卷 229-237页

作者： veniero Lenzi José p.B.Silva Břetislav Šmíd vladimir matoín Cosmin m.Istrate Corneliu ghica Judith L.macmanus-Driscoll Luís marques physics Center of minho and porto Universities(CF-Um-Up) University of MinhoCampus de Gualtar 4710-057Braga Portugal Laboratory of physics for materials and Emergent Technologies LapMETUniversity of Minho4710-057Braga Portugal Department of Surface and plasma Science Faculty of Mathematics and PhysicsCharles UniversityV Holešovičkách 218000Prague 8 Czech Republic national Institute of materials physics 105 bis Atomistilor 077125Magurele Romania Department of materials Science and metallurgy 27 Charles Babbage Rd.Cambridge CB3 OFSUK

Rhombohedral phase Hf_(x)Zr_(1.x)O_(2)(HZO,x from 0 to 1)films are promising for achieving robust ferroelectric polarization without the need for an initial wake-up pre-cycling,as is normally the case for the more commonly studied orthorhombic ***,a large spontaneous polarization observed in rhombohedral films is not fully understood,and there are also large discrepancies between experimental and theoretical *** this work,in rhombohedral ZrO_(2)thin films,we show that oxygen vacancies are not only a key factor for stabilizing the phase,but they are also a source of ferroelectric polarization in the *** is shown experimentally through the investigation of the structural properties,chemical composition and the ferroelectric properties of the films before and after an annealing at moderate temperature(400℃)in an oxygen environment to reduce the v_(o)concentration *** experimental work is supported by density functional theory(DFT)calculations which show that the rhombohedral phase is the most stable one in highly oxygen defective ZrO_(2)*** DFT calculations also show that v_(o)contribute to the ferroelectric *** findings reveal the importance of v_(o)for stabilizing rhombohedral ZrO_(2)thin films with superior ferroelectric properties.

关键词： charged defects ferroelectric polarization rhombohedral phase stability zirconia

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plasma electrolytic formation and characterization of mnWO_(4)/WO_(3) film heterostructures

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Chemphysmater 2024年第3期3卷 293-302页

作者： m.S.vasilyeva I.v.Lukiyanchuk Yu.B.Budnikova v.g.Kuryavyi D.H.Shlyk g.A.Zverev Department of Chemistry and materials of Institute of High Technology and Advanced materials Far Eastern Federal UniversityFEFU CampusVladivostok 690922Russia Institute of Chemistry Far Eastern BranchRussian Academy of SciencesVladivostok 690022Russia

mnWO_(4)/WO_(3) p-n heterojunction films were fabricated using a one-step method consisting of the plasma electrolytic oxidation(pEO)of titanium in homogeneous electrolytes containing paratungstate ions and stable watersoluble EDTA-chelated *** influences of the formation current density and W:mn molar ratio of the electrolyte,which was varied from 1:2 to 2:1,on the composition,morphology,and optical and photocatalytic properties of the resulting coatings were studied.X-ray diffraction analysis,scanning electron microscopy,energy dispersive X-ray analysis,Raman spectroscopy,and ultraviolet diffuse reflectance spectroscopy were used to characterize the formed *** of the W:mn ratio of the electrolyte,the coatings contained crystalline t-WO_(3) and m-mnWO_(4).Depending on the formation conditions,the optical band gap energies of the composites varied from 2.63 to 3.01 *** largest absorption red shift and lowest band gap energy were observed in the film composite formed in an electrolyte with W:mn=2:1,at a current density of 0.2 A cm^(−2).Composites obtained in electrolytes with W:mn ratios of 2:1 and 1:1 exhibited photocatalytic activity in the degradation of rhodamine C and methyl orange dyes in the presence of 10 mmol L^(–1) H2O_(2) under ultraviolet and visible light *** role of hydrogen peroxide in this dye degradation on pEO-coated composites under light irradiation is discussed.

