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Thermodynamic analysis, synthesis, characterization, and evaluation of 1-ethyl-3-methylimidazolium chloride: Study of its effect on pretreated rice husk

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中国化学工程学报:英文版 2023年第8期60卷 143-154页

作者： Eileen Katherine Coronado-Aldana Cindy Lizeth Ferreira-Salazar Nubia Yineth Piñeros-Castro Rubén Vázquez-Medina felipe A.Perdomo Universidad de BogotáJorge Tadeo Lozano Facultad de Ciencias Naturales e IngenieríaCra.422-61CundinamarcaBogotáColombia Instituto Politecnico Nacional CICATA QueretaroCerro Blanco 141Colinas del Cimatario76090 QueretaroMexico School of Engineering University of EdinburghEdinburgh EH93FBUnited Kingdom

This work is focused on the determination of the optimal reaction conditions to synthesize the ionic liquid 1-ethyl-3-methylimidazolium chloride([EMIM][Cl]) and assess its suitability for the pretreatment of rice husk. The modified UNIFAC(UNIversal quasi-chemical Functional-group Activity Coefficients)approach for ionic liquids is used to develop a thermodynamic model that describes the reactive system methylimidazole(MIM), chloroethane(C_(2)H_(5)Cl) and [EMIM][Cl]. The model allows to study the phase equilibria coexistence(vapor–liquid equilibria and solid–liquid equilibria) and yields the theoretically optimal conditions to synthesize the ionic liquid. The model predictions are validated with the available experimental and reported data. By implementing the developed model, a simple way to synthesize ionic liquid [EMIM][Cl] was found allowing to study its influence on the structure and morphology of pretreated rice husk. The lignocellulosic materials involved in this study are characterized by their composition, enzymatic digestibility, scanning electron microscopy, and crystallinity. Compared to untreated material, [EMIM][Cl]-pretreated rice husk produces cellulose that can be efficiently enzymatic hydrolyzed with high sugar yields. This work offers a suitable methodology to include the synthesis and thermodynamics of the solvent media within the design of low-cost ionic liquids for lignocellulosic biomass pretreatment.

关键词： Ionic liquids Fluid-phase equilibria Thermodynamics Waste treatment UNIFAC approach

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Congenital heart diseases trends in S?o Paulo State,Brazil:a national live birth data bank analysis

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World Journal of Pediatrics 2022年第7期18卷 472-481页

作者： Paola Soares Fernandes Larissa Rosario Magalhaes Tainara Rita Pezzini Edige felipe de Sousa Santos Mauricio Giusti Calderon Medical School Nine of July University(Uni9).Sao Bernardo do CampoSPBrazil Epidemiology Department Public Health SchoolSao Paulo University(USP)Sao PauloSPBrazil Pediatric Surgery Department Hospital Benficencia Portuguesa de Sao PauloRua Maestro Cardim768Sao PauloSP CEP 01323-011Brazil Pediatric Surgery Department Hospital Santa Catarina PaulistaAv.Paulista200.Sao PauloSP CEP:01310-000Brazil

Background Congenital heart diseases(CHD)are the most common type of birth defects,affecting millions of newborns every year;no prevalence data are available in S?o Paulo State,Brazil's most populous *** objective is to identify trends in prevalence and risk factors for CHD in Sao Paulo State,*** We developed a population-based study to estimate the CHD trend of prevalence in recent years,stratified by maternal age and geographical clusters,using all cases of CHD identified by the Live Births Information System(SINASC-Sistema de Informa??o Sobre Nascidos Vivos)from January 1,2005,to December 31,*** calculated the trends of prevalence,the regression coefficient(β),the annual percent change(APC),and 95%confidence interval using the Prais-Winsten regression model,with the Durbin-Watson *** We found 10,594 cases of CHD among 8,536,101 live births(LB),a prevalence of 12.4/10,000 *** was no difference in the sex distribution;they are primarily Caucasian(60.2%),75.2%born at term,and 74.4%weight>2500 g,66.9%of births were by cesarean section.S?o Paulo State presented an increasing CHD trend of prevalence(APC=18.9%).The highest CHD prevalence rate was in mothers aged≥35 years(22.2/10,000 LB).There were 12,271 specific congenital heart defects among 10,594 patients(1.16 CHD/patient).Atrial septal defect has the highest number of cases(3835),with a prevalence of 4.49/10,000 LB,corresponding to 31.3%of all *** CHD had an increasing prevalence trend in recent years,being highest in S?o Paulo City and≥35-year mothers.

