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Application of novel constrained friction processing method to produce fine grained biomedical Mg-Zn-Ca alloy

Journal of Magnesium and Alloys 2024年第2期12卷 516-529页

作者： Ting Chen Banglong fu Junjun Shen Uceu f.h.R.Suhuddin Björn Wiese Yuanding huang Min Wang Jorge f.dos Santos Jean Pierre Bergmann Benjamin Klusemann Solid State Materials Processing Institute of Material MechanicsHelmholtz-Zentrum HereonMax-Planck-Str.1Geesthacht 21502Germany functional Magnesium Materials Institute of Metallic BiomaterialsHelmholtz-Zentrum HereonMax-Planck-Str.1Geesthacht 21502Germany Shanghai Key Laboratory of Materials Laser Processing and Modification Shanghai Jiao Tong UniversityDongchuan Road 800Shanghai 200240China Applied Materials and Manufacturing Energy and Environment DivisionPacific Northwest National LaboratoryPO Box 999RichlandWA 99352USA Production Technology Group Technisiche Universität IlmenauGustav-Kirchhoff-Platz 2Ilmenau 98693Germany Institute for Production Technology and Systems Leuphana University of LüneburgUniversitätsallee 1Lüneburg 21335Germany

In order to obtain Mg alloys with fine microstructures and high mechanical performances,a novel friction-based processing method,name as“constrained friction processing(CfP)”,was *** CfP,defect-free Mg-Zn-Ca rods with greatly refined grains and high mechanical properties were *** to the previous as-cast microstructure,the grain size was reduced from more than 1 mm to around 4μm within 3 s by a single process *** compressive yield strength was increased by 350%while the ultimate compressive strength by 53%.According to the established material flow behaviors by“tracer material”,the plastic material was transported by shear *** the base material to the rod,the material experienced three stages,*** by the tool,upward flow with additional tilt,followed by upward *** microstructural evolution was revealed by“stop-action”*** microstructural development at regions adjacent to the rod is mainly controlled by twinning,dynamic recrystallization(DRX)as well as particle stimulated nucleation,while that within the rod is related to DRX combined with grain growth.

关键词： Constrained friction processing Magnesium alloys Microstructure Mechanical properties Grain refinement Plastic deformation

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Cognition on oxidation behavior of Ni-based superalloy Gh4742 when exposed to water vapor

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Journal of Materials Science & Technology 2024年第7期174卷 15-22页

作者： h.Xu S.f.Yang E.h.Wang C.Y.Guo Y.S.Liu X.M.hou Y.L.Zhang State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China Institute for Carbon Neutrality University of Science and Technology BeijingBeijing 100083China

The oxidation behavior of Ni-based superalloy Gh4742 exposed to water vapor was investigated at 900-1100℃for 50 h in Ar+20%h_(2)O,with Ar+20%O_(2)included for *** presence of h_(2)O is adverse to formation of continuous Cr_(2)O_(3)oxide layer but contributes to generation of big *** on this,Ni^(2+)and Co^(2+)are more easily to diffuse towards the outermost oxide layer(OOL),forming non-protective Ni-and Co-rich oxides with high *** leads to a higher weight gain in Ar+20%h_(2)O than that in Ar+20%O_(2).At elevated temperatures,the spallation of oxide scale occurs while the consumption of Cr is reduced in Ar+20%h_(2)O,and the contents of Ni-and Co-rich oxides at this moment are reduced in the *** oxidation mechanism was also discussed.

关键词： Gh4742 Superalloy h_(2)O Diffusion Oxidation Mechanism

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Reactive destabilization and bidirectional catalyzation for reversible hydrogen storage of LiBh_(4) by novel waxberry-like nano-additive assembled from ultrafine fe_(3)O_(4) particles

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Journal of Materials Science & Technology 2024年第6期173卷 63-71页

作者： S.Wang M.h.Wu Y.Y.Zhu Z.L.Li Y.X.Yang Y.Z.Li h.f.Liu M.X.Gao Department of Material Science Shenzhen MSU-BIT UniversityShenzhen 518172China State Key Laboratory of Silicon and Advanced Semiconductor Materials&School of Materials Science and Engineering Zhejiang UniversityHangzhou 310027China Institute of Resources Utilization and Rare Earth Development State Key Laboratory of Rare Metals Separation and Comprehensive UtilizationGuangdong Provincial Key Laboratory of Rare Earth Development and ApplicationGuangdong Academy of SciencesGuangzhou 510650China Institute of Science and Technology for New Energy Xi’an Technological UniversityXi’an 710021China National Supercomputing Center in Shenzhen Shenzhen 518055China

