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Design and optimization of electrochemical cell potential for hydrogen gas production

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Journal of Energy Chemistry 2021年第1期30卷 421-427,I0013页

作者： Nawar KAl-Shara farooq sher Sania ZIqbal Oliver Curnick George ZChen Department of Chemical and Environmental Engineering Faculty of EngineeringUniversity of NottinghamUniversity ParkNottingham NG72RDUK School of Mechanical Aerospace and Automotive EngineeringFaculty of EngineeringEnvironmental and ComputingCoventry UniversityCoventry CV12JHUK Department of Biochemistry University of AgricultureFaisalabad 38000Pakistan Institute for Future Transport and Cities Coventry UniversityCoventry CV15FBUK Department of Chemical and Environmental Engineering Faculty of Science and EngineeringUniversity of Nottingham Ningbo ChinaUniversity ParkNingbo 315100China

This study deals with the optimization of best working conditions in molten melt for the production of hydrogen(H2) *** research has been carried out on how electrochemical process occurs through steam splitting via molten hydroxide.54 combinations of cathode,anode,temperature and voltage have been investigated for the optimization of best working conditions with molten hydroxide for hydrogen gas *** these electrochemical investigations were carried out at 225 to 300℃ temperature and 1.5 to 2.5 V applied voltage *** current efficiency of 90.5,80.0 and 68.6% has been achieved using stainless steel anodic cell with nickel,stainless steel and platinum working cathode *** nickel cathode,an increase in the current directly affected the hydrogen gas flow rate at *** can be hypothesized from the noted results that increase in current is directly proportional to operating temperature and applied *** values were noted when the applied voltages increased from 1.5 to 2.5 V at 300℃,the flow rate of hydrogen gas increased from 1.5 to 11.3 cm^(3) min^(-1),1.0 to 13 cm^(3) min^(-1) in case of electrolysis@stainless steel and@graphite anode *** is observed that the current efficiency of stainless steel anodic cell was higher than the graphite anodic ***,steam splitting with the help of molten salts has shown an encouraging alternate to current methodology for H2 fuel production.

关键词： Sustainable energy Splitting steam Electrolysis Hydrogen gas production Electrochemical cell and Variable cathodes

Electrochemical study of different membrane materials for the fabrication of stable,reproducible and reusable reference electrode

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Journal of Energy Chemistry 2020年第10期29卷 33-41页

作者： Nawar K.Al-Shara farooq sher Sania Z.Iqbal Zaman Sajid George Z.Chen Department of Chemical and Environmental Engineering University of NottinghamUniversity ParkNottingham NG72RDUnited Kingdom School of Mechanical Aerospace and Automotive EngineeringFaculty of EngineeringEnvironmental and ComputingCoventry UniversityCoventry CV12JHUnited Kingdom Department of Biochemistry University of AgricultureFaisalabad 38000Pakistan Department of Process Engineering Memorial University of NewfoundlandSt John’s Newfoundland A1B 3×5Canada

Fabrication of stable,reproducible and reusable reference electrodes for low energy and high-temperature steam splitting is of great interest for hydrogen fuel production without anthropogenic carbon dioxide(CO2)*** study has been conducted for the detection of suitable material for the fabrication of novel reference *** the present scenario,this research is designed to fabricate a novel nickel reference electrode by using operating conditions of eutectic molten hydroxide(NaOH-KOH,49-51 mol%)at temperature 300℃in an ion-conducting membrane of alumina and mullite ***,the designed nickel reference electrode has been examined for its reusability and stability by using electrochemical technique and cyclic *** scans of cyclic voltammetry are performed for both membrane fabricated reference electrode.A slight positive shift in oxidation peaks is observed for mullite membrane electrode(64 mV from scan 1 to 5).The stability measurements are noted by changing the scan rate between 50 and 150 mV s−***,the results show that the Ni/Ni(OH)2 reference electrode covered with a mullite membrane is stable and reusable at 300℃temperature without any *** stability and reusability of prepared nickel reference electrode covered by mullite tube in the eutectic molten hydroxide were up to 9 days to carry out an electrochemical investigation,while for alumina tube reference electrode the stability and reliability were up to 3 *** internal electrolytic material and ionic conductance can play an important role for future studies with this reference electrode along with optimisation of temperature and scan rate parameters.

