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Rare earth elements and yttrium in ferromanganese deposits from the South China Sea:distribution,composition and resource considerations

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Acta Oceanologica Sinica 2018年第7期37卷 41-54页

作者： ZHONG Yi CHEN Zhong GONZALEZ francisco javier ZHENG Xufeng LI Gang LUO Yun MO Aibin XU Antao WANG Shuhong Key Laboratory of Ocean and Marginal Sea Geology South China Sea Institute of OceanologyChinese Academy of SciencesGuangzhou 510301China Department of Marine Science and Engineering Southern University of Science and Technology of ChinaShenzhen 518055China University of Chinese Academy of Sciences Beijing 100049China Geological Survey of Spain(IGME) Madrid 28003Spain

Ferromanganese nodules and crusts contain relatively high concentration of rare earth elements（REE） and yttrium（REY）,with a growing interest in exploitation as an alternative to land-based REY *** the basis of comprehensive geochemical approach,the abundance and distribution of REY in the ferromanganese nodules from the South China Sea are *** results indicate that the REY contents in ferromanganese deposits show a clear geographic *** REY contents range from 69.1×10^-6 to 2 919.4×10^-6,with an average value of 1 459.5×10^-***,the enrichment rate of Ce content is high,accounting for almost 60% of the total *** REE enrichment is controlled mainly by the sorption of ferromanganese oxides and clay minerals in the nodules and ***,the total REY are higher in ferromanganese deposits of hydrogenous origin than of diagenetic ***,Light REE（LREE） and heavy REE（HREE） oxides of the ferromanganese deposits in the study area can be classified into four grades： non-enriched type,weakly enriched type,enriched type,and extremely enriched *** to the classification criteria of rare earth resources,the Xisha and Zhongsha platform-central deep basin areas show a great potential for these rare earth metals.

关键词： ferromanganese deposits rare earth elements and yttrium abundance characteristics controlling factors potential source South China Sea

Highly graphitized carbon nanosheets with embedded Ni nanocrystals as anode for Li-ion batteries

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Nano Research 2020年第1期13卷 86-94页

作者： francisco javier Soler-Piña Celia Hernández-Rentero Alvaro Caballero Julián Morales Enrique Rodríguez-Castellón Jesús Canales-Vázquez Dpto.Química Inorgánica e Ingeniería Química Instituto de Química Fina y NanoquímicaUniversidad de Córdoba14071CórdobaSpain Dpto.Química Inorgánica Cristalografía y MineralogíaFacultad de CienciasUniversidad de Málaga29071MálagaSpain Instituto de Energías Renovables Universidad de Castilla-La ManchaPaseo de La Investigación 102071AlbaceteSpain

A C/Ni composite was prepared via thermal decomposition of a nickel oleate complex at 700℃,yielding disperse Ni nanocrystals with an average size of 20 nm,encapsulated by carbon nanosheets as deduced from transmission electron microscopy(TEM)images and confirmed from X-ray photoelectron spectroscopy(XPS).Furthermore,the X-ray diffraction pattern revealed a good ordering of the carbon layers,forced by the Ni encapsulation to adopt a bending *** the close interaction between the graphitized framework and the metallic nanoparticles we have studied the properties of the composite as an anode for Li-ion *** with other nanostructured synthetic carbons,this carbon composite has a low voltage hysteresis and a modest irreversible capacity value,properties that play a significant role in its behaviour as electrodes in full cell *** moderate rate values,0.25 C,the electrode delivers an average capacity value around 723 mAh·g^−1 on cycling,among the highest values so far reported for this carbon *** higher rate values,1 C,the average capacity values delivered by the cell on cycling decrease,around 205 mAh·g^−1,but it maintains good capacity retention,a coulombic efficiency close to 100%after the first cycles and recovery of the capacity values when the rate is restored from 3 to 0.1 C.

