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Journal of Ocean University of China 2024年第2期23卷 550-556页

作者： SUN Taohua LIU Jie yan Taishan ChEN Anjin ZhANG fang Department of Clinical Drug Trials Qingdao Municipal HospitalQingdao 266100China Department of Pharmacy Qingdao Municipal HospitalQingdao 266100China

This study was carried out explore the mechanism underlying the inhibition of platelet activation by kelp fucoidans in deep venous thrombosis(DVT)*** the control and sham mice,the walls of deep vein were regular and smooth with intact intima,myometrium and *** blood vessel was wrapped with the tissue and there was no thrombosis in the *** the DVT model,the wall was uneven with thicken intima,myometrium and *** treated with fucoidans Lf1 and Lf2,the thrombus was dissolved and the blood vessel was *** with the control group,the ROS content,ET-1 and VWf content and the expression of PKC-βand Nf-κB in the model were significantly higher(Phese levels were significantly reduced following treatments with Lf2 and *** with h_(2)O_(2)treated-hUVECs,combined Lf1 and Lf2 treatment resulted in significant decrease in the expression of PKC-β,Nf-κB,VWf and TM protein(Phat Lf1 and Lf2 reduces DVT-induced ET-1,VWf and TM expressions and production of ROS,thus inhibiting the activation of PKC-β/Nf-κB signal pathway and the activation of coagulation system and ultimately reducing the formation of venous thrombus.

关键词： kelp fucoidans Lf1 Lf2 deep vein thrombosis platelet

Ultrathin two-dimensional medium-entropy oxide as a highly efficient and stable electrocatalyst for oxygen evolution reaction

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Nano Research 2024年第4期17卷 2555-2562页

作者： Guangyuan yan Tianlu Wang Biwei Zhao Wenjing Gao Tong Wu Liming Ou School of Mechanical Electronic and Control EngineeringBeijing Jiaotong UniversityBeijing 100044China

Medium-entropy oxides(MEOs)with broad compositional tunability and entropy-driven structural stability,are receiving booming attention as a promising candidate for oxygen evolution reaction(OER)***,ultrathin two-dimensional(2D)nanostructure offers extremely large specific surface area and is therefore considered to be an ideal catalyst ***,it remains a grant challenge to synthesize ultrathin 2D MEOs due to distinct nucleation and growth kinetics of constituent multimetallic elements in 2D anisotropic *** this work,an ultrathin 2D MEO(MnfeCoNi)O was successfully synthesized by a facile and low-temperature ionic layer epitaxy *** from multi-metal synergistic effects within ultrathin 2D nanostructure,this 2D MEO(MnfeCoNi)O revealed excellent OER electrocatalytic performance with a quite low overpotential of 117 mV at 10 mA·cm^(-2) and an impressive stability for 120 h continuous operation with only 6.9%***,the extremely high mass activity(5584.3 A·g^(-1))was three orders of magnitude higher than benchmark RuO_(2)(3.4 A·g^(-1))at the same overpotential of 117 *** work opens up a new avenue for developing highly efficient and stable electrocatalysts by creating 2D nanostructured MEOs.

关键词： medium-entropy oxide two-dimensional nanomaterials ionic layer epitaxy oxygen evolution reaction electrocatalysis

Simultaneous removal of 1,2-dichlorobenzene and furan over Mn-Ce-fe oxide catalyst:Catalytic activity and product analysis

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Journal of Rare Earths 2024年第5期42卷 972-979,I0006页

作者： Juan Qiu Minghui Tang Yaqi Peng Xuanhao Guo Shengyong Lu Jianhua yan Taizhou Institute of Zhejiang University Taizhou 318000China State Key Laboratory for Clean Energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou 310027China

The Mn-Ce-fe mixed oxide(MCfe)was prepared by co-precipitation and the catalytic performance was tested by using 1,2-dichlorobenzene(1,2-DCB)and furan as model molecules of PCDD/*** effect of O_(2)concentration,SO_(2) and NO on the catalytic activity was *** 270℃,the MCfe oxide catalyst presents significant simultaneous removal efficiency of 75.25%and 100%for 1,2-DCB and furan,***-Emmett-Teller(BET)method(BET),X-ray diffraction(XRD),scanning electron microscopy(SEM),X-ray photoelectron spectroscopy(XPS),fourier transform infrared spectroscopy(fTIR),h_2-temperature programmed reduction(h_(2)-TPR),Nh_(3)-temperature programmed desorption(Nh_3-TPD)and O_(2)-TPD were used to characterize the catalysts before and after the *** tests suggest that the oxidation behavior of furan occurred prior to that of 1,*** to the intermediate products detected by gas chromatography-mass spectrometry(GC-MS),the by-products include chlorinated hydrocarbons,long-chain hydrocarbons,ketone,*** catalytic oxidation reaction paths are proposed.

