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Remarkable catalysis of spinel ferrite XFe2O4(X=Ni,Co,Mn,Cu,Zn)nanoparticles on the dehydrogenation properties of LiAlH_(4):An experimental and theoretical study

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Journal of Materials Science & Technology 2022年第16期111卷 189-203页

作者： Sheng Wei Jiaxi Liu Yongpeng Xia Huanzhi Zhang Riguang Cheng Lixian Sun Fen Xu Pengru Huang federico rosei Aleskey A.Pimerzin Hans Jüergen Seifert Hongge Pan School of Material Science&Engineering Guangxi Key Laboratory of Information Materials and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and MaterialsGuilin University of Electronic TechnologyGuilin 541004China School of Mechanical&Electrical Engineering Guilin University of Electronic TechnologyGuilin 541004China CentreÉnergie Matériaux et TélécommunicationsInstitut National de la Recherche Scientifique1650 Boul.Lionel BouletVarennesJ3×1S2QuébecCanada Samara State Technical University Samara443100Russia Institute for Applied Materials Karlsruhe Institute of TechnologyHermann von Helmholtz Platz 176344 Eggenstein LeopoldshafenGermany School of New Energy Science and Technology Xi’an Technological UniversityXi’an 710021China

Safe,compact,lightweight and cost-effective hydrogen storage is one of the main challenges that need to be addressed to effectively deploy the hydrogen economy.LiAlH_(4),as a solid-state hydrogen storage material,presents several advantages such as high hydrogen storage capacity,low price and abundant sources.Unfortunately,neither thermodynamic nor kinetic properties of dehydrogenation for LiAlH_(4)can fulfill the requirements of practical application.Thus,a series of spinel ferrite nanoparticles such as XFe_(2)O_(4)(X=Ni,Co,Mn,Cu,Zn,Fe)were prepared by using the modified thermal decomposition method,and then doped into LiAlH_(4)by using ball milling.Our results show that LiAlH_(4)doped with 7 wt%NiFe_(2)O_(4)starts to release hydrogen at 69.1°C,and the total amount of hydrogen released is 7.29 wt%before 300°C.The activation energies of the two-step hydrogen release reactions of LiAlH_(4)doped with 7 wt%NiFe_(2)O_(4)are 42.32 kJ mol^(-1)and 71.42 k J mol,which are 59.0%and 63.6%lower than those of as-received LiAlH_(4),respectively.Combining the density functional theory(DFT)calculations,we reveal that both the presence of Ni FeOand in-situ formed AlNiin ball-milling decrease the desorption energy barrier of Al-H bonding in LiAlH_(4)and accelerate the breakdown of Al-H bonding through the interfacial charge transfer and the dehybridization of the Al-H cluster.Thus,the experimental and theoretical results open a new avenue toward designing high effective catalysts applied to LiAlH_(4)as a candidate for hydrogen storage.

关键词： Hydrogen storage Lithium aluminum Spinel ferrite nanoparticles

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Guanine-assisted N-doped ordered mesoporous carbons as efficient capacity decaying suppression materials for lithium–sulfur batteries

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Journal of Materials Science & Technology 2022年第6期101卷 155-164页

作者： Riguang Cheng Yanxun Guan Yumei Luo Chenchen Zhang Yongpeng Xia Sheng Wei Mengmeng Zhao Qi Lin Hao Li Shiyou Zheng federico rosei Lixian Sun Fen Xu Hongge Pan School of Material Science&Engineering Guangxi Key Laboratory of Information Materials and Guangxi Collaborative Innovation Center of Structure and Property for New Energy and MaterialsGuilin University of Electronic TechnologyGuilin 541004China School of Mechanical&Electrical Engineering Guilin University of Electronic TechnologyGuilin 541004China School of Material Science&Engineering University of Shanghai for Science&TechnologyShanghai 200093China CentreÉnergie Matériaux et TélécommunicationsInstitut National de la Recherche Scientifique1650 Boul.Lionel BouletVarennesJ3×1S2QuébecCanada School of New Energy Science and Technology Xi’an Technological UniversityChina

Lithium–sulfur(Li–S)batteries are considered promising next-generation energy storage devices due to their high weight capacities and theoretical energy densities,which are significantly higher than those of conventional lithium-ion batteries.However,the sulfur cathode presents two major drawbacks,specifically low specific capacity caused by the poor electrical conductivities of the active materials and fast capacity decay caused by polysulfide dissolution/shuttling.Herein,a high-rate and high-stability dendritic material consisting of N-doped ordered mesoporous carbons(NOMCs)was successfully synthesized via a facile and low-cost calcination method.The highly ordered mesoporous carbon skeleton limited the growth of the sulfur nanofiller within its channels and provided the necessary electrical contact with the insulating sulfur.Furthermore,N-doped heteroatoms presented strong binding sites for trapping polysulfide intermediates,achieving high electrochemical activity,which promoted polysulfide conversion reactions.As a result,the prepared NOMC-2/S cathode material with 1.2-1.5 mg cm^(-2)of sulfur displayed excellent electrochemical performance with a high-rate capability of 460.5 m Ah g^(-1)at 1 C,a high specific capacity of 530.9 m Ah g^(-1)after 200 cycles at 0.1 C,and a decay rate of~0.19%per cycle.