LiBh_(4) containing 18.5 wt.%h_(2) is an attractive high-capacity hydrogen storage material,however,it suffers from high operation temperature and poor ***,a novel and low-cost bifunctional additive,waxberry-like fe_(3)O_(4) secondary nanospheres assembled from ultrafine primary fe_(3)O_(4) nanoparticles,is synthesized,which exhibits significant destabilization and bidirectional catalyzation towards(de)hydrogenation of LiBh_(4).With an optimized addition of 30 wt.% waxberry-like fe_(3)O_(4),the system initiated dehydrogenation below 100℃ and released a total of 8.1 wt.%h_(2) to 400℃.After 10 cycles,a capacity retention of 70% was achieved,greatly superior to previously reported oxides-modified *** destabilizing and catalyzing mechanisms of waxberry-like fe_(3)O_(4) on LiBh_(4) were systematically analyzed by phase and microstructural evolutions during dehydrogenation and hydrogenation cycling as well as density functional theory(DfT)*** present work provides new insights in developing advanced nano-additives with unique structural and multifunctional designs towards LiBh4 hydrogen storage.

关键词： LiBh_(4) hydrogen storage Waxberry-like fe_(3)O_(4) Destabilization Catalysis

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fast efficient photon deceleration in plasmas by using two laser pulses at different frequencies

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Matter and Radiation at Extremes 2024年第3期9卷 11-18页

作者： Y.X.Wang X.L.Zhu S.M.Weng P.Li X.f.Li h.Ai h.R.Pan Z.M.Sheng Key Laboratory for Laser Plasmas(moe) School of Physics and AstronomyShanghai Jiao Tong UniversityShanghai 200240China Collaborative Innovation Center of IfSA Shanghai Jiao Tong UniversityShanghai 200240China Research Center of Laser fusion of China Academy of Engineering Physics MianyangSichuan 621900China State key Laboratory of high field Laser Physics Shanghai Institute of Optics and Fine MechanicsChinese Academy of SciencesShanghai 201800China Tsung-dao Lee Institute Shanghai Jiao Tong UniversityShanghai 200240China

The generation of ultrashort high-power light sources in the mid-infrared(mid-IR)to terahertz(Thz)range is of interest for applications in a number of fields,from fundamental research to biology and *** conventional laser technology,photon deceleration in plasma wakes provides an alternative approach to the generation of ultrashort mid-IR or Thz ***,we present a photon deceleration scheme for the efficient generation of ultrashort mid-IR or Thz pulses by using an intense driver laser pulse with a relatively short wavelength and a signal laser pulse with a relatively long *** signal pulse trails the driver pulse with an appropriate time delay such that it sits at the front of the second wake bubble that is driven by the driver *** to its relatively long wavelength,the signal pulse will be subjected to a large gradient of the refractive index in the plasma wake ***,the photon deceleration in the plasma wake becomes faster and more efficient for signal pulses with longer *** greatly enhances the capacity and efficiency of photon deceleration in the generation of ultrashort high-power light sources in the long-wavelength IR and Thz spectral ranges.

关键词： laser ultrashort photon

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Precipitation of multi-type nano-quasicrystals in a Mg-Zn-Y alloy

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Journal of Magnesium and Alloys 2024年第3期12卷 997-1008页

作者： W.Z.Wang X.Z.Zhou L.f.Zhang h.Q.Ye Z.Q.Yang Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of ScienceShenyang 110016China Ji hua Laboratory Foshan 528251China foshan University Foshan 528231China

Mg-6Zn-1Y(at.%)ribbons with strengthening precipitates of multi-type nanoquasicrystals were prepared by melt-spinning followed by aging *** evolution of the rapidly solidified ribbons during isothermal aging was comprehensively studied using various electron microscopy *** new kinds of decagonal quasicrystals were formed in aged ribbons,in addition to precipitation of nanometer icosahedral ***-resolution observations reveal that both decagonal quasicrystals can be modeled by quasiperiodic tiling with decagonal clusters of 2.5 nm in diameter,but overlap of neighboring clusters in both decagonal quasicrystals is different from the Gummelt model observed in other quasicrystals.A shell composed of complex Laves Mg-Zn domains was formed surrounding each decagonal quasicrystal precipitate upon prolonged *** addition,all kinds of nanoprecipitates exhibit excellent structure and size stability at 573 *** findings may have implications for not only fundamental studies about quasicrystals,but also microstructural manipulation of high-performance Mg alloys.

关键词： Quasicrystal Mg alloys Rapid solidification Scanning-transmission electron microscopy.

