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Local-contrastive-learning machine with both generalization and adversarial robustness:A statistical physics analysis

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Science China(Physics,Mechanics & Astronomy) 2025年第1期68卷 105-119页

作者： Mingshan xie Yuchen Wang Haiping Huang PMI Lab School of PhysicsSun Yat-sen UniversityGuangzhou 510275China Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices Sun Yat-sen UniversityGuangzhou 510275China

Distinct from human cognitive processing,deep neural networks trained by backpropagation can be easily fooled by adversarial *** design a semantically meaningful representation learning,we discard backpropagation,and instead,propose a local contrastive learning,where the representations for the inputs bearing the same label shrink(akin to boson)in hidden layers,while those of different labels repel(akin to fermion).This layer-wise learning is local in nature,being biologically plausible.A statistical mechanics analysis shows that the target fermion-pair-distance is a key ***,the application of this local contrastive learning to MNIST benchmark dataset demonstrates that the adversarial vulnerability of standard perceptron can be greatly mitigated by tuning the target distance,i.e.,controlling the geometric separation of prototype manifolds.

关键词： machine learning statistical mechanics adversarial robustness neural networks

Embedding prescribed-time adaptive control protocol unveiling distributed consensus in multirobot systems via directed topology

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Science China(Information Sciences) 2025年第2期68卷 383-384页

作者： Yonghao xie Xinru MA Hengyu LI Shaorong xie School of Computer Engineering and Science Shanghai University School of Mechatronic Engineering and Automation Shanghai University

Recently, multirobot systems(MRSs) have found extensive applications across various domains, including industrial manufacturing, collaborative formation of unmanned equipment, emergency disaster relief, and war scenarios [1]. These advancements are largely supported by the development of consistency control theory. However, traditional dynamicsfree models may cause instability in complex robotic systems. Lagrangian dynamics offers a better approach for modeling these systems, as it facilitates controller design and optimization analysis. Despite this, challenges persist with unknown parameters and nonlinear friction within the systems.

关键词： Microrobots

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THE CONVEX SETS OF CONSTANT WIDTH CONSTRUCTED FROM OPPOSITE SECTORS

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Acta Mathematica Scientia 2025年第1期45卷 118-125页

作者： Fengfan xie Yong YANG Hubei Province Key Laboratory of Systems Science in Metallurgical Process(Wuhan University of Science and Technology) Wuhan430081China Henan University of Animal Husbandry and Economy Zhengzhou450046China

This paper presents a method for constructing a convex set of constant width from opposite sectors.

关键词： convex set constant width opposite sectors

STIL enhances the development of lung adenocarcinoma by regulating the glycolysis pathway

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Oncology Research 2025年第1期33卷 123-132页

作者： LEI WANG XIANJIN xie Department of Respiratory Medicine Jen Ching Memorial HospitalSuzhou215300China Department of Respiratory Medicine Shandong Provincial Third HospitalJinan250010China

Background:To investigate SCL/TAL 1 interrupting locus(STIL)’s role and prognostic significance in lung adenocarcinoma(LUAD)progression,we examined STIL and E2 promoter binding factor 1(E2F1)expression and their impacts on LUAD prognosis using Gene Expression Profiling Interactive Analysis(GEPIA).Methods:Functional assays including CCK-8,wound-healing,5-ethynyl-2-deoxyuridine(EdU),Transwell assays,and flow cytometry,elucidated STIL and E2F1’s effects on cell viability,proliferation,apoptosis,and *** set enrichment analysis(GSEA)identified potential pathways,while metabolic assays assessed glucose ***:Our findings reveal that STIL and E2F1 are overexpressed in LUAD,correlating with adverse *** enhances cell proliferation,migration,and invasion,and suppresses apoptosis,activating downstream of *** E2F1 reversed the promotion effect of the STIL overexpression on cell viability and ***,STIL modulates glycolysis,influencing glucose consumption,lactate production,and energy balance in LUAD ***:Our model,incorporating STIL,age,and disease stage,robustly predicts patient prognosis,underscored STIL’s pivotal role in LUAD pathogenesis through metabolic *** comprehensive approach not only confirms STIL’s prognostic value but also highlights its potential as a therapeutic target in LUAD.

