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Surface interaction between Pd and nitrogen derived from hyperbranched polyamide towards highly effective formic acid dehydrogenation

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Journal of Energy Chemistry 2020年第1期29卷 212-216,I0008页

作者： Yancun Yu Xian Wang Changpeng Liu fateev vladimir Junjie Ge Wei Xing Laboratory of Advanced Power Sources Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022JilinChina University of Chinese Academy of Sciences Beijing 100049China Jilin Province Key Laboratory of Low Carbon Chemical Power Sources Changchun 130022JilinChina State Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022JilinChina University of Science and Technology of China(USTC) Hefei 230026AnhuiChina National Research Center Kurchatov Institute Kurchatov sq.1MoscowRussia Laboratory of Advanced Power Sources Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchaun 130022Jilin.China

Hydrogen production from formic acid decomposition(FAD)is a promising means of hydrogen energy storage and utilization in fuel *** of efficient catalysts for dehydrogenation of formic acid is a challenging *** surface chemical and electronic structure of the active catalysis components is important in formic acid decomposition at ***,the pyrdinic-nitrogen doped catalysts from hyperbranched polyamide were prepared via in situ polymerization reaction process by using activated carbon as a *** of the introduction of the polymer,the particles of the catalysts were stabilized,and the average particle diameter was only 1.64 *** mild conditions,the catalysts activities were evaluated for *** optimized Pd-N30/C catalyst exhibited high performance achieving almost full conversion,with a turnover frequency of 3481 h^-1 at 30℃.

关键词： Formic acid decomposition Hydrogen generation Hyperbranched polymer Pd catalyst

人工智能在可再生能源材料研发领域的研究进展

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稀有金属 2023年第4期47卷 570-586页

作者：司司卡盖·索音图庄明兴刘妍 fateev vladimir N. 魏永生江苏师范大学物理与电子工程学院氢能研究中心江苏徐州221116 徐州徐工新能源汽车有限公司江苏徐州221116 Kurchatov Institute National Research Center 1 Akad Kurchatova SqMoscow 123182

近年来煤炭、石油、天然气等传统能源逐渐枯竭,大量化石能源的使用造成环境污染。为了降低二氧化碳的排放量,国家积极推动风、光、水电、氢能等可再生能源的发展,而这些能源技术的推广应用的关键是新材料的研发。目前新材料的研发主要... 详细信息

近年来煤炭、石油、天然气等传统能源逐渐枯竭,大量化石能源的使用造成环境污染。为了降低二氧化碳的排放量,国家积极推动风、光、水电、氢能等可再生能源的发展,而这些能源技术的推广应用的关键是新材料的研发。目前新材料的研发主要依赖于研究者根据材料结构以及其用于某一特定体系的预期催化活性为目标进行实验优化,导致新材料研发过程缓慢。随着计算材料学的进一步发展,研究人员整合了大量关于材料结构及性能表征的材料数据库,通过比较逐步优化筛选新材料。综述了当前材料开发的设计思路以及合成方法,以人工智能(AI)为着眼点阐述了近年来基于AI方法设计、制备可再生能源材料过程中的模型与算法,并总结了AI用于材料设计方面的研究意义和发展过程,最后对AI方法用以可再生能源材料设计、制备的发展进行了展望,介绍了本课题组提出的材料优化模型,并且列举了该模型成功应用于电解水析氢以及硼氢化钠制氢的材料优化的案例。未来,AI技术在新材料的理论计算、合成设计、性能预测、材料微观结构表征分析等方面具有非常广阔应用前景。

关键词：材料制备人工智能(AI) 可再生能源材料优化

Equilibrium Arrivals to Preemptive Queueing System with Fixed and Random Population Size

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Journal of the Operations Research Society of China 2024年第1期12卷 77-92页

作者： Julia Chirkova vladimir Mazalov Institute of Applied Mathematical Research Karelian Research Centre of RASPetrozavodsk185910Russia School of Mathematics and Statistics Qingdao UniversityQingdao266071ShandongChina