关键词： plasma electrolytic oxidation manganese tungstate Tungsten oxide Titanium Optical properties p-n heterojunction

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Inclusion of CoTiO_(3) to ameliorate the re/dehydrogenation properties of the mg–na–Al system

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Journal of magnesium and Alloys 2024年第3期12卷 1215-1226页

作者： n.A.Ali n.Y.Yusnizam n.A.Sazelee Sami-ullah Rather Haizhen Liu m.Ismail Energy Storage Research group Faculty of Ocean Engineering TechnologyUniversiti Malaysia Terengganu21030 Kuala NerusTerengganuMalaysia Department of Chemical and materials Engineering King Abdulaziz UniversityP.O.Box80204Jeddah 21589Saudi Arabia guangxi novel Battery materials Research Center of Engineering Technology School of Physical Science and TechnologyGuangxi UniversityNanning 530004China State Key Laboratory of Featured metal materials and Life-Cycle Safety for Composite Structures Nanning 530004China

For the first time,the mgH_(2)–naAlH_(4)(ratio 4:1)destabilized system with CoTiO_(3) addition has been *** CoTiO_(3)-doped mgH_(2)–naAlH_(4) sample begins to dehydrogenate at 130℃,which is declined by 40℃ compared to the undoped mgH_(2)–naAlH_(4).moreover,the de/rehydrogenation kinetics characteristics of the CoTiO_(3)-doped mgH_(2)–naAlH_(4) were greatly *** the inclusion of CoTiO_(3),the mgH_(2)–naAlH_(4) composite absorbed 5.2 wt.%H_(2),higher than undoped mgH_(2)–naAlH_(4).In the context of dehydrogenation,the CoTiO_(3)-doped mgH_(2)–naAlH_(4) sample desorbed 2.6 wt.%H_(2),almost doubled compared to the amount of hydrogen desorbed from the undoped mgH_(2)–naAlH_(4) *** activation energy obtained by the Kissinger analysis for mgH_(2) decomposition was significantly lower by 35.9 kJ/mol than the undoped mgH_(2)–naAlH_(4) *** reaction mechanism demonstrated that new phases of mgCo and AlTi_(3) were generated in situ during the heating process and are likely to play a substantial catalytic function and be useful in ameliorating the de/rehydrogenation properties of the destabilized mgH_(2)–naAlH_(4) system with the inclusion of CoTiO_(3).

关键词： Destabilize system magnesium hydride Sodium alanate Hydrogen storage Additive.

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Extracellular vesicles-coupled miRnAs from oviduct and uterus modulate signaling pathways related to lipid metabolism and bovine early embryo development

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Journal of Animal Science and Biotechnology 2024年第4期15卷 1528-1549页

作者： Rosane mazzarella Karina Canon‑Beltran Yulia n.Cajas meriem Hamdi Encina m.gonzalez Juliano C.da Silveira Claudia L.v.Leal D.Rizos Department of Animal Reproduction INIA-CSICMadridSpain Department of Biochemistry and molecular Biology Veterinary FacultyComplutense University of Madrid(UCM)MadridSpain Department Agrarian production Technical University of MadridUPMMadridSpain Departamento de Ciencias Biologicas Universidad Tecnica Particular de LojaUTPLLojaEcuador Department of Anatomy and Embryology FV-UCMMadridSpain Department of veterinary medicine FZEA-USPPirassunungaBrazil

