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Etching-free pixel definition in InGaN green micro-LEDs

Light(Science & Applications) 2024年第8期13卷 1655-1665页

作者： Zhiyuan Liu Yi Lu haicheng cao Glen Isaac Maciel Garcia Tingang Liu Xiao Tang Na Xiao Raul Aguileta Vazquez Mingtao Nong Xiaohang Li Advanced Semiconductor Laboratory Electrical and Computer Engineering ProgramCEMSE DivisionKing Abdullah University of Science and Technology(KAUST)Thuwal 23955-6900Kingdom of Saudi Arabia

The traditional plasma etching process for defining micro-LED pixels could lead to significant sidewall *** near sidewall regions act as non-radiative recombination centers and paths for current leakage,significantly deteriorating device *** this study,we demonstrated a novel selective thermal oxidation(STO)method that allowed pixel definition without undergoing plasma damage and subsequent dielectric *** annealing in ambient air oxidized and reshaped the LED structure,such as p-layers and InGaN/GaN multiple quantum ***,the pixel areas beneath the pre-deposited SiO_(2)layer were selectively and effectively *** was demonstrated that prolonged thermal annealing time enhanced the insulating properties of the oxide,significantly reducing LED leakage ***,applying a thicker SiO_(2)protective layer minimized device resistance and boosted device efficiency *** the STO method,InGaN green micro-LED arrays with 50-,30-,and 10-μm pixel sizes were manufactured and *** results indicated that after 4 h of air annealing and with a 3.5-μm SiO_(2)protective layer,the 10-μm pixel array exhibited leakage currents density 1.2×10^(-6)A/cm^(2)at-10 V voltage and a peak on-wafer external quantum efficiency of~6.48%.This work suggests that the STO method could become an effective approach for future micro-LED manufacturing to mitigate adverse LED efficiency size effects due to the plasma etching and improve device ***-LEDs fabricated through the STO method can be applied to micro-displays,visible light communication,and optical interconnect-based *** planar pixel geometry will provide more possibilities for the monolithic integration of driving circuits with ***,the STO method is not limited to micro-LED fabrication and can be extended to design other III-nitride devices,such as photodetectors,laser diodes,high-electron-mobility transistors

关键词： annealing protective quantum

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Efficient photocatalytic degradation of statin via optimization on ZnIn_(2)S_(4)/Bi_(2)WO_(6) Z-scheme heterostructure

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Journal of Advanced Dielectrics 2024年第4期14卷 104-114页

作者： Tingting Liu Libing cao Mengge Yan Yushan hu Tianlong Ren Zheng Wu School of Environmental and Chemical Engineering Xi’an Key Laboratory of Textile Chemical Engineering Auxiliaries Engineering Research Center of Biological Resources Development and Pollution Control Universities of Shaanxi Province Key Laboratory of Textile Dyeing Wastewater Treatment Universities of Shaanxi Province Xi’an Polytechnic University No.19Jin Hua RoadXi’an710048P.R.China Key Laboratory of Northwest Water Resource Environment and Ecology MOE Xi’an University of Architecture and Technology No.13Yan Ta RoadXi’an710055P.R.China Northwest Branch of Beijing CCI Architectural Design Co. Ltd No.26Gao Xin RoadXi’an 710065P.R.China Xi’an Capital Water Company Limited No.368 Kun Ming RoadXi’an 710086P.R.China

Statins are widely used in the treatment of hyperlipidemia disease,which are refractory in the municipal sewage treatment *** photocatalytic degradation of statins by the Z-scheme heterostructured photocatalyst is confirmed,but the degradation mechanism of statins needs to be further *** this study,the effects of photocatalyst dosage,solution ph and humic acid(hA)on the photocatalysis of fluvastatin by ZnIn_(2)S_(4)/Bi_(2)WO_(6) Z-scheme heterostructured photocatalyst(ZIS/BWO photocatalyst)were investigated and the degradation mechanism was *** showed that adsorption of fluvastatin was improved with the increase of photocatalyst dosage,but photoinduced desorption and light scattering resulted in the decrease of the removal of fluvastatin with high dosage.0.2 g/L of the ZIS/BWO photocatalyst was optimal dosage.65.21%of fluvastatin was removed at ph=9,because high concentration of Oh^(-)was conducive to produce·*** change of ph,competition of photons and active sites,and trapping of reactive oxygen species(ROS)by carboxyl group of hA combined to inhibit the photocatalysis of fluvastatin in the presence of *** C–C,C=C and C–N bonds of fluvastatin were attacked by a variety of ROS to generate degradable intermediates that were easily mineralized to h_(2)O and CO_(2).

