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Pore and fracture characteristics of Cretaceous tight reservoir and its control effect on hydrocarbon accumulation in the Liuhe Basin

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Petroleum Science 2022年第5期19卷 1939-1949页

作者： Wen-Hao Li er-qiang yang Min Wang Yan-Ran Huang Laboratory of Deep Oil and Gas China University of Petroleum(East China)QingdaoShandong266580China School of Geosciences China University of Petroleum(East China)QingdaoShandong266580China Hunan Provincial Key Laboratory of Shale Gas Resource Utilization Hunan University of Science and TechnologyXiangtanHunan411201China

Tight oil and gas in the Cretaceous has been found in the Liuhe Basin,but the rules of tight reservoir and oil and gas accumulation are not *** paper discusses the developmental characteristics and evolution law of pores and fractures in the Cretaceous tight reservoir in the Liuhe Basin,and reveals its controlling effect on tight oil and gas *** results show that intercrystalline pores,intergranular pores and dissolution pores are scattered and only developed in shallow tight reservoirs,while microfractures are developed in both shallow and deep layers,which are the main type of reservoir space in the study *** results of mercury intrusion porosimetry and nitrogen gas adsorption show that with the increase of depth,the proportion of macropores(microcracks)increases,while the proportion of micropores *** are two stages of microfractures developed in the study area,corresponding to the initial fault depression stage from late Jurassic to early late Cretaceous and compressional uplift at the end of late *** to the principle of“inversion and back-stripping method”,combined with the data of optical microscopy and inclusions,the time of each key diagenesis and its contribution to porosity are revealed,and the porosity evolution history of reservoirs in different diagenetic stages is quantitatively *** porosity reduction rate of compaction can reach more than 80%,which is the main reason for reservoir *** relationship between pore evolution history and oil and gas accumulation history reveals that during the oil and gas filling period of the Xiahuapidianzi Formation(90-85 Ma),the reservoir porosity is only 1.15%,but the development of microfractures in the first stage of the reservoir is conducive to oil and gas accumulation.

关键词： Tight reservoir Microscopic pore structure Microfracture Porosity evolution Hydrocarbon accumulation the liuhe Basin

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Self-assembly Induced by Complexation of Diblock Copolyelectrolytes and Oppositely Charged Homopolymers

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Chinese Journal of Polymer Science 2024年第9期42卷 1321-1332,I0006页

作者： Ling Zhao Zhi-Yuan Yin Jia-Di Jiang er-qiang Chen Shuang yang Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of EducationCenter for Soft Mater Science and EngineeringCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China

We investigate the solution self-assembly of a mixture of positively charged homopolymers and AB diblock copolymers,in which the A blocks are negatively charged,and the B blocks are *** electrostatic complexation between oppositely charged polymers drives the formation of many ordered *** microstructures and phase diagrams are calculated using self-consistent field theory(SCFT)based on an ion-pair model with an equilibrium constant K to characterize the strength of binding between positively and negatively charged *** effects of the charge ratio,representing the ratio of charges from the homopolymer over all charges from polymers in the system,on the ordered structure are systematically studied,both for hydrophobic and hydrophilic A *** charge ratio plays an important role in determining the phase boundaries in the phase diagram of salt concentration versus polymer *** also provide information about the varying tendency of the domain spacing and core size of the spherical phase when the charge ratio is changed,and the results are in good agreement with *** studies provide a deep understanding of the self-assembled microstructures of oppositely charged diblock copolymer-homopolymer systems.

关键词： Self-assembly Polyelectrolyte complexation Self-consistent field theory Ion-pair

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Comparison of engineering failures and seismic responses of 500 kV transformer-bushing systems in the 2022 Luding earthquake

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Earthquake Engineering and Engineering Vibration 2024年第4期23卷 1029-1041页

作者： Zhu Wang Wu Ming’er Xie qiang Department of Structural Engineering Tongji UniversityShanghai 200092China Key Laboratory of Performance Evolution and Control for Engineering Structures(Tongji University) Shanghai 200092China