关键词： Lithium–sulfur batteries N-doped ordered mesoporous carbons Electrochemistry

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Oxygen-promoted synthesis of armchair graphene nanoribbons on Cu(111)

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Science China Chemistry 2021年第4期64卷 636-641页

作者： Penghui Ji Oliver MacLean Gianluca Galeotti Dominik Dettmann Giulia Berti Kewei Sun Haiming Zhang federico rosei Lifeng Chi Jiangsu Key Laboratory for Carbon-Based Functional Materials&Devices Institute of Functional Nano&Soft MaterialsSoochow UniversitySuzhou 215123China Centre Energie Matériaux et TélécommunicationsInstitut National de la Recherche Scientifique1650 Boulevard Lionel-BouletVarennesQCCanada Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 610054China Deutsches Museum Museumsinsel 180538 MunichGermany Research Center for Advanced Measurement and Characterization National Institute for Materials ScienceTsukubaIbaraki 305-0047Japan

We report the systematic investigation of the effects of oxygen on the synthesis of 3 p sub-family armchair graphene nanoribbons(3 p-AGNRs),which revealed a strong catalytic effect with a reduction in the reaction temperature by approximately 180 K without degradation of the AGNRs.Poly(para-phenylene)(3-AGNR)was generated through Ullmann-type coupling of4,4’’-dibromo-p-terphenyl on Cu(111),which was then converted into wider 3 p-AGNRs via lateral fusion.Scanning tunneling microscopy(STM)and X-ray photoelectron spectroscopy demonstrated the formation of different ribbons up to 12-AGNR,which contained regions exhibiting increased STM contrast that we attribute to the intercalation of Br atoms during lateral fusion.

关键词： on-surface synthesis graphene nanoribbons C–H activation scanning tunneling microscopy X-ray photoelectron spectroscopy

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Asymmetric electrode design with built-in nitrogen transfer channel achieving maximized three-phase reaction region for electrochemical ammonia synthesis

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Electron 2023年第1期1卷 50-58页

作者： Chao Wang Qiyang Cheng Mengfan Wang Sisi Liu Yanzheng He Chengwei Deng Yi Sun Tao Qian Na Xu federico rosei Chenglin Yan Collaborative Innovation Center of Suzhou Nano Science and Technology College of EnergySoochow UniversitySuzhouChina Aerospace Hydrogen Energy Technology(Shanghai)Co.Ltd. ShanghaiChina School of Chemistry and Chemical Engineering Nantong UniversityNantongChina Light Industry Institute of Electrochemical Power Sources SuzhouChina Institut National de la Recherche Scientifique VarennesQuebecCanada

Carbon-free electrochemical nitrogen reduction reaction(NRR)is an appealing strategy for green ammonia synthesis,but there is still a significant performance bottleneck.Conventional working electrode is usually flooded by the electrolyte during the NRR test,and only the surface material could get access to the nitrogen,which inevitably gives rise to sluggish reaction rate.Herein,an asymmetric electrode design is proposed to tackle this challenge.An aerophilic layer is constructed on one face of the electrocatalyst-loaded electrode,while the other side maintains its original structure,aiming to achieve facilitated nitrogen transfer and electrolyte permeation within the conductive skeleton simultaneously.This asymmetric architecture affords extensive threephase reaction region within the electrode as demonstrated by the combination of theoretical simulations and experimental measurements,which gives full play to the loaded electrocatalyst.As expected,the proofof-concept asymmetric electrode delivers an NH_(3)yield rate of 40.81μg h^(−1)mg^(−1)and a Faradaic efficiency of 71.71%at−0.3 V versus the reversible hydrogen electrode,which are more than 4 and 7 times that of conventional electrode,respectively.This work presents a versatile strategy for enhancing the interfacial reaction kinetics and is instructive to electrode design for gas-involved electrochemical reactions.

