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Advancements in Polymer Science: Synthesis, Characterization, and Biomedical Applications of Homopolymers and Copolymers

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Open Journal of Polymer Chemistry 2024年第3期14卷 167-198页

作者： Anaif M. Alhewaitey Ishrat Khan emmanuel Ramsey Buabeng Department of Chemistry Clark Atlanta University Atlanta USA Department of Chemistry University of Tabuk Tabuk Saudi Arabia Department of Chemistry Georgia State University Atlanta GA USA

Polymer science encompasses a different range of materials critical to industries spanning from packaging to biomedicine. Understanding the synthesis, characterization, and applications of common homopolymers and copolymers is fundamental to advancing polymer research and development. In this comprehensive review, we explore various preparation methods, including free radical, anionic, and cationic polymerization, utilized for synthesizing homopolymers and copolymers. Furthermore, we investigate solvent choices commonly employed for polymer characterization, ranging from neat conditions, polar protic and polar aprotic solvents. We also explored characterization techniques, including Fourier Transform Infrared Spectroscopy (FTIR), Nuclear Magnetic Resonance (NMR), Atomic Force Microscopy (AFM), Differential Scanning Calorimetry (DSC), and Thermogravimetric Analysis (TGA). In addition to industrial applications, we highlight the diverse biological applications of homopolymers, poly(2-hydroxyethyl methacrylate) (pHEMA) and polystyrene, which find its extensive use in biomedicine. By synthesizing and analyzing this wealth of information, this review aims to provide a comprehensive understanding of the synthesis, characterization, and applications of homopolymers and copolymers, with a particular focus on their biological applications. This holistic approach not only contributes to advancements in polymer science and technology but also fosters innovation in biomedicine, ultimately benefiting human health and well-being.

关键词： Homopolymer Copolymer Poly(2-hydroxyethyl methacrylate) (pHEMA) Polystyrene Free Radical Polymerization Atomic Force Microscopy Solvent Polarity

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Coverage and determinants of infant postnatal care in Nigeria:A population-based cross-sectional study

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Pediatric Investigation 2024年第1期8卷 27-36页

作者： Bolaji emmanuel Egbewale Olusola Oyedeji Jesse Bump Christopher Robert Sudfeld Department of Global Health and Population Takemi Program in International HealthHarvard T.H.Chan School of Public HealthBostonMassachusettsUSA Department of Community Medicine College of Health SciencesLadoke Akintola University of TechnologyOgbomosoNigeria Department of Pediatrics and Child Health College of Health SciencesLadoke Akintola University of TechnologyOgbomosoNigeria

Importance:In 2019,Nigeria had the largest number of under-5 child deaths globally and many of these deaths occurred within the first week of *** World Health Organization recommends infant postnatal care(PNC)attendance to support newborn survival;however,utilization of PNC is known to be low in many ***:This study examined coverage and individual-level determinants of infant PNC attendance in ***:Nigeria Demographic Health Survey(NDHS)2018 data were used to evaluate infant PNC coverage and *** PNC was defined as receipt of care within 2 days of *** delivered up to 2 years before the 2018 NDHS were *** examined predictors of infant PNC with modified Poisson regression models to estimate relative risks(RRs).Results:The national coverage of infant PNC was 37.3%(95%confidence interval[CI]:35.8%–38.7%).Significant heterogeneity in PNC attendance existed at state and regional *** delivery was strongly associated with the uptake of PNC(RR:6.07;95%CI:5.60–6.58).Greater maternal education,maternal employment,urban residence,female head of household,and greater wealth were also associated with an increased likelihood of PNC ***:The uptake of infant PNC is low and interventions are urgently needed to promote equity in access and increase demand for PNC in Nigeria.

