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Acta Pharmaceutica Sinica B 2024年第9期14卷 4073-4086页

作者： Mengru Cai Tingting Fu Rongyue zhu Panxiang Hu Jiahui Kong Shilang Liao Yuji Du Yongqiang Zhang Changhai Qu Xiaoxv Dong Xingbin Yin Jian Ni School of Chinese Materia Medica Beijing University of Chinese MedicineBeijing 102488China

ferroptosis is a recently discovered pathway for regulated cell death ***,its efficacy is affected by limited iron content and intracellular ion ***,we designed a metalorganic framework(MOF)-based nanoplatform that incorporates calcium peroxide(CaO2)and oridonin(ORI).This platform can improve the tumor microenvironment and disrupt intracellular iron homeostasis,thereby enhancing ferroptosis *** cell membranes(FM)were used to modify nanoparticles(ORI@CaO2@fe-TCPP,NPs)to produce FM@ORI@CaO2@fe-TCPP(FM@NPs).The encapsulated ORI inhibited the HSPB1/PCBP1/IREB2 and FSP1/COQ10 pathways simultaneously,working in tandem with fe3t to induce *** therapy(PDT)guided by porphyrin(TCPP)significantly enhanced ferroptosis through excessive accumulation of reactive oxygen species(ROS).This selfamplifying strategy promoted robust ferroptosis,which could work synergistically with FM-mediated *** vivo experiments showed that FM@NPs inhibited 91.57%of melanoma cells within six days,a rate 5.6 times higher than chemotherapy ***@NPs were biodegraded and directly eliminated in the urine or faeces without substantial ***,this study demonstrated that combining immunotherapy with efficient ferroptosis induction through nanotechnology is a feasible and promising strategy for melanoma treatment.

关键词： Metal-organic frameworks Immunotherapy Self-amplifying ferroptosis Photodynamic therapy Chemodynamic therapy Oridonin Fused cell membrane coating Metabolization

Optical colorimetric LiTaO_(3)wafers for highprecision lithography on frequency control of SAW devices

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Photonics Research 2024年第2期12卷 341-349页

作者： MINg HUI FANg YINONg XIE FANgQI XUE ZHILIN WU JUN SHI SHENg YU YANg YILIN LIU ZHIHUANg LIU HSIN CHI WANg FAJUN LI QINg HUO LIU JINfe.g zhu School of Electronic Science and Engineering Xiamen UniversityXiamen 361005China Quanzhou San’an Integrated Circuit Co. Ltd.Quanzhou 362300China Eastern Institute of Technology Ningbo 315200China

Surface acoustic wave(SAW)resonators based on lithium tantalate(LT,LiTaO_(3))wafers are crucial elements of mobile communication *** use of intrinsic LT wafers typically brings about low fabrication accuracy of SAW resonators due to strong UV reflection in the lithography *** hinders their resonance frequency control seriously in industrial *** doping and chemical reduction could be applied to decrease the UV reflection of LT wafers for high lithographic ***,conventional methods fail to provide a fast and nondestructive approach to identify the UV performance of standard single-side polished LT wafers for highprecision frequency ***,we propose a convenient on-line sensing scheme based on the colorimetry of reduced fe-doped LT wafers and build up an automatic testing system for industrial *** levels of fe doping and chemical reduction are evaluated by the lightness and color difference of LT-based *** correlation between the wafer visible colorimetry and UV reflection is established to refine the lithography process and specifically manipulate the frequency performance of SAW *** study provides a powerful tool for the fabrication control of SAW resonators and will inspire more applications on sophisticated devices of mobile communication.

关键词： lithography doping wafer

Hydrogen Peroxide Electrosynthesis in a Strong Acidic Environment Using Cationic Surfactants

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Precision Chemistry 2024年第4期2卷 129-137页

作者： Zachary Adler Xiao Zhang guangxia fe.g Yaping Shi Peng zhu Yang Xia Xiaonan Shan Haotian Wang Rice University Department of Chemical and Biomolecular EngineeringHoustonTexas 77005United States University of Houston Department of Electrical and Computer EngineeringHoustonTexas 77004United States

