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采用DIC技术的超高性能混凝土的断裂性能研究

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混凝土 2024年第6期 220-225页

作者：樊春林丁小明刘恒波陈红鸟许应杰贵州大学空间结构研究中心贵州贵阳550025 浙江宏日泰耐克新材料科技有限公司浙江宁波315201 贵州省建筑材料科学研究设计院有限责任公司贵州贵阳550007 贵州省结构工程重点实验室贵州贵阳550025

为研究超高性能混凝土(UHPC)的Ⅱ型断裂性能,对不同初始缝高比(a/W)的UHPC双缺口立方体(DNC)试件进行了抗压试验。基于数字图像相关(DIC)技术分析了UHPC的DNC试件的失效特征和裂缝扩展过程,得到了UHPC的Ⅱ型断裂参数,并评估了不同a/W下U... 详细信息

为研究超高性能混凝土(UHPC)的Ⅱ型断裂性能,对不同初始缝高比(a/W)的UHPC双缺口立方体(DNC)试件进行了抗压试验。基于数字图像相关(DIC)技术分析了UHPC的DNC试件的失效特征和裂缝扩展过程,得到了UHPC的Ⅱ型断裂参数,并评估了不同a/W下UHPC的断裂性能。试验表明:试件的破坏模式为沿缺口尖端发生局部偏剪切破坏,其主裂缝包括斜裂缝和左、右垂直裂缝,试件的荷载-位移曲线呈现出双峰值现象,两个峰值荷载分别对应斜裂缝和垂直裂缝充分扩展的时刻;斜裂缝和垂直裂缝的张开位移(COD)和滑移位移(CSD)与韧带高度近似呈线性关系;随着a/W的增大,起裂荷载减小,断裂韧度和断裂能先增大后减小,斜裂缝的长度和起始角减小,斜裂缝缺口尖端处的COD减小,CSD基本不变。

关键词：超高性能混凝土双缺口立方体数字图像相关裂缝张开位移裂缝滑移位移断裂性能

一步式QuEChERS结合超高效液相色谱-质谱法检测豇豆和芒果中22种农药残留

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食品工业科技 2024年第17期45卷 252-261页

作者：仝凯旋夏寒李建勋谢瑜杰吴兴强范春林陈辉中国检验检疫科学研究院北京100176 中国农业科学院农产品加工研究所北京100193

基于超高效液相色谱-串联质谱法(UPLC-MS/MS)建立了豇豆和芒果中22种农药的一步式QuEChERS自动化检测技术,样品经1%乙酸乙腈提取,加入EN萃取盐(无水硫酸镁、氯化钠、柠檬酸三钠、柠檬酸二钠)除水后,使用C18和石墨化碳黑(GCB)净化,经ACQU... 详细信息

基于超高效液相色谱-串联质谱法(UPLC-MS/MS)建立了豇豆和芒果中22种农药的一步式QuEChERS自动化检测技术,样品经1%乙酸乙腈提取,加入EN萃取盐(无水硫酸镁、氯化钠、柠檬酸三钠、柠檬酸二钠)除水后,使用C18和石墨化碳黑(GCB)净化,经ACQUITY UPLC BEH C18色谱柱分离,以0.01%甲酸水溶液(含2 mmol/L甲酸铵)-0.01%甲酸甲醇为流动相,在多重反应监测(MRM)下进行测定。结果表明,22种农药在0.01~25.00μg/L质量浓度范围内线性关系良好,决定系数R2均大于0.994,方法的检出限(LOD,S/N=3)在0.05~2μg/kg范围内,定量限(LOQ,S/N=10)在0.1~5μg/kg范围内,在1倍LOQ、2倍LOQ和10倍LOQ 3个加标水平下进行回收率实验(n=6),豇豆3个水平的平均回收率分别为70.9%~116.6%、71.9%~118.3%、73.7%~113.7%,芒果平均回收率分别为70.2%~114.6%、71.2%~113.7%、74.3%~118.5%,两种基质相对标准偏差均在20%以内。方法成功应用于42批实际样品检测,有33批检出农药残留。该方法有较高的灵敏度和足够自动化,减少了人为操作步骤,适用于22种农药及农药代谢物的同时检测及准确定量。

关键词：一步式QuEChERS 超高效液相色谱-质谱法农药残留豇豆芒果

一步式QuEChERS-气相色谱-三重四极杆质谱法快速测定风干牦牛肉中15种N-亚硝胺

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色谱 2024年第5期42卷 465-473页

作者：夏寒仝凯旋朱浙辉谢瑜杰吴兴强常巧英张红医范春林陈辉中国检验检疫科学研究院北京100176 河北大学化学与材料科学学院河北保定071002 西藏自治区产品质量监督检验所西藏拉萨850000

