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Evolution of the 3.65-2.58 Ga Mairi Gneiss Complex,Brazil:Implications for growth of the continental crust in the São francisco Craton

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Geoscience Frontiers 2022年第5期13卷 110-128页

作者： Igor de Camargo Moreira Elson Paiva Oliveira Daniel francisco Martins de Sousa Institute of Geosciences University of Campinas(UNICAMP)CampinasSPBrazil

The composition and formation of the Earth’s primitive continental crust and mantle differentiation are key issues to understand and reconstruct the geodynamic terrestrial evolution,especially during the ***,the scarcity of exposure to these rocks,the complexity of lithological relationships,and the high degree of superimposed deformation,especially with long-lived magmatism,make it difficult to study ancient *** this complexity,exposures of the Archean Mairi Gneiss Complex basement unit in the São francisco Craton offer important information about the evolution of South America’s primitive ***,here we present field relationships,LA-ICP-SFMS zircon U-Pb ages,and LA-ICP-MCMS Lu-Hf isotope data for the recently identified Eoarchean to Neoarchean gneisses of the Mairi *** Complex is composed of massive and banded gneisses with mafic members ranging from dioritic to tonalitic,and felsic members ranging from TTG(Tonalite-Trondhjemite-Granodiorite)to granitic *** new data point to several magmatic episodes in the formation of the Mairi Gneiss Complex:Eoarchean(ca.3.65–3.60 Ga),early Paleoarchean(ca.3.55–3.52 Ga),middle-late Paleoarchean(ca.3.49–3.33 Ga)and Neoarchean(ca.2.74–2.58 Ga),with no records of Mesoarchean ***-Hf data unveiled a progressive evolution of mantle differentiation and crustal recycling over *** the Eoarchean,rocks are probably formed by the interaction between the pre-existing crust and juvenile contribution from chondritic to weakly depleted mantle sources,whereas mantle depletion played a role in the Paleoarchean,followed by greater differentiation of the crust with thickening and recycling in the middle–late Paleoarchean.A different stage of crustal growth and recycling dominated the Neoarchean,probably owing to the thickening of the continental crust by collision,continental arc growth,and mantle differentiation.

关键词： São francisco Craton Mairi Gneiss Complex Primitive continental crust Zircon U-Pb dating Lu-Hf isotope geochemistry

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Hydrolysis of Urea to Produce Ammonia Dircio francisco Xavier Fatima Ximenes

Hydrolysis of Urea to Produce Ammonia Dircio Francisco Xavie...

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作者： Dircio francisco Xavier Fatima Ximenes（弗朗西斯科）华东理工大学

学位级别：硕士

氮氧化物（NOx）引起了巨大的环境问题,是目前世界上最大的环境污染物之一,随着对NOx法规的逐步收紧,世界各国都在积极开展减少NOx污染的研究。目前已开发利用了多种技术,其中选择性催化还原（SCR）和选择性非催化还原（SNCR）具有较高... 详细信息

氮氧化物（NOx）引起了巨大的环境问题,是目前世界上最大的环境污染物之一,随着对NOx法规的逐步收紧,世界各国都在积极开展减少NOx污染的研究。目前已开发利用了多种技术,其中选择性催化还原（SCR）和选择性非催化还原（SNCR）具有较高的脱硝效率。在SCR和SNCR工艺中,还原剂被注入烟气中,将NOx还原为无害氮（N2）。目前最常用的还原剂是氨（NH3）。尿素催化水解制氨在氨基脱氮过程中起着重要作用。本论文的目标有三个。首先,对尿素水解的催化剂进行筛选,其中均相催化剂表现出了良好的性能,因此本文用选择该类催化剂来进行尿素催化水解反应,然后尿素水解的转化率采用滴定法来进行分析。第二是设计了四因素,三水平Box-Behnken实验,结合响应面法对工艺条件进行优化,研究反应温度,反应时间,反应压力和催化剂用量对尿素水解制氨的影响及其交互作用。建立了尿素水解率的相关模型。第三是采用物料平衡方程,热量平衡方程,化学平衡方程及相平衡方程组成的非线性方程组来构建开口体系内尿素水解过程的热力学模型和动力学模型,并引入修正的Lewis-Randall方程和修正的Herry方程来描述水解反应器内NH3-CO2-H2O-（NH2）2CO（ACWU）四元多自由度气液平衡关系,气液两相的非理想性则分解采用PR状态方程和扩展UNIQUAC模型进行修正。结果表明,采用催化活性较好的乙酸钠（7g）催化剂对工艺条件进行优化,响应面法最优化的合成条件为;反应温度160℃,反应时间4h,反应压力0.4MPa和催化剂用量0.034wt%,在此工艺条件下尿素水解的转化率为98.620%,同时建立了尿素水解制氨的二次数学模型,该模型对实验结果有良好的预测作用。

关键词：尿素水解制氨热力学动力学

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A perspective on potassic and ultrapotassic rocks:Constraints on the Paleoproterozoic late to post-collisional event in the São francisco paleocontinent

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Geoscience Frontiers 2022年第5期13卷 242-266页

