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Mapping urbanities

Mapping urbanities

High Na-ion conductivity andmechanical integrity of anion-exchanged polymeric hydrogel electrolytes for flexible sodium ion hybrid energy storage

作者： edited by kim Dovey Elek Pafka and Mirjana Ristic.

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SusMat 2024年第1期4卷 140-153页

作者： JungWoo Hong Harpalsinh H.Rana Jeong Hee Park Jun Su kim Sang Joon Lee Gun Jang Tae Hoon Kang Kang Ho Shin Sang Ha Baek Wooseok Yang Kwang Ho kim Ju-Hyuk Lee Ho Seok Park School of Chemical Engineering Sungkyunkwan UniversitySuwonRepublic of Korea Clean Energy Research Center Korea Institute of Science and Technology(KIST)SeoulRepublic of Korea KIST-SKKU Carbon-Neutral Research Center Sungkyunkwan University(SKKU)SuwonRepublic of Korea SKKU Institute of Energy Science and Technology(SIEST) Sungkyunkwan UniversitySuwonRepublic of Korea COSMOS LAB/92 Jomaru-ro 385beon-gilBucheon-siRepublic of Korea SKKU Advanced Institute of Nano Technology(SAINT) Sungkyunkwan UniversitySuwonRepublic of Korea Department of Health Sciences and Technology Samsung Advanced Institute for Health Sciences and Technology(SAIHST)Sungkyunkwan UniversitySuwonRepublic of Korea

The polymeric gel electrolytes are attractive owing to their higher ionic conductivities than those of dry polymer electrolytes and lowered water activity for enlarged potential ***,the ionic conductivity and mechanical strength of the Na-ion conducting polymeric gel electrolytes are limited by below 20 mS cm−1 and 2.2 ***,we demonstrate Na-ion conducting and flexible polymeric hydrogel electrolytes of the chemically coupled poly(diallyldimethylammonium chloride)-dextrin-N,N′-methylene-bisacrylamide film immersed in NaClO_(4) solution(ex-DDA-Dex+NaClO_(4))for flexible sodium-ion hybrid capacitors(f-NIHC).In particular,the anion exchange reaction and synergistic interaction of ex-DDA-Dex with the optimum ClO_(4)−enable to greatly improve the ionic conductivity up to 27.63 mS cm−1 at 25◦C and electrochemical stability window up to 2.6 V,whereas the double networking structure leads to achieve both the mechanical strength(7.48 MPa)and softness of hydrogel ***,the f-NIHCs with the ex-DDA-Dex+NaClO_(4) achieved high specific and high-rate capacities of 192.04 F g^(−1)at 500 mA g^(−1)and 116.06 F g^(−1)at 10000 mA g^(−1),respectively,delivering a large energy density of 120.03Wh kg^(−1)at 906Wkg^(−1)and long cyclability of 70%over 500 cycles as well as demonstrating functional operation under mechanical stresses.

关键词： anion exchange chemistry flexible energy storage hybrid energy storage hydrogel electrolytes renewable electrolytes sodium storage

Passivating contact-based tunnel junction Si solar cells using machine learning for tandem cell applications

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Energy and AI 2023年第4期14卷 550-558页

作者： HyunJung Park Audrey Morisset Munho kim Hae-Seok Lee Aicha Hessler-Wyser Franz-Josef Haug Christophe Ballif Photovoltaics and Thin Film Electronics Laboratory(PV-Lab) EPFLSchool of Engineering(STI)Maladière 71bNeuchâtelCH-2000Switzerland School of Electrical and Electronic Engineering Nanyang Technological University50 Nanyang Avenue639798SingaporeSingapore Graduate School of Energy and Environment(KU-KIST Green School) Korea University145Anam-roSeongbuk-gu02841SeoulRepublic of Korea

Tandem solar cells are a key technology for exceeding the theoretical efficiency limit of single-junction *** of the most promising combinations is the silicon–perovskite tandem cells,considering their potential for high efficiency,fabrication on a large scale,and low *** most research focuses on improving each subcell,another key challenge lies in the tunnel junction that connects these subcells,significantly impacting the overall cell ***,we demonstrate the first use of tunnel junctions using a stack of p+/n+polysilicon passivating contacts deposited directly on the tunnel oxide to overcome the drawbacks of conventional metal oxide-based tunnel junctions,including low tunneling efficiency and sputter *** Random Forest analysis,we achieved high implied open circuit voltages over 700 mV and low contact resistivities of 500 mΩcm 2,suggesting fill factor losses of less than 1%abs for the operating conditions of a tandem cell.