建立了一步式QuEChERS自动提取和净化技术结合气相色谱-串联质谱同时测定风干牦牛肉中15种N-亚硝胺的分析方法。样品水化后,经乙腈提取,加入4.0 g MgSO_(4)和1.0 g NaCl除水,经十八烷基硅烷(C_(18))和N-丙基乙二胺(PSA)填料净化,采用DB-... 详细信息

建立了一步式QuEChERS自动提取和净化技术结合气相色谱-串联质谱同时测定风干牦牛肉中15种N-亚硝胺的分析方法。样品水化后,经乙腈提取,加入4.0 g MgSO_(4)和1.0 g NaCl除水,经十八烷基硅烷(C_(18))和N-丙基乙二胺(PSA)填料净化,采用DB-HeavyWAX色谱柱(30 m×0.25 mm×0.25μm)分离15种N-亚硝胺,在多重反应监测(MRM)模式下进行测定,外标法定量。结果表明,15种N-亚硝胺分离性能良好,在0.1~200μg/L范围内线性关系良好,相关系数(r^(2))≥0.999 0;检出限(LOD)为0.05~0.20μg/kg,定量限(LOQ)为0.10~0.50μg/kg;在1倍、2倍和10倍LOQ 3个添加水平下的平均回收率分别为79.4%~102.1%、80.6%~109.5%、83.0%~110.6%,相对标准偏差(RSD)为0.8%~16.0%。应用建立的方法检测2种不同加工工艺的市售样品,其中7种N-亚硝胺类化合物(N-亚硝基二甲胺、N-亚硝基二异丁胺、N-亚硝基二正丁胺、N-亚硝基甲基苯胺、N-亚硝基乙基苯胺、N-亚硝基吡咯烷、N-亚硝基二苯胺)均有不同程度检出,平均含量为0.08~20.18μg/kg,且熟制风干牦牛肉中N-亚硝胺的检出率和平均含量均高于传统生制风干牦牛肉。该方法实现了前处理的自动化,相较于其他传统方法,操作简单,实验效率高,人为影响因素小,检测灵敏度高,适用于风干牦牛肉中15种N-亚硝胺的快速测定,为研究肉制品中N-亚硝胺的测定提供了方法支持。

关键词：一步式QuEChERS 气相色谱-串联质谱 N-亚硝胺风干牦牛肉

Zebrafish facilitates drug screening: potential of 3-deoxy-andrographoside from Chuanxinlian(Herba Andrographitis Paniculatae) as an anti-inflammatory agent

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Journal of Traditional Chinese Medicine 2022年第5期42卷 749-757页

作者： HE Xuemei XIAO Junjie fan chunlin LU Zibin CAO Huihui YU Linzhong ZHENG Yuanru LIU Junshan Third Level Research Laboratory of State Administration of Traditional Chinese Medicine School of Traditional Chinese MedicineSouthern Medical UniversityGuangzhou 510515China Guangdong Provincial Key Laboratory of Chinese Medicine Pharmaceutics Guangzhou 510515China Guangdong Province Key Laboratory of Pharmacodynamic Constituents of TCM and New Drugs Research College of PharmacyJinan UniversityGuangzhou 510632China School of Pharmacy Guangdong Pharmaceutical universityGuangzhou 510006China Department of Pharmacy Zhujiang HospitalSouthern Medical UniversityGuangzhou 510515China

OBJECTIVE: To systematically evaluate the in vivo antiinflammatory potential of diterpene lactones from Chuanxinlian(Herba Andrographitis Paniculatae)(AP). METHODS: We firstly adopted zebrafish, a novel and ideal animal model for high-throughput drug screening, to investigate the in vivo anti-inflammatory activities of 17 diterpene lactones isolated from ***: The results showed that most of diterpene lactones displayed significant anti-inflammatory effects in lipopolysaccharide microinjection-, copper sulfate exposure-or tail transection-induced zebrafish inflammation models. Moreover, diterpene lactone 3-deoxy-andrographoside(AP-5) was firstly found to attenuate inflammatory responses, which was closely associated with the myeloid differentiation primary response 88/nuclear factor-kappa B and signal transducer and activator of transcription 3 pathways. CONCLUSION: Our research sheds light on the inestimable roles of zebrafish in high-throughput drug screening, elucidates the potent inhibitory effects of diterpene lactones against inflammation and indicates that AP-5 may serve as a potential alternative agent for the treatment of inflammatory diseases.