关键词： fluvastatin photocatalytic technology Z-scheme heterostructured photocatalyst reaction condition degradation mechanism

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ZIf-8 coated gold nanospheres: A multi-responsive drug delivery system promoting the killing effect of photothermal therapy against osteosarcoma cells

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Nano Research 2024年第3期17卷 1772-1784页

作者： Miao Lei Weiye Cai Luetao Zou Bin Yu Lin Chen Yang cao Shanlin Xiang Chao Song Jiandu Lei Wei Jiang Zhenming hu Department of Orthopedics Orthopedic Laboratory of Chongqing Medical UniversityThe First Affiliated Hospital of Chongqing Medical UniversityNo.1 Youyi RoadChongqing 400010China The Affiliated Traditional Chinese Medicine hospital of Southwest Medical University Luzhou 646699China Department of Orthopedics The Third Affiliated Hospital of Chongqing Medical UniversityChongqing 400010China Department of Radiology The First Affiliated Hospital of Chongqing Medical UniversityNo.1 Youyi RoadChongqing 400010China Department of Orthopedics Chongqing University Three Gorges HospitalChongqing 404000China Department of Geriatrics The Affiliated Hospital of Guizhou Medical UniversityGuiyang 550025China Beijing Key Laboratory of Lignocellulosic Chemistry College of Material Science and TechnologyBeijing Forestry UniversityBeijing 100083China

Photothermal therapy(PTT)has been widely used in the treatment of tumors,but its efficacy is greatly limited by the inability of precise drug delivery and the increase of heat shock proteins(hSPs)caused by high *** article describes a therapeutic strategy to enhance PTT with starvation therapy in conjunction with ferroptosis mechanism.A nanoparticle platform ZIf-8@GA was constructed by wrapping together glucose oxidase(GOX)and gold nanospheres(AuNPs)loaded with dihydroartemisinin(DhA)with zeolitic imidazolate framework-8(ZIf-8).This platform can take advantage of the micro-environment of osteosarcoma(OS)cells,featuring low ph and high reactive oxygen species(ROS),for precision drug *** can effectively catalyze glucose to produce gluconic acid and h_(2)O_(2),and DhA can also induce ROS production in OS *** produced by GOX and DhA can further generate lipid peroxidation(LPO)and lead to ferroptosis of OS *** the same time,ROS and LPO produced can inhibit the expression of hSPs,thereby increasing the therapeutic effect of *** vitro experiments show that the nanoparticles are ph and ROS responsive.1μg/mL GOX combined with 0.2μg/mL DhA promotes ferroptosis of OS cells,and increases the killing effect of near-infrared(NIR)on OS *** in vivo experiments showed that the nano drug-delivery platform combined with PTT can effectively inhibit the growth of OS ***,this study provides a new idea for the treatment of OS with biomaterials combined with various treatment methods.

关键词： zeolitic imidazolate framework-8(ZIf-8) gold nanospheres(AuNPs) photothermal therapy(PTT) starvation therapy ferroptosis

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Residual alkali-evoked cross-linked polymer layer for anti-air-sensitivity LiNi_(0.89)Co_(0.06)Mn_(0.05)O_(2)cathode

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Journal of Energy Chemistry 2024年第5期92卷 450-458页

作者： Chao Zhao Xuebao Li Yun Zhao Jingjing he Yuanpeng cao Wei Luo Ding Wang Jianguo Duan Xianshu Wang Baohua Li National and Local Joint Engineering Research Center of Lithium-ion Batteries and Materials Preparation Technology Key Laboratory of Advanced Battery Materials of Yunnan ProvinceFaculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunming 650093YunnanChina School of Materials Science and Engineering Central South UniversityChangsha 410083HunanChina Institute of Materials Research Tsinghua Shenzhen International Graduate SchoolTsinghua UniversityShenzhen 518055Guangdong China City College Kunming University of Science and TechnologyKunming 650051YunnanChina