关键词： SCL/TAL1 interrupting locus(STIL) Lung adenocarcinoma E2 promoter binding factor 1 Glycolysis

Lewis Acid-catalyzed Regioselective Addition of Allenoates to Indoles for Synthesis of Bisindolylesters

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Chemical Research in Chinese Universities 2025年第1期41卷 48-58页

作者： xie Fuyu HE Jianghua ZHANG Yuetao State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun130012P.R.China

Indole derivatives,especially bisindolylesters,have attracted intense attention due to their important applications in medicinal chemistry and organic *** we develop a Lewis acid-catalyzed efficient and regioselective strategy to prepare a series of symmetric and unsymmetric bisindolylesters in high to excellent yields under mild *** systematic investigations,which include stoichiometric nuclear magnetic resonance(NMR)experiments and structural characterization of intermediates,have provided insights into the possible reaction mechanism for this B(C_(6)F_(5))_(3)-catalyzed addition ***,the sequential employment of Al(C_(6)F_(5))_(3)and B(C_(6)F_(5))_(3)as catalysts enabled us to successfully prepare the unsymmetric bisindolyl-compounds in one-pot two-step manner without the separation step.

关键词： B(C_(6)F_(5))_(3) Al(C_(6)F_(5))_(3) Indole Allenoate Indolylester

Understanding the iodine electrochemical behaviors in aqueous zinc batteries

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Journal of Energy Chemistry 2025年第2期101卷 402-415页

作者： Xuefang xie Xiaoxin Xu Shuquan Liang Guozhao Fang College of Physical Science and Technology Xinjiang University Xinjiang Key Laboratory of Solid State Physics and Devices Xinjiang University School of Materials Science & Engineering Key Laboratory of Electronic Packaging and Advanced Functional Materials of Hunan Province Central South University National Energy Metal Resources and New Materials Key Laboratory Central South University

Iodine is widely used in aqueous zinc batteries（ZBs） due to its abundant resources,low cost,and active redox *** addition to the active material in zinc-iodine batteries,iodine also plays an important role in other ZBs,such as regulating the electrochemical behavior of zinc ions,promoting the reaction kinetic and reversibility of other redox pairs,catalytic behaviors related to iodine reactions,coupling with other halogen ions,shuttle behaviors of polyiodides,***,there is currently a lack of comprehensive discussion on these ***,this review provides a comprehensive overview of the electrochemical behaviors of iodide in the aqueous *** effect of iodine ions on the Zn2+desolvation behaviors and the interfacial behaviors of Zn anode was *** redox pairs boosting other redox pairs,such as MnO2/Mn2+redox pair and vanadium redox pair to obtain high reversibility and capacity was also ***,the catalytic behaviors related to iodine reactions in aqueous ZBs,synergistic reaction with other halogen ions and suppression of shuttle behaviors for high performance zinc-iodine batteries were systematically ***,future prospects for designing effective iodine electrochemical behaviors with practicability are proposed,which will provide scientific guidance for the practical application of iodine-related aqueous ZBs.

关键词： Catalytic behavior Iodide ion Redox pairs Shuttle effect Zinc batteries

Investigation into enhanced performance of toluene and Hg0 stimulative abatement over Cr-Mn oxides co-modified columnar activated coke

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Journal of Environmental Sciences 2025年第2期148卷 88-106页

作者： Jiajie Wang Jie Liu Lei Gao Dong xie Caiting Li Liping Xiang Huiyu Xiong Jiaqi xie Tianren Zhang Yueguo Pan School of Resources Environment and Safety Engineering University of South ChinaHengyang 421001China National&Local Joint Engineering Research Center for Airborne Pollutants Control and Radioactivity Protection in Buildings Hengyang 421001China Key Laboratory of Prefabricated Building Energy Saving Technology of Hunan Province Hengyang 421001China College of Environmental Science and Engineering Hunan UniversityChangsha 410082China

In this study,a string of Cr-Mnco-modified activated coke catalysts(XCryMn1-y/AC)were prepared to investigate toluene and Hg0 removal *** characterizations including XRD,TEM,SEM,in situ DRIFTS,BET,XPS and H_(2)-TPR showed that 4%Cr0.5Mn0.5/AC had excellent physicochemical properties and exhibited the best toluene and Hg0 removal efficiency at 200◦*** varying the experimental gas components and conditions,it was found that too large weight hourly space velocity would reduce the removal efficiency of toluene and *** O_(2) promoted the abatement of toluene and Hg0,the inhibitory role of H_(2)O and SO_(2) offset the promoting effect of O_(2) to some *** significantly inhibited Hg0 removal,resulting from that toluene was present at concentrations orders of magnitude greater than mercury’s or the catalyst was more prone to adsorb toluene,while Hg0 almost exerted non-existent influence on toluene *** mechanistic analysis showed that the forms of toluene and Hg0 removal included both adsorption and oxidation,where the high-valent metal cations and oxygen vacancy clusters promoted the redox cycle of Cr^(3+)+Mn^(3+)/Mn^(4+)+Cr^(6+)+Mn^(2+),which facilitated the conversion and replenishment of reactive oxygen species in the oxidation process,and even the CrMn1.5O4 spinel structure could provide a larger catalytic interface,thus enhancing the adsorption/oxidation of toluene and ***,its excellent physicochemical properties make it a costeffective potential industrial catalyst with outstanding synergistic toluene and Hg0 removal performance and preeminent resistance to H_(2)O and SO_(2).