关键词： Congenital abnormalities Epidemiology Heart defects Interrupted time series PrevalencePublic health

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Adsorbents Derived from Xylan Hemicellulose with Removal Properties of Pollutant Metals

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Chinese Journal of Polymer Science 2023年第6期41卷 874-886,I0007页

作者： Elizabeth Elgueta Yerko Becerra Ana Martínez Miguel Pereira Isabel Carrillo-Varela felipe Sanhueza Dariela Nuez BernabéL.Rivas Centro de Investigación de Polímeros Avanzados CIPAAvenida Collao 1202Edificio de LaboratoriosConcepcionChile Departamento de Química Ambiental Facultad de CienciasUniversidad Católica de la Santísima ConcepciónCaila 160-cConcepcionChile Polymer Department Faculty of ChemistryUniversity of ConcepciónCasilla 160-CConcepcionChile Departamento de Ingeniería Química Facultad de IngenieríaUniversidad de ConcepciónConcepcionChile Department of Materials Engineering Faculty of EngineeringUniversidad de ConcepciónConcepcionChile

The adsorption capacity of hydrogels derived from modified xylan hemicellulose has been tested in order to develop new bio-based adsorbent materials useful for removing metal ions pollutants,such as Cd(Ⅱ),Cu(Ⅱ)and Pb(Ⅱ)from an aqueous *** was extracted from bleached kraft pulp of eucalyptus and subsequently modified with different proportions of functional sulfonic acid groups(HA3-HA7)and sulfonate groups(HS30-HS70)to generate *** results showed that all the synthesized hydrogels were capable of adsorbing metal ions,being the hydrogels with 30%and 50%xylan the ones that presented the highest adsorption *** capacity studies at different initial concentrations revealed that at an initial concentration of 300 mg·L-1,the HA3 hydrogel presented an adsorption capacity of 193mg Pb(Ⅱ),182 mg Cd(Ⅱ),and 66 mg Cu(Ⅱ)per g *** HA5 hydrogel presented a capacity of 185 mg Pb(Ⅱ),113 mg Cd(Ⅱ),and 48 mg Cu(Ⅱ)per g *** HS30 hydrogel exhibited an adsorption of 205 mg Pb(Ⅱ),174 mg Cd(Ⅱ),and 71 mg Cu(Ⅱ)per g hydrogel,and HS50 hydrogel exhibited an adsorption capacity of 273 mg Pb(Ⅱ),143 mg Cd(Ⅱ),and 45 mg Cu(Ⅱ)per g *** results show that modified Xylan hemicellulose is a promising adsorbent for removal Cd(Ⅱ),Cu(Ⅱ),and Pb(Ⅱ)ions from aqueous solutions.

关键词： Pb(Ⅱ) solution capacity

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On the Tractability of Shortest Path Problems in Weighted Edge-Coloured Graphs

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Journal of Systems Science & Complexity 2018年第2期31卷 527-538页

作者： ENSOR Andrew LILLO felipe School of Computing and Mathematical Sciences Auckland University of Technology 2 - 14 Wakefield St Auckland 1142 New Zealand Department of Economics and Management Universidad Catolica del Maule PO Box 617 Avenida San Miguel 3605 Talca Chile

A weighted edge-coloured graph is a graph for which each edge is assigned both a positive weight and a discrete colour, and can be used to model transportation and computer networks in which there are multiple transportation modes. In such a graph paths are compared by their total weight in each colour, resulting in a Pareto set of minimal paths from one vertex to another. This paper will give a tight upper bound on the cardinality of a minimal set of paths for any weighted edge-coloured graph. Additionally, a bound is presented on the expected number of minimal paths in weighted edge-bicoloured graphs. These bounds indicate that despite weighted edge-coloured graphs are theoretically intractable, amenability to computation is typically found in practice.

