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An innovative classification system for ranking the biological effects of marine aromatic hydrocarbons based on fish embryotoxicity

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Acta Oceanologica Sinica 2024年第6期43卷 153-162页

作者： Ronghui Zheng Chao fang Fukun Hong Min zhang Fulong Gao Yusheng zhang Jun Bo Key Laboratory of Marine Ecological Conservation and Restoration Third Institute of OceanographyMinistry of Natural ResourcesXiamen 361005China Observation and Research Station of Coastal Wetland Ecosystem in Beibu Gulf Ministry of Natural ResourcesBeihai 536015China

Petroleum hydrocarbon pollution is a global concern,particularly in coastal *** aromatic hydrocarbons(PAHs) are regarded as the most toxic components of petroleum *** this study,the biomonitoring and ranking effects of petroleum hydrocarbons and PAHs on the marine fish model Oryzias melastigma embryos were determined in the Jiulong River Estuary(JRE) and its adjacent waters in *** results showed that the levels of petroleum hydrocarbons from almost all sites met the primary standard for marine seawater quality,and the concentrations of the 16 priority PAHs in the surface seawater were lower compared with those in other coastal areas worldwide.A new fish expert system based on the embryotoxicity of ***(OME-FES) was developed and applied in the field to evaluate the biological effects of petroleum hydrocarbons and *** selected physiological index and molecular indicators in OME-FES were appropriate biomarkers for indicating the harmful effects of petroleum hydrocarbons and *** outcome of OME-FES revealed that the biological effect levels of the sampling sites ranged from level Ⅰ(no stress) to level Ⅲ(medium stress),which is further corroborated by the findings of nested analysis of variance(ANOVA) *** results suggest that the OME-FES is an effective tool for evaluating and ranking the biological effects of marine petroleum hydrocarbons and *** method may also be applied to evaluate other marine pollutants based on its framework.

关键词： petroleum hydrocarbons polycyclic aromatic hydrocarbons fish expert system integrated biomarker response nested one-way analysis of variance

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Multi-spheric interactions driven differential formation and accumulation of hydrocarbon resources in the North Sea Basin

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Science China Earth Sciences 2024年第11期67卷 3397-3420页

作者： Rixiang ZHU Shuichang zhang Huajian WANG Xiaomei WANG Yuke LIU Wang zhang fang HAO Zhijun JIN Key Laboratory of Deep Petroleum Intelligent Exploration and Development Institute of Geology and Geophysics Chinese Academy of Sciences State Key Laboratory of Enhanced Oil & Gas Recovery Research Institute of Petroleum Exploration and Development China National Petroleum Corporation State Key Laboratory of Deep Oil and Gas China University of Petroleum (East China) Institute of Energy Peking University

The North Sea Basin is the most important oil and gas producing area in Europe and the birthplace of many classic petroleum geological theories. From the perspective of multi-spheric interactions in the Earth, this study investigated the riftforeland-rift evolution process of the North Sea Basin, which was controlled by the deep dynamic driving forces of the continental collision orogeny, mantle plume uplift, and intraplate deformation. The North Sea Basin was found to have drifted northward since the Carboniferous and passed through the low-latitude Hadley and the mid-latitude Ferrel cells. Two sets of main hydrocarbon source rocks have formed, the coals and coal measures of the Upper Carboniferous Westphalian and the marine shale of the Upper Jurassic Kimmeridge Clay Formation. We propose that the deep processes, tectonic activity, and transgression-climate evolution jointly controlled the types and horizons of the source rocks, reservoirs, and seals in different regions of the North Sea Basin. In the southern North Sea Basin, a Carboniferous-Lower Triassic gas-rich petroleum system was formed,which is characterized by transitional coal measure source rocks, desert aeolian sandstone reservoirs, and evaporite cap rocks. In the northern North Sea Basin, an Upper Triassic-Paleogene oil-rich petroleum system was formed, which is characterized by marine graben-type source rocks, deltaic sandstone and marine limestone reservoirs, and marine tight marl and shale cap *** late tectonic burial and uplift in the North Sea Basin further controlled the processes of oil and gas generation and accumulation, ultimately leading to a differential distribution pattern which is oil rich in the northern part and gas rich in the southern part of the basin. In the future, there is an urgent need to re-examine the mechanisms for the petroleum generation and accumulation in large mature exploration areas(e.g., super basins such as the North Sea) and low exploration areas(e.g., the O