high-energy density lithium-ion batteries(LIBs)with layered high-nickel oxide cathodes(LiNi_(x)Co_(y)Mn_(1-x-y)O_(2),x≥0.8)show great promise in consumer electronics and vehicular ***,LiNi_(x)Co_(y)Mn_(1-x-y)O_(2)faces challenges related to capacity decay caused by residual alkalis owing to high sensitivity to *** address this issue,we propose a hazardous substances upcycling method that fundamentally mitigates alkali content and concurrently induces the emergence of an anti-air-sensitive layer on the cathode *** the neutralization of polyacrylic acid(PAA)with residual alkalis and then coupling it with 3-aminopropyl triethoxysilane(Kh550),a stable and ion-conductive cross-linked polymer layer is in situ integrated into the LiNi_(0.89)Co_(0.06)Mn_(0.05)O_(2)(NCM)*** characterization and measurements demonstrate its *** NCM material exhibits impressive cycling performance,retaining 88.4%of its capacity after 200 cycles at 5 C and achieving an extraordinary specific capacity of 170.0 mA h g^(-1) at 10 ***,this layer on the NCM efficiently suppresses unfavorable phase transitions,severe electrolyte degradation,and CO_(2)gas evolution,while maintaining commendable resistance to air *** surface modification strategy shows widespread potential for creating air-stable LiNi_(x)Co_(y)Mn_(1-x-y)O_(2)cathodes,thereby advancing high-performance LIBs.

关键词： Lithium-ion batteries Nickel-rich layered cathode Residual alkalis Cross-linked polyme rmodification Airsensitivity

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Microbially-mediated formation of Ca-fe carbonates during dissimilatory ferrihydrite reduction:Implications for the origin of sedimentary ankerite

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Science China Earth Sciences 2024年第1期67卷 208-221页

作者： Deng LIU Jinpeng cao Shanshan YANG Yating YIN Pengcong WANG Dominic PAPINEAU hongmei WANG Xuan QIU Genming LUO Zongmin ZhU fengping WANG State Key Laboratory of Biogeology and Environmental Geology China University of GeosciencesWuhan 430074China School of Environmental Studies China University of GeosciencesWuhan 430074China London Centre for Nanotechnology University College LondonLondon WC1H 0AHUK Department of Earth Sciences University College LondonLondon WC1E 6BTUK Center for Planetary Sciences University College London and Birkbeck College LondonLondon WC1E 6BTUK State Key Laboratory of Microbial Metabolism State Key Laboratory of Ocean EngineeringShanghai Jiao Tong UniversityShanghai 200240China

The origin of sedimentary dolomite has become a long-standing problem in the Earth *** carbonate minerals like ankerite have the same crystal structure as dolomite,hence their genesis may provide clues to help solving the dolomite *** purpose of this study was to probe whether microbial activity can be involved in the formation of ***-carbonation experiments associated with microbial iron reduction were performed in batch systems with various concentrations of Ca^(2+)(0–20 mmol/L),with a marine iron-reducing bacterium Shewanella piezotolerans WP3 as the reaction mediator,and with lactate and ferrihydrite as the respective electron donor and *** biomineralization data showed that Ca-amendments expedited microbially-mediated ferrihydrite reduction by enhancing the adhesion between WP3 cells and ferrihydrite *** bioreduction,siderite occurred as the principal secondary mineral in the Ca-free ***,Ca-fe carbonates were formed when Ca^(2+)ions were *** CaCO_(3) content of microbially-induced Ca-fe carbonates was positively correlated with the initial Ca2+*** Ca-fe carbonate phase produced in the 20 mmol/L Ca-amended biosystems had a chemical formula of Ca_(0.8)fe_(1.2)(CO_(3))_(2),which is close to the theoretical composition of *** ankeritelike phase was nanometric in size and spherical,Ca-fe disordered,and structurally *** simulated diagenesis experiments further demonstrated that the resulting ankerite-like phase could be converted into ordered ankerite under hydrothermal *** introduced the term“proto-ankerite”to define the Ca-fe phases that possess near-ankerite stoichiometry but disordered cation *** the basis of the present study,we proposed herein that microbial activity is an important contributor to the genesis of sedimentary ankerite by providing the metastable Ca-fe carbonate precursors.

关键词： Ankerite Proto-ankerite Microbial iron reduction Dolomite problem Mineral transformation

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Mechanical robust and self-healing flexible perovskite solar cells with efficiency exceeding 23%

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Science China Chemistry 2024年第8期67卷 2670-2678页

作者： Yaohua Wang Ruikun cao Yuanyuan Meng Bin han Ruijia Tian Xiaoyi Lu Zhenhua Song Shuncheng Yang Congda Lu Chang Liu Ziyi Ge College of Mechanical Engineering Zhejiang University of TechnologyHangzhou 310014China Zhejiang Provincial Engineering Research Center of Energy Optoelectronic Materials and Devices Ningbo Institute of Materials TechnologyEngineeringChinese Academy of SciencesNingbo 315201China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences Beijing 100049China