关键词： Edge-coloured chain graph minimal paths multimodal networks Pareto set cardinality upper bounds.

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Queens remate despite traumatic mating in stingless bees

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Current Zoology 2022年第1期68卷 81-92页

作者： Jamille Costa VEIGA Gustavo Rodrigo Sanches RUIZ Gislene Almeida CARVALHO-ZILSE Cristiano MENEZES felipe Andres Leon CONTRERA Bee Biology and Ecology Lab Instituto de Ciencias BiologicasUniversidade Federal do ParaBelem66075-110 ParaBrazil Biodiversity and Ecosystem Services Research Group Instituto Tecnologico Vale-Desenvolvimento SustentavelBelem66055-090 ParaBrazil Ecology and Zoology of Invertebrates Lab Instituto de Ciencias BiologicasUniversidade Federal do ParaBelem66075-110 ParaBrazil Bee Research Group Instituto Nacional de Pesquisas da AmazoniaManaus69067-375 AmazonasBrazil Research and Development Embrapa Meio AmbienteJaguariuna13820-000 Sao PauloBrazil

Males can control female reproduction using genital plugs to impede access by *** social bees,ants,and wasps,plugging may involve traumatic mating,with females being *** stingless bees,chances are that plugs may promote ovarian activan,and are thought to ensure single mating—a general tendency among the social ***,understanding on relationships between mating plugs,traumatic mating,and mating systems in stingless bees remains *** address this,we(1)compared mated queens of 7 Neotropical species to understand the patterns of copulatory marks in females and(2)compared pre-and post-mating genitalia of males and females in Melipona fasciculata to depict plug functional *** revealed an unprecedented consequence of mating in stingless bees:the characteristic marks left by mating plugs on female abdomens and the inferences that can be made from *** our surprise,in 1 species *** we found that queens retain the plug long after mating,and may carry it for the rest of their *** the other 6 species retained the plug for only a short *** queens were only found in ***,whose multiple copulatory marks match previous findings of polyandry in this *** study shows that queens can remate,and suggests that male genital morphology may determine in part the time persistence of *** conclude that traumatic mating plugs do not fully prevent remating in stingless bees and that mating systems are not uniform in this ***,exceptional cases of facultative polyandry in social insects—for example,when mating plugs fail—may confirm a general tendency for single mating in close link with efficient mating plugs.

关键词： copulatory marks facultative polyandry genital morphology male harm sexual conflict

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An interactive tool for visualization and prediction of solar radiation and photovoltaic generation in Colombia

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Big Earth Data 2023年第3期7卷 904-929页

作者： Gabriel Narvaez Luis felipe Giraldo Michael Bressan Camilo A.Guillen María A.Pabón Nicolás Díaz Manuel felipe Porras Brayan Herney Medina Fernando Jiménez Guillermo Jiménez-Estévez Andres Pantoja Corinne Alonso Department of Electrical and Electronic Engineering Universidad de Los AndesBogotáColombia Laboratory for Analysis and Architecture of Systems ToulouseFrance Department of BiomedicalEngineering Universidad de Los AndesBogotáColombia Department of Systems Engineering Corporacion Universitaria del HuilaNeivaColombia Department of Electronic Engineering Universidad deNariñoPastoColombia

