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Defect engineering of water-dispersible g-C_(3)N_(4) photocatalysts by chemical oxidative etching of bulk g-C_(3)N_(4) prepared in different calcination atmospheres

引用

Journal of Materials Science & Technology 2022年第8期103卷 232-243页

作者： Thi Kim Anh Nguyen Thanh-Truc Pham Bolormaa Gendensuren eun-suok oh eun Woo Shin School of Chemical Engineering University of UlsanDaehakro 93Ulsan 44610South Korea Department of Material Technology Faculty of Applied ScienceHo Chi Minh City University of Technology and Education(HCMUTE)No.1 Vo Van Ngan StreetLinh Chieu WardThu Duc DistrictHo Chi Minh City 700000Viet Nam

In this study,water-dispersible graphitic carbon nitride(g-C_(3)N_(4))photocatalysts were successively prepared through the chemically oxidative etching of bulk g-C_(3)N_(4) that was polymerized thermally in different calcination atmospheres such as air,CO_(2),and N_(2).The different calcination atmospheres directly influenced the physicochemical and optical properties of both bulk and water-dispersible g-C_(3)N_(4),changing the photocatalytic degradation behavior of methylene blue(MB)and tetracycline hydrochloride(TCHCl)for water-dispersible g-C_(3)N_(4).The bubble-burst process in the thermal polymerization of thiourea produced defective edges containing C=O groups that preferred substituting the C-NHx groups over bulk g-C_(3)N_(4).In the oxygen-free N_(2) atmosphere among the different calcination atmospheres,more C=O functional groups were generated on the defective edges of bulk g-C_(3)N_(4),resulting in the highest N vacancy of the tri-s-triazine structure.During the successive chemical oxidation,S-or O-containing functional groups were introduced onto water-dispersible g-C_(3)N_(4).The water-dispersible g-C_(3)N_(4) photocatalyst from the oxygen-free N_(2) atmosphere(NTw)contained the most O-and S-functional groups on the g-C_(3)N_(4) surface.Consequently,NTw exhibited the highest photocatalytic activity in the MB and TC-HCl photodegradation because of its slowest recombination process,which was ascribed to the unique surface properties of NTw such as abundant functional groups on the defective edges and N-deficient property.

关键词： g-C_(3)N_(4) Water-dispersible photocatalyst Calcination atmosphere Charge separation Chemically oxidative etching Defect edges

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