关键词： Toluene Element mercury Cr-Mn oxides Activated coke

From earthquake resistance structure to earthquake resilience city–urban seismic resilience assessment

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Earthquake Engineering and Engineering Vibration 2025年第1期24卷 1-13页

作者： xie Lili Zhao Yonggang Wen Weiping Zhai Changhai Key lab of Structures Dynamic Behaviour and Control of the Ministry of Education Harbin Institute of TechnologyHarbin 150090China Key lab of Smart Prevention and Mitigation of Civil Engineering Disasters of the Ministry of Industry and Information Technology Harbin Institute of TechnologyHarbin 150090China Institute of Engineering Mechanics China Earthquake AdministrationHarbin 150080China

Earthquakes pose significant perils to the built environment in urban *** avert the calamitous aftermath of earthquakes,it is imperative to construct seismic resilient *** to the intricacy of the concept of urban seismic resilience(USR),its assessment is a large-scale system engineering *** assessment of USR should be based on the notion of urban seismic capacity(USC)assessment,which includes casualties,economic loss,and recovery time as *** loss is also included in the assessment of USR in addition to these *** assessment indicator system comprising five dimensions(building and lifeline infrastructure,environment,society,economy,and institution)and 20 indicators has been devised to quantify *** analytical hierarchy process(AHP)is utilized to compute the weights of the criteria,dimensions,and indicators in the urban seismic resilience assessment(USRA)indicator *** the necessary data for a city are obtainable,the seismic resilience of that city can be assessed using this *** illustrate the proposed methodology,a moderate-sized city in China was selected as a case *** assessment results indicate a high level of USR,suggesting that the city possesses strong capabilities to withstand and recover from potential future earthquakes.

关键词： urban seismic capacity urban seismic resilience assessment analytic hierarchy process functionality loss

Superhydrophobic and corrosion-resistant siloxane-modified MgAl-LDHs coatings on magnesium alloy prepared under mild conditions

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 450-463页

作者： Wenxi Zhang Zhangzelong Zhuo Dan Xu Liang Wu Zhihui xie Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province College of Chemistry and Chemical EngineeringChina West Normal UniversityNanchong 637002China College of Materials Science and Engineering/National Engineering Research Center for Magnesium Alloys Chongqing UniversityChongqing 400044China

We have developed a superhydrophobic and corrosion-resistant LDH-W/PFDTMS composite coating on the surface of Mg *** composite comprised a tungstate-intercalated(LDH-W)underlayer that was grown at low temperature(relative to hydrothermal reaction conditions)under atmospheric pressure and an outer polysiloxane layer created from a solution containing perfluorodecyltrimethoxysilane(PFDTMS)using a simple immersion *** successful intercalation of tungstate into the LDH phase and the following formation of the polysiloxane layer were confirmed through X-ray diffraction(XRD),Fourier transform infrared(FTIR)spectroscopy,and X-ray photoelectron spectroscopy(XPS).The corrosion resistance of the LDH-W film,both before and after the PFDTMS modification,was evaluated using electrochemical impedance spectroscopy(EIS),Tafel curves,and immersion *** results showed that Mg coated with LDH-W/PFDTMS exhibited significantly enhanced corrosion protection compared to the unmodified LDHW film,with no apparent signs of corrosion after exposure to 3.5wt%NaCl solution for 15 ***,the LDH-W/PFDTMS coating demonstrated superior superhydrophobicity and self-cleaning properties against water and several common beverages,as confirmed by static contact angle and water-repellency *** results offer valuable insights into preparing superhydrophobic and corrosion-resistant LDH-based composite coatings on Mg alloy surfaces under relatively mild reaction conditions.

关键词： Mg alloy corrosion coating layered double hydroxide