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All-electron basis sets for h to Xe specific for ZORA calculations:Applications in atoms and molecules

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Chinese Physics B 2024年第8期33卷 238-246页

作者： C.S.Gomes f.E.Jorge A.Canal Neto Departamento de fisica Universidade Federal do Espirito Santo29075-910 VitoriaESBrazil Departamento de fisica Instituto de Ciencias Exatas e BiologicasUniversidade Federal de Ouro Preto Campus Universitario Morro do Cruzeiro35402-136 Ouro PretoMGBrazil

A segmented basis set of quadruple zeta valence quality plus polarization functions(QZP)for h through Xe was developed to be used in conjunction with the ZORA *** set was augmented with diffuse functions to describe electrons farther away from the nuclei *** the ZORA-CCSD(T)/QZP-ZORA theoretical model,atomic ionization energies and bond lengths,harmonic vibrational frequencies,and atomization energies of some molecules were *** addition of core-valence corrections has been shown to improve the agreement between theoretical and experimental results for molecular *** atomization energies,a similar observation emerges when considering spin-orbit *** the augmented QZP-ZORA set,static mean dipole polarizabilities of a set of atoms were calculated and compared with previously published recommended and experimental *** evaluations of the ZORA and Douglas–Kroll–hess hamiltonians were made for each property studied.

关键词： QZP-ZORA and AQZP-ZORA basis sets elements from h to Xe CCSD(T)method atomic and molecular properties

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Reviewing 40 years of artificial intelligence applied to power systems-A taxonomic perspective

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Energy and AI 2024年第1期15卷 136-150页

作者： f.heymann h.Quest T.Lopez Garcia C.Ballif M.Galus Swiss federal Office for Energy(SfOE) Section Geoinformation and Digital InnovationIttigenSwitzerland Ecole Polytechnique fédérale de Lausanne(EPfL) Photovoltaics and Thin-Film Electronics Laboratory(PV-LAB)Institute of Electrical and Micro Engineering(IEM)NeuchâtelSwitzerland 3S Swiss Solar Solutions AG ThunSwitzerland Swiss Center for Electronics and Microtechnology(CSEM) Sustainable Energy CenterNeuchâtelSwitzerland Digital Energy and Electric Power Lucerne University of Applied Sciences and ArtsLucerneSwitzerland

Artificial intelligence(AI)as a multi-purpose technology is gaining increased attention and is now widely used across all sectors of the *** growing complexity of planning and operating power systems makes AI extremely valuable for the power *** now,there has been a lack of clarity regarding the specific points along the power system supply chain where AI applications demonstrate significant value,as well as which AI domains are best suited for such *** study employs an AI taxonomy and automated web search to qualitatively and quantitatively unveil the biggest potentials of AI in the power *** analysis,based on a review of 258’919 publications between 1982 and 2022,reveals where AI applications are particularly *** consider six AI domains(reasoning,planning,learning,communication,perception,integration&interaction)and 19 use cases from the power supply chain(i.e.,generation,transmission networks,distribution networks,isolated grids/microgrids,market operations and retail).Our findings indicate that,as of now,the focus is predominantly on AI applications in power retail(55%),transmission(14%)and generation(13%).Most analyzed works describe applications built on algorithms of the AI domains“learning”(45%)and“planning”(14%).Results also suggest that the current definition of AI domains is ambiguous,and they highlight missing information on the actual use and successful implementation of AI in power system use cases.

关键词： Artificial intelligence Power systems Electricity Taxonomy Policy

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A new technique for fault diagnosis in transformer insulating oil based on infrared spectroscopy measurements

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high Voltage 2024年第2期9卷 319-335页

作者： Mohamed M.f.Darwish Mohamed h.A.hassan Nagat M.K.Abdel-Gawad Matti Lehtonen Diaa-Eldin A.Mansour Department of Electrical Engineering Faculty of Engineering at ShoubraBenha UniversityCairoEgypt Department of Electrical Engineering and Automation School of Electrical EngineeringAalto UniversityEspooFinland Department of Electrical Power Engineering Egypt-Japan University of Science and Technology(E-JUST)New Borg El-Arab CityEgypt Department of Electrical Power and Machines Engineering Faculty of EngineeringTanta UniversityTantaEgypt

Condition monitoring of the insulating system within power transformers has a massive importance according to the electrical *** gas analysis(DGA)is frequently used for this ***,DGA lacks the necessary level of accuracy to identify all equipment faults,particularly in their initial stages of ***,it does not have the capability for real-time monitoring and relies on manual sampling and laboratory testing,causing potential delays in fault ***,the interpretation of DGA data necessitates specialised expertise,which may pose difficulties for smaller entities that have limited access to ***,the contribution of this research is to use infrared spectroscopy measurements as a new effective technique substituting the DGA method for fault diagnosis in insulating *** inception faults that were considered in this study were the electrical fault(discharges of high energy)and the thermal fault(300°Chat,two test cells were crafted especially for serving the simulation processes inside the laboratory for both types of inception ***,six samples of pure paraffinic mineral oil were taken to be degraded in the *** that,all of them besides another sample that were not subjected to any kind of faults were taken to be examined by fourier transform infrared(fTIR)spectroscopy to obtain an overview of the oil's behaviour in each fault *** that,the fTIR analysis was initially verified utilising the DGA ***,for further affirmation,the dielectric dissipation factor(DDf)for all samples was *** the final analysis,the verification tests provide experimental evidence about the outperformance of this new optical technique in detecting the transformer's inception faults in addition to proving its potential for being a superior alternative to the well-known traditional diagnostic techniques.