Cemented and mechanically clamped types of end fittings(fitting-C and fitting-M)are commonly used in transformer *** the Luding Ms 6.8 earthquake that occurred in China on September 5,2022,all transformer bushings with the two types of end fittings in a 500 kV substation were ***-earthquake field investigations were conducted,and the failures of the two types of bushings were *** elementary simulation models of the transformer-bushing systems were developed to simulate the engineering failures,and further compute their seismic responses for *** results indicate that the hitch lugs of the connection flange are structurally harmful to seismic ***-M can decrease the bending stiffness of the bushing due to the flexible sealing rubber *** it provides a more flexible connection that dissipates energy,the peak accelerations and relative displacements at the top of the bushing are significantly lower than those of the bushing with *** with fitting-C,fitting-M transfers the high-stress areas from the connection flange to the root of the porcelain,so the latter becomes the most vulnerable ***-M increases the failure risk of the low-strength porcelain,indicating the unsuitability of applying it in high-intensity fortification regions.

关键词： transformer bushing end fitting Luding earthquake,engineering failure seismic responses

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Distribution and isotopic signature of 2-alkyl-1,3,4-trimethylbenzenes in the Lower Paleozoic source rocks and oils of Tarim Basin:Implications for the oil-source correlation

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Petroleum Science 2022年第6期19卷 2572-2582页

作者： Tao-Hua He Wen-Hao Li Shuang-Fang Lu er-qiang yang Tao-Tao Jing Jun-Feng Ying Peng-Fei Zhu Xiu-Zhe Wang Wen-Qing Pan Zhong-Hong Chen Key Laboratory of Oil and Gas Resources and Exploration Technology Yangtze UniversityWuhanHubei430100China School of Geosciences China University of Petroleum(East China)QingdaoShandong266580China Key Laboratory of Deep Oil and Gas China University of Petroleum(East China)QingdaoShandong266580China Sanya Offshore Oil&Gas Research Institute Northeast Petroleum UniversitySanyaHainan 572025China Petroleum Exploration&Production Research Institute Tarim Oilfield CompanyPetro ChinaKorlaXinjiang841000China

Series of 2-alkyl-1,3,4-trimethylbenzenes(ATMBs)were detected in most of crude oils and source rocks collected from various strata and locations of the Tarim *** appeared to have heavy carbon isotopic signatures(δ13C,up to~-16‰)compared to those hydrocarbons from oxygenic phototrophic organisms,indicating that the unequivocal source of green sulfur bacteria(GSB)and photic zone euxinia(PZE)existed in the original *** the high paleoproductivity,the PZE may have enhanced the preservation of organic matter,which triggered the formation of extremely organic-rich source rocks with TOC up to 29.8%for the Lower Cambrian Yuertus Formation(€1y).The coexistence of ATMBs and the diagnostic products from secondary alterations(e.g.,abundant 25-norhopanes,thiadiamondoids,and diamondoids)indicated a stronger ability of *** with the results of quantitatively de-convoluting mixed oil,the oil-source correlation based on ATMBs from a large number of Lower Paleozoic samples of the Tarim Basin suggested that the abundant deep crude oil resources co ntained a dominant contribution(>50%)from the€1y source ***,the ATMBs,as diagnostic biomarkers indicating unequivocal precursors under special habitat conditions,might provide important insights for the exploration of deep Lower Paleozoic crude oils in the Tarim Basin.

关键词： 2-alkyl-1,3,4-trimethylbenzenes Carbon isotopes Deep lower paleozoic crude oils Thiadiamondoid Oil-source correlation Tarim Basin

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Quantitatively unmixing method for complex mixed oil based on its fractions carbon isotopes: A case from the Tarim Basin, NW China

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Petroleum Science 2023年第1期20卷 102-113页

作者： Tao-Hua He Wen-Hao Li Shuang-Fang Lu er-qiang yang Tao-Tao Jing Jun-Feng Ying Peng-Fei Zhu Xiu-Zhe Wang Wen-Qing Pan Bao-Shou Zhang Zhong-Hong Chen Key Laboratory of Oil and Gas Resources and Exploration Technology Yangtze UniversityWuhanHubei 430100China School of Geosciences China University of Petroleum(East China)QingdaoShandong266580China Sanya Offshore Oil&Gas Research Institute Northeast Petroleum UniversitySanyaHainan 572025China Petroleum Exploration&Production Research Institute Tarim Oilfield CompanyPetroChinaKorlaXinjiang841000China Key Laboratory of Deep Oil and Gas China University of Petroleum(East China)QingdaoShandong266580China

