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Design of Biologically Active Macromolecular Ligands and Their Luminescent Complexes with Terbium Ions

Chinese Journal of Polymer Science 2024年第5期42卷 604-611,I0007页

作者： Tatiana N.Nekrasova Andrei I.fischer Natalia A.Nesterova Anatoliy V.Dobrodumov Anzhelika V.Garshinina Olga D.Shuvaeva Natalya V.Zakharova evgenii f.panarin Institute of Macromolecular Compounds Russian Academy of Sciences31 Bolshoy pr.St Petersburg199004Russia Smorodintsev Research Institute of Influenza Russian Ministry of Health15/17 ul.prof.PopovaSt Petersburg197376Russia

Water-soluble copolymers of p-methacrylamidobenzoic acid(MABA)with neutral comonomers(N-vinylpyrrolidone(VP),N-methyl-N-vinylacetamide(MVAA),N-methacryloyl glucosamine(MAG))and anionic comononer sodium styrene sulfonate(NaSS)were synthesized by radical *** interactions between the prepared copolymers and Tb^(3+)ions in aqueous solutions were studied;the significant influence of chemical structure of a comonomer on luminescence intensity of Tb^(3+)complexes with the copolymers was *** luminescence intensity of Tb^(3+)complexes with the copolymers containing N-vinylamide units(VP,MVAA)is three times more intense than that observed for the complexes between Tb^(3+)and MAG-containing *** the case of NaSS-containing copolymers,the luminescence intensity is controlled by the values of binding constants between Tb^(3+)and MABA and the content of MABA units in a *** studied copolymers and their complexes with Tb^(3+)have low cytotoxicity and a pronounced antiviral activity against human respiratory syncytial virus.

关键词： Luminescence Water-soluble copolymers Lanthanide complexes Antiviral activity Cytotoxicity

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Corona with Streamers in Atmospheric Pressure Air in a Highly Inhomogeneous Electric field

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Journal of Atmospheric Science Research 2020年第4期3卷 28-37页

作者： Victor Tarasenko evgenii Baksht Vladimir Kuznetsov Victor panarin Victor Skakun Eduard Sosnin Dmitry Beloplotov Institute of High Current Electronics Siberian Branch(SB)Russian Academy of Sciences(RAS)2/3 Akademicheskii Ave.Tomsk634055Russia

The paper presents research data on positive and negative coronas inatmospheric pressure air in a highly inhomogeneous electric field. Thedata show that irrespective of the polarity of pointed electrodes placed ina high electric field (200 kV/cm), this type of discharge develops via ballstreamers even if the gap voltage rises slowly (0.2 kV/ms). The start voltageof first positive streamers, compared to negative ones, is higher andthe amplitude and the frequency of their current pulses are much lower:about two times and more than two orders of magnitude, *** higher frequency of current pulses from negative streamers provideshigher average currents and larger luminous areas of negative coronascompared to positive ones. Positive and negative cylindrical streamersfrom a pointed to a plane electrode are detected and successive dischargetransitions at both polarities are identified.

关键词： Positive and negative coronas Atmospheric pressure air Highly inhomogeneous electric field ICCD camera Ball streamer Cylindrical streamer

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