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Molecular Ferroelastic Induced by Mono-/Double-Protonation Strategy

Chinese Journal of Chemistry 2024年第15期42卷 1706-1712页

作者： Jia-Qi Luo Meng-Meng Lun Qiang-Qiang Jia zhi-Jie Wang Hai-Feng Lu Yi Zhang Da-Wei fu Institute for Science and Applications of Molecular Ferroelectrics Key Laboratory of the Ministry of Education for Advanced Catalysis MaterialsZhejiang Normal UniversityJinhuaZhejiang 321004China Ordered Matter Science Research Center Jiangsu Key Laboratory for Science and Applications of Molecular FerroelectricsSoutheast UniversityNanjingJiangsu 211189China

Molecular ferroelastics with the natural features of mechanical flexibility and switchable spontaneous strain have attracted widespread attention in the scientific community due to their potential applications in tunable gratings,flexible memorizers,strain sensors,and intelligent ***,most designs of molecular ferroelastics remain in the stage of blind exploration,posing a challenge to achieve a functional ferroelastic more ***,we have successfully obtained a molecular ferroelastic,[Me_(2)NH(CH_(2))_(2)NH_(3)](ReO_(4))_(2)(Me_(2)NH(CH_(2))_(2)NH_(3)=N,N-dimethylethylenediammonium),under the guidance of the mono-/double-protonation ***_double-protonated[Me_(2)NH(CH_(2))_(2)NH_(3)](ReO_(4))_(2) undergoes a paraelastic-ferroelastic phase transition with the Aizu notation of 2/mFi at 322 ***,the theoretical calculation and experimental measurement simultaneously show that[Me_(2)NH(CH_(2))_(2)NH_(3)](ReO_(4))_(2) possesses good mechanical flexibility,because its elastic modulus(E)of 8.26 GPa and hardness(H)of 0.45 GPa are smaller than the average values of organic crystals(E of 12.05 GPa and H of 0.5 GPa),which makes it promising to apply in wearable pressure sensors,implantable medical sensors,high-precision tuners,*** work further enriches the molecular ferroelastic family and demonstrates that mono-/double-protonation is one of the effective molecular modification strategies for designing ferroelastics.

关键词： Molecular crystal Ferroelastic Mono-/double-protonation Mechanical flexibility Phase transition Crystal engineering Computational chemistry Molecular dynamics

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Quantum key distribution over a mimicked dynamic-scattering channel

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Science China(Information Sciences) 2024年第4期67卷 323-330页

作者： Qi-Hang LU Fang-Xiang WANG Wei CHEN Hai-Yang fu Yin-Jie LU Shuang WANG de-Yong HE Zhen-Qiang YIN Guang-Can GUO Zheng-fu HAN CAS Key Laboratory of Quantum Information University of Science and Technology of China CAS Center for Excellence in Quantum Information and Quantum Physics University of Science and Technology of China Hefei National Laboratory University of Science and Technology of China

Free-space quantum key distribution(QKD) plays an important role in the global quantum network. However, free space channels suffer from the atmospheric turbulence and scattering effects of haze,fog, and dust, which significantly weaken the performance of QKD or even block the secure quantum ***, we prove the performance of QKD over a dynamic scattering channel can be enhanced significantly using a fast wavefront shaping technique. The system achieves on average 10-dB enhancement of quantum transmission efficiency and establishes a secure quantum link for QKD. Our work demonstrates the feasibility of QKD through free-space dynamic scattering channels and enhances the deployment capability of complex-channel QKD system.

关键词： quantum key distribution free space channel channel turbulence channel scattering wavefront shaping

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New insights into the deposition of natural gas hydrate on pipeline surfaces:A molecular dynamics simulation study

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Petroleum Science 2024年第1期21卷 694-704页

作者： Jun Zhang Hai-Qiang fu Mu-zhi Guo Zhao Wang Li-Wen Li Qi Yin You-Guo Yan Wei Wei Wei-Feng Han Jie Zhong School of Materials Science and Engineering China University of Petroleum(East China)Qingdao 266580ShandongChina School of Petroleum Engineering China University of Petroleum(East China)Qingdao 266580ShandongChina department of Alternative Energy PetroChina Research Institute of Petroleum Exploration&DevelopmentLangfang 065007HebeiChina