关键词： Renewable energy Hydrogen production Electrode process Cyclic voltammetry Reference electrode and Molten salts

Preparation of active coke combining coal with biomass and its denitrification performance

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Journal of Iron and Steel Research International 2021年第10期28卷 1203-1211页

作者： Xiao-hu Zhou Sheng-fu Zhang Yu-yang Wei farooq sher Yang Li Wen-zhou Yu Liang-ying Wen College of Materials Science and Engineering Chongqing UniversityChongqing400044China Chongqing Key Laboratory of Vanadium-Titanium Metallurgy and Advanced Materials Chongqing UniversityChongqing400044China School of Mechanical Aerospace and Automotive EngineeringFaculty of EngineeringEnvironment and ComputingCoventry UniversityCoventryCV15FBUK

To improve the selective catalytic reduction of NO with NH3 over active coke(AC),coal–biomass ACs were prepared from the mixture of poplar and 1/3 coking coal for increasing the active *** resultant ACs were characterized by N2 adsorption and X-ray photoelectron ***,the denitrification performance was tested at laboratory *** addition,density functional theory was used to analyze active sites on the surface of *** result revealed that,with an increase in poplar content,the decrease in micropores volume appeared in the reduction of denitrification ***,C−O group including hydroxyl and ether increased with the increase in poplar content,which was found to be most likely responsible for the promoted catalytic activity of AC toward NO reduction mainly because of enhancing NH3 *** comprehensive effect of two factors made the denitrification ability of AC increased first and then decreased.

关键词： Active coke Denitrification Pore structure Functional group Density functional theory

Vanillin cross-linked hydrogel membranes interfacial reinforced by carbon nitride nanosheets for enhanced antibacterial activity and mechanical properties

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Chinese Chemical Letters 2023年第4期34卷 164-171页

作者： Umer Shahzad Malik Qixiang Duan Muhammad Bilal K.Niazi Zaib Jahan Usman Liaqat farooq sher Yanchang Gan Honghao Hou School of Chemical and Materials Engineering National University of Sciences and TechnologyIslamabad 44000Pakistan Guangdong Provincial Key Laboratory of Construction and Detection in Tissue Engineering School of Basic Medical ScienceSouthern Medical UniversityGuangzhou 510515China Department of Engineering School of Science and TechnologyNottingham Trent UniversityNottingham NG118NSUnited Kingdom

Biopolymer based hydrogels are highly adaptable, compatible and have shown great potential in biological tissues in biomedical applications. However, the development of bio-based hydrogels with high strength and effective antibacterial activity remains challenging. Herein, a series of vanillin-cross-linked chitosan nanocomposite hydrogel interfacially reinforced by g-C_(3)N_(4)nanosheet carrying starch-caped Ag NPs were prepared for wound healing applications. The study aimed to enhance the strength, sustainability and control release ability of the fabricated membranes. Starch-caped silver nanoparticles were incorporated to enhance the anti-bacterial activities The fabricated membranes were assessed using various characterization techniques such as FT-IR, XRD, SEM, mechanical testing, Gel fraction and porosity alongside traditional biomedical tests i.e., swelling percentage, moisture retention ability, water vapor transmission rate, oxygen permeability, anti-bacterial activity and drug-release of the fabricated membranes. The mechanical strength reached as high as 25.9 ± 0.24 MPa for the best optimized sample. The moisture retention lied between 87%–89%, gel fraction 80%–85%, and water vapor transmission up to 104 ± 1.9g m^(-2)h^(-1)showing great properties of the fabricated membrane. Swelling percentage surged to 225% for blood while porosity fluctuated between 44% ± 2.1% and 52.5% ± 2.3%. Oxygen permeability reached up to 8.02 mg/L showing the breathable nature of fabricated membranes. The nanocomposite membrane shown excellent antibacterial activity for both gram-positive and gram-negative bacteria with a maximum zone of inhibition 30 ± 0.25 mm and 36.23 ± 0.23 mm respectively. Furthermore, nanoparticles maintained sustainable release following non-fickian diffusion. The fabricated membrane demonstrated the application of inorganic filler to enhance the strength of biopolymer hydrogel with superior *** results envisage the potential of synthesized m

关键词： Green synthesis Sustainable membranes Starch capped silver nanoparticles g-C_(3)N_(4)nanosheets Wound dressing Antibacterial

Integrating artificial intelligence and high-throughput phenotyping for crop improvement

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Journal of Integrative Agriculture 2024年第6期23卷 1787-1802页

作者： Mansoor Sheikh farooq Iqra Hamadani Ambreen Kumar A Pravin Manzoor Ikra Yong Suk Chung Phenomics Laboratory Department of Plant Resources and EnvironmentJeju National UniversityJeju 63234Republic of Korea Council of Scientific&Industrial Research Indian Institute of Integrative MedicinePulwamaJ&K 192301India Animal and Dairy Science University of WisconsinMadisonWI 530706United States of America Division of Fruit Science Faculty of HorticultureSher-e-Kashmir University of Agricultural Sciences and Technology of KashmirSrinagar 190025India