关键词： 1 2-dichlorobenzene furan Catalytic oxidation Product analysis Rare earths

Mechanism study of Cu(Ⅱ) adsorption from acidic wastewater by ultrasonic-modified municipal solid waste incineration fly ash

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Chinese Journal of Chemical Engineering 2024年第3期67卷 157-165页

作者： Shunda lin yang Lu Lin Zheng Ling Long Xuguang Jiang Jianhua yan State Key Laboratory of Clean Energy Utilization Institute for Thermal Power EngineeringZhejiang UniversityHangzhou 310027China Zhejiang University Qingshanhu Energy Research Center Hangzhou 310027China hangzhou Xiaoshan Jinjiang Green Energy Co. Ltd.XiaoshanHangzhou 310000China

high concentrations of copper ions(Cu(Ⅱ)) in water will pose health risks to humans and the ecological environment. Therefore, this study aims to utilize ultrasonic-cured modified municipal solid waste incineration(MSWI) fly ash for Cu(Ⅱ) adsorption to achieve the purpose of “treating waste by waste.” The effects of p h, adsorption time, initial concentration, and temperature on the modified MSWI fly ash’s adsorption efficiency were systematically studied in this article. The adsorption performance of the modified MSWI fly ash can be enhanced by the ultrasonic modification. At ph = 2, 3 and 4, the adsorption capacity of the modified MSWI fly ash for Cu(Ⅱ) increased by 2.7, 1.9 and 1.2 times, respectively. furthermore, it was suggested that the adsorption process of the modified MSWI fly ash can be better simulated by the pseudo-second-order kinetic model, with a maximum adsorption capacity calculated by the Langmuir model of 24.196 mg.g-1. Additionally, the adsorption process is spontaneous,endothermic, and chemisorption-dominated from the thermodynamic studies(Δh and ΔS > 0, ΔG finally, the enhanced adsorption performance of the modified MSWI fly ash for Cu(Ⅱ) may be attributed to electrostatic interaction and chelation effects.

关键词： Ultrasound MSWI fly ash Cu(Ⅱ) Wastewater Adsorption

Effects of gravel on the water absorption characteristics and hydraulic parameters of stony soil

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Journal of Arid Land 2024年第7期16卷 895-909页

作者： MA yan WANG Youqi MA Chengfeng YUAN Cheng BAI Yiru Breeding Base for State Key Laboratory of Land Degradation and Ecological Restoration in Northwest China Ningxia UniversityYinchuan 750021China School of Geography and Planning Ningxia UniversityYinchuan 750021China School of Ecology and Environment Ningxia UniversityYinchuan 750021China

The eastern foothills of the helan Mountains in China are a typical mountainous region of soil and gravel,where gravel could affect the water movement process in the *** study focused on the effects of different gravel contents on the water absorption characteristics and hydraulic parameters of stony *** stony soil samples were collected from the eastern foothills of the helan Mountains in April 2023 and used as the experimental materials to conduct a one-dimensional horizontal soil column absorption *** experimental groups with gravel contents of 0%,10%,20%,30%,40%,and 50%were established to determine the saturated hydraulic conductivity(K_(s)),saturated water content(θ_(s)),initial water content(θ_(i)),and retention water content(θ_(r)),and explore the changes in the wetting front depth and cumulative absorption volume during the absorption *** Philip model was used to fit the soil absorption process and determine the soil water absorption *** the length of the characteristic wetting front depth,shape coefficient,empirical parameter,inverse intake suction and soil water suction were derived from the van Genuchten ***,the hydraulic parameters mentioned above were used to fit the soil water characteristic curves,unsaturated hydraulic conductivity(K_(θ))and specific water capacity(C(h)).The results showed that the wetting front depth and cumulative absorption volume of each treatment gradually decreased with increasing gravel *** with control check treatment with gravel content of 0%,soil water absorption rates in the treatments with gravel contents of 10%,20%,30%,40%,and 50%decreased by 11.47%,17.97%,25.24%,29.83%,and 42.45%,*** the gravel content increased,inverse intake suction gradually increased,and shape coefficient,K_(s),θ_(s),andθ_(r)gradually *** the same soil water content,soil water suction and K_(θ)gradually decreased with increasing gravel *** the same soil water s

关键词： stony soil gravel content water absorption characteristics hydraulic parameters one-dimensional horizontal soil column absorption experiment van Genuchten model eastern foothills of helan Mountains