关键词： Infant postnatal care Epidemiology Coverage Determinants Nigeria

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The Impacts and Causes of Land Fragmentation on Farm Productivity: Case Review of East African Countries

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Open Journal of Ecology 2024年第5期14卷 455-482页

作者： Joseph Mayindo Mayele Jacob B. Kolleh Joel emmanuel Saburi Department of Agricultural and Resource Economics The University of Tokyo Tokyo Japan Department of Forestry and Wildlife College of Natural Resources and Environmental Studies University of Juba Juba South Sudan Department of Socio-Economic and Applied Statistics Central Agricultural Research Institute (CARI) Suakoko Liberia

This report provides an overall assessment of land fragmentation problems in East Africa. Many parts of East Africa have become highly fragmented, putting development systems and activities in these areas at risk of complete collapse. Land fragmentation occurs when land gets converted for agriculture, industrialization, or urbanization, invaded by non-local plants, or enclosed for individual use and by subdividing farmlands into subsequent smaller units called parcels with varying average farm sizes. Fragmentation results from inappropriate agricultural development processes and ineffective land use planning that fails to recognize how farmland is used, and the importance of its interconnected areas. Insecurity of tenure and resource rights are key factors in making this possible. Land fragmentation is one of the key reasons why the ability of most resources in East Africa becomes scarcer, and those remaining become “privatized” by more powerful community members—keen to maintain their access to them. Such individualistic attitudes are new and disadvantage the poorest even further by affecting the traditional customary safety nets and agricultural outputs. Neither the government nor customary governance systems effectively protect resource access for the poorest. This review summary report identifies the key causes, measures, and implications, government interventions, and the common remedies to land fragmentation problems in the East African Countries of Kenya, Uganda, Rwanda, and Tanzania including neighboring Ethiopia, and the Sudan. The findings indicated from 2005 to 2015, the population kept increasing for all the named countries in East Africa with Rwanda and Uganda having a substantial increase in population density. The study review further explores the trend in the performance of agriculture by average farm sizes within the intervals of five years by highlighting their strong linkages and found that the average farm size has declined drastically, especiall

关键词： Land Fragmentation Land Consolidation Farm Productivity Industrialization Impacts Causes Average Farm Size Population East Africa

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Fermat and Pythagoras Divisors for a New Explicit Proof of Fermat’s Theorem:a⁴ + b⁴ = c⁴. Part I

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Advances in Pure Mathematics 2024年第4期14卷 303-319页

作者： Prosper Kouadio Kimou François emmanuel Tanoé Kouassi Vincent Kouakou Laboratoire d’ Informatique et de Math&#233matiques appliqu&#233es Institut Polytechnique F&#233lix Houphou&#235t BOIGNY Yamoussoukro Cote d&#8217Ivoire UFR Mathé matiques et Informatique Universit&#233 F&#233lix Houphouet BOIGNY Abidjan Cote d&#8217Ivoire UFR Sciences Fondamentales Appliqué es Universit&#233 NANGUI ABROGOUA Abidjan Cote d&#8217Ivoire