Background Extracellular vesicles(Evs) present in oviductal(OF) and uterine fluid(UF) have been shown to enhance bovine embryo quality during in vitro culture by reducing lipid contents and modulating lipid metabolism-related genes(Lmgs), while also influencing cell proliferation, suggesting their involvement on the regulation of different biological pathways. The regulation of signaling pathways related to cell differentiation, proliferation, and metabo-lism is crucial for early embryo development and can determine the success or failure of the pregnancy. Bioactive molecules within Evs in maternal reproductive fluids, such as micro RnAs(miRnAs), may contribute to this regulatory process as they modulate gene expression through post-transcriptional *** This study evaluated miRnA cargo in OF-Evs from the early luteal phase and UF-Evs from the mid-luteal phase, coinciding with embryo transit within oviduct and uterus in vivo, and its possible influence on Lmgs and sign-aling pathways crucial for early embryo development. A total of 333 miRnAs were detected, with 11 exclusive to OF, 59 to UF, and 263 were common between both groups. From the 20 differentially expressed miRnAs, 19 up-regulated in UF-Evs(bta-miR-134, bta-miR-151-3p, bta-miR-155, bta-miR-188, bta-miR-181b, bta-miR-181d, bta-miR-224, bta-miR-23b-3p, bta-miR-24-3p, bta-miR-27a-3p, bta-miR-29a, bta-miR-324, bta-miR-326, bta-miR-345-3p, bta-miR-410, bta-miR-652, bta-miR-677, bta-miR-873 and bta-miR-708) and one(bta-miR-148b) in OF-Evs. These miRnAs were predicted to modulate several pathways such as Wnt, Hippo, mApK, and lipid metabolism and degradation. Differ-ences in miRnAs found in OF-Evs from the early luteal phase and UF-Evs from mid-luteal phase may reflect differ-ent environments to meet the changing needs of the embryo. Additionally, miRnAs may be involved, particularly in the uterus, in the regulation of embryo lipid metabolism, immune system, and *** Our study su

关键词： Embryo-maternal interaction Epigenetic Exosomes mammalian preimplantation Reproductive fluids

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A facile strategy for tuning the density of surface-grafted biomolecules for melt extrusion-based additive manufacturing applications

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Bio-Design and manufacturing 2024年第3期7卷 277-291页

作者： I.A.O.Beeren g.Dos Santos p.J.Dijkstra C.mota J.Bauer H.Ferreira Rui L.Reis n.neves S.Camarero-Espinosa m.B.Baker L.moroni Department of Complex Tissue Regeneration MERLN Institute for Technology-Inspired Regenerative MedicineMaastricht University6229 ER MaastrichtThe Netherlands 3B’s Research group I3Bs–Research Institute on BiomaterialsBiodegradables and BiomimeticsHeadquarters of the European Institute of Excellence on Tissue Engineering and Regenerative MedicineUniversity of MinhoAveParkZona Industrial da Gandra4805-017 BarcoGuimarãesPortugal ICvS/3B’s-pT government Associate Laboratory 4806-909 Braga/GuimarãesPortugal pOLYmAT University of the Basque Country UPV/EHU20018 Donostia/San SebastiánSpain IKERBASQUE Basque Foundation for Science48009 BilbaoSpain

melt extrusion-based additive manufacturing(mE-Am)is a promising technique to fabricate porous scaffolds for tissue engi-neering ***,most synthetic semicrystalline polymers do not possess the intrinsic biological activity required to control cell *** of biomolecules on polymeric surfaces of Am scaffolds enhances the bioactivity of a construct;however,there are limited strategies available to control the surface ***,we report a strategy to tune the surface density of bioactive groups by blending a low molecular weight poly(ε-caprolactone)5k(pCL5k)containing orthogonally reactive azide groups with an unfunctionalized high molecular weight pCL75k at different *** porous three-dimensional(3D)scaf-folds were then fabricated using a high weight percentage(75 wt.%)of the low molecular weight pCL *** a proof-of-concept test,we prepared films of three different mass ratios of low and high molecular weight polymers with a thermopress and reacted with an alkynated fluorescent model compound on the surface,yielding a density of 201-561 pmol/cm^(2).Subsequently,a bone morphogenetic protein 2(Bmp-2)-derived peptide was grafted onto the films comprising different blend compositions,and the effect of peptide surface density on the osteogenic differentiation of human mesenchymal stromal cells(hmSCs)was *** two weeks of culturing in a basic medium,cells expressed higher levels of Bmp receptor II(BmpRII)on films with the conjugated *** addition,we found that alkaline phosphatase activity was only significantly enhanced on films contain-ing the highest peptide density(i.e.,561 pmol/cm^(2)),indicating the importance of the surface *** together,these results emphasize that the density of surface peptides on cell differentiation must be considered at the cell-material ***,we have presented a viable strategy for mE-Am community that desires to tune the bulk and surface functionality via blending of(m

