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Effect of silicon carbide-based iron catalyst on reactor optimization for non-oxidative direct conversion of methane

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Journal of Energy Chemistry 2023年第6期81卷 519-532,I0012页

作者： Eun-hae Sim Sung Woo Lee Jin Ju Lee Seung Ju Han Jung Ho Shin gracia Lee Sungrok Ko Kwan-Young Lee Yong Tae Kim C1 Gas&Carbon Convergent Research Center Korea Research Institute of Chemical TechnologyDaejeon 34114Republic of Korea Department of Chemical and Biological Engineering Korea University145 Anam-roSeoul 02841Republic of Korea Department of Chemical and Biomolecular Engineering Yonsei University50 Yonsei-roSeoul 03722Republic of Korea Chemical Data-Driven Research Center Korea Research Institute of Chemical TechnologyDaejeon 34114Republic of Korea Prospective Tech.Exploring Section Basic Chemical R&D centerLottechemical Corp.Daejeon 34059Republic of Korea Department of Advanced Materials and Chemical Engineering University of Science and Technology(UST)Gajeong-dongYuseongDaejeon 34113Republic of Korea

The conversion of methane to olefins,aromatics,and hydrogen(MTOAH)can be used to stably obtain hydrocarbons when the effect of the catalytic surface is optimized from the reaction engineering *** this study,Fe/Si C catalysts were packed into a quartz tube *** catalytic surfaces of Si C and the impregnated Fe species decreased the apparent activation energies(E_a)of methane consumption in the blank reactor between 965 and 1020℃.Consequently,the hydrocarbon yield increased by 2.4times at 1020℃.Based on the model reactions of ethane,ethylene,and acetylene mixed with hydrogen in the range of 500-1020℃,an excess amount of Fe in the reactor favored the C-C coupling reaction over the selective hydrogenation of acetylene;consequently,coke formation was favored over the hydrogenation *** gas-phase reactions and catalyst properties were optimized to increase hydrocarbon yields while reducing coke *** 0.2Fe catalyst-packed reactor(0.26 wt%Fe)resulted in a hydrocarbon yield of 7.1%and a coke selectivity of<2%when the ratio of the void space of the postcatalyst zone to the catalyst space was adjusted to be≥*** on these findings,the facile approach of decoupling the reaction zone between the catalyst surface and the gas-phase reaction can provide insights into catalytic reactor design,thereby facilitating the scale-up from the laboratory to the commercial scale.

关键词： Non-oxidative methane conversion Ethylene Aromatic Methane pyrolysis Fe/SiC Coke resistance Catalytic reactor

Photocatalytic reduction of CO2 with H2O over modified TiO2 nanofibers： Understanding the reduction pathway

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Nano Research 2016年第7期9卷 1956-1968页

作者： Anjana Sarkar Eduardo gracia-Espino Thomas Wagberg Andrey Shchukarev Melinda Mohl Anne-Riikka Rautio Olli Pitkanen Tiva Sharifi Krisztian Kordas Jyri-Pekka Mikkola Technical Chemistry Department of Chemistry Chemical-Biological Centre Umea University SE-901 87 Umea Sweden Department of Physics Umea University SE-901 87 Umea Sweden Microelectronics and Materials Physics Laboratories Department of Electrical Engineering University of Oulu P.O. Box 4500 Oulu FI-90014 Finland Laboratory of Industrial Chemistry and Reaction Engineering Johan Gadofin Process Chemistry Centre Abo Akademi University Biskopsgatan 8 Abo-Turku FI-20500 Finland

Nanosized metal （Pt or Pd）-decorated TiO2 nanofibers （NFs） were synthesized by a wet impregnation method. CdSe quantum dots （QDs） were then anchored onto the metal-decorated TiO2 NFs. The photocatalytic performance of these catalysts was tested for activation and reduction of CO2 under UV-B light. Gas chromatographic analysis indicated the formation of methanol, formic acid, and methyl formate as the primary products. In the absence of CdSe QDs, Pd-decorated TiO2 NFs were found to exhibit enhanced performance compared to Pt-decorated TiO2 NFs for methanol production. However, in the presence of CdSe, Pt-decorated TiO2 NFs exhibited higher selectivity for methanol, typically producing -90 ppmg^-1.h^-1 methanol. The CO2 photoreduction mechanism is proposed to take place via a hydrogenation pathway from first principles calculations, which complement the experimental observations.