关键词： Tunnel junction Tandem Passivating contact Solar cell Machine learning

Measurement and evaluation of whole body vibration of agricultural tractor operator

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International Journal of Agricultural and Biological Engineering 2017年第1期10卷 248-255页

作者： Md.Shaha Nur Kabir Sun-Ok Chung Yong-Joo kim Nam-Seok Sung Soon-Jung Hong Department of Biosystems Machinery Engineering Chungnam National UniversityDaejeon 34134Korea Department of Agricultural and Industrial Engineering Hajee Mohammad Danesh Science and Technology UniversityDinajpur 5200Bangladesh Rural Human Development Center Rural Development AdministrationJeonju 54875Korea

Exposure of whole body vibration(WBV)influences performance,comfort,and long term health risks of tractor ***,measurement and evaluation of WBV parameters should be carried out to find probable effects on the health of tractor *** this study,a system was designed to measure the WBV of agricultural tractor operators and evaluated the hazard risks on operator’s body according to the ISO standards,and implementation of the WBV test in the official testing station was also suggested.A tri-axial accelerometer was employed to measure vibrations transmitted to the seated operator body as a whole through the supporting surface of the buttock on four typical farm roads under different *** vector sum A(8)exposures on the rough tracks(earthen and grassland roads)exceeded the action limits of 0.5 m/s2 at a 10.9 km/h forward speed and reached to the action limit value at a 16.0 km/h forward speed on the concrete *** vector sum of VDV(8)exposures did not exceed the action limits of 9.1 m/s1.75 and was greater on the grassland *** vector sum Sed(8)exposures values exceeded the moderate probability of an adverse health limit of 0.5 MPa on all farm roads at high forward speeds and exceeded the high probability of an adverse health limit of 0.8 MPa on asphalt,concrete,and grassland roads which should be lower than the exposure limit values as suggested by the ISO and EC *** WBV evaluation procedure should be considered for implementation at the official tractor test station,which would response to domestic and international tractor test regulations and improve the market competitiveness.

关键词： agricultural tractor whole body vibration tractor operator driving safety ride comfort test standard health risk

Intrinsic electrochemical activity of Ni in Ni_(3)Sn_(4) anode accommodating high capacity and mechanical stability for fast-charging lithium-ion batteries

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Journal of Energy Chemistry 2022年第8期31卷 470-477,I0013页

作者： Janghyuk Moon Trung Dinh Hoang Seong Soo Park Seowan Park Dong Young Rhee Junwon Lee Sang A Han Min-Sik Park Jung Ho kim School of Energy Systems Engineering Chung-Ang UniversityHeukseok-RoDongjak-guSeoul 06974Republic of Korea Department of Advanced Materials Engineering for Information and Electronics Integrated Education Institute for Frontier Science&Technology(BK21 Four)Kyung Hee University1732 Deogyeong-daeroGiheung-guYongin 17104Republic of Korea Institute for Superconducting&Electronic Materials(ISEM) Australian Institute of Innovative Materials(AIIM)University of WollongongInnovation CampusSquires WayNorth WollongongNSW 2500Australia