The two-electron oxygen reduction reaction(2e^(−)-ORR)can be exploited for green production of hydrogen peroxide(H_(2)O_(2)),but it still suffers from low selectivity in an acidic electrolyte when using non-noble metal ***,inspired by biology,we demonstrate a strategy that exploits the micellization of surfactant molecules to promote the H_(2)O_(2)selectivity of a low-cost carbon black catalyst in strong acid *** surfactants near the electrode surface increase the oxygen solubility and transportation,and they provide a shielding effect that displaces protons from the electric double layer(EDL).Compared with the case of a pure acidic electrolyte,we find that,when a small number of surfactant molecules were added to the acid,the H_(2)O_(2)Faradaic efficiency(fe)was improved from 12%to 95%H_(2)O_(2)under 200 mA cm^(−2),suggesting an 8-fold *** in situ surface enhanced Raman spectroscopy(SERS)and optical microscopy(OM)studies suggest that,while the added surfactant reduces the electrode’s hydrophobicity,its micelle formation could promote the O_(2) gas transport and its hydrophobic tail could displace local protons under applied negative potentials during catalysis,which are responsible for the improved H_(2)O_(2)selectivity in strong acids.

关键词： electrocatalysis hydrogen peroxide electrosynthesis oxygen reduction reaction interfacial engineering surfactant CTAB

Electrode Potential Explaining the growth of Anodic Oxides

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稀有金属材料与工程 2024年第9期53卷 2485-2492页

作者： Jiang Longfei gong Tianle Li Pengze Zhang Shaoyu Chen Binye zhu Yunxuan Wang Bing zhu Xufei Key Laboratory of Soft Chemistry and Functional Materials of Ministry of Education Nanjing University of Science and TechnologyNanjing 210094China Jiangsu Urban and Rural Construction College Changzhou 213147China

The formation mechanism of porous anodic oxides remains unclear till *** classical field-assisted dissolution(FAD)theory cannot explain the relationship between the current curve and FAD reaction,and the influence of the electrode potential on anodization is rarely *** electrode potential theory,oxygen bubble model and the ionic current and electronic current theories were introduced to explain the growth of porous anodic oxides of three metals(Ti,Zr and fe).Taking the anodization of Ti in aqueous solution containing 0.5wt% NH_(4)F as an example,the electrode potential was calculated,and the morphology of porous anodic oxides was investigated at low *** show that the growth of porous anodic oxides is determined by the ratio of the ionic current to the electronic *** the anodization,metals are classified into two groups:one is easy to form the compact oxide layer,and the other is easy to induce oxygen releasing,thus forming oxygen *** electrolyte is also classified into two groups correspondingly:compact oxide layer-assisted electrolyte and releasing oxygen-assisted electrolyte.

关键词： anodization electrode potential theory oxygen bubble model electronic current low voltage

Analysis of spot defects on the surface of a cold-rolled fe-36%Ni alloy strip

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Baosteel Technical Research 2024年第2期18卷 27-31页

作者： TIAN Yuxin WANg Yu zhu Yincun Baowu Special Metallurgy Co. Ltd.Shanghai 200940China

Many spot defects were found on the surface of a cold-rolled fe-36%Ni alloy strip produced in a factory,which seriously affected the surface quality of the *** metallographic microscopy and scanning electron microscopy analyses,it was found that the spot defects were caused by the residual oxide layer on the surface of the cold-rolled fe-36%Ni alloy strip after hydrogen *** properly increasing the grinding amount of the blank before cold rolling to remove the oxide layer,the spot defects on the surface of the cold-rolled strip were effectively eliminated,and the surface quality of the product was ensured.

关键词： fe-36%Ni alloy cold-rolled strip spot defect

Nano friction behaviour between magnetic materials and copper considering the inter-diffusion effect

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Friction 2024年第7期12卷 1532-1547页

作者： Zilin LI Lisha DOU Shiyu YANg Huajiang OUYANg Qichen zhu Xiaoyang CHEN Xin JIA Shuaiwei DOU Xiaolong CUI Yudong ZHANg Jingjiang QIU guochen QI Bangbang NIE Pan LIU Ronghan WEI School of Mechanics and Safety Engineering Zhengzhou UniversityZhengzhou 450001China Engineering Technology Research Center of Henan Province for MEMS Manufacturing and Application Zhengzhou UniversityZhengzhou 450001China Institute of Intelligent Sensing Zhengzhou UniversityZhengzhou 450001China School of Engineering University of LiverpoolLiverpool L693GHUK School of Cyber Science and Engineering&Hanwei Institute of Internet of Things Zhengzhou UniversityZhengzhou 450001China