关键词： TiO2 photocatalysis CdSe quantum dots CO2 photoreduction

Current Knowledge on Hepatitis E

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Journal of Clinical and Translational Hepatology 2015年第2期3卷 117-126页

作者： María Teresa Pérez-gracia Mario García Beatriz Suay María Luisa Mateos-Lindemann (A)rea de Microbiología Departamento de Farmacia Instituto de Ciencias Biomédicas Facultad de Ciencias de la Salud Universidad CEU Cardenal Herrera Valencia Spain Unidad de Virología Servicio de Microbiología Hospital Universitario Ramóny Cajal Madrid Spain

Although only a single serotype of hepatitis E virus (HEV),the causative agent of hepatitis E,has been identified,there is great genetic variation among the different HEV isolates *** are at least four major recognized genotypes of HEV:genotypes 1 and 2 are mainly restricted to humans and linked to epidemic outbreaks in nonindustrialized countries,whereas genotypes 3 and 4 are zoonotic in both developing and industrialized *** human strains,genotype 3 and 4 strains of HEV have been genetically characterized from swine,sika deer,mongooses,sheep,and ***,there are approximately 11,000 human and animal sequences of HEV available at the International Nucleotide Sequence Database *** is the major cause of waterborne outbreaks of hepatitis in areas of poor ***,it is responsible for sporadic cases of viral hepatitis in not only endemic but industrialized countries as *** of HEV occurs predominantly by the fecal-oral route,although parenteral and perinatal routes have been *** infection develops in most individuals as a self-limiting,acute,icteric hepatitis;with mortality rates around 1%.However,some affected individuals will develop fulminant hepatic failure,a serious condition that is frequently fatal without a liver *** complication is particularly common when the infection occurs in pregnant women,where mortality rates rise dramatically to up to 25%.Among the preventive measures available to avoid HEV infection,two separate subunit vaccines containing recombinant truncated capsid proteins of HEV have been shown to be highly effective in the prevention of *** of them,HEV 239,was approved in China,and its commercialization by Innovax began in November 2012 under the name Hecolin(R).

关键词： Hepatitis E virus Hepatitis E HEV Zoonosis

Treatment of Childhood Cancer in Southern Nigeria:Parents Perspective

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Psychology Research 2019年第11期9卷 458-464页

作者： gracia Eke Nwadiuto Akani University of Port Harcourt Teaching Hospital Port HarcourtNigeria

Background:The care and treatment of a child with cancer is stressful for *** their challenges and addressing them are important strategies in aiding families cope with cancer ***:To ascertain the perspectives of parents on childhood cancer therapy and understand their challenges in order to devise effective ways of supporting ***:This qualitative study was conducted between June and November *** were obtained through semi-structured interviews held with 27 parents whose children were being treated for various cancers at the Paediatric Oncology Unit of the University of Port Harcourt Teaching Hospital,***:Respondents were 19 mothers,2 fathers,and 3 *** children were aged 11 months to 15 *** of respondent knew the diagnosis of their children while few could only name the site of the *** undergoing chemotherapy,refusal to eat,vomiting,fever,pain,and falling of hairs were symptoms parents perceived as most distressing,which also affected them *** related costs drained families’monthly incomes and were considered the major challenge to treatment *** support and prayers received were much appreciated and helped them cope better with their child’s ***:Parents of children with cancer experience various stressors related to *** is need to consistently offer them information regarding the side effects of cancer therapy and best ways of coping with *** need to be supported in various ways to ensure compliance to their child’s therapy.