关键词： North Sea Basin Multi-spheric interactions Petroleum system Okhotsk Sea region

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Vanadium(V) Complexes Containing Unsymmetrical N-Heterocyclic Carbene Ligands: Highly Efficient Synthesis and Catalytic Behavior towards Ethylene/Propylene Copolymerization

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Chinese Journal of Polymer Science 2024年第1期42卷 32-41,I0006页

作者： Yi-Cong Wang Hui Zhat Pei-Yi Cheng Shu zhang xiang-Wei Liu Yi-xian Wu State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBejing 100029China

The highly efficient method has been developed for the synthesis of NHC·VOCl_(3) containing symmetrical or unsymmetrical Nheterocyclic carbene(NHC) ligands by the transmetallation reaction of NHC·AgCl with VOCl_(3).The total isolated yield of VOCl_(3)[1,3-(2,4,6-Me_(3)C_(6)H_(2))_(2)(NCH=)_(2)C:](V4') reached 86% by transmetallation reaction,which is much higher than that(48%) by direct coordination *** methodology has also been used to synthesize the novel vanadium complexes containing unsymmetrical NHC ligands of VOCl_(3)[PhCH_(2)NCH=CHNR)C:](V5',R=2,4,6-Me_(3)C_(6)H_(2);V6',R=2,4-Me_(2)-6-Ph-C_(6)H_(2);V7',R=2,6-^(i)Pr_(2)-C_(6)H_(3)) with high yield,which could not be obtained by direct coordination *** catalytic activity and copolymerization ability would be improved by introducing unsymmetrical NHC ligands due to their less steric bulky *** vanadium complex V5' containing unsymmetrical NHC ligand exhibits higher catalytic activity(3.7×10^(5)g_(copolymer)·mol^(-1) of V·h^(-1)) than that of V4' containing symmetrical NHC ***,the higher propylene incorporation ratio(45.6 mol%) in the copolymers of ethylene with propylene could be obtained by using V5' than that(39.9%) by using V4'.The results would provide a highly efficient strategy for the synthesis of early transition metal complexes containing versitile NHC ligands,affording the catalyst with both high catalytic activity and copolymerization ability for the synthesis of high performance polyolefin elastomers.

关键词： Vanadium complex N-heterocyclic carbene ligand Transmetallation reaction Copolymerization of ethylene with propylene

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Sidewall rockburst of highly stressed D-shape hole tunnel triggered by impact load: An experimental investigation

Rock Mechanics Bulletin

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Rock Mechanics Bulletin 2024年第1期3卷 64-80页

作者： Wuxing Wu Fengqiang Gong Zong-xian zhang School of Civil Engineering Southeast UniversityNanjing211189China Oulu Mining School University of OuluOulu90570Finland

This study aims to clarity the failure mechanism of sidewall rockburst of highly stressed D-shape tunnel triggered by impact *** the biaxial Hopkinson pressure bar(BHPB)system,we have developed experimental capabilities to study the sidewall rockburst of D-shape tunnel by applying various prestresses,including horizontal and vertical static stresses,to sand prefabricated D-shape hole specimen,followed by impact ***-speed(HS)camera and digital image correlation(DIC)were used to tracked the process and strain field of the sidewall *** test results reveal that the process of sidewall rockburst can be summarized as:calm stage,crack initiation,propagation,and coalesce stage,spalling stage and rock fragments ejection *** the rockburst process,the surrounding rock experienced spalling and violent ejection,involving both tensile and tensile-shear *** mechanism of sidewall rockburst under the coupled of static stress and impact loads has been elucidated,i.e.,the static prestress determines the initial stress and strain distribution,and the horizontal prestress influences the affected range and strain values of strain concentration zone;the impact load disrupts the original static stress equilibrium,inducing alterations in the stress and strain of the surrounding rock and triggering sidewall rockburst.