关键词： ammonia synthesis asymmetric electrode nitrogen reduction nitrogen transfer threephase reaction region

Dynamical evolution of Ge quantum dots on Si(111):From island formation to high temperature decay

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Aggregate 2022年第4期3卷 114-120页

作者： Navathej Preetha Genesh Fabrizio De Marchi Stefan Heun Stefano Fontana Rachid Belkhou Rahul Purandare Nunzio Motta Anna Sgarlata Massimo Fanfoni Jennifer MacLeod Oliver MacLean federico rosei CentreÉnergie Matériaux et TélécommunicationsInstitut National de la Recherche ScientifiqueQuébecCanada NEST Istituto Nanoscienze-CNR and Scuola Normale SuperiorePisaItaly Sincrotrone Trieste SCpA BasovizzaItaly LURE UniversitéParis-SudOrsay CedexFrance School of Chemistry and Physics and Centre for Materials Science Queensland University of TechnologyBrisbaneAustralia Dipartimento di Fisica Universitàdi Roma“Tor Vergata”RomeItaly Key Laboratory of Functional Materials Physics and Chemistry of the Ministry of Education Jilin Normal UniversityChangchunP.R.China

Heteroepitaxial growth is a process of profound fundamental importance as well as an avenue to realize nanostructures such as Ge/Si quantum dots(QDs),with appealing properties for applications in opto-and nanoelectronics.However,controlling the Ge/Si QD size,shape,and composition remains a major obstacle to their practical implementation.Here,Ge nanostructures on Si(111)were investigated in situ and in real-time by low energy electron microscopy(LEEM),enabling the observation of the transition from wetting layer formation to 3D island growth and decay.The island size,shape,and distribution depend strongly on the growth temperature.As the deposition temperature increases,the islands become larger and sparser,consistent with Brownian nucleation and capture dynamics.At 550◦C,two distinct Ge/Si nanostructures are formed with bright and dark appearances that correspond to flat,atoll-like and tall,faceted islands,respectively.During annealing,the faceted islands increase in size at the expense of the flat ones,indicating that the faceted islands are thermodynamically more stable.In contrast,triangular islands with uniform morphology are obtained from deposition at 600◦C,suggesting that the growth more closely follows the ideal shape.During annealing,the islands formed at 600◦C initially show no change in morphology and size and then rupture simultaneously,signaling a homogeneous chemical potential of the islands.These observations reveal the role of dynamics and energetics in the evolution of Ge/Si QDs,which can serve as a step towards the precise control over the Ge nanostructure size,shape,composition,and distribution on Si(111).

关键词： epitaxial growth GeSi heterostructures low energy electron microscopy

Facing ethical concerns in the age of precise gene therapy:Outlook on inherited arrhythmias

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World Journal of Cardiology 2024年第2期16卷 64-66页

作者： federico Carbone Fabrizio Montecucco Department of Internal Medicine University of GenoaGenoa 16132Italy IRCCS Ospedale Policlinico San Martino Genoa Italian Cardiovascular NetworkGenoa 16132Italy

This editorial,comments on the article by Spartalis et al published in the recent issue of the World Journal of Cardiology.We here provide an outlook on potential ethical concerns related to the future application of gene therapy in the field of inherited arrhythmias.As monogenic diseases with no or few therapeutic options available through standard care,inherited arrhythmias are ideal candidates to gene therapy in their treatment.Patients with inherited arrhythmias typically have a poor quality of life,especially young people engaged in agonistic sports.While genome editing for treatment of inherited arrhythmias still has theoretical application,advances in CRISPR/Cas9 technology now allows the generation of knock-in animal models of the disease.However,clinical translation is somehow expected soon and this make consistent discussing about ethical concerns related to gene editing in inherited arrhythmias.Genomic off-target activity is a known technical issue,but its relationship with ethnical and individual genetical diversity raises concerns about an equitable accessibility.Meanwhile,the costeffectiveness may further limit an equal distribution of gene therapies.The economic burden of gene therapies on healthcare systems is is increasingly recognized as a pressing concern.A growing body of studies are reporting uncertainty in payback periods with intuitive short-term effects for insurance-based healthcare systems,but potential concerns for universal healthcare systems in the long term as well.Altogether,those aspects strongly indicate a need of regulatory entities to manage those issues.