CO2-Induced Modulation of Si-O Bonds for Low Temperature Plastic Deformation of Amorphous Silica Nanoparticles with Enhanced Photoluminescence

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Energy & Environmental Materials 2024年第4期7卷 404-412页

作者： Kang huang Wenzhuo Wu Song Xu Pengfei yan Zhongming Wei Qun Xu henan Institute of Advanced Technology Zhengzhou University College of Materials Science and Engineering Zhengzhou University State Key Laboratory of Superlattices and Microstructures Institute of Semiconductors Chinese Academy of Sciences

Modulation of Si-O bonds under mild conditions has been a challenging issue in the field of material science,which is critical to manufacture highperformance silica-based optical and photonic ***,we introduce a nondestructive technique to achieve Si-O bond rearrangement,leading to plastic deformation and photoluminescence enhancement of amorphous silica nanoparticles using supercritical carbon dioxides in EtOh/h2O solution under mild temperature.

关键词： amorphous silica anisotropic stress photoluminescence plastic deformation supercritical CO2

Influence and optimization of swirler parameters on elbow wear of deep coal fluidization pipeline transportation system

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friction 2024年第7期12卷 1408-1433页

作者： Shaodi ZhAO Jiusheng BAO Shirong GE Zhongbin WANG yan YIN Congguang hUANG School of Mechanical and Electrical Engineering China University of Mining and TechnologyXuzhou 221116China School of Mechanical Electronic and Information Engineering China University of Mining and Technology-BeijingBeijing 100083China frontier Scientific Research Center for fluided Mining of Deep Underground Resources China University of Mining and TechnologyXuzhou 221008China

Elbow wear is a major threat to the multiphase pipeline transportation industry,which has a negative impact on the stable operation of the transportation *** order to find the wear reduction methods of elbows in the fluidization pipeline transportation system for 2000-meter-deep coal resources,the swirler was installed upstream of the elbows,and wear simulations and tests of three kinds of elbows were carried *** results showed that the maximum wear rate(MWR)of elbows increased and then decreased along the elbow *** to the different directions of gravity,the heavy wear position(hWP)of the horizontal-vertical(h-V)elbow was in front of the vertical-horizontal(V-h)*** the downstream portion of the horizontal-horizontal(h-h)elbow was still a horizontal pipe,the hWP of the h-h elbow almost covered the whole *** swirler placed upstream of the elbows could make the particles at the elbow move to the intrados of the elbows,resulting in less collision between the particles and the extrados of the elbows,thus reducing the wear of the *** wear reduction effects of swirlers on three different elbows were favorably connected with the guide vane angle(GVA)and negatively correlated with the guide vane length(GVL),decreased first and then increased as the guide vane height(GVh)increased,and were little affected by the guide vane number(GVN)and the guide vane thickness(GVT).The mathematical models between the MWR of the elbows and guide vane parameters were *** bench tests,the wear reduction effect of three kinds of elbows under the optimal guide vane parameters was 58.4%,76.9%,and 78.6%,*** errors between the bench test results and the simulation results were around 10%.

关键词： pipe elbow erosion wear spiral flow swirler guide vane parameters particle collision

Boosted sustained-release with iron-based MOf-derived mesoporouscarbon-spheres as a nitroimidazole drugs carrier

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Particuology 2024年第3期86卷 269-280页

作者： Danping Wu Jiaying Zou Junyi Chen yan Li Na Ma Wei Dai College of Chemistry and Materials Science Zhejiang Normal UniversityJinhua321004China College of Life Sciences Zhejiang Normal UniversityJinhua321004China College of Geography and Environmental Sciences Zhejiang Normal UniversityJinhua321004China

Metal-organic framework(Mof)with a buildable internal structure has aroused great interest focus as self-sacrificing precursors of porous carbon(PC).however,as a drug carrier,the MOf-derived PC developed thus far are generally composed of irregular powder shape due to their crystalline nature,which consequently causing the cerebral infarction,cerebral thrombosis,and other blood *** this article,we propose a novel approach to constructing amorphous carbon microspheres(AcMs)by dis-torting the topological network through hydrothermal treatment precursors of MIL-101(fe).Then,a distinctive MIL-101(fe)-derived spherical porous carbons(MSPC)is achieved through high temperature calcination toward *** of the glucose initial concentration and hydrothermal treatment time on the sphericity of the as-prepared mesoporous MsPC were investigated in *** the loading capacities and sustained-release performances of nitroimidazole drugs over MsPC through simulation internal environment of human body at different ph values was systematically *** nitro-imidazole drugs loading rate and release time of MsPC are 10% and 17 h under preferred ***,the MSPC exhibited very low toxicity on hela cells and 293T cells at the concentrations tested(10-800μg mL^(-1)).This study,therefore,supports the potential of the mesoporous carbon spheres as a carrierfor nitroimidazole drug delivery.