Natural gas hydrate(NGH)can cause pipeline blockages during the transportation of oil and gas under high pressures and low *** hydrate adhesion on pipelines is viewed as an efficient way to prevent NGH *** studies suggested the water film can greatly increase hydrate adhesion in gas-dominant ***,by performing the molecular dynamics simulations,we find in water-dominant system,the water film plays different roles in hydrate deposition on Fe and its corrosion ***,due to the strong affinity of water on Fe surface,the deposited hydrate cannot convert the adsorbed water into hydrate,thus,a water film *** water affinities decrease(Fe>Fe_(2)O_(3)>FeO>Fe_(3)O_(4)),adsorbed water would convert to amorphous hydrate on Fe_(2)O_(3)and form the ordered hydrate on FeO and Fe_(3)O_(4)after hydrate *** absorbed water film converts to amorphous or to hydrate,the adhesion strength of hydrate continuously increases(Fedetachment of deposited hydrate prefers to occur at soft region of liquid layer,the process of which becomes harder as liquid layer *** a result,contrary to gas-dominant system,the water film plays the weakening roles on hydrate adhesion in water-dominant ***,our results can help to better understand the hydrate deposition mechanisms on Fe and its corrosion surfaces and suggest hydrate deposition can be adjusted by changing water affinities on pipeline surfaces.

关键词： deposition Natural gas hydrate Pipelines Water affinity Adhesion strength

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Concurrent hetero-/homo-geneous electrocatalysts to bi-phasically mediate sulfur species for lithium-sulfur batteries

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Journal of Energy Chemistry 2024年第6期93卷 663-668,I0016页

作者： Rui-Bo LingHu Jin-Xiu Chen Jin-Hao Zhang Bo-Quan Li Qing-Shan fu Gulnur Kalimuldina Geng-zhi Sun Yunhu Han Long Kong Xi’an Institute of Flexible Electronics(IFE) Northwestern Polytechnical UniversityXi’an 710129ShaanxiChina Institute of Advanced Materials Nanjing Tech UniversityNanjing 211816JiangsuChina Advanced Research Institute of Multidisciplinary Science Beijing Institute of TechnologyBeijing 100081China department of Mechanical and Aerospace Engineering School of Engineering and Digital SciencesNazarbayev UniversityKabanbay Batyr Ave.53Astana 010000Kazakhstan

Expediting redox kinetics of sulfur species on conductive scaffolds with limited charge accessible surface is considered as an imperative approach to realize energy-dense and power-intensive lithium-sulfur(Li-S)*** this work,the concept of concurrent hetero-/homo-geneous electrocatalysts is proposed to simultaneously mediate liquid-solid conversion of lithium polysulfides(LiPSs)and solid lithium disulfide/sulfide(Li_(2)S_(2)/Li_(2)S)propagation,the latter of which suffers from sluggish reduction kinetics due to buried conductive scaffold surface by extensive deposition of Li_(2)S_(2)/Li_(2)*** selected model material to verify this concept is a two-in-one catalyst:carbon nanotube(CNT)scaffold supported iron-cobalt(Fe-Co)alloy nanoparticles and partially carbonized selenium(C-Se)*** Fe-Co alloy serves as a heterogeneous electrocatalyst to seed Li_(2)S_(2)/Li_(2)S through sulphifilic active sites,while the C-Se sustainably releases soluble lithium polyselenides and functions as a homogeneous electrocatalyst to propagate Li_(2)S_(2)/Li_(2)S via solution *** bi-phasic mediation of the sulfur species benefits reduction kinetics of LiPS conversion,especially for the massive Li_(2)S_(2)/Li_(2)S growth scenario by affording an additional solution directed route in case of conductive surface being largely *** strategy endows the Li-S batteries with improved cycling stability(836 mA h g^(-1)after 180 cycles),rate capability(547 mA h g^(-1)at 4 C)and high sulfur loading superiority(2.96 mA h cm^(-2)at 2.4 mg cm^(-2)).This work hopes to enlighten the employment of bi-phasic electrocatalysts to dictate liquid-solid transformation of intermediates for conversion chemistry batteries.

