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Vertically aligned montmorillonite aerogel-encapsulated polyethylene glycol with directional heat transfer paths for efficient solar thermal energy harvesting and storage

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International Journal of Minerals,Metallurgy and Materials 2024年第5期31卷 907-916页

作者： Qijing guo Cong guo Hao Yi Feifei Jia Shaoxian Song Key Laboratory of Green Utilization of Critical Non-metallic Mineral Resources Ministry of EducationWuhan University of TechnologyWuhan 430070China School of Resources and Environmental Engineering Wuhan University of TechnologyWuhan 430070China Hubei Key Laboratory of Mineral Resources Processing and Environment Wuhan University of TechnologyWuhan 430070China

The conversion and storage of photothermal energy using phase change materials(PCMs)represent an optimal approach for harnessing clean and sustainable solar ***,we encapsulated polyethylene glycol(PEG)in montmorillonite aerogels(3D-Mt)through vacuum impregnation to prepare 3D-Mt/PEG composite *** used as a support matrix,3D-Mt can effectively prevent PEG leakage and act as a flame-retardant barrier to reduce the flammability of ***,3D-Mt/PEG demonstrates outstanding shape retention,increased thermal energy storage density,and commendable thermal and chemical *** phase transition enthalpy of 3D-Mt/PEG can reach 167.53 J/g and remains stable even after 50 heating-cooling ***,the vertical sheet-like structure of 3D-Mt establishes directional heat transport channels,facilitating efficient phonon *** configuration results in highly anisotropic thermal conductivities that ensure swift thermal responses and efficient heat *** study addresses the shortcomings of PCMs,including the issues of leakage and inadequate flame *** achieves the development and design of 3D-Mt/PEG with ultrahigh strength,superior flame retardancy,and directional heat ***,this work offers a design strategy for the preparation of high-performance composite *** 3D-Mt/PEG with vertically aligned and well-ordered array structure developed in this research shows great potential for thermal management and photothermal conversion applications.

关键词： montmorillonite aerogel polyethylene glycol phase change materials solar thermal energy storage flame retardant

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Thermodynamic and experimental study of high-temperature roasting of blast furnace gas ash for recovery of metallic zinc and iron

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Journal of Iron and Steel Research International 2024年第1期31卷 108-120页

作者： Zi-han Wang Jing guo Han-jie guo Bin Li School of Metallurgical Engineering University of Science and Technology BeijingBeijing100083China School of Metallurgical Engineering Xi’an University of Architecture and TechnologyXi’an710055ShaanxiChina

A high-temperature reduction roasting method was used to achieve metallic iron and zinc recovery from blast furnace gas ash(BFA).The reduction processes for Zn-containing and Fe-containing oxides were analyzed in detail by using ther-modynamic equilibrium calculation and the principle of minimum free *** results showed that the main reaction in the system is the reduction of ZnFe_(2)_(4)and iron *** the full temperature range,iron oxides were more easily reduced than zinc *** of the amount of CO contained in the system,the reduction of ZnO to Zn was difficult to proceed below the boiling point(906℃)of *** the reduction temperature is below 906℃,the reduction process of zinc ferrate was ZnFe_(2)_(4)→ZnO;when the reduction temperature is above 906℃,its reduction process becomed ZnFe_(2)_(4)→ZnO→Zn(g).The metallization and dezincification rates of the BFA gradually increased with increasing reaction *** the C/O ratio increased,the metallization and dezincification rates first increased and then *** effect of reduction time on BFA reduction was similar to that of reaction temperature.

关键词： Blast furnace gas ash Thermodynamics Zinc removal Iron reduction High-temperature reduction roasting Integrated utilization

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In situ anchoring in carbon matrix of Bi_(2)O_(2)CO_(3) as a high-performance anode material for Li-ion batteries

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Rare Metals 2024年第8期43卷 3634-3646页

作者： Pu-Qiang He Jun guo Hui Huang Zhong-Cheng guo Faculty of Metallurgy and Energy Engineering Kunming University of Science and TechnologyKunming 650093China Research Center of Metallurgical Electrode Materials Engineering Technology Kunming 650106China Kunming Hendera Science and Technology Co. Ltd.Kunming 650106China

Bismuth-based anode materials have been regarded as promising Li-ion batteries due to their high theoretical ***,their low conductivity and associated volume expansion inhabited their *** this work,Bi_(2)O_(2)CO_(3)@C composites were successfully synthesized by in situ anchoring of flower-like Bi_(2)O_(2)CO_(3) nanosheets on a carbon-based substrate via *** unique composited structure of Bi_2O_(2)-CO_(3)@C leads to a stable specific capacity of 547 mAh·g^(-1)after 100 cycles at a current density of 0.1 A·g^(-1).Notably,it demonstrates excellent rate capability with a specific capacity of 210 mAh·g^(-1)at 5 A·g^(-1).After 550 cycles at a current density of 0.5 A·g^(-1),a high reversible capacity of nearly 400 mAh·g^(-1)was ***,in situ X-ray diffraction measurements clearly demonstrate the conversion between Bi and Li_(3)Bi during alloying/dealloying,confirming the good electrochemical reversibility of the materials for Li *** reaction kinetics of Bi_(2)O_(2)CO_(3)@C were further investigated using galvanostatic intermittent titration ***,Bi_2O_(2)-CO_(3)@C exhibited excellent long-term stability,maintaining its high reversible capacity for over 200 cycles at a current density of 0.5 A·g^(-1)in a full cell configuration using Li_(1.20)Mn_(0.54)Ni_(0.13)Co_(0.13)O_(2) as the cathode *** result further underscores its promising potential for lithium-ion *** work may provide inspiration for the design of alloy-type negative electrode materials for high-performance rechargeable batteries.