A single-server queueing system with preemptive access is *** customer has one attempt to enter the system at its working interval[0,T].As soon as the customer request enters the system,the server immediately starts the *** when the next request arrives in the system,the previous one leaves the system even he has not finished his service *** study a non-cooperative game in which the customers wish to maximize their probability of obtaining service within a certain period of *** characterize the Nash equilibrium and the price of anarchy,which is defined as the ratio between the optimal and equilibrium social *** models are *** the first model the number of players is fixed,while in the second it is random and obeys the Poisson *** demonstrate that there exists a unique symmetric equilibrium for both ***,we calculate the price of anarchy for both models and show that the price of anarchy is not monotone with respect to the number of customers.

关键词： Service system Preemptive priorities Strategic users Random number of players Optimal arrivals Kolmogorov backward equations Nash equilibrium Price of anarchy

Study of asphaltene reaggregation in toluene/heptane mixture by dynamic and static light scattering

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Petroleum Research 2024年第1期9卷 48-54页

作者： vladimir N.Kuryakov Oil and Gas Research Institute of RAS(OGRI RAS) Gubkina Str.3119333MoscowRussian Federation

This paper presents the study of the effect of multiple ultrasonic impacts on submicron asphaltene aggregates in a toluene/heptane solution,conducted with dynamic light scattering *** objects of the study were four samples of asphaltenes obtained from four different *** all samples,the change in the average size of the asphaltene submicron aggregates with time was measured after the addition of a precipitant(heptane)to a solution of asphaltenes in toluene at an amount above the threshold *** aggregates formed in solution after the addition of the precipitant and were subjected to ultrasonic treatment,which led to the destruction of the asphaltene *** of destroyed asphaltenes was *** kinetics of this aggregation were similar to the kinetics of aggregation of asphaltenes after the addition of a *** iterations of asphaltene aggregate destruction in the sample led to a significant change in the kinetics of aggregation:the growth of aggregates slowed and stabilized at a size of approximately 200 nm and 30 nm for the different studied samples.

关键词： Asphaltenes Aggregation Sonication Dynamic light scattering Re-aggregation Colloidal stability Resins

On Differential Equations of Integrable Billiard Tables

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Acta Mathematica Sinica,English Series 2024年第1期40卷 417-424页

作者： vladimir DRAGOVIC Andrey E.MIRONOV Department of Mathematical Sciences The University of Texas at DallasRichardson TXUSA Mathematical Institute SANU BelgradeSerbia Novosibirsk State University NovosibirskRussia Sobolev Institute of Mathematics of the Siberian Branch of the Russian Academy of Sciences NovosibirskRussia

We introduce a method to find differential equations for functions which define tables,such that associated billiard systems admit a local first *** illustrate this method in three situations:the case of(locally)integrable wire billiards,for finding surfaces in R^(3)with a first integral of degree one in velocities,and for finding a piece-wise smooth surface in R^(3)homeomorphic to a torus,being a table of a billiard admitting two additional first integrals.

关键词： Polynomial first integrals wire billiards piece-wise smooth surfaces

Attempts to restore loss of function in damaged ACD cells open the way to non-mutational oncogenesis

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Genes & Diseases 2024年第3期11卷 5-6页

作者： vladimir F.Niculescu 86420 Diedorf Germany Kirschenweg

This correspondence to Gene&Diseases calls attention to the controversy between proponents of genetic modification in carcinogenesis and supporters of non-mutational *** from molecular cancer research and findings from evolutionary cancer cell biology support the latter claim and provide no rationale for the mutational origin of sporadic *** is more conceivable that the general susceptibility of asymmetric cell division(ACD)phenotypes to oxygen leads to irreparable DNA defects and dysregulated defective symmetric cell division(DscD)phenotypes.

