检索结果-南通市图书馆

Effect of metal fluorides on chromium ions doped bismuth borate glasses for optical applications

Chinese Physics B 2019年第3期28卷 366-372页

作者： L Haritha K Chandra Sekhar R Nagaraju g ramadevudu Vasanth g Sathe Md.Shareefuddin Department of Physics Telangana University Department of Physics Osmania University Department of Physics Vasavi College of Engineering UgC-DAE Consortium of Scientific Research

Fluoride based glasses with composition CaF_2-ZnF_2-Bi_2 O_3-B_2 O_3 doped with chromium ions have been investigated using physical, optical, electron paramagnetic resonance(EPR), Fourier-transform infrared spectroscopy(FTIR), and Raman studies. The amorphous nature of samples was confirmed from x-ray diffraction spectra. The density is evaluated from the Archimedes principle and the values of optical band gap and Urbach energy values were evaluated from the optical absorption spectra. Thus, molar volume, refractive index, etc., were also evaluated. The observed decrease in density and the optical band gap with CaF2 is explained using the crystalline density of metal fluorides and the ionicity of fluorine ions,respectively. The three peaks near 450 nm, 606 nm, and 720 nm, which are shown in the absorption spectra, are accredited to ~4 A)(2 g) → ~4 T_(1 g), ~4 A_(2 g)→ ~4 T_(2 g), ~4 A_(2 g)→~2 E transitions, respectively. Resonance signals at g≈ 4.82 and g≈ 1.99 were observed in EPR spectra which are assigned. FTIR and Raman analysis were carried out to examine the impact of metal fluorides on the structure of bismuth borate glasses.

关键词： glasses x-ray diffraction electron paramagnetic resonance Fourier-transform infrared spectroscopy(FTIR) Raman spectra

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Electron Paramagnetic Resonance Studies of Cu2+and VO2+Spin Probes in RO-Li2O-Na2O-K2O-B2O3(R = Zn, Mg, Sr and Ba) glass Systems

引用

New Journal of glass and Ceramics 2012年第1期2卷 51-58页

作者： Abdul Hameed gokarakonda ramadevudu Siddey Laksmisrinivasa Rao Mohmmad Shareefuddin Mudumba Narasimha Chary 不详

Mixed alkali and alkaline earth oxide glasses of RO-Li2O-Na2O-K2O-B2O3(R = Zn, Mg, Sr and Ba) system were studied by electron paramagnetic resonance (EPR) and optical absorption spectroscopy. Cu2+ and VO2+ ions were used as the spin probes. The glasses containing 1 mole% of Cu2+ and 2mole% of VO2+ were prepared by the melt quenching method. X-ray diffraction studies of the samples did not reveal crystalline phases. EPR measurements were made at X-band frequencies with 100 kHz field modulation, at 310 K. Optical spectra were recorded in the wavelength range 300 nm - 800 nm. From the EPR spectra the spin-Hamiltonian parameters were evaluated. The spin-Hamiltonian parameter values in the case of Cu2+ indicated that the ground state of Cu2+ was orbital (2B1g) and the site symmetry around Cu2+ is tetragonally distorted octahedral. The variation of gll and All with the alkaline earth oxide (RO) composition was found to be non-linear which may be due to the change in the ligand field strength at the site of Cu2+ ions. From the spin-Hamiltonian parameters of VO2+, it was observed that the vanadyl ions exist as VO2+ ions in octahedral coordination with tetragonal compression and have C4V symmetry with ground state dxy. Tetragonality (△gll/△g) of V4+ ion sites exhibited non-linear variation with RO content, which indicated change in the ligand field at the site of V4+. A broad optical absorption band was observed in the glass containing Cu2+ ions corresponding to the 2B1g → 2B2g transition. From the EPR and optical data the bond parameters were evaluated. In the case of VO2+ ions, the covalency rates were estimated.

关键词： Borate glasses Electron Paramagnetic Resonance (EPR) Optical Absorption Spin-Hamiltonian Parameters

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：