In this paper we prove in a new way, the well known result, that Fermat’s equation a4 + b4 = c4, is not solvable in ℕ , when abc≠0 . To show this result, it suffices to prove that: ( F 0 ): a 1 4 + ( 2 s b 1 ) 4 = c 1 4 , is not solvable in ℕ , (where a 1 , b 1 , c 1 ∈2ℕ+1 , pairwise primes, with necessarly 2≤s∈ℕ ). The key idea of our proof is to show that if (F0) holds, then there exist α 2 , β 2 , γ 2 ∈2ℕ+1 , such that ( F 1 ): α 2 4 + ( 2 s−1 β 2 ) 4 = γ 2 4 , holds too. From where, one conclude that it is not possible, because if we choose the quantity 2 ≤ s, as minimal in value among all the solutions of ( F 0 ) , then ( α 2 ,2 s−1 β 2 , γ 2 ) is also a solution of Fermat’s type, but with 2≤s−10) is solvable in ( a 1 ,2 s b 1 , c 1 ) , s ≥ 2 like above;afterwards, proceeding with “Pythagorician divisors”, we creat the notions of “Fermat’s b-absolute divisors”: ( d b , d ′ b ) which it uses hereafter. Then to conclude our proof, we establish the following main theorem: there is an equivalence between (i) and (ii): (i) (F0): a 1 4 + ( 2 s b 1 ) 4 = c 1 4 , is solvable in ℕ , with 2≤s∈ℕ , ( a 1 , b 1 , c 1 )∈ ( 2ℕ+1 ) 3 , coprime in pairs. (ii) ∃( a 1 , b 1 , c 1 )∈ ( 2ℕ+1 ) 3 , coprime in pairs, for wich: ∃( b ′ 2 , b 2 , b ″ 2 )∈ ( 2ℕ+1 ) 3 coprime in pairs, and 2≤s∈ℕ , checking b 1 = b ′ 2 b 2 b ″ 2 , and such that for notations: S=s−λ( s−1 ) , with λ∈{ 0,1 } defined by c 1 − a 1 2 ≡λ( mod2 ) , d b =gcd( 2 s b 1 , c 1 − a 1 )= 2 S b 2 and d ′ b = 2 s−S b ′ 2 = 2 s B 2 d b , where ( 2 s B 2 ) 2 =gcd( b 1 2 , c 1 2 − a 1 2 ) , the following system is checked: { c 1 − a 1 = d b 4 2 2+λ = 2 2−λ ( 2 S−1 b 2 ) 4 c 1 + a 1 = 2 1+λ d ′ b 4 = 2 1+λ ( 2 s−S b ′ 2 ) 4 c 1 2 + a 1 2 =2 b ″ 2 4;and this system implies: ( b 1−λ,2 4 ) 2 + ( 2 4s−3 b λ,2 4 ) 2 = ( b ″ 2 2 ) 2;where: ( b 1−λ,2 , b λ,2 , b ″ 2 )={ ( b ′ 2 , b 2 , b ″ 2 ) if λ=

关键词： Factorisation in ℤ Greatest Common Divisor Pythagoras Equation Pythagorician Triplets Fermat's Equations Pythagorician Divisors Fermat's Divisors Diophantine Equations of Degree 2 4-Integral Closure of ℤ in ℚ

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Quintom cosmology and modified gravity after DESI 2024

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Science Bulletin 2024年第17期69卷 2698-2704页

作者： Yuhang Yang Xin Ren Qingqing Wang Zhiyu Lu Dongdong Zhang Yi-Fu Cai emmanuel N.Saridakis Department of Astronomy School of Physical SciencesUniversity of Science and Technology of ChinaHefei 230026China CAS Key Laboratory for Researches in Galaxies and Cosmology School of Astronomy and Space ScienceUniversity of Science and Technology of ChinaHefei 230026China Deep Space Exploration Laboratory Hefei 230088China Department of Physics Tokyo Institute of TechnologyTokyo 152-8551Japan Kavli IPMU(WPI) UTIASThe University of TokyoChiba 277-8583Japan National Observatory of Athens Lofos Nymfon 11852Greece Departamento de Matemáticas Universidad Católica del NorteAntofagasta 1270398Chile

We reconstruct the cosmological background evolution under the scenario of dynamical dark energy through the Gaussian process approach,using the latest Dark Energy Spectroscopic Instrument(DESI)baryon acoustic oscillations(BAO)combined with other *** results reveal that the reconstructed dark-energy equation-of-state(EoS)parameter w(z)exhibits the so-called quintom-B behavior,crossing-1 from phantom to quintessence regime as the universe *** investigate under what situation this type of evolution could be achieved from the perspectives of field theories and modified *** particular,we reconstruct the corresponding actions for f(R),f(T),and f(Q)gravity,*** explicitly show that,certain modified gravity can exhibit the quintom dynamics and fit the recent DESI data efficiently,and for all cases the quadratic deviation from theΛCDM scenario is mildly favored.