关键词： diterpenes lactones inflammation zebrafish myeloid differentiation factor 88 NF-kappa B STAT3 transcription factor

Uncovering the electrooxidation behavior of 5-hydroxymethylfurfural on Ni/Co electrodes

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Journal of Energy Chemistry 2024年第5期92卷 1-7页

作者： Shilin fan Bin Zhu Xiao Yu Yang Gao Weiping Xie Yong Yang Jian Zhang chunlin Chen Ningbo Institute of Materials Technology&Engineering Chinese Academy of SciencesNingbo 315201ZhejiangChina University of Chinese Academy of Sciences Beijing 100049China

Biomass,derived from plant photosynthesis that captures carbon dioxide to form carbohydrates,offers vast renewable *** electrooxidation of biomass,coupled with the hydrogen evolution reaction,enables the simultaneous production of biomass-based plastic monomers and green hydrogen,attracting significant scholarly ***,ambiguity remains regarding the adsorption mechanism at the catalyst surface(Langmuir-Hinshelwood or Eley-Rideal)and the adsorbed substrate *** address this,we prepared a Ni/Co electrode for the electrooxidation of 5-hydroxymethylfurfural(HMF)into 2,5-furandicarboxylic acid(FDCA)through a corrosion reaction and electro-reduction *** conversion reached 100.00%,FDCA yield reached 96.82%,and Faradic efficiency(FE)reached 92.14%.Meaningfully,utilizing in-situ spectroscopy and electrochemical methods,this work provided valuable insights into active sites and catalyst surface adsorption.

关键词： Electrocatalysis Electrochemistry 2,5-Furandicarboxylicacid 5-Hydroxymethylfurfural Biomass

Microbial-driven ectopic uranium extraction with net electrical energy production

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Frontiers of Environmental Science & Engineering 2024年第1期18卷 49-58页

作者： Xin Tang Yin Ye chunlin Wang Bingqian Wang Zemin Qin Cui Li Yanlong Chen Yuheng Wang Zhiling Li Miao Lv Aijie Wang fan Chen School of Ecology and Environment Northwestern Polytechnical UniversityXi’an 710129China School of Materials Science and Engineering Xi’an University of Architecture and TechnologyXi’an 710055China State Key Laboratory of Urban Water Resource and Environment School of EnvironmentHarbin Institute of TechnologyHarbin 150090China Faculty of Geosciences and Environmental Engineering Southwest Jiaotong UniversityChengdu 611756China

The extraction of uranium (U) from U-bearing wastewater is of paramount importance for mitigating negative environmental impacts and recovering U resources. Microbial reduction of soluble hexavalent uranium (U(VI)) to insoluble tetravalent uranium (U(IV)) holds immense potential for this purpose, but its practical application has been impeded by the challenges associated with managing U-bacterial mixtures and the biotoxicity of U. To address these challenges, we present a novel spontaneous microbial electrochemical (SMEC) method that spatially decoupled the microbial oxidation reaction and the U(VI) reduction reaction. Our results demonstrated stable and efficient U extraction with net electrical energy production, which was achieved with both synthetic and real wastewater. U(VI) removal occurred via diffusion-controlled U(VI)-to-U(IV) reduction-precipitation at the cathode, and the UIVO_(2) deposited on the surface of the cathode contributed to the stability and durability of the abiotic U(VI) reduction. Metagenomic sequencing revealed the formation of efficient electroactive communities on the anodic biofilm and enrichment of the key functional genes and metabolic pathways involved in electron transfer, energy metabolism, the TCA cycle, and acetate metabolism, which indicated the ectopic reduction of U(VI) at the cathode. Our study represents a significant advancement in the cost-effective recovery of U from U(VI)-bearing wastewater and may open a new avenue for sustainable uranium extraction.

关键词： U(VI)bioreduction Electricity production Reaction decoupling Uranium-bearing wastewater Biofilm microbiome

Simultaneous Screening of 733 Pesticide Residues in Fruits and Vegetables by a GC/LC-Q-TOFMS Combination Technique

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Engineering 2020年第4期6卷 432-441页

作者： Guofang Pang Qiaoying Chang Ruobin Bai chunlin fan Zijuan Zhang Hongyuan Yan Xingqiang Wu Chinese Academy of Inspection and Quarantine Beijing 100176China College of Chemistry and Environmental Science Hebei UniversityBaoding 071002China Beijing Uni-Star Inspection Technology Co.Ltd. Beijing 100176China