Deep mixed oils with secondary alterations have been widely discovered in the Tarim Basin,but current methods based on biomarkers and isotopes to de-convolute mixed oil cannot calculate the exact mixing proportion of different end-member oils,which has seriously hindered further exploration of deep hydrocarbons in the study *** solve this problem,we constructed a novel method based on the carbon isotope(δ13C)of the group components to de-convolute mixed liquid hydrocarbons under the material balance *** results showed that the mixed oil in the Tazhong Uplift was dominantly contributed at an average proportion of 68% by an oil end-member with heavier d13C that was believed to be generated from the Cambrian-Lower Ordovician source rocks,whereas the mixed oil in the Tabei Uplift was predominantly contributed at an average proportion of 61% by an oil end-member with lighter d13C that was believed to be generated from the Middle-Upper Ordovician source *** indicates that,on the basis of the detailed description of the distribution of effective source rocks,the proposed method will be helpful in realizing differential exploration and further improving the efficiency of deep liquid hydrocarbon exploration in the Tarim *** addition,compared to traditional δ13C methods for whole oil and individual n-alkanes in de-convoluted mixed oil,the proposed method has a wider range of applications,including for mixed oils with variations in color and density,indicating potential for promoting the exploration of deep complex mixed oils in the Tarim Basin and even around the world.

关键词： Mixed crude oil Carbon isotopes End-member oil De-convolution Secondary alteration Tarim Basin

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Highly efficient room temperature phosphorescent liquid crystalline polymer optical waveguides for advanced optoelectronics

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Science China Chemistry 2024年第10期67卷 3450-3457页

作者： Jie Li Yan Guan Wei Xia Jin-Kang Chen Jiang Huang Yi Chen Qi Lin er-qiang Chen He-Lou Xie Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education and Key Laboratory of Advanced Functional Polymer Materials of CollegesUniversities of Hunan Province and College of ChemistryXiangtan UniversityXiangtan 411105China School of Physics and Optoelectronics Xiangtan UniversityXiangtan 411105China Beijing National Laboratory for Molecular Sciences Key Laboratory of Polymer Chemistry and Physics of Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China

Active organic optical waveguide materials(OOWMs)incorporating room temperature phosphorescence(RTP)hold significant promise for diverse applications in photonic and optoelectronic *** this potential,realizing active RTP optical waveguides with large-sized ordered structures and minimal light loss remains a formidable *** address this issue,we present a groundbreaking thermoplastic active OOWM with low light loss,leveraging room temperature phosphorescent liquid crystalline polymer(LCP).This innovative material can be easily synthesized through the copolymerization of phosphorescent and liquid crystalline *** resulting RTP copolymer exhibits a nematic liquid crystal phase with a phosphorescence lifetime of approximately 0.15 ms and an afterglow duration of around 1 *** the excellent processability of LCP,we successfully produce meter-scale fibers via melt *** RTP LCP fibers,characterized by a high orientation of mesogens along the fiber axis,demonstrate superior light confinement and efficient light conduction compared to unoriented samples,resulting in a low optical loss coefficient of 0.13 dB/***,the thermal responsiveness of the RTP LCP optical waveguide enables its use as a photo *** pioneering work paves the way for the design of new OOWMs tailored for advanced photonics and optoelectronics devices.