关键词： Bi_(2)O_(2)CO_(3) Composite materials Anode materials Full batteries

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Thermogravimetric characteristics of corn straw and bituminous coal copyrolysis based the ilmenite oxygen carriers

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Chinese Journal of Chemical Engineering 2024年第4期68卷 8-15页

作者： Pengxing Yuan Xiude Hu Jingjing Ma Tuo guo Qingjie guo College of Chemical Engineering Qingdao University of Science&TechnologyQingdao 266042China State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering Ningxia UniversityYinchuan 750021China

Herein,the co-pyrolysis reaction characteristics of corn straw(CS)and bituminous coal in the presence of ilmenite oxygen carriers(OCs)are investigated via thermogravimetry coupled with mass *** results reveal that the participation of OCs weakens the devolatilization intensity of *** the CS blending ratio is<50%,the mixed fuel exhibits positive synergistic *** fitting results according to the Coats-Redfern integral method show that the solid-solid interaction between OCs and coke changes the reaction kinetics,enhancing the co-pyrolysis reactivity at the high-temperature zone(750-950C).The synergistic effect is most prominent at a 30%CS blending ratio,with copyrolysis activation energy in the range of 26.35-40.57 kJ·mol^(-1).

关键词： Oxygen carrier Co-pyrolysis Biomass Coal

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Proof of Two Supercongruences of Truncated Hypergeometric Series_(4)F_(3)

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Acta Mathematica Sinica,English Series 2024年第4期40卷 1015-1028页

作者： guo Shuai MAO Department of Mathematics Nanjing University of Information Science and TechnologyNanjing 210044P.R.China

In this paper,we prove two supercongruences conjectured by Z.-*** via the Wilf-Zeilberger *** of them is,for any prime p>3,4F3[7/6 1/2 1/2 1/2 1/6 1 1]-1/8]-1/2≡p(-2/p)+p^(3)/4(2/p)Ep-3 (mod p^(4))where(·/p)stands f... 详细信息

关键词： Supercongruence truncated hypergeometric series Wilf–Zeilberger method Euler numbers Legendre symbol

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Exploring a new path of green and efficient utilization of sinter return fine to produce composite pellets

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Journal of Iron and Steel Research International 2024年第7期31卷 1610-1622页

作者： Yan-biao Chen Wen-guo Liu Hao guo Jing-song Wang Qing-guo Xue Hai-bin Zuo State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China MCC Capital Engineering and Research Incorporation Limited Beijing 100176China

Efficient utilization of sinter return fine is an important measure to reduce cost,increase efficiency,save energy and reduce emission.A new path of green and efficient utilization of return fine was proposed to produce composite *** metallurgical properties of composite pellets under the condition of hydrogen-rich blast furnace were *** experimental results indicate that the coated concentrate was consolidated for the composite pellets through normal Fe_(2)O_(3) *** the surface of core return fine,the liquid phase formed due to its low-melting point,assimilated the adjacent concentrate,and then consolidated with the temperature *** with regular pellets,the com-pressive strength and reduction swelling index of composite pellets were decreased,but the reducibility index and softening-melting properties were *** addition,the reduction degradation index of composite pellets was sig-nificantly higher than that of ***,adding composite pellets was conducive to indirect reduction in blast furnace,reducing fuel ratio and improving production *** to the effect of the roasting system on the metallurgical properties,the roasting temperature and time were determined as 1250℃and 30 min,*** composite pellets can be produced under the traditional pelletizing process.

关键词： Sinter Return fine Composite pellet Roasting system Metallurgical property Hydrogen-rich blast furnace

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Underoil superhydrophilic flame-retardant 3D porous composite for efficient on-demand emulsion separation:Interface engineering design on sphagnum moss

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Friction 2024年第10期12卷 2222-2240页

作者： Yuyan guo Peng LIU Wenhao ZHANG Zhiguang guo Weimin LIU Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials Hubei UniversityWuhan 430062China State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou730000China