In this paper,we report the construction of two accurate mass databases and the development of a combination detection method that simultaneously screens for 733 pesticide and chemical contaminant multi-residues via high-throughput liquid chromatography(LC)-and gas chromatography(GC)-quadru pole-time-of-flight mass spectrometry(Q-TOFMS).This work demonstrates that electronic mass spectral standards may replace chemical-source standard materials as references through one sample preparation and the combination of GC/LC-Q-TOFMS *** cutting-edge technique has also replaced multiresidue determination using targeted detection with non-targeted *** pesticide residue types,sensitivity,recovery,and reproducibility of this combination technique are evaluated in eight fruit and vegetable *** technique shows three advantages:①In comparison with the discovery capability of a single technique,the combination technique shows an improvement of 51.1%(GC-QTOFMS)and 39.6%(LC-Q-TOFMS),respectively;②the combination technique can satisfy a screening limit lower than 10μg·kg^-1 and meet the requirements of“uniform standards,”although some of the pesticide residues could be optimized to further improve screening sensitivity;③over 488 pesticides with recoveries between 60%-120%and relative standard deviation(RSD)<20%at a spiked level of 10μg·kg^-1 were detected with the combination technique in eight different *** 2012 to 2017,this combination technique was applied in an investigation to screen pesticide residues from 1384 sampling locations for 38138 batched samples covering 18 categories and 134 types of fruits and vegetables obtained from across the mainland of *** statistical analysis,533 pesticides in 115891 determinations were detected,and the regularity of pesticides in the fruits and vegetables sold on the Chinese market was shown.

关键词： Pesticide multi-residues GC-Q-TOFMS LC-Q-TOFMS Accurate mass database Spectra library Fruits and vegetables

A progressive framework for rotary motion deblurring

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Defence Technology（防务技术） 2024年第2期32卷 159-172页

作者： Jinhui Qin Yong Ma Jun Huang fan fan You Du School of Electronic Information Wuhan UniversityWuhan430072China

The rotary motion deblurring is an inevitable procedure when the imaging seeker is mounted in the rotating *** rotary motion deblurring methods suffer from ringing artifacts and noise,especially for large blur *** solve the above problems,we propose a progressive rotary motion deblurring framework consisting of a coarse deblurring stage and a refinement *** the first stage,we design an adaptive blur extents factor(BE factor)to balance noise suppression and details *** a novel deconvolution model is proposed based on BE *** the second stage,a triplescale deformable module CNN(TDM-CNN)is designed to reduce the ringing artifacts,which can exploit the 2D information of an image and adaptively adjust spatial sampling *** establish a standard evaluation benchmark,a real-world rotary motion blur dataset is proposed and released,which includes rotary blurred images and corresponding ground truth images with different blur *** results demonstrate that the proposed method outperforms the state-of-the-art models on synthetic and real-world rotary motion blur *** code and dataset are available at https://***/JinhuiQin/RotaryDeblurring.

关键词： Rotary motion deblurring Progressive framework Blur extents factor TDM-CNN

Optimization of microstructure design for enhanced sensing performance in flexible piezoresistive sensors

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Journal of Advanced Ceramics 2024年第6期13卷 711-728页

作者： Xinghao fan Hailong Hu Bin Liao Yaqi Zhang fan Zhang School of Minerals Processing and Bioengineering Central South UniversityChangsha 410083China Research Institute of Aerospace Technology Central South UniversityChangsha 410083China

Flexible piezoresistive strain sensors have received significant attention due to their diverse applications in monitoring human activities and health,as well as in robotics,prosthetics,and human–computer interaction *** the various flexible sensor types,those with microstructure designs are considered promising for strain sensing due to their simple structure,high sensitivity,extensive operational range,rapid response time,and robust *** review provides a concise overview of recent advancements in flexible piezoresistive sensors based on microstructure design for enhanced strain sensing performance,including the impact of microstructure on sensing mechanisms,classification of microstructure designs,fabrication methods,and practical ***,this review delves into the analysis of piezoresistive sensor sensing mechanisms and performance parameters,exploring the relationship between microstructure design and performance ***,an in-depth discussion is presented,focusing on the primary themes of microstructure design classification,process selection,performance characteristics,and specific *** review employs mathematical modeling and hierarchical analysis to emphasize the directionality of different microstructures on performance enhancement and to highlight the performance advantages and applicable features of various microstructure *** conclusion,this review examines the multifunctionality of flexible piezoresistive sensors based on microstructure design and addresses the challenges that still need to be overcome and improved,such as achieving a wide range of stretchability,high sensitivity,and robust *** review summarizes the research directions for enhancing sensing performance through microstructure design,aiming to assist in the advancement of flexible piezoresistive sensors.

关键词： microstructure design sensing performance flexible piezoresistive strain sensors microsensing mechanism