关键词： Additive manufacturing Blending Surface functionalization Surface density Click chemistry Human

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Effects of site preparation methods on soil physical properties and outplanting success of coniferous seedlings in boreal forests

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Journal of Forestry Research 2024年第2期35卷 70-80页

作者： Aleksey S.Ilintsev Elena n.nakvasina Alexander p.Bogdanov northern Research Institute of Forestry 13 Nikitova Str.Arkhangelsk 163062Russian Federation Department of Silviculture and Forest management Northern(Arctic)Federal University Named After M.V.LomonosovSevernoy Dviny Emb.17Arkhangelsk 163002Russian Federation

This study assessed the effect of patch scarification and mounding on the physical properties of the root layer and the success of tree planting in various types of *** study was conducted on 12 forest sites in taiga forests of the European part of Russia.A total of 54 plots were set up to assess seedling survival;root collar diameter,height,and heigh increment were measured for 240 seedlings to assess *** the rooting layer,240 soil samples were taken to determine physical *** study showed that soil treatment methods had no effect on bulk density and total porosity in Cladina ***,reduced soil moisture was noted,particularly in mounds,resulting in increased *** myrtillus sites,there were increased bulk density,reduced soil moisture,and total porosity in the *** treatment in polytrichum sites resulted in reduced soil moisture and increased aeration *** the myrtillus and polytrichum sites,patch scarification had no effects on physical *** polytrichum sites,survival rates,heights,and heigh increments of bareroot norway spruce seedlings in mounds were higher than in patches;however,the same did not apply to *** Cladina and myrtillus sites,there was no difference in growth for bareroot and containerised seedlings with different soil *** conditions and soil types should be considered when applying different soil treatment methods to ensure high survival rates and successful seedling growth.

关键词： Boreal forests mechanical site preparation patch scarification mounding Soil properties Containerised seedlings Bareroot seedlings

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Enhanced heavy and extra heavy oil recovery:Current status and new trends

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petroleum 2024年第3期10卷 399-410页

作者： Sayed gomaa Khalaf g.Salem A.n.El-hoshoudy mining and petroleum Engineering Department Faculty of EngineeringAl-Azhar UniversityEgypt Department of Reservoir Engineering South Valley Egyptian Petroleum Holding Company(GANOPE)CairoEgypt pvT Lab-production Department Egyptian Petroleum Research Institute(EPRI)Cairo 11727Egypt pvT-Service Center Egyptian Petroleum Research Institute(EPRI)Cairo 11727Egypt

Due to the increased demand for energy resources these days,especially due to the Russian-Ukrainian war,the focus of the major countries is turning strongly towards improving oil production,especially heavy and extra heavy oil,which represents 40%of the world oil ***-based and thermal(EOR)procedures are promising techniques for recovering heavy oil reservoirs,but they suffer from a sequence of problems and complications that arise after long-term *** complications comprise steam breakthrough,steam overlap,and steam/rock *** research presents the currently applied techniques to maximize the productivity of heavy oil,such as steam injection,cyclic steam stimulation,in-situ combustion,and steam-assisted gravity *** technologies face numerous obstacles,as they are energy and water-intensive processes that are not environmentally *** research also presents future trends in energy-saving and environmentally friendly techniques that enhance heavy oil recovery through vapor extraction(vApEX)steam-solvent hybrid techniques,electromagnetic energy,sonication,and *** findings of this review reported that all the presented techniques focus on how to reduce the oil viscosity and in-situ upgrade the crude oil *** turn,these enhance both the productivity rate and oil recovery and minimize the production *** article can be considered a comprehensive review of thermal recovery methods in heavy and extra-heavy oil,in addition to screening criteria used for each method.