关键词： experience parents treatment of childhood cancer Southern Nigeria

Multiscale assessment of ground,aerial and satellite spectral data for monitoring wheat grain nitrogen content

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Information Processing in Agriculture 2023年第4期10卷 504-522页

作者： Joel Segarra Fatima Zahra Rezzouk Nieves Aparicio Jon González-Torralba Iker Aranjuelo Adrian gracia-Romero Jose Luis Araus Shawn C.Kefauver Integrative Crop Ecophysiology Group Plant Physiology SectionFaculty of BiologyUniversity of BarcelonaBarcelona 08028Spain AGROTECNIO(Center for Research in Agrotechnology) Lleida 251981Spain Agro-technological Institute of Castilla y León(ITACyL) Valladolid 47071Spain Grupo AN Tajonar 31192NavarreSpain Instituto de Agrobiotecnología(IdAB) CSIC-Gobierno de NavarraMutilva Baja 31192PamplonaNavarreSpain

Wheat grain quality characteristics have experienced increasing attention as a central factor affecting wheat end-use products quality and human ***,in the last decades a reduction in grain quality has been ***,it is central to develop efficient quality-related phenotyping *** this sense,one of the most relevant wheat features related to grain quality traits is grain nitrogen content,which is directly linked to grain protein content and monitorable with remote sensing ***,the relation between nitrogen fertilization and grain nitrogen content(protein)plays a central role in the sustainability of *** aiming to develop efficient phenotyping tools using remote sensing instruments and to advance towards a field-level efficient and sustainable monitoring of grain nitrogen status,this paper studies the efficacy of various sensors,multispectral and visible red-greenblue(RGB),at different scales,ground and unmanned aerial vehicle(UAV),and phenological stages(anthesis and grain filling)to estimate grain nitrogen *** models were calculated using vegetation indices at each sensing level,sensor type and phenological ***,this study explores the up-scalability of the best performing model to satellite level Sentinel-2 equivalent *** found that models built at the phenological stage of anthesis with UAV-level multispectral cameras using red-edge bands outperformed grain nitrogen content estimation(R2=0.42,RMSE=0.18%)in comparison with those models built with RGB imagery at ground and aerial level,as well as with those built with widely used ground-level multispectral *** also demonstrated the possibility to use UAV-built multispectral linear models at the satellite scale to determine grain nitrogen content effectively(R2=0.40,RMSE=0.29%)at actual wheat fields.

关键词： Wheat Remote sensing Sentinel-2 Grain nitrogen content Phenotyping

Fe-substituted cobalt-phosphate polyoxometalates as enhanced oxygen evolution catalysts in acidic media

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Chinese Journal of Catalysis 2020年第5期41卷 853-857页

作者： Xin-Bao Han Dong-Xue Wang Eduardo gracia-Espino Yu-Hui Luo Yuan-Zhi Tan Dong-Fei Lu Yang-Guang Li Thomas Wagberg En-Bo Wang Lan-Sun Zheng State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of ChemistryCollege of Chemistry and Chemical EngineeringXiamen UniversityXiamen 361005FujianChina Key Laboratory of Polyoxometalate Science of the Ministry of Education Faculty of ChemistryNortheast Normal UniversityChangchun 130024JilinChina Department of Physics Ume?UniversityUme?90187Sweden Department of Chemical Engineering Huaihai Institute of TechnologyLianyungang 222000JiangsuChina

All-inorganic and earth-abundant bi-/trimetallic hydr(oxy)oxides are widely used as oxygen evolution electrocatalysts owing to their remarkable ***,their atomically precise structures remain undefined,complicating their optimization and limiting the understanding of their enhanced ***,the underlying structure-property correlation is explored by using a well-defined cobalt-phosphate polyoxometalate cluster [{(Co4)(OH)3(PO4)}4(SiW9 O34)4]^32-(1),which may serve as a molecular model of multimetal hydr(oxy)*** catalytic activity is enhanced upon replacing Co by Fe in 1,resulting in a reduced overpotential(385 mV) for oxygen evolution(by 66 mV) compared to that of the parent 1 at 10 mA cm^-2 in an acidic medium;this overpotential is comparable to that for the IrO2 catalyst These abundant-metal-based polyoxometalates exhibit high stability,with no evidence of degradation even after 24 h of operation.