Crop improvement is crucial for addressing the global challenges of food security and sustainable *** advancements in high-throughput phenotyping(HTP)technologies and artificial intelligence(AI)have revolutionized the field,enabling rapid and accurate assessment of crop traits on a large *** integration of AI and machine learning algorithms with HTP data has unlocked new opportunities for crop *** algorithms can analyze and interpret large datasets,and extract meaningful patterns and correlations between phenotypic traits and genetic *** technologies have the potential to revolutionize plant breeding programs by providing breeders with efficient and accurate tools for trait selection,thereby reducing the time and cost required for variety ***,further research and collaboration are needed to overcome the existing challenges and fully unlock the power of HTP and AI in crop *** leveraging AI algorithms,researchers can efficiently analyze phenotypic data,uncover complex patterns,and establish predictive models that enable precise trait selection and crop *** aim of this review is to explore the transformative potential of integrating HTP and AI in crop *** review will encompass an in-depth analysis of recent advances and applications,highlighting the numerous benefits and challenges associated with HTP and AI.

关键词： artificial intelligence crop improvement data analysis high-throughput phenotyping machine learning precision agriculture trait selection

Length-weight relationship of eleven species of marine catfishes from the northern Arabian Sea coast of Pakistan

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Chinese Journal of Oceanology and Limnology 2017年第5期35卷 1218-1220页

作者： Noureen farooq Nazia QAMAR Shahnaz RASHID sher Khan PANHWAR Center of Excellence in Marine Biology University of Karachi Sindh Pakistan

This study records length-weight relationships （LWRs） for eleven commercially important marine catfish species of the family Ariidae （sea catfishes） and Plotosidae （eel catfishes） from the northern Arabian Sea coast of Pakistan. The specimens were sampled from December 2014 to November 2015, using bottom trawls with various mesh sizes by commercial vessels. The species were Nemapteryx caelatus, Sciades sona, Arius gagora, Batrachocephalus mino, Neturna thalassina, N. bilineata, Osteogeneiosus militaris, Plicofollis dussumieri, P. tenuispinis, Plotosus limbatus, and P. lineatus. Of the eleven species, two species A. gagora and N. bilineata were recorded for the first time and LWRs for four species A. gagora, N. bilineata, S. sona, and B. mino still have no data in the FishBase database. In addition, new maximum length for each of the three species N. bilineata, O. militaris andB. mino was also found.

关键词： marine catfishes Arridae Plotosidae northern Arabian Sea

Phytoecological evaluation with detail floristic appraisal of the vegetation arround Malam Jabba,Swat,Pakistan

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Asian Pacific Journal of Tropical Biomedicine 2011年第6期1卷 461-467页

作者： Abdur Rashid Mohammad farooq Swati Hassan sher Mohammad N Al-Yemeni Department of Botany University of Peshawar Department of Botany&Biodiversity Conservation University of Swat Department of Botany&Microbiology King Saud University

Objective:To determine the present status of plant communities and their possible association with the habitat in Malam Jabba,Swat,***:A study on the phytoecology was conducted in various ecologically important sites of Malam Jabba,Swat,Pakistan from 2002 to *** altitude of these sites ranged from 1200 m to.1200 *** method was used for evaluation of plants communities and the data on these attributes was converted to relative values. The plant communities were named after 3 leading species with highest importance values. Biological spectrum of the flora based on the life form was prepared by following Raunkiar's life form ***:The floristic composition and structure of the study area were found to be 200 species belonging to 75 ***,Lamiaceae and Poaceae were important families in the study *** biological spectrum showed that therophytic and hemicrytophytic life form and micro-nonophyllous leaf sizes were dominant in the *** air and soil temperatures were decreasing with increasing *** the air and soil temperatures were relatively higher in south slopes than on the northeast *** vegetation analysis of the area indicated eleven plant communities around the *** present vegetation is the relics of moist temperate coniferous forest in the *** communities reflect highly deteriorated conditions. Both the structure and composition of the surrounding vegetation were associated with the types of ***:The conservation of the remaining populations of the reported communities will be best achieved by proper time of sustainable *** is only possible with the participation of local communities.