关键词： Enhanced oil recovery Heavy crude oil Steam flood Hybrid techniques nanotechnology

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The multi-impurity system in CdSe nanoplatelets:electronic structure and thermodynamic properties

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Communications in Theoretical physics 2024年第3期76卷 165-173页

作者： D A Baghdasaryan v A Harutynyan E m Kazaryan H A Sarkisyan Russian-Armenian University H Emin 1230051YerevanArmenia Institute of Applied problems of physics 25 Nersisyan St0014YerevanArmenia

This paper theoretically studies the impurity states and the effects of impurity concentration and configuration on the optical,electrical,and statistical properties of CdSe nanoplatelets(npLs).An image charge-based model of electron-impurity interaction is *** charge-carrier energy spectra and corresponding wave functions depending on the impurity number and configuration are *** electron binding energies are calculated for different npL *** is shown that the image charge-based interaction potential that arises due to the dielectric constants mismatch is much stronger than the interaction potential that does not take such a mismatch into ***,it is demonstrated that the binding energies are increasing with the number of *** calculate the canonical partition function using the energy levels of the electron,which in turn is used to obtain the mean energy,heat capacity,and entropy of the non-interacting electron *** thermodynamic properties of the non-interacting electron gas that depend on the geometric parameters of the npL,impurity number,configuration,and temperature are studied.

关键词： nanoplateletes thermodynamic properties impurity states

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Solid-liquid extraction for yttrium recovery using porous polymeric resin(XAD-7) functionalized with D_(2)EHpA

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Journal of Rare Earths 2024年第9期42卷 1764-1773,I0005页

作者： p.A.martínez-montoya R.g.Sanchez-Alvarado D.Y.medina-velazquez m.L.Carrera-Jota p.garnica-Chávez A.de J.morales-Ramirez Higher School of Chemical Engineering and Extractive Industries ESIQIEIPNDepartment of Metallurgical EngineeringUPALM S/NCol.LindavistaGustavo A.Madero Cd.de MéxicoC.P07738Mexico metropolitan Autonomous University Department of MaterialsBasic Sciences and EngineeringAv.San Pablo No.180Col.Reynosa TamaulipasCd.de MéxicoC.P02200Mexico Center for Research and Technological Innovation CIITECIPNCda.de CECATIs/nSanta CatarinaAzcapotzalcoC.P02250CDMXMexico

The recovery of yttrium is proposed by applying a solid-liquid extraction process using di-2-ethyl hexylphosphoric acid(D2EHpA) as extracting *** extracting agents were supported on a macro porous polymeric resin XAD-7(solid phase).Yttrium ions extraction and discharge tests were performed,firstly from a synthetic aqueous solution of 100 mg/L Y(liquid phase) at 25℃ with *** effects of pH of aqueous solutions bearing yttrium,volume fraction of extracting agents and the solid/liquid(S/L)ratio on the yttrium recovery were *** most favorable conditions for yttrium ions extraction are;20 vol% D_(2)EHpA functionalized resin,pH=1.5 and an S/L ratio of 10 mg/mL The discharge of yttrium ions was done under the same conditions of extraction stage,using a 2 mol/L [H_(2)SO_(4)] as stripping *** to 80% yttrium is extracted,while 75% yttrium is recovered in the striping *** all experiments,the reaction equilibrium is reached after 20 min,and the kinetics for the extraction stage was determined as a second-order ***,experiments were carried out to discharge the yttriumloaded resins,and it has been determined that the best pH value to strip the Y ions is *** tests of extraction and discharge for yttrium ions show that the functionalized resin can work at least five cycles without decreasing its ***,the proposed process was tested in a real solution with Y ions fro m a waste fluorescent la mp powder leached in H_(2)SO_(4),demonstrating the ability to effectively recover yttrium,separating it from various metals from the studied residue.

关键词： Yttrium recovery Rare earth solid-liquid extraction XAD-7 resin Fluorescent lamps recycling Solid-liquid kinetics extraction

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