This paper presents the building process of an interactive instrument called the Colombian Solar Atlas able to easily visualize meteorological data but also assess the current and future potentials of solar photovoltaic generation throughout the whole territory of Colombia,South *** new tool is based on two different meteorological *** first one is done with historical data extracted from satellite imagery information,and the other one corresponds to data issues from regional-scale climate change projection *** satellite database was validated with different in-situ *** Colombian Solar Atlas uses basic and advanced photovoltaic generation models to estimate the generation of a custom solar *** this tool,a user selects a point on the map and can have directly pertinent information to search for an optimal location with a spatial resolution of 4 *** tool is the first open interactive online tool particularly adapted to study the photovoltaic power potential in Colombia,considering the country’s needs and native language.

关键词： Solar atlas PV power potential climate change Colombia data validation

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Pile Running in Layered Soils

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China Ocean Engineering 2023年第5期37卷 829-841页

作者： ZHAO Huan WANG Le SUN Li-qiang TIAN Ying-hui oliver REUL CHEN Quan-zhen State Key Laboratory of Hydraulic Engineering Intelligent Construction and Operation Tianjin UniversityTianjin 300072China Department of Infrastructure Engineering The University of MelbourneParkvilleVictoria 3010Australia Department of Geotechnical Engineering University of KasselKassel 34109Germany

This paper presents a case study on incidents of offshore pile running in layered *** study provides a detailed description of the seabed soil data,pile driving records,and field surveillance video ***-dimensional large deformation finite element(LDFE)analyses were conducted to retrospectively analyze the incidents,considering the remoulding of seabed soil and degradation of the pile-soil interface in the LDFE *** comparing the field observations with the LDFE analysis,the mechanism of pile running was discussed,with a focus on investigating the pile penetration resistance in each *** study revealed that pile running in layered soils primarily resulted from a significant reduction in pile base resistance when transitioning from a strong layer to an adjacent weak *** further investigate the pile running mechanism in layered soils,a parametric study on the strength variation of adjacent soil layers and its influence on pile base resistance was ***,a simplified prediction model of pile base resistance,suitable for assessing the risk of pile running in layered soils,was proposed.

关键词： pile running coupled Eulerian−Lagrangian method layered soil penetration resistance pile−soil interaction

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Light-Driven Ion Transport in Nanofluidic Devices:Photochemical,Photoelectric,and Photothermal Effects

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CCS Chemistry 2022年第1期4卷 54-65页

作者： Kai Xiao oliver G.Schmidt Department of Biomedical Engineering Southern University of Science and Technology(SUSTech)Shenzhen 518055 Center for Materials Architectures and Integration of Nanomembranes(MAIN)Chemnitz University of TechnologyChemnitz 09126 Institute for Integrative Nanosciences Leibniz IFW DresdenDresden 01069

Light-driven ion transport in nanofluidic devices is a phenomenon where ions move unidirectionally by consuming optical energy,either from low concentration to high concentration or vice *** light-driven unidirectional ion transport offers intriguing application potential in desalination and ion separation,osmosis energy harvesting,and ionic machines benefiting from the remote noncontact light ***,we review recent progress in nanofluidic-based light-driven ion transport systems and emphasize similarities and differences in the three underlying working principles based on photochemical,photoelectric,and photothermal *** current challenges and future developments of light-driven ion transport in nanofluidic devices are *** believed that this article encourages further innovation in this exciting and emerging research field.