Oil pollution and the energy crisis make oil-water separation an urgent for human *** widespread use of materials with a single emulsion separation capability is *** on-demand separation materials can adapt to a wide range of application scenarios,thus having a wider range of *** underoil superhydrophilic surface is of great significance for realizing the on-demand separation of oil/water emulsions through the removal of water in the oil and oil in the water.A 3D porous emulsion separation material based on the superhydrophilic principle of sphagnum moss was *** material was prepared in a simple step by taking advantage of the adhesion of polydopamine and the introduction of the as-prepared superhydrophilic BaSO4 nanoparticles to achieve superhydrophilicity with a water contact angle(WCA)of 0°and an oil contact angle(OCA)of 157.3°,resulting in excellent separation performance for both water-in-oil and oil-in-water *** superhydrophilic porous composite(OSPC)can complete two kinds of emulsion separations by filtration or *** adsorbs water from water-in-oil emulsion to achieve separation,with a good adsorption capacity of 74.38 g/g and efficiency up to 99%.It can also filter oil-in-water emulsions with an efficiency of 99.92%.The separation efficiencies are all almost unchanged after ten separation ***,the material has excellent flame retardancy,which reduces the possibility of secondary *** three-dimensional porous sponge has excellent on-demand separation performance for multiple *** provides a new preparation strategy for underoil superhydrophilic materials and a new idea for the design direction of special wetting materials for the on-demand separation of oil/water emulsions.

关键词： on-demand emulsion separation porous absorption filtration underoil hydrophilicity superwettability

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Light People:*** Mazur speaks about ultrafast optics and education

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Light(Science & Applications) 2024年第3期13卷 402-406页

作者： Chenzi guo Yang Li Changchun Institute of Optics Fine Mechanics and PhysicsChinese Academy of SciencesChangchunChina State Key Laboratory of Precision Measurement Technology and Instrument Department of Precision InstrumentTsinghua UniversityBeijingChina

*** Mazur is a great influencer over and beyond the optics *** a physicist,he is a pioneer of ultrafast optics and was one of the inventors of colliding-pulse mode-locked *** an educator,he not only gave talks to thousands,but also revolutionized teaching with his globally renowned methodology“Peer Instruction”.As a leader and entrepreneur,he co-founded several companies and was President of Optica(formerly the Optical Society)and currently is the Chair of the Optica ***,Light:Science&Applications talked with *** Mazur about his opinions on research,education and *** full interview video can be found in the Supplementary File.

关键词： optics education companies

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CMAS-phobic and infiltration-inhibiting protective layer material for thermal barrier coatings

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Journal of Advanced Ceramics 2024年第8期13卷 1254-1267页

作者： Shjun Meng Lei guo Hongbo guo Yuanpeng Wang Hongli Liu School of Materials Science and Engineering Tianjin UniversityTianjin 300072China Tianjin Key Laboratory of Advanced Joining Technology Key Lab of Advanced Ceramics and Machining Technology of Ministry of EducationTianjin300072China School of Materials Science and Engineering Beihang UniversityBeijing 100191China College of Aeronautical Engineering Civil Aviation University of ChinaTianjin 300300China

Calcium-magnesium-alumina-silicate(CMAS)corrosion has attracted special attention in the thermal barrier coating(TBC)*** high temperatures,when CMAS melts,it adheres to the coating surface and penetrates the interior,severely destroying the *** this study,a promising CMAS-phobic and infiltration-inhibiting material,GdPO4,on which molten CMAs is difficult to wet and penetrate,was *** desirable attributes are explained by analyzing the material characteristics of GdPO_(4) and its interfacial reaction with ***4 is demonstrated to have low surface energy,making it difficult for molten CMAS to wet and adhere to the *** in contact with molten CMAS,a double-layer structured reaction layer consisting of an acicular upper sublayer and a compact lower sublayer is formed on the GdPO4 surface,which can effectively impede molten CMAS spreading and ***-principles calculation results revealed that the reaction layer has low surface energy and low adhesion to CMAS,which are favorable for molten CMAS ***,the formation of the reaction layer increases the viscosity of the molten CMAS,which can increase melt wetting and ***,GdPO4,which exhibits excellent CMAS-phobicity and infiltration-inhibiting ability,is a promising protective layer material for TBCs against CMAS adhesion and attack.

关键词： thermal barrier coatings(TBCs) calcium-magnesium-alumina-silicate(CMAS)-phobicity GdPO_(4) interface reaction layer first-principles calculation

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风力发电应用技术研究

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建筑电气 2019年第5期38卷 26-29页

作者：孔令兵申蕾郭凤群中船第九设计研究院工程有限公司

面对气候变暖和能源危机双重压力,寻求和发展可替代传统能源的新型能源已成为当前迫切需要解决的问题。风电作为迄今为止最具大规模开发价值的清洁能源已逐渐发展成为最具代表性的替代能源。本文就风力发电的应用技术进行研究探讨,并根... 详细信息

面对气候变暖和能源危机双重压力,寻求和发展可替代传统能源的新型能源已成为当前迫切需要解决的问题。风电作为迄今为止最具大规模开发价值的清洁能源已逐渐发展成为最具代表性的替代能源。本文就风力发电的应用技术进行研究探讨,并根据国内某个以山地为主地区的实际风能资源进行风电场内风电机组的优化布置和发电量计算。

关键词：能源危机清洁能源风力发电风能资源风电场风电机组风谱图尾流效应

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