关键词： Colbalt-phosphate Polyoxometalate Oxygen evolution reaction Isostructural substitution

Effects of Recreational Soccer on Health Outcomes:A Narrative Review

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Journal of Science in Sport and Exercise 2019年第2期1卷 142-150页

作者： Israel Castillo-Bellot Jose Mora-Gonzalez Luis Fradua Francisco B.Ortega Luis gracia-Marco Department of Physical Education and Sport Faculty of Sport SciencesUniversity of GranadaGranadaSpain PROmoting FITness and Health Through Physical Activity(PROFITH)Research Group Department of Physical Education and SportFaculty of Sport SciencesUniversity of GranadaGranadaSpain

Soccer is a very popular team sport that involves a variety of physical actions,such as sprints,accelerations,sudden decelera-tions,and jumps,among *** has placed recreational soccer in a good position as a strategy to increase physical activity levels and promote health across the *** this regard,recreational(non-competitive)soccer promotes social interaction and has the potential to increase long-term adherence to physical activity,even in those without prior experience in this *** this narrative review,we address the effects of recreational soccer on various health outcomes across the lifespan(i.e.,from childhood to the elderly years)in both *** addition,the beneficial effects of recreational soccer for people with prevalent pathologies,such as hypertension,type II diabetes mellitus,and cancer,are discussed.

关键词： Physical fitness Physical activity Hypertension Diabetes Cancer Football

Fibrosing cholestatic hepatitis following cytotoxic chemotherapy for small-cell lung cancer

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World Journal of Gastroenterology 2009年第18期15卷 2290-2292页

作者： Jaime Ceballos-Viro José M López-Picazo José L Pérez-gracia Jesús J Sola Gregorio Aisa Ignacio Gil-Bazo Department of Oncology Clínica Universidad de NavarraPio XII 3631008 PamplonaSpain Department of Pathology Clínica Universidad de NavarraPio XII 3631008 PamplonaSpain

Fibrosing cholestatic hepatitis(FCH) is a variant of viral hepatitis reported in hepatitis B virus or hepatitis C virus infected liver,renal or bone transplantation recipients and in leukemia and lymphoma patients after conventional cytotoxic *** constitutes a well-described form of fulminant hepatitis having extensive fibrosis and severe cholestasis as its most characteristic pathological ***,we report a case of a 49-year-old patient diagnosed with small-cell lung cancer who developed this condition following conventional chemotherapy-induced *** is the first reported case in the literature of FCH after conventional chemotherapy for a solid *** addition to a detailed report of the case,a physiopathological examination of this potentially life-threatening condition and its treatment options are discussed.

关键词： Fibrosing cholestatic hepatitis Immunosuppression Chemotherapy Lung cancer Hepatitis Bvirus Lamivudine

Spontaneous twisting of a collapsed carbon nanotube

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Nano Research 2017年第6期10卷 1942-1949页

作者： Hamid Reza Barzegar Aiming Yan Sinisa Coh Eduardo gracia-Espino Claudia Ojeda-Aristizabal Gabriel Dunn Marvin L. Cohen Steven G. Louie Thomas Wagberg Alex Zettl Department of Physics University of California Berkeley CA 94720 USA Department of Physics Umea University 90187 Umea Sweden Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA Kavli Energy NanoSciences Institute at the University of California Berkeley and the Lawrence Berkeley National Laboratory Berkeley CA 94720 USA

We study the collapsing and subsequent spontaneous twisting of a carbon nanotube by in situ transmission electron microscopy （TEM）. A custom-sized nanotube is first created in the microscope by selectively extracting shells from a parent multi-walled tube. The few-walled, large-diameter daughter nanotube is driven to collapse via mechanical stimulation, after which the ribbon-like collapsed tube spontaneously twists along its long axis. In situ diffraction experiments fully characterize the uncollapsed and collapsed tubes. The experimental observations and associated theoretical analysis indicate that the origin of the twisting is compressive strain.

关键词： multi-walled carbonnanotube collapsed carbon nanotube in situ TEM electron diffraction twisting graphene nanoribbons