Fast interfacial kinetics derived from bicontinuous three-dimensional(3D)architecture is a strategic feature for achieving fast-charging lithium-ion batteries(LIBs).One of the main reasons is its large active surface and short diffusion ***,understanding of unusual electrochemical properties still remain great challenge due to its *** this study,we proposed a nickel–tin compound(Ni_(3)Sn_(4))supported by 3D Nickel scaffolds as main frame because the Ni_(3)Sn_(4) clearly offers a higher reversible capacity and stable cycling performance than bare tin(Sn).In order to verify the role of Ni,atomic-scale simulation based on density functional theory systematically addressed to the reaction mechanism and structural evolution of Ni_(3)Sn_(4) during the lithiation *** findings are that Ni enables Ni_(3)Sn_(4) to possess higher mechanical stability in terms of reactive flow stress,subsequently lead to improve Li storage *** study elucidates an understanding of the lithiation mechanism of Ni_(3)Sn_(4) and provides a new perspective for the design of high-capacity and high-power 3D anodes for fast-charging LIBs.

关键词： Lithium-ion batteries Ni_(3)Sn_(4) High-capacity anode 3D-structured electrode Inverse opal structure Density functional theory

Tailoring local structures of atomically dispersed copper sites for highly selective CO_(2) electroreduction

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Carbon Energy 2024年第4期6卷 79-90页

作者： Kyung‐Jong Noh Byoung Joon Park Ying Wang Yejung Choi Sang‐Hoon You Yong‐Tae kim Kug‐Seung Lee Jeong Woo Han Department of Chemical Engineering Pohang University of Science and Technology(POSTECH)PohangGyeongbukRepublic of Korea Department of Materials Science and Engineering Pohang University of Science and Technology(POSTECH)PohangGyeongbukRepublic of Korea Pohang Accelerator Laboratory(PAL) Beamline DivisionPohangGyeongbukRepublic of Korea

Atomically‐dispersed copper sites coordinated with nitrogen‐doped carbon(Cu–N–C)can provide novel possibilities to enable highly selective and active electrochemical CO_(2) reduction ***,the construction of optimal local electronic structures for nitrogen‐coordinated Cu sites(Cu–N_(4))on carbon remains ***,we synthesized the Cu–N–C catalysts with atomically‐dispersed edge‐hosted Cu–N_(4) sites(Cu–N_(4)C_(8))located in a micropore between two graphitic sheets via a facile method to control the concentration of metal ***‐hosted Cu–N_(4)C_(8) catalysts outperformed the previously reported M–N–C catalysts for CO_(2)‐to‐CO conversion,achieving a maximum CO Faradaic efficiency(FECO)of 96%,a CO current density of–8.97 mA cm^(–2) at–0.8 V versus reversible hydrogen electrode(RHE),and over FECO of 90%from–0.6 to–1.0 V versus *** studies revealed that the micropore of the graphitic layer in edge‐hosted Cu–N_(4)C_(8) sites causes the d‐orbital energy level of the Cu atom to shift upward,which in return decreases the occupancy of antibonding states in the*COOH *** research suggests new insights into tailoring the locally coordinated structure of the electrocatalyst at the atomic scale to achieve highly selective electrocatalytic reactions.

关键词： atomic local structure density functional theory electrochemical CO_(2)reduction metal nitrogen‐doped carbon single‐atom catalyst

Understanding bat ecosystem services on a global scale requires caution and wider collaboration:a critical evaluation of Ramírez-Fráncel et al.(2022)

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Integrative Zoology 2023年第2期18卷 385-390页

作者： Krizler C.TANALGO kim MCCONKEY Paul RACEY Sheema Abdul AZIZ Tuanjit SRITONGCHUAY Alice CHUGHES Tammy MILDENSTEIN Center for Integrative Conservation Xishuangbanna Tropical Botanical GardenChinese Academy of SciencesMenglunChina School of Environmental and Geographical Sciences University of Nottingham MalaysiaSemenyihSelangorMalaysia Centre for Ecology and Conservation University of ExeterExeterUnited Kingdom Project Pteropus RimbaKuala LumpurMalaysia Helmholtz-Centre for Environmental Research-UFZ Department of Computational Landscape EcologyLeipzigGermany Ecology and Conservation Research Laboratory(Eco/Con Lab) Department of Biological SciencesCollege of Science and MathematicsUniversity of Southern MindanaoKabacanNorth CotabatoPhilippines Department of Biology Cornell CollegeMount VernonIowaUSA School of Biological Sciences The University of Hong KongPokfulamHong KongChina