关键词： carbon nanosheets nickel nanoparticles anode lithium batteries

Acral lesions in a pediatric population during the COVID-19 pandemic: a case series of 36 patients from a single hospital in Spain

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World Journal of Pediatrics 2020年第6期16卷 629-632页

作者： Pan Roses-Gibert javier Gimeno Castillo Amaia Saenz Aguirre francisco javier De la Torre Gomar Lucia Carnero Gonzalez Zurine Martinez de Lagran Alvarez de Arcaya Ricardo Gonzalez-Perez Araba University Hospital Francisco Leandro de Viana Street01009 VitoriaSpain

Background To describe the cutaneous acral findings in a pediatric population noticed during this *** A retrospective descriptive study was performed collecting data on 36 patients under 14 years old,presenting suspicious acral skin manifestations for coronavirus disease 2019(COVID-19).Results Patients were mostly male(63.8%).The mean age was 11.11 years.66.67%of patients showed erythematous papules,and 44.44%purpuric *** were aifected in 97.22%of patients and hands in 5.55%.Lesions were asymptomatic in 50%of patients.30.55%of patients showed extracutaneous findings,preceding skin lesions in 12.62 *** patients underwent specific severe acute coronavirus 2(SARS-CoV-2)testing;all of these patients tested *** The association between these symptoms and SARS-CoV-2 remains *** recommend using these manifestations as a sign of SARS-CoV-2 infection in *** could lead to the examination of asymptomatic and mildly symptomatic children so that contagions may be avoided.

关键词： Acral lesions Acute acro-ischemia Chilblain-like COVID-19

Dissecting the molecular pathophysiology of drug-induced liver injury

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World Journal of Gastroenterology 2018年第13期24卷 1373-1385页

作者： Hui Ye Leonard J Nelson Manuel Gómez del Moral Eduardo Martínez-Naves francisco javier Cubero Department of Immunology Ophtalmology and ORLComplutense University School of MedicineMadrid 28040Spain 12 de Octubre Health Research Institute(imas12) Madrid 28041Spain Institute for BioEngineering(Human Liver Tissue Engineering Faraday BuildingThe University of EdinburghThe King BuildingsMayfield RoadEdinburgh EH9 3 JLScotlandUnited Kingdom Department of Cell Biology Complutense University School of MedicineMadrid 28040Spain

Drug-induced liver injury(DILI) has become a major topic in the field of Hepatology and Gastroenterology. DILI can be clinically divided into three phenotypes: hepatocytic, cholestatic and mixed. Although the clinical manifestations of DILI are variable and the pathogenesis complicated, recent insights using improved preclinical models, have allowed a better understanding of the mechanisms that trigger liver damage. In this review, we will discuss the pathophysiological mechanisms underlying DILI. The toxicity of the drug eventually induces hepatocellular damage through multiple molecular pathways, including direct hepatic toxicity and innate and adaptive immune responses. Drugs or their metabolites, such as the common analgesic, acetaminophen, can cause direct hepatic toxicity through accumulation of reactive oxygen species and mitochondrial dysfunction. The innate and adaptive immune responses play also a very important role in the occurrence of idiosyncratic DILI. Furthermore, we examine common forms of hepatocyte death and their association with the activation of specific signaling pathways.

关键词： signaling pathways acetaminophen Drug-induced liver injury cell death reactive oxygen species

Study of an Ionic Fluid on the Electrochemical Test of A36 Carbon Steel Ingot

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Journal of Materials Science and Chemical Engineering 2022年第2期10卷 29-43页

作者： Socorro Valdez Rodriguez Martin Ignacio Pech-Canul Hugo Rojas Oscar Sotelo francisco javier Rodríguez Araceli Espinoza-Vazquez Ociel Rodríguez Instituto de Ciencias Físicas-UNAM Cuernavaca Morelos México Centro de investigación y de Estudios Avanzadas del Instituto Politécnico Nacional Civestav-Saltillo Coahuila México Facultad de Ciencias Químicas e Ingeniería-UAEM Morelos México Departamento de Ingeniería Metalúrgica Facultad de Química-UNAM Ciudad de México México

An ionic fluid based on aromatic heterocyclic family constituted by 1,3-diazole groups was investigated. The purpose is to describe their electrochemical characteristics in order to identify the strategy to avoid the A36 carbon steel surface degradation by using electrochemical measurements. We found that the linear polarization resistance reveals an increasing value when the organic unsaturated cyclic ionic fluid was added to the corrosive electrolyte. The polarization curves and Tafel Extrapolation obtained to know the slopes tafel and the inhibitor efficiency from current density (icorr) shows a high efficiency inhibition value.