关键词： DESI Dark energy Quintom cosmology Modified gravity

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Evaluating the Impacts of Human Activities on Diversity, Abundance, and Distribution of Large Mammals in Nimule National Park, South Sudan

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Open Journal of Ecology 2024年第5期14卷 483-507页

作者： Abdallah Gordon Shazali Joseph Mayindo Mayele Joel emmanuel Saburi Jubara Nadlin Department of Wildlife College of Natural Resources and Environmental Studies University of Juba Juba South Sudan Department of Environment and Natural Resources School of Forestry Environmental and Geographical Sciences College of Agricultural and Environmental Sciences Makerere University Kampala Uganda Department of Forestry College of Natural Resources and Environmental Studies University of Juba Juba South Sudan Department of Agricultural and Resource Economics The University of Tokyo Tokyo Japan

Globally, human activities have a significant impact on the diversity, abundance, and distribution of large mammals in Protected Areas (PAs). These disturbances increase human pressure on biodiversity and species habitats, highlighting the need for conservation. This study aimed to assess the abundance and distribution of large mammals in different habitat types within Nimule National Park (NNP) and understand the impacts of human activities on them. Data on the abundance and distribution of large mammals and their respective habitat types were collected through line transect surveys. Human activity signs were observed and recorded along the transect lines. To estimate the impacts of human activities on the diversity, abundance, and distribution of large mammal species, as well as to identify any significant differences between them and their habitat types, the study utilized the Kruskal Wallis test, Polynomial multiple regressions, and diversity indices. The findings from the Shannon-Weiner and Simpson indices indicated that large mammal species were more diverse inside the park (H’ = 1.136;D = 0.570) compared to the buffer zone (H’ = 0.413;D = 0.171), with 85% (443 out of 510 samples) recorded within Nimule National Park. The species abundance showed a semi-balanced status (0.58). The diversity results among different habitat types revealed that large mammals were more diverse and highly distributed in both open woodlands (244) and dense woodlands (192), while riverine vegetation had the lowest diversity (8). Statistical tests demonstrated a highly significant difference at a 99% confidence interval (p-value = 0.01) between habitat types and identified species of large mammals. Additionally, the results highlighted the high abundance of Uganda kob (274), baboons (141), and warthog (57) across most habitat types, accounting for at least 75% of their distribution. The most prevalent human activities observed were cattle footprints (27%) and cattle dung (14%). Human

关键词： Diversity of Large Mammals Abundance and Distribution Impacts Biodiversity Conservation Human Activities Nimule National Park South Sudan

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COVID-19 vaccination produces exercise-responsive SARS-CoV-2 specific T-cells regardless of infection history

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Journal of Sport and Health Science 2024年第1期13卷 99-107页

作者： Kyle A.Smith Tiffany M.Zúñiga Forrest L.Baker Helena Batatinha Charles R.Pedlar Shane C.Burgess Michael P.Gustafson emmanuel Katsanis Richard J.Simpson School of Nutritional Sciences and Wellness The University of ArizonaTucsonAZ 85721USA Department of Pediatrics The University of ArizonaTucsonAZ 85724USA Faculty of Sport Allied Health and Performance ScienceSt.Mary's UniversityTwickenham TW14SXUK Institute of Sport Exercise and Health University College LondonLondon WC1E 7HUUK Department of Animal and Comparative Biomedical Sciences The University of ArizonaTucsonAZ 85721USA The University of Arizona Cancer Center The University of ArizonaTucsonAZ 85719USA Laboratory Medicine and Pathology Mayo Clinic ArizonaPhoenixAZ 85054USA Department of Immunobiology The University of ArizonaTucsonAZ 85724USA Department of Medicine The University of ArizonaTucsonAZ 85724USA Department of Pathology The University of ArizonaTucsonAZ 85724USA