关键词： impact rock load

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Strong electron correlation-induced Mott-insulating electrides of Ae_(5)X_(3)(Ae=Ca,Sr,and Ba;X=As and Sb)

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Matter and Radiation at Extremes 2024年第3期9卷 74-82页

作者： Ya Xu Lu Zheng Yunkun zhang Zhuangfei zhang QianQian Wang Yuewen zhang Liangchao Chen Chao fang Biao Wan Huiyang Gou Key Laboratory of Material Physics of Ministry of Education School of Physics and Laboratory of Zhongyuan LightZhengzhou UniversityZhengzhou 450052China School of Mechanical and Equipment Engineering Hebei University of EngineeringHandan 056038China Center for High Pressure Science and Technology Advanced Research Beijing 100094China

The presence of interstitial electrons in electrides endows them with interesting attributes,such as low work function,high carrier concentration,and unique magnetic *** knowledge and understanding of electrides are thus of both scientific and technological ***,we employ first-principles calculations to investigate Mott-insulating Ae_(5)X_(3)(Ae=Ca,Sr,and Ba;X=As and Sb)electrides with Mn_(5)Si_(3)-type structure,in which half-filled interstitial electrons serve as ions and are *** Mott-insulating property is induced by strong electron correlation between the nearest interstitial electrons,resulting in spin splitting and a separation between occupied and unoccupied *** half-filled antiferromagnetic configuration and localization of the interstitial electrons are critical for the Mott-insulating properties of these *** with that in intermetallic electrides,the orbital hybridization between the half-filled interstitial electrons and the surrounding atoms is weak,leading to highly localized magnetic centers and pronounced correlation ***,the Mott-insulating electrides Ae_(5)X_(3)have very large indirect bandgaps(0.30 eV).In addition,high pressure is found to strengthen the strong correlation effects and enlarge the *** present results provide a deeper understanding of the formation mechanism of Mott-insulating electrides and provide guidance for the search for new strongly correlated electrides.

关键词： intermetallic filled occupied

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AdaPIP: Adaptive picture-in-picture guidance for 360° film watching

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Computational Visual Media 2024年第3期10卷 487-503页

作者： Yi-Xiao Li Guan Luo Yi-Ke Xu Yu He fang-Lue zhang Song-Hai zhang Department of Computer Science and Technology Tsinghua UniversityBeijingChinaand Beijing National Research Center for Information Science and Technology(BNRist)Tsinghua UniversityBeijingChina Key Laboratory of Space Utilization Technology and Engineering Center for Space UtilizationChinese Academy of SciencesBeijingChina Victoria University of Wellington WellingtonNew Zealand

360°videos enable viewers to watch freely from different directions but inevitably prevent them from perceiving all the helpful *** mitigate this problem,picture-in-picture(PIP)guidance was proposed using preview windows to show regions of interest(ROIs)outside the current view *** identify several drawbacks of this representation and propose a new method for 360° film watching called *** enhances traditional PIP by adaptively arranging preview windows with changeable view ranges and *** addition,AdaPIP incorporates the advantage of arrow-based guidance by presenting circular windows with arrows attached to them to help users locate the corresponding ROIs more *** also adapted AdaPIP and Outside-In to HMD-based immersive virtual reality environments to demonstrate the usability of PIP-guided approaches beyond 2D *** user experiments on 2D screens,as well as in VR environments,indicate that AdaPIP is superior to alternative methods in terms of visual experiences while maintaining a comparable degree of immersion.