flexible perovskite solar cells(f-PSCs) have experienced rapid advancements due to the light-weight, flexibility, and solution processability of the perovskite materials, which prompted the power conversion efficiency(PCE) to 24.08%. however, f-PSCs still face challenges in terms of mechanical and environmental stability. This is primarily due to their inherent brittleness, the presence of residual tensile strain, and the high density of defects along the boundaries of perovskite grains. To this end, we carefully developed a cross-linkable elastomers 3-[(3-acrylamidopropyl)dimethylammonium] propanoate(ADP) with electrostatic dynamic bond, which could be in-situ cross-linked and coordinate with [Pb I6]4-to regulate the crystallization process of perovskite. The cross-linked elastomers attached to the perovskite grain boundaries could release the remaining tensile strains and mechanical stresses, leading to enhanced stability and flexibility of the f-PSCs. More importantly, the electrostatic interaction between positive and negative groups of cross-linked elastomers and hydrogen bond formation between N–h and C=O accelerate the cross-linking of ADP, endowing the flexible perovskite films with self-healing ability under mild treating conditions(60 °C for 30 min). As a result, the device achieves a remarkable PCE of 23.53%(certified 23.16%). Additionally, the device exhibits impressive mechanical sustainability and durability, retaining over 90% of initial PCE even after undergoing8,000 bending cycles.

关键词： Mechanical robust and self-healing flexible perovskite solar cells with efficiency exceeding 23

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Enhancing solar-driven overall water splitting via both sacrifice and noble metal free photocatalysis: copper cluster/boron-doped carbon nitride catalysts

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Science China Chemistry 2024年第11期67卷 3886-3896页

作者： Yun-Dong cao Yuxi Zhang Jian Song hong Liu Zhiyuan Song Lin-Lin fan Cai-Li Lv Guang-Gang Gao School of Materials Science and Engineering University of Jinan

The major impediment to the additional industrialization of water splitting is the high cost of the co-catalyst made of noble metals and the sacrificial reagent. A binary photocatalytic system, consisting of B-doped g-C3N4nanosheets(Cu20@BCN-X) and atomically accurate copper clusters, is designed in this study. The copper clusters serve as co-catalysts for h2evolution and exhibit Pt-like activity, whereas the nanosheets serve as carriers and semiconductor components for O2evolution. Such binary system, created using simple techniques, demonstrates hydrogen bonding interactions that promote synergistic effects and efficient binding and charge transfer across the interface between the two components. Band position manipulation of carbon nitride nanosheets demonstrates a Z-scheme charge transfer mechanism between the nanosheets and copper clusters. This photocatalytic system can accomplish the photocatalytic overall water splitting process(259.9 μmol g-1h-1of h2and 129.4 μmol g-1h-1of O2) without using sacrificial agents or noble metal co-catalysts. This work lays the foundation for the design of overall water splitting catalysts by precisely manipulating the energy levels, and it also paves the way for commercialized photocatalytic catalysts that do not require noble metals or sacrificial chemicals.

关键词： copper clusters band modulation photocatalysts water splitting

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Efficient and bright broadband electroluminescence based on environmentfriendly metal halide nanoclusters

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Light(Science & Applications) 2024年第4期13卷 727-737页

作者： Dingshuo Zhang Meiyi Zhu Yifan he Qingli cao Yun Gao hongjin Li Guochao Lu Qiaopeng Cui Yongmiao Shen haiping he Xingliang Dai Zhizhen Ye School of Materials Science and Engineering State Key Laboratory of Silicon and Advanced Semiconductor MaterialsZhejiang University310027 HangzhouChina Wenzhou Key Laboratory of Novel Optoelectronic and Nano Materials and Engineering Research Centre of Zhejiang Province Institute of WenzhouZhejiang University325006 WenzhouChina Wenzhou XINXINTAIJING Tech.Co.Ltd. 325006 WenzhouChina Department of Chemistry Zhejiang Sci-Tech University310018 HangzhouChina

Broadband electroluminescence based on environment-friendly emitters is promising for healthy lighting yet remains an unprecedented challenge to *** copper halide-based emitters are competitive candidates for broadband emission,but their high-performance electroluminescence shows inadequate broad emission bandwidth of less than 90 ***,we demonstrate efficient ultra-broadband electroluminescence from a copper halide(CuI)nanocluster single emitter prepared by a one-step solution synthesis-deposition process,through dedicated design of ligands and subtle selection of *** CuI nanocluster exhibits high rigidity in the excitation state as well as dual-emissive modes of phosphorescence and temperature-activated delayed fluorescence,enabling the uniform cluster-composed film to show excellent stability and high photoluminescent *** consequence,ultra-broadband light-emitting diodes(LEDs)present nearly identical performance in an inert or air atmosphere without encapsulation and outstanding high-temperature operation performance,reaching an emission full width at half maximum(fWhM)of~120 nm,a peak external quantum efficiency of 13%,a record maximum luminance of~50,000 cd m^(−2),and an operating half-lifetime of 137 h at 100 cd m^(−2).The results highlight the potential of copper halide nanoclusters for next-generation healthy lighting.