Copper,permalloy,cobalt,and silicon are the materials that have been widely utilised in magnetic *** the size of interest is down to the nanoscale,the inter-diffusion between certain materials becomes *** paper studies the nanoscale friction characteristics between frictional pairs with and without inter-diffusion properties through the atomic force *** distinct evolution features of nanoscale friction force when inter-diffusion is involved are discovered experimentally,which is also confirmed through theoretical ***,through the thin film deposition method,four pairs of contact materials(Cu–Ni_(81)fe_(19),Si–Ni_(81)fe_(19),Cu–Co,Cu–Si)are designed for friction tests,in which diffusion occurs at the interface of Cu–Ni_(81)fe_(19)***,the effects of sliding velocity and loading force on the nano friction of each pair are *** is found that regardless of the diffusion phenomenon:(1)the adhesion force values exhibit a notable correlation to the values of the friction force;(2)the friction force in all four material pairs consistently increases with the growth of the normal loading force,although the growth rate may *** terms of the sliding velocity effect,the friction forces of immiscible materials(Si–Ni_(81)fe_(19),Cu–Co,and Cu–Si)are found to increase with the increasing sliding ***,the friction force of Cu–Ni_(81)fe_(19),decreases with the increasing sliding ***,a compositive friction model considering both the velocity and the normal force effect was proposed,which shows good agreement with the experimental results and explains the nano friction behaviour of both miscible and immiscible metals.

关键词： atomic force microscope friction force normal load sliding velocity

Berberine alleviates ovarian tissue damage in mice with hepatolenticular degeneration by suppressing ferroptosis and endoplasmic reticulum stress

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Journal of Integrative Medicine 2024年第4期22卷 493-502页

作者： Qian-zhuo Liu Hui Han Xin-ru Fang Lu-yao Wang Dan Zhao Miao-zhu Yin Nian Zhang Peng-yu Jiang Zhi-hui Ji Li-min Wu Department of Neurology the First Affiliated Hospital of Anhui University of Chinese MedicineHefei 230031Anhui ProvinceChina Center for Reproduction and genetics the First Affiliated Hospital of USTCDivision of Life Sciences and MedicineUniversity of Science and Technology of ChinaHefei 230031Anhui ProvinceChina

Objective:Hepatolenticular degeneration (HLD) is an autosomal recessive disorder that manifests as multiorgan damage due to impaired copper (Cu) metabolism. female patients with HLD often experience reproductive impairments. This study investigated the protective effect of berberine against ovarian damage in toxic-milk (TX) mice, a murine model for ***:Mice were categorized into control group, HLD TX group (HLD group), penicillamine (Cu chelator)-treated TX group and berberine-treated TX group. Body weight, ovary weight and the number of ovulated eggs were recorded. Follicular morphology and cellular ultrastructure were examined. Total iron, ferrous iron (fe2+) and trivalent iron (fe3+) levels, as well as malondialdehyde (MDA), glutathione(gSH) and oxidized glutathione (gSSg), were measured in the ovaries. Western blot analysis was used to analyze the expression of proteins related to ferroptosis and endoplasmic reticulum (ER) ***:Ovarian tissue damage was evident in the HLD group, with a significant increase in ferroptosis and ER stress compared to the control group. This damage was inhibited by treatment with penicillamine,a Cu chelator. Compared with the HLD group, berberine increased the number of ovulations, and improved ovarian morphology and ultrastructure. Further, we found that berberine reduced total iron,fe2+, MDA and gSSg levels, elevated gSH levels, decreased the expression of the ferroptosis marker protein prostaglandin-endoperoxide synthase 2 (PTgS2), and increased glutathione peroxidase 4 (gPX4)expression. Furthermore, berberine inhibited the expression of ER stress-associated proteins mediated by the protein kinase RNA-like ER kinase (PERK) ***:ferroptosis and ER stress are involved in Cu-induced ovarian damage in TX mice. Berberine ameliorates ovarian damage in HLD TX mice by inhibiting ferroptosis and ER stress.