关键词： Ornidazole Metronidazole Carbon spheres Sustained-release performance Biocompatibility

MnO_(2)-coated nanodiamond-driven photodynamic therapy for enhanced antitumor effect by addressing hypoxia and glutathione depletion

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Particuology 2024年第9期92卷 305-315页

作者： Jicheng Cui Dongmei Zhang hui Qiao Zeyu yan Wenxia Zhang Yingqi Li Key Laboratory of Chemical Biology and Molecular Engineering of Ministry of Education Institute of Molecular ScienceShanxi UniversityTaiyuan030006China Taiyuan Central hospital Taiyuan030009China School of Chemistry and Chemical Engineering Shanxi UniversityTaiyuan030006China

The generation of reactive oxygen species(ROS)at the tumor site to induce destruction is emerging as a novel strategy for cancer treatment,which involves photodynamic therapy(PDT).Nevertheless,tumors typically create a hypoxic environment and are equipped with an endogenous antioxidant defense system that could potentially impede the efficiency of the therapeutic *** overcome these drawbacks,herein,a tumor microenvironment-responsive the ND-PAA-CD-Ce6@MnO_(2)(NPCC@M)delivery system was fabricated by disulfide bond coupling chlorin e6(Ce6)to nanodiamond(ND)and further wrapped by MnO_(2)nanosheets to facilitate *** use of disulfide bond not only stabilizes Ce6 in the blood circulation to prevent premature leakage,but also destroys the antioxidant barrier of overexpressed glutathione(GSh)in tumor ***,the outer MnO_(2)was rapidly degraded by the endogenous hydrogen peroxide(h_(2)O_(2))in the acidic ph and GSh within the tumor cells,which leads to an abundance of O_(2)and while increases the level of 1O_(2)under laser *** results eventually broke the redox homeostasis and attenuate hypoxia,thereby inducing apoptosis and necrosis of tumor *** in vitro and in vivo biological effect has revealed a good biosafety profile and a high tumor suppression *** a novel ND-based system with tumor microenvironment-modulating capability to elevate oxygen content and promote GSh consumption in tumor cells opens new opportunities for enhanced ROS treatment paradigms.

关键词： Nanodiamond Photodynamic Chlorin e6 MnO_(2) Tumor suppression

Effect of coral sand on the mechanical properties and hydration mechanism of magnesium potassium phosphate cement mortar

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2024年第2期25卷 116-129页

作者： hao LIU huamei yanG houzhen WEI Jining YU Qingshan MENG Rongtao yan College of Civil Engineering and Architecture Guilin University of TechnologyGuilin541004China Guangxi Key Laboratory of Geomechanics and Geotechnical Engineering Guilin University of TechnologyGuilin541004China State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil MechanicsChinese Academy of SciencesWuhan430071China School of Intelligent Construction Wuchang University of TechnologyWuhan430002China hydraulic Concrete Institute China Three Gorges CorporationBeijing100038China The first Railway Survey and Design Institute Group Corporation Xi’an710043China

Damaged structures on coral islands have been spalling and cracking due to the dual corrosion of tides and *** ensure easy access to aggregate materials,magnesium potassium phosphate cement(MKPC)and coral sand(CS)are mixed to repair damaged structures on coral ***,CS is significantly different from land-sourced sand in mineral composition,particle morphology,and *** has a substantial impact on the hydration characteristics and macroscopic properties of MKPC ***,in this study we investigated the compressive strength,interfacial mechanical properties,and corrosion resistance of MKPC CS *** in the morphology,microstructure,and relative contents of hydration products were revealed by scanning electron microscope-energy dispersive spectrometer(SEM-EDS)and X-ray diffraction(XRD).The results indicated that the compressive strength increased linearly with the interfacial micro-hardness,and then stabilized after long-term immersion in pure water and Na2SO4 solution,showing excellent corrosion *** with MKPC river sand(RS)mortar,the hydration products of CS mortar were an intermediate product 6KPO2·8h2O with a relative content of 3.9%at 1 h and 4.1%at 12 *** hydration product MgKPO_(4)·6h_(2)O increased rapidly after 7-d curing,with an increased growth rate of 1100%.Our results showed that CS promoted the nucleation and formation of hydration products of MKPC,resulting in better crystallinity,tighter overlapping,and a denser interfacial transition *** results of this study provide technical support for applying MKPC mortar as a rapid repair material for damaged structures on coral islands.

关键词： Magnesium potassium phosphate cement(MKPC) Coral sand(CS) Mechanical properties Corrosion resistance hydration mechanism