关键词： Lithium-sulfur batteries Electrocatalysis Lithium polysulfides Sulfur cathode Energy density

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胡先骕的《任公豆歌》--简介冯澄如绘画《任公豆图》

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武汉植物学研究 2009年第2期27卷 225-231页

作者：孙英宝马履一傅德志北京林业大学资源与环境学院北京100083 中国科学院植物研究所北京100093

详细研究了冯澄如创作的一幅彩色植物绘画。结果表明其中的植物是豆科植物任公豆(即任豆)Zenia insignis Chun。1946年陈焕镛为纪念著名学者任鸿隽而以其名字命名建立了任公豆(即任豆)属,并由冯澄如进行彩色绘画,胡先骕为赞颂此事在画... 详细信息

详细研究了冯澄如创作的一幅彩色植物绘画。结果表明其中的植物是豆科植物任公豆(即任豆)Zenia insignis Chun。1946年陈焕镛为纪念著名学者任鸿隽而以其名字命名建立了任公豆(即任豆)属,并由冯澄如进行彩色绘画,胡先骕为赞颂此事在画中赋诗《任公豆歌》。介绍了与此画相关的我国近代植物分类学的奠基人胡先骕、陈焕镛,我国近代植物科学绘画的奠基人冯澄如,以及我国近代科学的奠基人之一任鸿隽四人在植物科学发展工作中的履历。这幅《任公豆图》生动地表现出了四位科学工作者的友好情谊和杰出贡献。

关键词：胡先骕冯澄如陈焕镛任鸿隽《任公豆图》

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Blastomas of the digestive system in adults:A review

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World Journal of Gastrointestinal Surgery 2024年第4期16卷 1030-1042页

作者： Yu Liu Tony El Jabbour Jonathan Somma Yukihiro Nakanishi Saverio Ligato Hwajeong Lee zhi-Yan fu department of Pathology LSU Health Sciences Center School of MedicineNew OrleansLA 70112United States department of Pathology Hartford HealthCareHartfordCT 06102United States department of Pathology Moffitt Cancer CenterTampaFL 33612United States department of Pathology and Laboratory Medicine Albany Medical CenterAlbanyNY 12208United States

Blastomas,characterized by a mixture of mesenchymal,epithelial,and undifferentiated blastematous components,are rare malignant neoplasms originating from precursor blast *** review focuses on digestive system blastomas in adult patients,including gastroblastoma,hepatoblastoma,and *** is a biphasic,epitheliomesenchymal tumor,with only sixteen cases reported to *** addition to the characteristic histology,metastasisassociated lung adenocarcinoma transcript 1-glioma-associated oncogene homolog 1 gene fusion is typical,although recently novel ewing sarcoma breakpoint region 1-c-terminal binding protein 1 and patched 1-glioma-associated oncogene homolog 2 fusions have been *** is exceptionally rare in adults and can show a variety of histologic patterns which may cause diagnostic ***,primarily a pediatric tumor,displays acinar differentiation and squamoid nests with other lines of differentiation also present,especially *** approaches for these blastomas include a combination of imaging modalities,histopathological examination,and molecular *** treatment generally involves surgical resection,which may be supplemented by chemotherapy or radiotherapy in some *** vary with gastroblastoma generally showing favorable outcomes post-surgery whereas hepatoblastoma and pancreatoblastoma often have poorer outcomes,particularly in the setting of *** review highlights the complexity of diagnosing and managing these rare adult blastomas as well as the need for ongoing research to better understand their pathogenesis and improve treatment strategies.

关键词： Adult blastomas Gastroblastoma Hepatoblastoma Pancreatoblastoma Digestive system

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植物区系学中特有现象的研究进展(Ⅰ)——概念、类型、起源及其研究意义

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湖南环境生物职业技术学院学报 2003年第1期9卷 11-20页

作者：左家哺傅德志湖南环境生物职业技术学院湖南衡阳421005 中国科学院植物研究所北京香山100093

植物区系学中的特有现象是其研究的重点内容 ,对特有现象的概念、类型、起源及其研究意义作了详细的论述 ;其次 ,总结了中国植物区系的基本情况、生活型、分布区学、水平分布、垂直分布与起源等研究成果 ;第三 ,介绍了研究特有现象的形... 详细信息

植物区系学中的特有现象是其研究的重点内容 ,对特有现象的概念、类型、起源及其研究意义作了详细的论述 ;其次 ,总结了中国植物区系的基本情况、生活型、分布区学、水平分布、垂直分布与起源等研究成果 ;第三 ,介绍了研究特有现象的形态—地理学方法、细胞地理学方法和等位酶分析方法 ;第四 ,指出了中国植物区系中特有现象研究所面临的困境 ,认为应该集中力量重点研究滇黔桂、横断山脉以及华中等 3个地区的植物区系基本特征、组成、起源。