关键词： Ethics Inherited arrhythmias CRISPR/Cas9 Gene therapy Equitable accessibility

CBE Clima Tool:A free and open-source web application for climate analysis tailored to sustainable building design

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Building Simulation 2024年第3期17卷 493-508页

作者： Giovanni Betti federico Tartarini Christine Nguyen Stefano Schiavon Center for the Built Environment University of California BerkeleyBerkeleyUSA Berkeley Education Alliance for Research in Singapore SingaporeSingapore Heat and Health Research Incubator Faculty of Medicine and HealthThe University of SydneyCamperdownAustralia College of Letters and Sciences University of California BerkeleyBerkeleyUSA

Climate-responsive building design holds immense potential for enhancing comfort,energy efficiency,and environmental sustainability.However,many social,cultural,and economic obstacles might prevent the wide adoption of designing climate-adapted buildings.One of these obstacles can be removed by enabling practitioners to easily access,visualize and analyze local climate data.The CBE Clima Tool(Clima)is a free and open-source web application that offers easy access to publicly available weather files and has been created for building energy simulation and design.It provides a series of interactive visualizations of the variables contained in the EnergyPlus Weather Files and several derived ones like the UTCI or the adaptive comfort indices.It is aimed at students,educators,and practitioners in the architecture and engineering fields.Since its inception,Clima’s user base has exhibited robust growth,attracting over 25,000 unique users annually from across 70 countries.Our tool is poised to revolutionize climate-adaptive building design,transcending geographical boundaries and fostering innovation in the architecture and engineering fields.

关键词： architectural design climate analysis sustainable building design web application building energy simulation open-source software

Distinct vibrational signatures and complex phase behavior in metallic oxygen

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Matter and Radiation at Extremes 2024年第2期9卷 4-11页

作者： Philip Dalladay-Simpson Bartomeu Monserrat Li Zhang federico Gorelli Center for High Pressure Science Technology Advanced Research 1690 Cailun RoadShanghai 201203China Department of Materials Science and Metallurgy University of Cambridge27 Charles Babbage RoadCambridge CB3 OFSUnited Kingdom Cavendish Laboratory University of CambridgeJ.J.Thomson AvenueCambridge CB3 OHEUnited Kingdom Istituto Nazionale di Ottica Consiglio Nazionale delle Ricerche(CNR-INO)50125 FlorenceItaly Shanghai Advanced Research in Physical Sciences(SHARPS) ShanghaiChina

Evidence for metallization in dense oxygen has been reported for over 30 years[Desgreniers et al.,J.Phys.Chem.94,1117(1990)]at a now routinely accessible 95 GPa[Shimizu et al.,Nature 393,767(1998)].However,despite the longevity of this result and the technological advances since,the nature of the metallic phase remains poorly constrained[Akahama et al.,Phys.Rev.Lett.74,4690(1995);Goncharov et al.,Phys.Rev.B 68,224108(2003);Ma,Phys.Rev.B 76,064101(2007);and Weck et al.,Phys.Rev.Lett.102,255503(2009)].In this work,through Raman spectroscopy,we report the distinct vibrational characteristics of metallicζ-O_(2) from 85 to 225 GPa.In comparison with numerical simulations,weﬁnd reasonable agreement with the candidate structure up to about 150 GPa.At higher pressures,the C2/mstructure is found to be unstable and incompatible with experimental observations.Alternative candidate structures,and Ci,with C2/m C2/conly two molecules in the primitive unit cell,are found to be stable and more compatible with measurements above 175 GPa,indicative of the dissociation of(O_(2))4 units.Further,we report and discuss a strong hysteresis and metastability with the precursory phaseϵ-O_(2).Theseﬁndings will reinvigorate experimental and theoretical work into the dense oxygen system,which will have importance for oxygen-bearing chemistry,prevalent in the deep Earth,as well as fundamental physics.

关键词： metallic phase vibrational

Aspirin interruption before neurosurgical interventions:A controversial problem

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World Journal of Cardiology 2024年第4期16卷 191-198页

作者： Alexander Kulikov Anton Konovalov Pier Paolo Pugnaloni federico Bilotta Department of Anesthesiology Burdenko National Medical Research Center of NeurosurgeryMoscow 125047Russia Department of Vascular Neurosurgery Burdenko National Medical Research Center of NeurosurgeryMoscow 125047Russia Department of Anesthesiology Critical Care and Pain MedicineUniversity of Rome“Sapienza”Rome 00161Italy

Aspirin is widely used for primary or secondary prevention of ischemic events.At the same time,chronic aspirin consumption can affect blood clot formation during surgical intervention and increase intraoperative blood loss.This is especially important for high-risk surgery,including neurosurgery.Current European Society of Cardiology guidelines recommend aspirin interruption for at least 7 d before neurosurgical intervention,but this suggestion is not supported by clinical evidence.This narrative review presents evidence that challenges the necessity for aspirin interruption in neurosurgical patients,describes options for aspirin effect monitoring and the clinical implication of these methods,and summarizes current clinical data on bleeding risk associated with chronic aspirin therapy in neurosurgical patients,including brain tumor surgery,cerebrovascular procedures,and spinal surgery.

关键词： Aspirin Neurosurgery Postoperative complications Bleeding risk Brain tumor surgery Cerebrovascular surgery Spinal surgery