关键词： room temperature phosphorescence liquid crystalline polymer active optical waveguide

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Current understanding of ELF4 deficiency:a novel inborn error of immunity

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World Journal of Pediatrics 2024年第5期20卷 444-450页

作者： Hong-qiang Du Xiao-Dong Zhao Department of Rheumatology&Immunology National Clinical Research Center for Child Health and DisordersMinistry of Education Key Laboratory of Child Development and DisordersChongqing Key Laboratory of Child Rare Diseases in Infection and ImmunityChildren’s Hospital of Chongqing Medical UniversityZhongshan Er Road 136Yuzhong DistrictChongqingChina

Background ELF4 deficiency has been recently recognized as a novel disorder within the spectrum of inborn errors of immunity(IEIs),specifically categorized as a“disease of immune dysregulation.”Cases of this condition,reported by our team and others,are very limited *** such,our current knowledge of this new disease remains *** review aims to provide a brief overview of the clinical manifestations,pathogenesis,and treatment strategies for this novel *** sources A comprehensive review was conducted after an extensive literature search in the PubMed/Medline database and websites concerning transcriptional factor ELF4 and reports concerning patients with ELF4 *** search strategy was“ELF4 OR ETS-related transcription factor Elf-4 OR EL4-like factor 4 OR myeloid Elf-1-like factor”as of the time of manuscript *** The current signature manifestations of ELF4 deficiency disorder are recurrent and prolonged oral ulcer,abdominal pain,and diarrhea in pediatric *** some cases,immunodeficiency and autoimmunity can also be *** Sanger sequencing or whole exome sequencing can be used to detect variation in ELF4 *** blotting for ELF4 expression of the patient’s cells can confirm the pathogenic effect of the *** fully confirm the pathogenicity of the variant,further functional test is strongly *** and biologics are the mainstream management of ELF4 deficiency *** Pediatric males presenting with recurring ulcerations in digestive tract epithelium with or without recurrent fever should be suspected of *** atypical presentations are prominent,variations in ELF4 gene should be carefully evaluated functionally due to the complex nature of ELF4 *** of treating DEX includes use of glucocorticoid and biologics and more precise treatment needs more patients to identify and further mechanistic study.

关键词： ELF4 transcription factor Immune dysregulation Inborn errors of immunity Mechanism Recurrent infections

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Single-cell analysis of tumor microenvironment and cell adhesion reveals that interleukin-1 beta promotes cancer cell proliferation in breast cancer

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Animal Models and Experimental Medicine 2024年第05期 617-625页

作者： Wenyan Wang Gehong Dong Ziguo yang Shaoxiang Li Jia Li Lin Wang qiang Zhu Yuchen Wang Department of General Surgery Beijing Tiantan Hospital Capital Medical University Department of Pathology Beijing Tiantan Hospital Capital Medical University Department of Pharmacology Institute of Materia Medica Chinese Academy of Medical Sciences and Peking Union Medical College

Background: Triple-negative breast cancer(TNBC), which is so called because of the lack of estrogen receptors(er), progesterone receptors(PR), and human epidermal growth factor receptor 2(Her2) receptors on the cancer cells, accounts for 10%–15% of all breast cancers. The heterogeneity of the tumor microenvironment is ***, the role of plasma cells controlling the tumor migration progression in TNBC is still not fully ***: We analyzed single-cell RNA sequencing data from five Her2 positive, 12er positive/PR positive, and nine TNBC samples. The potential targets were validated by ***: Plasma cells were enriched in TNBC samples, which was consistent with validation using data from The Cancer Genome Atlas. Cell communication analysis revealed that plasma cells interact with T cells through the intercellular adhesion molecule 2–integrin–aLb2 complex, and then release interleukin 1 beta(IL1B), as verified by immunohistochemistry, ultimately promoting tumor ***: Our results revealed the role of plasma cells in TNBC and identified IL1B as a new prognostic marker for TNBC.

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产业链与创新链融合发展:内涵、动力与路径

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南京社会科学 2024年第2期 27-37页

作者：巫强胡蕾蒋真儿南京大学江苏数字经济研究院、长三角经济社会发展研究中心南京210093 南京大学长江产业经济研究院中共安徽省委党校(安徽行政学院)乡村振兴教研部合肥230022 南京大学长三角经济社会发展研究中心南京210093

产业链与创新链融合发展是我国进入新发展阶段后,应对世界百年未有之大变局与全球价值链产业链重构的必然选择,也是我国加快实现高水平科技自立自强,构建双循环新发展格局的关键举措。马克思主义社会再生产理论、科技创新与产业创新历... 详细信息