Global biodiversity is currently in the midst of the sixth mass extinction,and countless species and their key ecosystem services are threatened across different habitats(Vos et al.2015).Constructive actions to address the negative impacts of changing conditions require rigorous biodiversity data integration and synthesis to inform effective policy-making decisions(Heberling et al.2021).Care is needed to ensure objectivity and remove biases in analyses to avoid generating misleading ***,Ramírez-Fráncel et al.(2022)published a review offering an update on the vital ecosystem services of bats on a global *** applaud the authors for their attempt to conduct an extremely challenging large-scale analysis in major areas of bat ecosystem services.

关键词： services global offering

Potentiostatic corrosion protection technology under cavitation condition for 5083-H116 Al alloy

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Transactions of Nonferrous Metals Society of China 2013年第11期23卷 3206-3214页

作者： Seung-Jun LEE Young-Soo PARK Seong-Jong kim Division of Marine Engineering Mokpo Maritime University Division of Maritime Transportation Science College of Maritime Sciences Korea Maritime and Ocean University

This study aims to characterize the cavitation damage behavior of aluminum alloys in seawater and thus to enhance its cavitation resistance. Potentiostatic experiments were performed under various potential conditions to determine the optimum protection potentials, at which cavitation damage was suppressed. A potential range was selected for the experiment from -2.2 to -1.4 V, which corresponded to the concentration and activation polarization regions on the cathodic polarization curve of the 5083-H116 alloy. After the experiments, the current density-time behavior was investigated, and the degree of surface damage was observed using three-dimensional microscopy and scanning electron microscopy （SEM）, The optimum protection potential was determined to be in the range of-l.9 to -1.5 V under which the cavitation damage was reduced significantly.

关键词： Al alloy cavitation potentiostatic experiment seawater

Retinoic acid enhances lactoferrin-induced IgA responses by increasing betaglycan expression

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Cellular & Molecular Immunology 2016年第6期13卷 862-870页

作者： Jeong-Min Lee Young-Saeng Jang Bo-Ra Jin Sun-Jin kim Hyeon-Jin kim Bo-Eun Kwon Hyun-Jeong Ko Sung-il Yoon Geun-Shik Lee Woan-Sub kim Goo-Young Seo Pyeung-Hyeun kim Department of Molecular Bioscience School of Biomedical Science Kangwon National University Chuncheon Republic of Korea Laboratory of Microbiology and Immunology College of Pharmacy Kangwon National University Chuncheon Republic of Korea Department of Systems Immunology College of Biomedical Science Kangwon National University Chuncheon 200-701 Republic of Korea College of Veterinary Medicine Kangwon National University Chuncheon Gangwon 200-701 Republic of Korea Department of Animal Life and Environmental Science College of Agriculture and Life Science Hankyong National University Anseong-si 456-749 Republic of Korea

Lactoferrin （LF） and retinoic acid （RA） are enriched in colostrum, milk, and mucosal tissues. We recently showed that LF-induced IgA class switching through binding to betaglycan （transforming growth factor-beta receptor III, TpRIII） and activation of canonical TGF-p signaling. We investigated the combined effect of LF and RA on the overall IgA response. An increase in IgA production by LF was further augmented by RA. This combination effect was also evident in Ig germ-line α （GLa） transcription and GLa promoter activity, indicating that LF in cooperation with RA increased IgA isotype switching. We subsequently found that RA enhanced TβRIII expression and that this increase contributed to LF-stimulated IgA production. In addition to the IgA response, LF and RA in combination also enhanced the expression of the gut-homing molecules C-C chemokine receptor 9 （CCR9） and a4β7 on B cells. Finally, peroral administration of LF and RA enhanced the frequency of CCR9＋ IgA＋ plasma cells in the lamina propria. Taken together, these results suggest that LF in cooperation with RA can contribute to the establishment of gut IgA responses.

关键词： gut homing molecule IgA lactoferrin retinoic acid TGF-β receptor