作者： Samuel Moreira Bersan AndréDanderfer Craig Storey Henrique Bruno Hugo Moreira francisco Abreu Cristiano Lana Leonardo Gonçalves Isabela Nahas Universidade Federal de Ouro Preto Departamento de GeologiaCampus Morro do CruzeiroOuro PretoMG CEP 35400-000Brazil University of Portsmouth School of the EnvironmentGeography and GeosciencesBurnaby BuildingBurnaby RoadPortsmouth PO13QLUK Tektos Research Group UERJ-Rio de Janeiro State UniversityBrazil Sustain Geologia Belo HorizonteBrazil

The late-to post-collisional stage in orogenic systems is characterized by the coeval existence of bimodal potassic to ultrapotassic magmatic activity related to partial melting of an enriched lithospheric mantle together with crustal derived *** this paper,we present new whole rock geochemical analyses combined with zircon and titanite U–Pb and zircon Hf isotopic data from potassic to ultrapotassic rocks from six plutons that occur within the Archean Itacambira-Monte Azul block(BIMA),to discuss their petrogenesis and the tectonic implications for the São francisco *** new U–Pb ages range from ca.2.06 Ga to 1.98 Ga and reveal long-lasting potassic magmatism within the BIMA,which is within the late-to-post-collisional stage of the São francisco paleocontinent *** ultrapotassic rocks are compatible with a fluid-related metasomatized mantle source enriched by previous subduction events,whereas the potassic rocks are bimodal and have a transitional shoshonitic to A-type *** rocks have a hybrid nature,possible related to the mixing between the mafic potassic/ultrapotassic rocks and high temperature crustal melts of the Archean continental *** results also show an increase of within-plate signature towards the younger potassic *** participation of an important Archean crustal component in the genesis of these rocks is highlighted by the common and occasionally abundant occurrence of Archean inherited *** Hf isotopic record shows that most of the zircon inheritance has dominantly subchondriticεHf(t)values,which fits a crustal reworking derivation from a similar Eo-to Paleoarchean precursor ***,the presence of juvenile 2.36 Ga zircon inheritance in an ultrapotassic sample reveal the existence of a hidden reservoir that is somewhat similar to the described for the Mineiro Belt in southern São francisco paleocontinent.

关键词： Late-to post-collisional Potassic-ultrapotassic rocks U–Pb dating São francisco paleocontinent Rhyacian-Orosirian orogenic system

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francisco Goya, 1746-1828

Francisco Goya, 1746-1828

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作者： Hagen Rose-Marie. (1928-)Hagen Rainer (1746-1828.)Goya francisco

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Paleoproterozoic juvenile magmatism within the northeastern sector of the Sao francisco paleocontinent:Insights from the shoshonitic high Ba-Sr Montezuma granitoids

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Geoscience Frontiers 2020年第5期11卷 1821-1840页

作者： Samuel Moreira Bersan Alice Fernanda de Oliveira Costa Andre Danderfer francisco Roberio de Abreu Cristiano Lana Glaucia Queiroga Craig Storey Hugo Moreira Universidade Federal de Ouro Preto Programa de Pos-graduacaoDepartamento de GeologiaCampus Morro do CruzeiroOuro PretoMGCEP 35400-000Brazil Universidade Federal de Ouro Preto Departamento de GeologiaCampus Morro do CruzeiroOuro PretoMGCEP 35400-000Brazil Sustain Geologia Ltda Teresa M.Valadares 503/502Belo HorizonteMGCEP 30575-160Brazil University of Portsmouth School of Earth and Environmental SciencesBurnaby BuildingBurnaby RoadPortsmouthPO13QLUK

New,integrated petrographic,mineral chemistry,whole rock geochemical,zircon and titanite UPb geochronology,and zircon Hf isotopic data from the Montezuma granitoids,as well as new geochemical results for its host rocks represented by the Corrego Tingui Complex,provides new insights into the late-to post-collisional evolution of the northeastern Sao francisco paleocontinent.U-Pb zircon dates from the Montezuma granitoids spread along the Concordia between ca.2.2 Ga to 1.8 Ga and comprise distinct *** I have crystallization ages between ca.2.15 Ga and 2.05 Ga and are interpreted as inherited *** II zircon dates vary from 2.04 Ga to1.9 Ga and corresponds to the crystallization of the Montezuma granitoids,which were constrained at ca.2.03 Ga by the titanite U-Pb *** age zoning is common within the ca.1.8 Ga Group III zircon ages,being related to fluid isotopic re-setting during the Espinhaco rifiting ***εHf(t)analysis show dominantly positive values for both Group I(-4 to+9)andⅡ(-3 to+8)zircons and TDM2 model ages of 2.7-2.1 Ga and 2.5-1.95 Ga,***,the Montezuma granitoids are weakly peraluminous to metaluminous magnesian granitoids,enriched in LILES and LREE,with high to moderate Mg#and depleted in some of the *** lithochemical signature,added to the juvenile signature of both inherited and crystallized zircons,allowed its classification as a shoshonitic high Ba-Sr granitoid related to a late-to post-collisional lithosphere delamination followed by asthenospheric *** this scenario,the partial melting of the lithospheric mantle interacted with the roots of an accreted juvenile intra-oceanic arc,being these hybrid magma interpreted as the source of the Montezuma *** Corrego Tingui Complex host rocks are akin to a syn-to late-collisional volcanic arc granitoids originated from the partial melting of ancient crustal *** results presented in this study have revealed the occurrence of j