关键词： Plant communities Altitudinal variation Conservation Slopes Biological spectrum Climatic conditions Phytoecological evaluation Vegetation Floristic appraisal Phytoecology Composition

Bioassay-guided isolation of novel and selective urease inhibitors from Diospyros lotus

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Chinese Journal of Natural Medicines 2017年第11期15卷 865-870页

作者： Abdur Rauf Ghias Uddin Bina S. Siddiqui Ajmal Khan Umar farooq Farhan A. Khan Syed Majid Bukhari sher Bahadar Khan Department of Chemistry University ofSwabi Anbar-23561 Khyber Pakhtunkhwa Pakistan Institute of Chemical Sciences University ofPeshawar Peshawar-25120 Pakistan H.E.J. Research Institute of Chemistry International Center for Chemical and Biological Sciences University ofKarachL Ka- rachi- 75270 Pakistan Department of Chemistry COMSAT Institute of Information Technology Abbottabad-22060 Pakistan UoN Chair of Oman 's Medicinal Plants and Marine Natural Products University ofNizwa Birkat Al-Mouz Nizwa-616 Oman Center of Excellence for Advanced Materials Research (CEAMR) Department of Chemistry Faculty of Science King Abdulaziz University Jeddah 21589 Saudi Arabia Kingdom

Two new dimeric naphthoquinones, 5′,8′-dihydroxy-6,6′-dimethyl-7,3′-binaphthyl-1,4,1′,4′-tetraone(1; Di-naphthodiospyrol D) and 5′,8′-dihydroxy-5,8-dimethoxy-6,6′-dimethyl-7,3′-binaphthyl-1,4,1′,4′-tetraone(2; Di-naphthodiospyrol E), along with known naphthoquinones diospyrin(3) and 8-hydroxy diospyrin(4) were isolated from the chloroform fraction of extract of Diospyros lotus roots. Their structures were elucidated by advanced spectroscopic analyses, including HSQC, HMBC, NOESY, and J-resolved NMR experiments. The fractions and compounds 1-4 were evaluated for urease activity and phosphodiesterase-Ⅰ, carbonic anhydrase-Ⅱ and α-chymotrypsin enzyme inhibitory activities. Compounds 1 and 2 and their corresponding fractions showed significant and selective inhibitory effects on urease activities. The IC_(50) values of 1 and 2 were 260.4 ± 6.37 and 381.4 ± 4.80 μmol·L-1, respectively, using thiourea(IC_(50) = 21 ± 0.11 μmol·L^(-1)) as the standard inhibitor. This was the first report demonstrating that the naphthoquinones class showed urease inhibition.

关键词： Diospyros lotus Naphthoquinones Phosphodiesterase-Ⅰ Carbonic anhydrase-Ⅱ α-Chymotrypsin Urease inhibitory activities

Comparative assessment of clinical profile and outcomes after primary percutaneous coronary intervention in young patients with single vs multivessel disease

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World Journal of Cardiology 2020年第4期12卷 136-143页

作者： Atif sher Muhammad Tariq Ashraf Ayaz Mir Syed Alishan Faiza farooq Ali Ammar Musa Karim Syed Nadeem Hassan Rizvi Tahir Saghir Jawaid Akbar Sial Naveed Ullah Khan Department of Adult Cardiology National Institute of Cardiovascular DiseasesKarachi 75510Pakistan Department of Clinical Research National Institute of Cardiovascular DiseasesKarachi 75510Pakistan

BACKGROUND Even though percutaneous coronary intervention(PCI)improved the survival of patients with acute myocardial infarction,still multivessel coronary artery disease remains an important factor burdening prognosis and it is being associated with a worse prognosis compared to single-vessel disease(SVD).AIM To compare the clinical profile and outcomes after the primary PCI in young patients with SVD vs multivessel disease(MVD).METHODS The retrospective cohort of patients were divided into two groups:SVD and MVD *** study population consisted of both male and female young(≤45 years)patients presented with ST-elevation myocardial infarction(STEMI)at the National Institute of Cardiovascular Disease,Karachi,Pakistan and undergone primary PCI from 1 st July 2017 to 31 st March *** and postprocedure management of the patients was as per the guidelines and institutional *** A total of 571 patients with STEMI,≤45 years were stratified into two groups by the number of vessels involved,342(59.9%)with SVD and 229(40.1%)with *** average age of these patients was 39.04±4.86 years.A lower prevalence of hypertension and diabetes was observed in SVD as compare to MVD group(25.1%vs 38%,P<0.01;11.7%vs 27.5%,P<0.001)***,smoking was more prevalent among the SVD group as compare to MVD group(36.3%vs 28.4%,P=0.05).The high-C Lesion was observed in a significantly higher number of younger patients with MVD as compared to SVD group(48.8%vs 39.2%,P=0.021).Post-procedure thrombolysis in myocardial infarction flow grade was found to be not associated with the number of diseased vessels with a P value of 0.426 and thrombolysis in myocardial infarction flow grade III was observed in 98%vs 96.5%of the patients is SVD vs MVD *** The MVD comprised of around 40%of the young patients presented with ***,this study shows that diabetes and hypertension have a certain role in the pathogenesis of multivessel diseases,therefore,preventive

关键词： Young Multivessel disease Primary percutaneous coronary intervention STelevation myocardial infarction Premature coronary artery diseases Single-vessel disease