关键词： Berberine Hepatolenticular degeneration Copper deposition ferroptosis Endoplasmic reticulum stress

Formation and growth of nanophase iron particles on the surface of Mercury revealed by experimental study

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Acta geochimica 2024年第4期43卷 774-784页

作者： Ronghua Pang Yang Li Chen Li Pengfei Zhang zhuang guo Sizhe Zhao Han Yu Li Wang Chenxi zhu Shuangyu Wang Kairui Tai Qinwei Zhang Yuanyun Wen Rui Li Center for Lunar and Planetary Sciences Institute of GeochemistryChinese Academy of SciencesGuiyangChina University of Chinese Academy of Sciences BeijingChina Center for Excellence in Comparative Planetology Chinese Academy of SciencesHefeiChina Institute of Remote Sensing and geographical Information System School of Earth and Space SciencesPeking UniversityBeijingChina State Key Laboratory of Lunar and Planetary Sciences Macao University of Science and TechnologyMacaoChina Faculty of Metallurgical and Energy Engineering Kunming University of Science and TechnologyKunmingChina State Key Laboratory of High Performance Ceramics and Superfi ne Microstructures Shanghai Institute of CeramicsChinese Academy of SciencesShanghaiChina Laboratory for Space Environment and Physical Sciences Harbin Institute of TechnologyHarbinChina Research Center for Planetary Science College of Earth ScienceChengdu University of TechnologyChengduChina Key Laboratory of Planetary Sciences Purple Mountain ObservatoryChinese Academy of SciencesNanjingChina

Space weathering is a primary factor in altering the composition and spectral characteristics of surface materials on airless ***,current research on space weathering focuses mainly on the Moon and certain types of *** particular,the impacts of meteoroids and micrometeoroids,radiation from solar wind/solar flares/cosmic rays,and thermal fatigue due to temperature variations are being *** weathering produces various transformation products such as melted glass,amorphous layers,iron particles,vesicles,and solar wind *** in turn lead to soil maturation,changes in visible and near-infrared reflectance spectra(weakening of characteristic absorption peaks,decreased reflectance,increased near-infrared slope),and alterations in magnetism(related to small iron particles),collectively termed the“lunar model”of space weathering *** to the Moon and asteroids,Mercury has unique spatial environmental characteristics,including more intense meteoroid impacts and solar thermal radiation,as well as a weaker particle radiation environment due to the global distribution of its magnetic ***,the lunar model of space weathering may not apply to *** studies have extensively explored the eff ects of micrometeoroid ***,this work focuses on the eff ects of solar-wind particle radiation in global magnetic-field distribution and on the weathering transformation of surface materials on Mercury under prolonged intense solar *** the utilization of highvalence state,heavy ion implantation,and vacuum heating simulation experiments,this paper primarily investigates the weathering transformation characteristics of the major mineral components such as anorthite,pyroxene,and olivine on Mercury’s surface and compares them to the weathering transformation model of the *** experimental results indicate that ion implantation at room temperature is insufficient to generate np-fe^(0)directly but

关键词： Mercury Space weathering Np-fe^(0) Solar thermal radiation Solar wind

暖等离子体合成过渡金属掺杂氧化锰析氧电催化剂

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无机材料学报 2024年第7期39卷 835-844,I0008-I0011页

作者：李家琪李小松李煊赫朱晓兵朱爱民大连理工大学等离子体物理化学实验室大连116024 大连理工大学氢能与环境催化中心大连116024

可再生能源发电与质子交换膜水电解结合产生“绿色氢”对能源安全具有战略意义,其速控步骤是析氧反应。从稳定性、活性和成本角度考虑,本研究采用滑动弧暖等离子体一步合成了氧化锰(MnO_(x))及过渡金属掺杂(fe-MnO_(x),Co-MnO_(x),Ni-Mn... 详细信息