关键词： Zircon U–Pb-Hf Titanite U–Pb High Ba–Sr Late-to post-collisional Sao francisco paleocontinent

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Pesticides Exposure:The Case of Workers on Growing Grapes in San francisco Valley,Petrolina/Brazil

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Agricultural Sciences 2014年第10期5卷 805-812页

作者： francisco Alves Pinheiro Paulo Jose Adissi Department of Production Engineering Federal University of San Francisco ValleyJuazeiroBrazil Department of Production Engineering Federal University of ParaibaJoao PessoaBrazil

The objective of this work is to analyze the systems of application of pesticides used in harvesting grapes of the sub-medium San francisco valley, in relation to the risks of occupational contamination. The manual, mechanized and semi mechanized systems of application, adopted by the grape growers of the city of Petrolina/PE, have been analyzed through a method of both quantitative and qualitative evaluation. In such a way, two production units were visited: a mid-sized company and another one from of the CODEVASF. Five simulations were carried out in four systems of pesticide application using the European entire body method. Pre-application processes, such as storage and dilution of pesticides, as well as post-application processes, including equipment maintenance, cleaning and storage of clothes used for the application process were also analyzed. The results show large differences in risk among the systems that were analyzed and better conditions offered by the agricultural company, which was seeking to obtain the certification process.

关键词： Agricultural Work Growing Grapes Chemical Risk Pesticides Exposure

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Molecular Med TRI-CON 2013 : February 11-15, 2013; San francisco, CA.

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2013年

作者： Molecular Medicine TRI-CON. (2013 : San francisco CA.) Cambridge Healthtech Institute

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在古典与奇幻之间 francisco Hernandez Marzal的创意环境人像

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人像摄影 2021年第12期 12-25页

作者： Demi(采访/文) 弗朗西斯科·赫尔南德斯·马萨尔(摄影) 不详

从绘画到摄影弗朗西斯科•赫尔南德斯•马萨尔(francisco Hernandez Marzal),是一名来自西班牙瓦伦西亚的摄影师。近年来Marzal创造了众多精妙绝伦且充满想象力的作品,在广告摄影方面的成就也使他声名鹊起。

关键词：广告摄影瓦伦西亚想象力摄影师

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走进画中,讲一个故事——francisco Hernandez Marzal的创意环境人像

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人像摄影 2020年第1期 14-27页

作者： Demi(文\采访) 【西班牙】费朗西斯科·赫尔南徳斯·马萨尔(摄影) 不详

维米尔画中走出的女孩弗朗西斯科·赫尔南德斯·马萨尔(francisco Hernandez Marzal),是一名来自西班牙瓦伦西亚的摄影师。他在很小的时候,就对各类艺术形式很感兴趣,绘画就是其中之一。1994年,Marzal在瓦伦西亚理工大学获得了美术专业... 详细信息

维米尔画中走出的女孩弗朗西斯科·赫尔南德斯·马萨尔(francisco Hernandez Marzal),是一名来自西班牙瓦伦西亚的摄影师。他在很小的时候,就对各类艺术形式很感兴趣,绘画就是其中之一。1994年,Marzal在瓦伦西亚理工大学获得了美术专业的学士学位,后又获得了平面艺术的硕士学位,成为了数字图像技术方面的专家。"大学时,我沉浸在绘画世界里,进行了深入的研究和探索,也正是绘画将我引向了另一个领域一摄影."

关键词：平面艺术维米尔数字图像技术美术专业学士学位硕士学位瓦伦西亚研究和探索

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An approximate Kerr-Newman-like metric endowed with a magnetic dipole and mass quadrupole

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Communications in Theoretical Physics 2024年第8期76卷 124-138页

作者： francisco Frutos-Alfaro Space Research Center and School of Physics University of Costa RicaSan PedroSan JoseCosta Rica

Approximate all-terrain spacetimes for astrophysical applications are presented. The metrics possess five relativistic multipole moments, namely, mass, rotation, mass quadrupole, charge,and magnetic dipole moment. All these spacetimes approximately satisfy the Einstein-Maxwell field equations. The first metric is generated using the Hoenselaers-Perjés method from given relativistic multipoles. The second metric is a perturbation of the Kerr-Newman metric, which makes it a relevant approximation for astrophysical calculations. The last metric is an extension of the Hartle-Thorne metric that is important for obtaining internal models of compact objects perturbatively. The electromagnetic field is calculated using Cartan forms for locally non-rotating observers. These spacetimes are relevant for inferring properties of compact objects from astrophysical observations. Furthermore, the numerical implementations of these metrics are straightforward, making them versatile for simulating potential astrophysical applications.

关键词： Gravitation Einstein-Maxwell equations Compact objects

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