关键词： rational latter finding

A Privacy-preserving Energy Management System Based on Homomorphic Cryptosystem for IoT-enabled Active Distribution Network

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Journal of Modern Power Systems and Clean Energy 2024年第1期12卷 167-178页

作者： Qian Hu Siqi Bu Wencong Su vladimir Terzija the Department of Physics Hong Kong Baptist UniversityHong KongChina the Department of Electrical and Electronic Engineering Shenzhen Research InstituteThe Hong Kong Polytechnic UniversityHong KongChina the Department of Electrical and Computer Engineering University of Michigan-DearbornDearbornMI 48128USA the School of Engineering Newcastle UniversityNewcastleUK

Active distribution network(ADN),as a typically cyber-physical system,develops with the evolution of Internet of Things(IoTs),which makes the network vulnerable to cybersecurity *** this paper,the eavesdropping attacks that lead to privacy breaches are addressed for the IoT-enabled ADN.A privacy-preserving energy management system(EMS)is proposed and empowered by secure data exchange protocols based on the homomorphic *** the information transmission among distributed generators and load customers in the EMS,private information including power usage and electricity bidding price can be effectively protected against eavesdropping *** correctness of the final solutions,e.g.,optimal market clearing price and unified power utilization ratio,can be deterministically *** simulation results demonstrate the effectiveness and the computational efficiency of the proposed homomorphically encrypted EMS.

关键词： Eavesdropping attack energy management system homomorphic cryptosystem Internet of Things(IOTs) active distribution network(ADN) privacy-preserving

Preface: The Special Issue on Dynamic and Networking Games

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Journal of the Operations Research Society of China 2024年第1期12卷 1-3页

作者： Hong-Wei Gao vladimir Mazalov School of Mathematics and Statistics Qingdao University266071QingdaoShandongChina Institute of Applied Mathematical Research Karelian Research Centre of RAS185910PetrozavodskRussia

Numerous game theory-based techniques to characterize agent behavior haveemerged in response to the swift advancements in technology,communications,indus-trial organization,economic integration,and international *** is a huge varietyof mathematical techniques used in game *** application of dynamic and net-working game techniques is the main topic of this special *** strategicinteractions between many decision-makers with dynamic and varied connections isthe focus of research in the game theory discipline of dynamic and networking *** field of study examines how agents or people make choices in dynamic circum-stances and how those choices impact their overall outcomes and payoffs.

关键词： agent strategic advancement

Changes in filtration and capacitance properties of highly porous reservoir in underground gas storage:CT-based and geomechanical modeling

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第8期16卷 2982-2995页

作者： Valerii Khimulia vladimir Karev Yury Kovalenko Svyatoslav Barkov Ishlinsky Institute for Problems in Mechanics RAS Moscow119526Russia

The paper presents the results of comprehensive studies of filtration and capacitance properties of highly porous reservoir rocks of the aquifer of an underground gas storage *** geomechanical part of the research included studying the dependence of rock permeability on the stress-strain state in the vicinity of the wells,and physical modeling of the implementation of the method of increasing the permeability of the wellbore zone-the method of directional unloading of the *** digital part of the research included computed tomography(CT)-based computer analysis of the internal structure,pore space characteristics,and filtration properties before and after the *** to the results of physical modeling of deformation and filtration processes,it is found that the permeability of rocks before fracture depends on the stress-strain state insignificantly,and this influence is ***,when downhole pressure reaches 7-8 MPa,macrocracks in the rock begin to grow,accompanied by irreversible permeability ***,geodesic tortuosity and permeability values were obtained based on digital studies and numerical modeling.A weak degree of transversal anisotropy of the filtration properties of rocks was *** on the analysis of pore size distribution,pressure field and flow velocities,high homogeneity and connectivity of the rock pore space is *** absence of pronounced changes in pore space characteristics and pore permeability after non-uniform triaxial loading rocks was *** the basis of geometrical analysis of pore space,the reasons for weak permeability anisotropy were *** filtration-capacitance properties obtained from the digital analysis showed very good agreement with the results of field and laboratory *** physical modeling has confirmed the efficiency of application of the directional unloading method for the reservoir under *** necessary parameters of its application were calcu

关键词： Permeability anisotropy Reservoir porosity Rocks computed tomography(CT) Digital core analysis Filtration flow numerical modeling