关键词： nanofluidic artificial ion pump nanochannel ion transport photoelectric effect

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Optimal Deep Dense Convolutional Neural Network Based Classification Model for COVID-19 Disease

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Computers, Materials & Continua 2022年第1期70卷 2031-2047页

作者： A.Sheryl oliver P.Suresh A.Mohanarathinam Seifedine Kadry Orawit Thinnukool Department of Computer Science and Engineering St.Joseph’s College of Engineering600119ChennaiIndia Department of Computer Science and Engineering KPR Institute of Engineering and TechnologyCoimbatore641407India Faculty of Engineering Karpagam Academy of Higher EducationCoimbatore641021India Faculty of Applied Computing and Technology Noroff University CollegeKristiansand4608Norway Research Group of Embedded Systems and Mobile Application in Health Science College of ArtsMedia and TechnologyChiang Mai UniversityChiang Mai50200Thailand

Early diagnosis and detection are important tasks in controlling the spread of COVID-19.A number of Deep Learning techniques has been established by researchers to detect the presence of COVID-19 using CT scan images and ***,these methods suffer from biased results and inaccurate detection of the ***,the current research article developed Oppositional-based Chimp Optimization Algorithm and Deep Dense Convolutional Neural Network(OCOA-DDCNN)for COVID-19 prediction using CT images in IoT *** proposed methodology works on the basis of two stages such as pre-processing and ***,CT scan images generated from prospective COVID-19 are collected from open-source system using IoT *** collected images are then preprocessed using Gaussian *** filter can be utilized in the removal of unwanted noise from the collected CT scan ***,the preprocessed images are sent to prediction *** this phase,Deep Dense Convolutional Neural Network(DDCNN)is applied upon the pre-processed *** proposed classifier is optimally designed with the consideration of Oppositional-basedChimp Optimization Algorithm(OCOA).This algorithm is utilized in the selection of optimal parameters for the proposed ***,the proposed technique is used in the prediction of COVID-19 and classify the results as either COVID-19 or *** projected method was implemented in MATLAB and the performances were evaluated through statistical *** proposed method was contrasted with conventional techniques such as Convolutional Neural Network-Firefly Algorithm(CNN-FA),Emperor Penguin Optimization(CNN-EPO)*** results established the supremacy of the proposed model.

关键词： Deep learning deep dense convolutional neural network covid-19 CT images chimp optimization algorithm

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Optimal Deep Convolutional Neural Network with Pose Estimation for Human Activity Recognition

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Computer Systems Science & Engineering 2023年第2期44卷 1719-1733页

作者： S.Nandagopal G.Karthy A.Sheryl oliver M.Subha Department of Computer Science and Engineering Nandha College of TechnologyErode638052TamilnaduIndia Department of Electronics and Communication Engineering Kalasalingam Academy of Research and EducationKrishnankoil626126TamilnaduIndia Department of Computer Science and Engineering St.Joseph's College of EngineeringChennai600119TamilnaduIndia Department of Electronics and Communication Engineering University College of Engineering NagercoilNagercoil629004TamilnaduIndia

Human Action Recognition(HAR)and pose estimation from videos have gained signiﬁcant attention among research communities due to its applica-tion in several areas namely intelligent surveillance,human robot interaction,robot vision,*** considerable improvements have been made in recent days,design of an effective and accurate action recognition model is yet a difﬁcult process owing to the existence of different obstacles such as variations in camera angle,occlusion,background,movement speed,and so *** the literature,it is observed that hard to deal with the temporal dimension in the action recognition *** neural network(CNN)models could be used widely to solve *** this motivation,this study designs a novel key point extraction with deep convolutional neural networks based pose estimation(KPE-DCNN)model for activity *** KPE-DCNN technique initially converts the input video into a sequence of frames followed by a three stage process namely key point extraction,hyperparameter tuning,and pose *** the keypoint extraction process an OpenPose model is designed to compute the accurate key-points in the human ***,an optimal DCNN model is developed to classify the human activities label based on the extracted key *** improving the training process of the DCNN technique,RMSProp optimizer is used to optimally adjust the hyperparameters such as learning rate,batch size,and epoch *** experimental results tested using benchmark dataset like UCF sports dataset showed that KPE-DCNN technique is able to achieve good results compared with benchmark algorithms like CNN,DBN,SVM,STAL,T-CNN and so on.

关键词： Human activity recognition pose estimation key point extraction classiﬁcation deep learning RMSProp

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