关键词： 360°videos picture-in-picture(PIP) virtual reality(VR) visual guidance

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Free radicals trigger the closure of open pores in lignin-derived hard carbons toward improved sodium-storage capacity

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Journal of Energy Chemistry 2024年第7期94卷 551-559页

作者： Wen-Jun Ji Zong-Lin Yi Ming-Xin Song Xiao-Qian Guo Yi-Lin Wang Yi-Xuan Mao fang-Yuan Su Jing-Peng Chen xian-xian Wei Li-Jing Xie Cheng-Meng Chen CAS Key Laboratory of Carbon Materials Institute of Coal ChemistryChinese Academy of SciencesTaiyuan 030001ShanxiChina University of Chinese Academy of Sciences Beijing 100049China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing 100049China School of Environment and Safety Taiyuan University of Science and TechnologyTaiyuan 030001ShanxiChina

The chemical activation of various precursors is effective for creating additional closed pores in hard carbons for sodium ***,the formation mechanism of closed pores under the influence of pore-forming agents is not well ***,an effective chemical activation followed by a high-temperature self-healing strategy is employed to generate interconnected closed pores in lignin-derived hard carbon(HCs).By systematic experimental design combined with electron paramagnetic res-onance spectroscopy,it can be found that the content of free radicals in the carbon matrix influences the closure of open pores at high *** high activation temperature(>700 C)leads to a low free radical concentration,making it difficult to achieve self-healing of open pores at high *** activation at 700°C,a balance between pore making and self-healing is achieved in the final hard carbon.A large number of free radicals triggers rapid growth and aggregation of carbon microcrys-tals,blocking pre-formed open micropores and creating additional interconnected closed pores in as-obtained hard *** a result,the optimized carbon anode(LK-700-1300)delivers a high reversible capacity of 330.8 mA h g^(-1) at 0.03 A g^(-1),which is an increase of 86 mA h g^(-1) compared to the pristine lignin-derived carbon anode(L-700-1300),and exhibits a good rate performance(202.1 mA h g^(-1) at 1 A g^(-1)).This work provides a universal and effective guidance for tuning closed pores of hard carbons from otherprecursors.

关键词： Hard carbon Chemical activation Free radical Self-healing Closed pores Sodium ion batteries

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Training Generative Adversarial Networks with Adaptive Composite Gradient

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Data Intelligence 2024年第1期6卷 120-157页

作者： Huiqing Qi fang Li Shengli Tan xiangyun zhang School of Mathematical Sciences East China Normal UniversityShanghai 200241China

The wide applications of Generative adversarial networks benefit from the successful training methods,guaranteeing that an object function converges to the local ***,designing an efficient and competitive training method is still a challenging task due to the cyclic behaviors of some gradient-based ways and the expensive computational cost of acquiring the Hessian *** address this problem,we proposed the Adaptive Composite Gradients(ACG)method,linearly convergent in bilinear games under suitable *** analysis and toy-function experiments both suggest that our approach alleviates the cyclic behaviors and converges faster than recently proposed SOTA *** convergence speed of the ACG is improved by 33%than other *** ACG method is a novel Semi-Gradient-Free algorithm that can reduce the computational cost of gradient and Hessian by utilizing the predictive information in future *** mixture of Gaussians experiments and real-world digital image generative experiments show that our ACG method outperforms several existing technologies,illustrating the superiority and efficacy of our method.