Background:The mobilization and redistribution of severe acute respiratory syndrome coronavirus 2(SARS-CoV-2)specific T-cells and neutralizing antibodies(nAbs)during exercise is purported to increase immune surveillance and protect against severe coronavirus disease 2019(COVID-19).We sought to determine if COVID-19 vaccination would elicit exercise-responsive SARS-CoV-2 T-cells and transiently alter nAb ***:Eighteen healthy participants completed a 20-min bout of graded cycling exercise before and/or after receiving a COVID-19 *** major leukocyte subtypes were enumerated before,during,and after exercise by flow cytometry,and immune responses to SARS-CoV-2 were determined using whole blood peptide stimulation assays,T-cell receptor(TCR)-βsequencing,and SARS-CoV-2 nAb ***:COVID-19 vaccination had no effect on the mobilization or egress of major leukocyte subsets in response to intensity-controlled graded ***,non-infected participants had a significantly reduced mobilization of CD4+and CD8+naive T-cells,as well as CD4+central memory T-cells,after vaccination(synthetic immunity group);this was not seen after vaccination in those with prior SARS-CoV-2 infection(hybrid immunity group).Acute exercise after vaccination robustly mobilized SARS-CoV-2 specific T-cells to blood in an intensity-dependent *** groups mobilized T-cells that reacted to spike protein;however,only the hybrid immunity group mobilized T-cells that reacted to membrane and nucleocapsid *** increased significantly during exercise only in the hybrid immunity ***:These data indicate that acute exercise mobilizes SARS-CoV-2 specific T-cells that recognize spike protein and increases the redistribution of nAbs in individuals with hybrid immunity.

关键词： Anti-viral COVID-19 Exercise immunology SARS-CoV-2 T-Cells Vaccine

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Geospatial Variability of Cholera Cases in Malawi Based on Climatic and Socioeconomic Influences

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Journal of Geographic Information System 2024年第1期16卷 1-20页

作者： emmanuel Chinkaka Francis Chauluka Ruth Chinkaka Billy Kachingwe Esther Banda Latif Department of Geography and Spatial Sciences University of Delaware Newark USA Department of Earth Sciences Malawi University of Science and Technology Limbe Malawi Department of Water Resources Management Malawi University of Science and Technology Limbe Malawi Department of Obstetrics and Gynecology Queen Elizabeth Central Hospital Blantyre Malawi Department of Public Health Nkhoma Mission Hospital Nkhoma Malawi

Cholera remains a public health threat in most developing countries in Asia and Africa including Malawi with seasonal recurrent outbreaks. Malawi’s recent Cholera outbreak in 2022 and 2023, exhibited higher morbidity and mortality rates than the past two decades. Lack of spatiotemporal-based technology and variability assessment tools in Malawi’s Cholera monitoring and management, limit our understanding of the disease’s epidemiology. The present work developed a spatiotemporal variability model for Cholera disease at district level and its relationship to socioeconomic and climatic factors based on cumulative confirmed Cholera cases in Malawi from March 2022 to July 2023 using Z-score statistic and multiscale geographically weighted regression (MGWR) in a Geographical Information System (GIS). We found out that socioeconomic factors such as access to safe drinking water, population density and poverty level, and climatic factors including temperature and rainfall strongly influenced Cholera prevalence in a complex and multifaceted manner. The model shows that Lilongwe, Mangochi, Blantyre and Balaka districts were highly vulnerable to Cholera disease followed by lakeshore districts of Salima, Nkhotakota, Nkhata-Bay and Karonga than other districts. We recommend strategic measures such as Water, Sanitation, and Hygiene (WASH) interventions, community awareness on proper water storage, Cholera case management, vaccination campaigns and spatial-based surveillance systems in the most affected districts. This research has shown that MGWR, as a surveillance system, has the potential of providing insights on the disease’s spatial patterns for public health authorities to identify high-risk districts and implement early response interventions to reduce the spread of the disease.