关键词： halide cluster rigidity

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Identification of P-type plasma membrane h^(+)-ATPases in common wheat and characterization of TahA7 associated with seed dormancy and germination

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Journal of Integrative Agriculture 2024年第7期23卷 2164-2177页

作者： Bingli Jiang Wei Gao Yating Jiang Shengnan Yan Jiajia cao Litian Zhang Yue Zhang Jie Lu Chuanxi Ma Cheng Chang haiping Zhang Key Laboratory of Wheat Biology and Genetic Improvement on Southern Yellow&huai River Valley Ministry of Agriculture and Rural Affairs/College of AgronomyAnhui Agricultural UniversityHefei 230036China

The P-type plasma membrane(PM)h^(+)-ATPases(hAs)are crucial for plant development,growth,and *** hAs have been thoroughly characterized in many different ***,despite their importance,the functions of hAs in germination and seed dormancy(SD)have not been validated in ***,we identified 28 TahA genes(TahA1-28)in common wheat,which were divided into five *** examination of gene expression in strong-and weak-SD wheat varieties led to the discovery of six candidate genes(TahA7/-12/-14/-16/-18/-20).Based on a single nucleotide polymorphism(SNP)mutation(C/T)in the TahA7 coding region,a CAPS marker(hA7)was developed and validated in 168 wheat varieties and 171 Chinese mini-core collections that exhibit diverse germination and SD *** further verified the roles of the two allelic variations of TahA7 in germination and SD using wheat mutants mutagenized with ethyl methane sulphonate(EMS)in‘Jimai 22’and‘Jing 411’backgrounds,and in transgenic Arabidopsis ***7 appears to regulate germination and SD by mediating gibberellic acid(GA)and abscisic acid(ABA)signaling,metabolism,and *** results presented here will enable future research regarding the TahAs in wheat.

关键词： wheat P-type plasma membrane h^(+)-ATPase seed dormancy abscisic acid gibberellin

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Asymmetric orbital hybridization in Zn-doped antiperovskite Cu_(1-x)Zn_(x)NMn_(3)enables highly efficient electrocatalytic hydrogen production

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Journal of Energy Chemistry 2024年第2期89卷 304-312,I0008页

作者： Yuxiang Yan Yuxin cao Zhichao Wang Ka Wang hengdong Ren Shaoqi Zhang Yi Wang Jian Chen Yong Zhou Lizhe Liu Jun Dai Xinglong Wu National Laboratory of Solid States Microstructures and School of Physics Nanjing UniversityNanjing 210093JiangsuChina College of Engineering and Applied Sciences Nanjing UniversityNanjing 210093JiangsuChina National Laboratory of Solid States Microstructures and Research Institute of Superconductor Electronics Nanjing UniversityNanjing 210093JiangsuChina School of Mathematics&Physics Jiangsu University Science&TechnologyZhenjiang 212003JiangsuChina

Rational design of efficient and robust earth-abundant alkaline hydrogen evolution reaction(hER)catalysts is a key factor for developing energy conversion ***,antiperovskite nitride CuNMn_(3)has garnered significant interest due to its remarkable properties such as negative/zero thermal expansion and magnetocaloric ***,when utilized as hydrogen evolution catalysts,it encounters large challenge resulting from excessively strong/weak interactions with adsorbed h on Mn/Cu active sites,which leads to low hER *** this study,we introduce an asymmetric orbital hybridization strategy in Zn-doped Cu_(1-x)Zn_(x)NMn_(3)by leveraging the localization of Zn electronic states to reconfigure the electronic structures of Cu and Mn,thereby reducing the energy barrier for water dissociation and optimizing Cu and Mn active sites for hydrogen adsorption and h_(2)*** evaluations reveal that Cu_(0.85)Zn_(0.15)NMn_(3)with x=0.15 demonstrates exceptional electrocatalytic activity in alkaline electrolytes.A low overpotential of 52 mV at 10 mA cm^(-2)and outstanding stability over a 150-h test period are achieved,surpassing commercial Pt/*** research offers a novel strategy for enhancing hER performance by modulating asymmetric hybridization of electron orbitals between multiple metal atoms within a material structure.

关键词： Cu_(1-x)ZnxNMn_(3) Asymmetric orbital hybridization hydrogen adsorption hydrogen production

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