关键词： Generative adversarial networks adaptive composite gradient semi-gradient free game theory bilinear game

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Surface-state controlled synthesis of hydrophobic and hydrophilic carbon dots

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Nano Research 2024年第5期17卷 4391-4399页

作者： Chan Wang Yuan fang Mi zhang Huan Zhuo Qijun Song Han Zhu Key Laboratory of Synthetic and Biological Colloids Ministry of EducationSchool of Chemical and Material EngineeringJiangnan UniversityWuxi 214122China Jiangsu Snow Leopard Household Chemical Co. Ltd.Wuxi 214400China

It is of great significance to synthesize carbon dots(CDs)with desirable hydrophilicity for the ever-growing application of CDs in different *** this study,the hydrophilic and hydrophobic CDs were facilely prepared by solvothermal treatment of o-dihydroxybenzene and urea in N,N-dimethylformamide(DMF).Optimization experiments revealed that the solvothermal temperature has a great impact on the surface states of the *** hydrophobic CDs with a contact angle of 110.7°was obtained at 200℃.The structural and optical characterizations,along with theoretical calculations elucidated that the lipophilic nature of the CDs was resulting from the formation of polymer *** presence of extended conjugated sp^(2)-domains and amino groups contributed to the red emission of the CDs synthesized at low reaction temperatures(160-200℃).With the further increase of solvothermal temperature,the hydrophobic CDs were gradually transformed to the hydrophilic state accompanying the blue shift of the fluorescence of the *** highly hydrophilic CDs with a contact angle of 25.9°were obtained at 240℃ due to the increased formation of hydrophilic functional groups on the surface of *** red emissive CDs exhibited a sensitive color and fluorescence response to ethanol content while the fluorescence of the blue emissive CDs remained *** combining the two kinds of CDs,a dual-emission sensor was constructed,which was successfully applied for the evaluation of the alcoholic strength in commercial Baijiu commodities in both fluorometric and colorimetric modes.

关键词： carbon dots surface chemistry hydrophilicity and hydrophobicity solvothermal temperature alcoholic strength evaluation

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Synergy enhancement of Co single atoms and asymmetric subnanoclusters for Fenton-like activation

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Nano Research 2024年第9期17卷 7935-7944页

作者： Ming Ma Zhiyi Sun Ziwei Deng xiang Li fang zhang Wenxing Chen School of Materials Key Laboratory of Cluster Science Ministry of EducationBeijing Key Laboratory of Photoelectronic/Electrophotonic Conversion MaterialsAdvanced Technologies Research Institute(Jinan)Advanced Research Institute of Multidisciplinary ScienceSchool of Chemistry and Chemical EngineeringBeijing Institute of TechnologyBeijing 100081China Energy and Catalysis Center School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Analysis and Testing Center Beijing Institute of TechnologyBeijing Institute of TechnologyBeijing 100081China

As a new water treatment technology,Fenton-like reaction has great *** this study,we successfully prepared an excellent Fenton-like catalyst,which is composed of cobalt monoatoms and asymmetric subnanoclusters(labeled CoSA/Clu-C_(2)N),and exhibits excellent peroxymonosulfate(PMS)activation *** directly comparing the catalytic properties of CoSA-C_(2)N and CoSA/Clu-C_(2)N,the synergistic effects of coasymmetric Co subclusters and Co atoms on the activation of PMS and degradation of organic micropollutants were *** results showed that CoSA/Clu-C_(2)N had higher degradation rates of carbamazepine(CBZ),antipyrine(AT)and chlorobenzoic acid(CA)when combined with active oxidant *** cyclic frequency of CBZ was 5.4 min^(-1),which was twice as high as the catalytic constant of CoSA-C_(2)N(2.4 min^(-1)).The results show that CoSA/Clu-C_(2)N cobalt subnanoclusters and cobalt single atom can synergistically improve the catalytic performance of activated PMS oxidation of micropollutants in *** addition,electron paramagnetic resonance(EPR)technology has proved that the introduction of Co subnano clusters in CoSA/Clu-C_(2)N is conducive to the production of singlet oxygen(1O_(2)),thereby improving the efficiency of pollutant *** work lays a solid foundation for the future design of advanced multifunctional catalysts by carefully regulating and combining monmetallic atoms and metal subnanoclusters.

关键词： carbamazepine Fenton-like reaction Co single atoms asymmetrical sub-nanoclusters peroxymonosulfate synergy enhancement

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