关键词：植物区系学特有现象概念类型起源研究意义中国植物区系

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植物区系学中特有现象的研究进展(Ⅱ)——中国植物区系、研究方法与任务

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湖南环境生物职业技术学院学报 2003年第2期9卷 93-106页

作者：左家哺傅德志湖南环境生物职业技术学院湖南衡阳421005 中国科学院植物研究所北京香山100093

植物区系学中的特有现象是其研究的重点内容 ,对特有现象的概念、类型、起源及其研究意义作了详细的论述 ;其次 ,总结了中国植物区系的基本情况、生活型、分布区学、水平分布、垂直分布与起源等研究成果 ;第三 ,介绍了研究特有现象的形态 -地理学方法、细胞地理学方法和等位酶分析方法 ;第四 ,指出了中国植物区系中特有现象研究所面临的困境 ,认为应该集中力量重点研究滇黔桂、横断山脉以及华中等 3个地区的植物区系基本特征、组成、起源。

关键词：植物区系学特有现象概念类型起源中国植物区系研究成果研究任务

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Organic polaritonic light-emitting diodes with high luminance and color purity toward laser displays

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Light(Science & Applications) 2024年第9期13卷 1956-1963页

作者： Jianbo de Ruiyang Zhao Fan Yin Chunling Gu Teng Long Han Huang Xue Cao Cunbin An Bo Liao Hongbing fu Qing Liao Beijing Key Laboratory for Optical Materials and Photonic devices Department of ChemistryCapital Normal University100048 BeijingChina Beijing Special Engineering design and Research Institute 100028 BeijingChina Institute of Process Engineering Chinese Academy of Sciences100190 BeijingChina Institute of Molecule Plus Tianjin University and Collaborative Innovation Center of Chemical Science and Engineering(Tianjin)300072 TianjinChina School of Materials Science and Engineering Hunan University of Science and Technology411201 XiangtanHunanChina

Achieving high-luminescence organic light-emitting devices(OLEDs)with narrowband emission and high color purity is important in various optoelectronic *** displays exhibit outstanding advantages in next-generation display technologies owing to their ultimate visual experience,but this remains a great ***,we develop a novel OLED based organic single *** strongly coupling the organic exciton state to an optical microcavity,we obtain polariton electroluminescent(EL)emission from the polariton OLEDs(OPLEDs)with high luminance,narrow-band emission,high color purity,high polarization as well as excellent optically pumped polariton ***,we evaluate the potential for electrically pumped polariton laser through theoretical analysis and provide possible *** work provides a powerful strategy with a material–device combination that paves the way for electrically driven organic single-crystal-based polariton luminescent devices and possibly lasers.

关键词： pumped laser polarization

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AquaticTox:A Web-Based Tool for Aquatic Toxicity Evaluation Based on Ensemble Learning to Facilitate the Screening of Green Chemicals

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Environment & Health 2024年第4期2卷 202-211页

作者： Xing-Xing Shi zhi-Zheng Wang Yu-Liang Wang Fan Wang Guang-fu Yang National Key Laboratory of Green Pesticide Central China Normal UniversityWuhan 430079China

The widespread use of chemical products inevitably brings many side effects as environmental *** assessment of compounds to aquatic life plays an important role in protecting the environment from their ***,in vivo animal testing approaches for aquatic toxicity evaluation are timeconsuming,expensive,and ethically limited,especially when there are a great number of *** silico modeling methods can effectively improve the toxicity evaluation efficiency and save ***,we present a web-based server,AquaticTox,which incorporates a series of ensemble models to predict acute toxicity of organic compounds in aquatic organisms,covering Oncorhynchus mykiss,Pimephales promelas,Daphnia magna,Pseudokirchneriella subcapitata,and Tetrahymena *** predictive models are built through ensemble learning algorithms based on six base *** ensemble models outperform all corresponding single models,achieving area under the curve(AUC)scores of 0.75−*** to the best single models,the average precisions of the ensemble models have been increased by 12−22%.Additionally,a self-built knowledge base of the structure-aquatic toxic mode of action(MOA)relationship was integrated into AquaticTox for toxicity mechanism ***,the user-friendly tool(https://***/ccb/server/AquaticTox);could facilitate the identification of aquatic toxic chemicals and the design of green molecules.

关键词： ecotoxicity aquatic toxicity water environment protection toxicity prediction structure−toxicity relationship deep learning

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