关键词： fault diagnosis spectroscopy

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MgO-attached graphene nanosheet(MgO@GNS)reinforced magnesium matrix nanocomposite with superior mechanical,corrosion and biological performance

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International Journal of Minerals,Metallurgy and Materials 2024年第9期31卷 2062-2076页

作者： S.Abazari A.Shamsipur h.R.Bakhsheshi-Rad M.S.Soheilirad f.Khorashadizade S.S.Mirhosseini Department of Materials and Metallurgical Engineering Amirkabir University of TechnologyTehran ***Iran Iranian National Standards Organization of hormozgan HormozganIran Advanced Materials Research Center Department of Materials EngineeringNajafabad BranchIslamic Azad UniversityNajafabadIran Department of Materials and Metallurgical Engineering Iran University of Science and TechnologyTehranIran

Magnesium(Mg)alloys are gaining great consideration as body implant materials due to their high biodegradability and ***,they suffer from low corrosion resistance and antibacterial *** this research,semi-powder metallurgy followed by hot extrusion was utilized to produce the magnesium oxide@graphene nanosheets/magnesium(MgO@GNS/Mg)composite to improve mechanical,corrosion and cytocompatibility *** have revealed that the incorporation of MgO@GNS nanohybrids into Mg-based composite enhanced microhardness and compressive *** vitro,osteoblast cell culture tests show that using MgO@GNS nanohybrid fillers enhances osteoblast adhesion and apatite *** presence of MgO@GNS nanoparticles in the composites decreased the opening defects,micro-cracks and micro-pores of the composites thus preventing the penetration of the corrosive solution into the *** demonstrated that the MgO@GNS/Mg composite possesses excellent antibacterial properties because of the combination of the release of MgO and physical damage to bacterium membranes caused by the sharp edges of graphene nanosheets that can effectively damage the cell wall thereby facilitating penetration into the bacterial lipid ***,the MgO@GNS/Mg composite with high mechanical strength,antibacterial activity and corrosion resistance is considered to be a promising material for load-bearing implant applications.

关键词： metal matrix composites MgO@GNS nanohybrid strengthening mechanisms antibacterial activity biocompatibility

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SARS-CoV-2 variants are associated with different clinical courses in children with MIS-C

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World Journal of Pediatrics 2024年第2期20卷 143-152页

作者： Andres f.Moreno Rojas Emelia Bainto helen harvey Adriana h.Tremoulet Jane C.Burns Kirsten B.Dummer Department of Pediatrics Division of Pediatric CardiologyUniversity of California San Diegoand Rady Children’s Hospital3020 Children’s Way MC 5004San DiegoCA 92123USA Kawasaki Disease Research Center La JollaCAUSA Department of Pediatrics Division of Pediatric Critical CareUniversity of California San Diegoand Rady Children’s HospitalSan DiegoCAUSA Department of Pediatrics University of California San Diegoand Rady Children’s HospitalSan DiegoCAUSA

Background Recent infection with SARS‑CoV-2 in children has been associated with multisystem inflammatory syndrome in children(MIS-C).SARS‑CoV-2 has undergone different *** publications exist about specific variants and their correlation with the severity of *** This was a single-center,retrospective study including all patients admitted with MIS-C at Rady Children’s hospital-San Diego between May 2020 and March *** epidemiologic data,including viral genomic information,were obtained from public ***,clinical presentation,laboratory values,and outcomes were obtained from electronic medical *** The analysis included 104 pediatric *** MIS-C waves were *** variants in San Diego during the first wave included clades 20A to *** the second wave,there were variants from clades 20A to C,20G,21C(Epsilon),20I(Alpha),and 20J(Gamma).The third wave had Delta strains(clades 21A,21I,and 21J),and the fourth had Omicron variants(clades 21K,21L,and 22C).MIS-C presented with similar symptoms and laboratory findings across all *** patients were admitted to the pediatric intensive care unit(PICU)(74%)and required inotropic support(63%)during the second *** of the patients required mechanical circulatory support,and only two required invasive ventilatory *** was no *** The various strains of SARS-CoV-2 triggered MIS-C with differing severities,with the second wave having a more severe clinical *** the differences in disease severity across variants were due to changes in the virus or other factors remains unknown.

关键词： Complications COVID-19 MIS-C SARS-CoV-2 variants

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