可再生能源发电与质子交换膜水电解结合产生“绿色氢”对能源安全具有战略意义,其速控步骤是析氧反应。从稳定性、活性和成本角度考虑,本研究采用滑动弧暖等离子体一步合成了氧化锰(MnO_(x))及过渡金属掺杂(fe-MnO_(x),Co-MnO_(x),Ni-MnO_(x)的析氧电催化剂,并对其晶体结构、形貌尺寸、元素组成和表面价态进行了表征。氧化锰主要由晶相Mn_(2)O_(3)和无定形Mn_(3)O_(4)组成。与之相比,掺杂的氧化锰尽管晶相组成基本不变,但其粒径明显变小、比表面积增大;掺杂Co促使氧化锰的表面电子增多。氧化锰基催化剂在酸性电解液的循环伏安测试中表现出独特的电流阶跃现象(低电势Ⅰ-Ⅱ区:1.4~1.8~2.4 V;高电势Ⅲ区:2.4~2.7 V)。该电流阶跃过程与Bulter-Volmer简化方程的电极动力学参照曲线相吻合,属于多价态锰参与的电催化反应。低电势区fe-MnO_(x)的电化学活性最优,而高电势区Co-MnO_(x)表现最优。Co-MnO_(x)的起始电位比MnO_(x)低160 mV,且在恒电位电解中其末端电流密度是MnO_(x)的3倍。与其活性趋势一致,fe-MnO_(x)、Co-MnO_(x)分别在低电势区、高电势区更具稳定性。本研究通过掺杂过渡金属优化氧化锰的颗粒尺寸、比表面积和电子结构,显著提高了催化剂析氧反应活性及稳定性。

关键词： MnO_(x) 过渡金属掺杂电流阶跃析氧反应滑动弧暖等离子体

Interface engineering of 2D Nife LDH/NifeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation

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Chinese Chemical Letters 2024年第9期35卷 514-520页

作者： Lili Wang Ya Yan Rulin Li Xujie Han Jiahui Li Ting Ran Jialu Li Baichuan Xiong Xiaorong Song Zhaohui Yin Hong Wang Qingjun zhu Bowen Cheng Zhen Yin State Key Laboratory of Separation Membranes and Membrane Processes School of ChemistryTiangong UniversityTianjin 300387China School of Chemical Engineering and Technology Tiangong UniversityTianjin 300387China College of Chemical Engineering and Materials Science Tianjin University of Science and TechnologyTianjin 300457China State Key Laboratory of Biobased Fiber Manufacturing Technology Tianjin University of Science and TechnologyTianjin 300457China School of Materials Science and Engineering Tiangong UniversityTianjin 300387China Deutsches Elektronen-Synchrotron DESY Platanenallee 6Zeuthen 15738Germany Department of Chemistry and The Center for the Science of Materials Berlin Humboldt-Universitäzu BerlinBerlin 12489Germany

The electrochemical oxidation of 5-hydroxymethylfurfural(HMF)to valuable chemicals is an efficient way to upgrade biomass molecules and replace traditional catalytic *** is crucial to develop efficient and low-cost earth-abundant electrocatalysts to enhance catalytic performance of HMF ***,a new type of two-dimensional(2D)hybrid arrays consisting of Ni fe layered double hydroxides(LDH)nanosheets and bimetallic sulfide(Ni fe S)is constructed via interface engineering for efficient electrocatalytic oxidation of HMF to 2,5-furandicarboxylic acid(FDCA).The preparation process of 2D Ni fe LDH/NifeS with ultrathin heterostructure involves in anchoring a Co-based metal-organic framework(Co MOF)as template onto the carbon cloth(CC)via in-situ growth,formation of Nife LDH on the surface of Co MOF and subsequent partial *** electrocatalyst of Ni fe LDH/Ni fe S exhibits outstanding performance towards HMF oxidation,about 98.5%yield for FDCA and 97.2%Faraday efficiency(fe)in the alkaline electrolyte with 10 mmol/L HMF,as well as excellent stability retaining 90.1%fe for FDCA after six cycles ***,even at an HMF concentration of 100 mmol/L,the yield and fe for FDCA remain high at 83.6%and 93.6%,*** findings highlight that 2D heterostructure containing abundant interfaces between Ni fe LDH nanosheets and Ni fe S can enhance the intrinsic activity of LDH and thus promote the oxidation reaction ***,the synergistic effect of the bimetallic Ni fe compounds also improved the selectivity of HMF conversion to *** present work demonstrates that constructing 2D ultrathin heterostructure of Ni fe LDH/Ni fe S is a facile strategy via interface engineering to enhance the intrinsic activity of LDH electrocatalysts,which would open new avenues toward low-cost and advanced 2D nanocatalysts for sustainable energy conversion and electrochemical valorization of biomass derivatives.

关键词： Electrocatalytic oxidation Interface engineering 2D ultrathin heterostructure Layered double hydroxides 5-Hydroxymethylfurfural