关键词： A36-Steel Ionic Fluid Electrochemical Degradation Tafel Extrapolation Linear Polarization Resistance Diazole Group Organic Inhibitor

Testing the effectiveness of conservation management within biosphere reserves:the case of the Mexican deer mouse(Peromyscus mexicanus)as a bioindicator

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Integrative Zoology 2019年第5期14卷 422-434页

作者： Irene COBO-SIMÓN Belén MÉNDEZ-CEA Héctor PORTILLO Fausto ELVIR Hermes VEGA francisco javier GALLEGO Gustavo FONTECHA Department of Genetics Physiology and MicrobiologyComplutense University of MadridMadridSpain 2Department of Physical Chemical and Natural SystemsUniversity Pablo de OlavideSevilleSpain Grupo de Investigación Para La Biodiversidad de Honduras GIBH-BALAM National Autonomous University of HondurasTegucigalpaHonduras

Biosphere reserves are protected areas whose purpose is to combine conservation and sustainable ***,their effectiveness has not been tested sufficiently,especially from an ecological and genetic ap*** this sense,the Peromyscus genus represents an excellent bioindicator to address these questions,due to its short life and high evolutionary rate and *** conservation managers,genetic structure can increase the rate of loss of genetic diversity because alleles exclusive of a subpopulation are more likely to disappear as a consequence of genetic drift in comparison with a panmictic *** we analyzed the abundance,movement distances,morphology/morphometry and genetic structure of 3 populations of Mexican deer mouse(Peromyscus mexicanus)located in different protected zones of La Tigra National Park(Honduras).Our results are consistent among the 3 approaches and showed the highest values of abundance,morphometry and genetic diversity in the population located at the core zone,whereas non-statistically significant differences were found between buffer and transition zone populations,suggesting suitable effectiveness of conservation management in the core zone but a lack of ecological buffering function of the other *** addition,the low movement distances and high genetic structure among the studied populations provide evidence of poor conservation management in the buffer and transition ***,we discuss the utility of the novel methodology used in this work,combining morphometry,abundance and genetics,in testing the effectiveness of conservation strategies in biosphere reserves,and the value of the Peromyscus genus as a bioindicator.

关键词： bioindicator conservation Peromyscus mexicanus SSR

Enduring association between irritable bowel syndrome and war trauma during the Nicaragua civil war period:A population-based study

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World Journal of Gastroenterology 2023年第45期29卷 5953-5961页

作者： Edgar M Peña-Galo Daniel Wurzelmann javier Alcedo Rodolfo Peña Loreto Cortes Douglas Morgan Department of Digestive Diseases Miguel Servet University HospitalZaragoza 50009AragonSpain javier Alcedo Aragon Health Research InstituteIIS AragonZaragoza 50009AragonSpain Department of Mental Health Carolina PartnersDurhamNC 27707United States Department of Data Analysis CIDE(ResearchDevelopment and Epidemiology Center)Tegucigalpa 11101Francisco MorazánHonduras School of Medicine National Autonomous University of NicaraguaLeon 21000LeonNicaragua Department of Gastroenterology and Hepatology UAB University of Alabama BirminghamBirminghamAL 35233United States School of Medcine The University of North CarolinaChapel HillNC 9500United States

BACKGROUND Psychosocial and physical trauma are known risk factors for irritable bowel syndrome(IBS),including in war veterans,whereas war exposure in civilians is *** experienced two wars,1970-1990:The Sandinistas Revolution(1970s)and The Contra War(1980s).Our aim was to investigate the role of exposure to war trauma in the subsequent development of IBS in the context of an established health surveillance system(11000 households).AIM To investigate in a civilian population the relationship between exposure to war trauma and events and the subsequent development of IBS in the context of an established public health and demographic surveillance system in western *** We conducted a nested population-based,cross-sectional study focused on functional gastrointestinal disorders based on Rome II criteria.1617 adults were randomly *** Spanish Rome II Modular Questionnaire and Harvard Trauma Questionnaire were validated in *** exposure was assessed with 10 measures of direct and indirect war trauma and post-war *** exposures were defined by≥3 *** The prevalence of IBS was 15.2%[Female(F)17.1%,Male(M)12.0%],war exposure 19.3%(F 9.3%,M 36.7%),and post-traumatic stress disorder(PTSD)5.6%(F 6.4%,M 4.3%).Significant associations with IBS in the civilian population were observed(adjusted by gender,age,socioeconomic status,education):physical and psychological abuse[adjusted odds ratio(aOR):2.25;95%confidence interval:1.1-4.5],witnessed execution(aOR:2.4;1.1-5.2),family member death(aOR:2.2;1.2-4.2),and multiple exposures(aOR:2.7;1.4-5.1).PTSD was independently associated with IBS(aOR:2.6;1.2-5.7).CONCLUSION An enduring association was observed in the Nicaragua civilian population between specific civil war-related events and subsequent *** populations in regions with extended armed conflict may warrant provider education and targeted interventions for patients.