关键词： Cholera Geospatial Variability Prevalence GIS MGWR Vulnerability Malawi

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Theoretical Assessment of Environmental Factors and Untreated Infectious Individuals in the Transmission Dynamics of Buruli ulcer

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Applied Mathematics 2024年第8期15卷 477-498页

作者： Codjo Cesaire Yadouleton Myriam Djoukwe Tapi Judicael Deguenon Ghislain emmanuel Sopoh International Chair in Mathematical Physics and Applications University of Abomey-Calavi Abomey-Calavi Benin Department of Mathematics and Computer Science Faculty of Science University of Douala Douala Cameroon Polytechnic School of Abomey-Calavi University of Abomey-Calavi Abomey-Calavi Benin Regional Institute for Public Health University of Abomey-Calavi Abomey-Calavi Benin

Buruli ulcer is the third most common mycobacterial disease worldwide, posing a significant public health burden, especially in impoverished regions of West and Central Africa, such as Benin. The management of Buruli ulcer (BU) in Africa is often hindered by limited resources, delays in treatment, and inadequate medical facilities. Additionally, a portion of the population does not seek hospital care, which facilitates the continued presence of the pathogen in the environment. This paper aims to investigate the role of environmental factors in the transmission of Buruli ulcer. We develop a mathematical model to describe the dynamics of Buruli ulcer transmission, incorporating the presence of the bacterium in the environment. Theoretical results are presented to demonstrate that the model is well-posed. We compute the equilibria, including the disease-free equilibrium and the endemic equilibrium, and study their stability. To achieve this, we derive a threshold parameter called the basic reproduction number ℛ0, which determines whether the disease will persist in a human population. If ℛ0is less than one, the disease will eventually die out;if ℛ0is greater than one, the disease will persist. Sensitivity analysis is performed to understand the impact of various parameters on the dynamics of Buruli ulcer transmission and to identify the parameters that influence the basic reproduction number ℛ0. Finally, numerical simulations are conducted to validate the theoretical results obtained from the mathematical analysis.

关键词： Buruli Ulcer Mathematical Models Equilibria Stability

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Analysis of Secured Cloud Data Storage Model for Information

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Journal of Software Engineering and Applications 2024年第5期17卷 297-320页

作者： emmanuel Nwabueze Ekwonwune Udo Chukwuebuka Chigozie Duroha Austin Ekekwe Georgina Chekwube Nwankwo Department of Computer Science Imo State University Owerri Nigeria Department of Computer Science Gregory University Abia Nigeria Department of Computer Science Anambra State University Awka Nigeria

This paper was motivated by the existing problems of Cloud Data storage in Imo State University, Nigeria such as outsourced data causing the loss of data and misuse of customer information by unauthorized users or hackers, thereby making customer/client data visible and unprotected. Also, this led to enormous risk of the clients/customers due to defective equipment, bugs, faulty servers, and specious actions. The aim if this paper therefore is to analyze a secure model using Unicode Transformation Format (UTF) base 64 algorithms for storage of data in cloud securely. The methodology used was Object Orientated Hypermedia Analysis and Design Methodology (OOHADM) was adopted. Python was used to develop the security model;the role-based access control (RBAC) and multi-factor authentication (MFA) to enhance security Algorithm were integrated into the Information System developed with HTML 5, JavaScript, Cascading Style Sheet (CSS) version 3 and PHP7. This paper also discussed some of the following concepts;Development of Computing in Cloud, Characteristics of computing, Cloud deployment Model, Cloud Service Models, etc. The results showed that the proposed enhanced security model for information systems of cooperate platform handled multiple authorization and authentication menace, that only one login page will direct all login requests of the different modules to one Single Sign On Server (SSOS). This will in turn redirect users to their requested resources/module when authenticated, leveraging on the Geo-location integration for physical location validation. The emergence of this newly developed system will solve the shortcomings of the existing systems and reduce time and resources incurred while using the existing system.

关键词： Cloud Data Information Model Data Storage Cloud Computing Security System Data Encryption

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