产业链与创新链融合发展是我国进入新发展阶段后,应对世界百年未有之大变局与全球价值链产业链重构的必然选择,也是我国加快实现高水平科技自立自强,构建双循环新发展格局的关键举措。马克思主义社会再生产理论、科技创新与产业创新历史规律,以及我国产业迈向全球价值链中高端的历程都证明,产业链创新链融合存在历史必然性。产业链与创新链融合发展要求以实体经济为基础,以科技创新为动力,以协同创新为依托,以产业链供应链自主可控为目标,实现科技创新与产业发展的精准对接。其动力来源于释放微观主体的自发推动力和发挥政策改革推动力,实现路径包括加强基础研究与原始创新,推进政产学研用深度融合,强化企业创新主体地位,发挥数字技术在产业链创新链融合中的黏合剂功能等。

关键词：产业链创新链融合发展

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Direct measurement of the break-out ^(19)F(p,γ)^(20)Ne reaction in the China Jinping underground laboratory(CJPL)

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Nuclear Science and Techniques 2024年第8期35卷 142-152页

作者： Yin‑Ji Chen Hao Zhang Li‑Yong Zhang Jian‑Jun He Richard James deBoer Michael Wiescher Alexander Heger David Kahl Jun Su Daniel Odell Xin‑Yue Li Jian‑Guo Wang Long Zhang Fu‑qiang Cao Zhi‑Cheng Zhang Xin‑Zhi Jiang Luo‑Huan Wang Zi‑Ming Li Lu‑yang Song Liang‑Ting Sun Qi Wu Jia‑Qing Li Bao‑Qun Cui Li‑Hua Chen Rui‑Gang Ma er‑Tao Li Gang Lian Yao‑De Sheng Zhi‑Hong Li Bing Guo Wei‑Ping Liu Key Laboratory of Beam Technology of the Ministry of Education College of Nuclear Science and TechnologyBeijing Normal UniversityBeijing 100875China Department of Physics and Astronomy The Joint Institute for Nuclear AstrophysicsUniversity of Notre DameNotre DameIN 46556USA School of Physics and Astronomy Monash UniversityClaytonVIC 3800Australia Facility for Rare Isotope Beams Michigan State UniversityEast LansingMI 48824USA Institute of Nuclear and Particle Physics and Department of Physics and Astronomy Ohio UniversityAthensOH 45701USA Institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China China Institute of Atomic Energy Beijing 102413China College of Physics and Optoelectronic Engineering Shenzhen UniversityShenzhen 518060China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China College of Science Southern University of Science and TechnologyShenzhen 518055China Institute of Radiation Technology Beijing Academy of Science and TechnologyBeijing 100875China Key Laboratory of Nuclear Physics and Ion‑Beam Application(MOE) Institute of Modern PhysicsFudan UniversityShanghai 200433China School of Mathematics and Physics Handan UniversityHandan 056005China

Calcium production and the stellar evolution of first-generation stars remain fascinating mysteries in *** one possible nucleosynthesis scenario,break-out from the hot carbon–nitrogen–oxygen(HCNO)cycle was thought to be the source of the calcium observed in these oldest ***,according to the stellar modeling,a nearly tenfold increase in the thermonuclear rate ratio of the break-out ^(19)F(p,γ)^(20) Ne reaction with respect to the competing ^(19)F(p,α)^(16) O back-processing reaction is required to reproduce the observed calcium *** performed a direct measurement of this break-out reaction at the China Jinping underground *** measurement was performed down to the low-energy limit of E_(c.m.)=186 keV in the center-of-mass *** key resonance was observed at 225.2 keV for the first *** a temperature of approximately 0.1 GK,this new resonance enhanced the thermonuclear ^(19)F(p,γ)^(20) Ne rate by up to a factor of≈7.4,compared with the previously recommended NACRE *** is of particular interest to the study of the evolution of the first stars and implies a stronger breakdown in their“warm”CNO cycle through the ^(19)F(p,γ)^(20) Ne reaction than previously *** break-out resulted in the production of the calcium observed in the oldest stars,enhancing our understanding of the evolution of the first stars.

关键词： Nuclear astrophysics First stars Abundance of calcium Reaction cross section Reaction rate China Jinping underground laboratory(CJPL) JUNA

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