关键词： Irritable bowel syndrome Functional gastrointestinal disorders War trauma Civil war Post-traumatic stress disorder Central America

Role of microRNAs in alcohol-induced liver disorders and non-alcoholic fatty liver disease

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World Journal of Gastroenterology 2018年第36期24卷 4104-4118页

作者： Jorge-Luis Torres Ignacio Novo-Veleiro Laura Manzanedo Lucía Alvela-Suárez Ronald Macías francisco-javier Laso Miguel Marcos Department of Internal Medicine University Hospital of SalamancaInstitute of Biomedical Research of Salamanca-IBSAL Spanish Working Group on Alcohol and Alcoholism Spanish Society of Internal Medicine Department of Internal Medicine University Hospital of Santiago de Compostela Department of Internal Medicine HM Rosaleda HospitalSantiago de Compostela Department of Medicine Faculty of MedicineUniversity of Salamanca

MicroRNAs(miRNAs) are small non-coding RNAs that regulate multiple physiological and pathological functions through the modulation of gene expression at the post-transcriptional level. Accumulating evidence has established a role for miRNAs in the development and pathogenesis of liver disease. Specifically, a large number of studies have assessed the role of miRNAsin alcoholic liver disease(ALD) and non-alcoholic fatty liver disease(NAFLD), two diseases that share common underlying mechanisms and pathological characteristics. The purpose of the current review is to summarize and update the body of literature investigating the role of miRNAs in liver disease. In addition, the potential use of miRNAs as biomarkers and/or therapeutic targets is discussed. Among all miRNAs analyzed, miR-34 a, miR-122 and miR-155 are most involved in the pathogenesis of NAFLD. Of note, these three miRNAs have also been implicated in ALD, reinforcing a common disease mechanism between these two entities and the pleiotropic effects of specific miRNAs. Currently, no single miRNA or panel of miRNAs has been identified for the detection of, or staging of ALD or NAFLD. While promising results have been shown in murine models, no therapeutic based-miRNA agents have been developed for use in humans with liver disease.

关键词： Alcohol use disorder Alcoholic liver disease Non-alcoholic fatty liver disease Steatosis Obesity miRNA Biomarkers

Ayahuasca:Uses,Phytochemical and Biological Activities

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Natural Products and Bioprospecting 2019年第4期9卷 251-265页

作者： Edgar Antonio Estrella‑Parra Julio Cesar Almanza‑Pérez francisco javier Alarcón‑Aguilar Laboratorio de Farmacología.Dpto.Ciencias de la Salud.Div.C.B.S.Universidad Autónoma Metropolitana Unidad Iztapalapa.Av.San Rafael Atlixco No.186Col.Vicentina09340 Mexico CDMXMexico Laboratorio de Fitoquímica Laboratorio de FarmacognosiaLaboratorio de Fisiología VegetalUnidad UBIPROFES-IztacalaUNAMTlalnepantla de Baz54090 Mexico CDMXMexico

Ayahuasca(caapi,yajé),is a psychoactive brew from the Amazon Basin region of South America traditionally considered a“master plant.”It is prepared as a decoction from Banisteriopsis caapi and Psychotria viridis,which it is thought that it stimulates creative thinking and visual *** healers of the Orinoco and Amazon basins have used traditionally ayahuasca as a healing tool for multiple purposes,particularly to treat psychological disorders in the patients,with some beneficial effects experimentally and clinically ***,several syncretic religions,as the“Uniao de Vegetal”(UDV)group in Brazil,have been spread around the *** use of ayahuasca has been popularized by internet and smart-shops,bringing the psychoactive substance to new highs,emerging new“ayahuasqueros.”Ayahuasca has alkaloids asβ-carbolines and dimethyltryptamines,which inhibit the monoamine oxidase and active the 5-HT_(2A)(5-hydroxytryptamine)receptor,respectively,resulting in hallucinations in the *** induces a psychedelic change in the anteroposterior coupling of the electrophysiological brain oscillations in *** ayahuasca beverage is generating pharmacological,commercial and spiritual interest among the scientific community,government people,and different populations *** goal of this article is to report about the uses,chemistry and biological activities of ayahuasca.

关键词： Ayahuasca Banisteriopsis caapi Psychotria viridis-dimethyltryptamine β-carbolines Psychotherapy