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Solution chemistry back‐contact FTO/hematite interface engineering for efficient photocatalytic water oxidation

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Chinese Journal of Catalysis 2022年第5期43卷 1247-1257页

作者： Karen cristina Bedin Beatriz Mouriño Ingrid Rodríguez-Gutiérrez João Batista souza Junior Gabriel Trindade dos Santos Jefferson Bettini Carlos Alberto Rodrigues Costa Lionel Vayssieres Flavio Leandro souza The National Nanotechnology Laboratory(LNNANO) Brazilian Center for Research in Energy and Materials(CNPEM)Campinas 13083‐970Brazil Centro de Ciências Naturais e Humanas(CCNH) Federal University of ABC(UFABC)Santo André09210580Brazil Federal University of Rio Grande do Sul(UFRGS) Rio Grande do SulBrazil International Research Center for Renewable Energy(IRCRE) State Key Laboratory of Multiphase Flow in Power EngineeringSchool of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an 710049ShaanxiChina

This work describes a simple yet powerful scalable solution chemistry strategy to create back‐contact rich interfaces between substrates such as commercial transparent conducting fluorine‐doped tin oxide coated glass(FTO)and photoactive thin films such as hematite for low‐cost water oxidation ***‐resolution electron microscopy(SEM,TEM,STEM),atomic force microscopy(AFM),elemental chemical mapping(EELS,EDS)and photoelectrochemical(PEC)investigations reveal that the mechanical stress,lattice mismatch,electron energy barrier,and voids between FTO and hematite at the back‐contact interface as well as short‐circuit and detrimental reaction between FTO and the electrolyte can be alleviated by engineering the chemical composition of the precursor solutions,thus increasing the overall efficiency of these low‐cost photoanodes for water oxidation reaction for a clean and sustainable generation of hydrogen from PEC water‐*** findings are of significant importance to improve the charge collection efficiency by minimizing electron‐hole recombination observed at back‐contact interfaces and grain boundaries in mesoporous electrodes,thus improving the overall efficiency and scalability of low‐cost PEC water splitting devices.

关键词： Nanostructure Iron oxide Water oxidation Photoanode Surface engineering Chemical synthesis

Effect of propranolol on the splanchnic and peripheral renin angiotensin system in cirrhotic patients

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World Journal of Gastroenterology 2008年第44期14卷 6824-6830页

作者： Walkíria Wingester Vilas-Boas Antnio Ribeiro-Oliveira Jr Renata da Cunha Ribeiro Renata Lúcia Pereira Vieira Jerusa Almeida Ana Paula Nadu Ana cristina Sim■es e Silva Robson Augusto souza Santos Laboratório de Hipertenso Departamento de Fisiologia e BiofísicaICB-UFMGAv. Antonio Carlos6627Belo HorizonteMG31270-901Brazil Laboratório de Endocrinologia Departamento de Clínica MédicaFaculdade de Medicina-UFMGAv. Alfredo Balena190Belo HorizonteMG30130-100Brazil departamento de Pediatria Faculdade de MedicinaUniversidade Federal de Minas Gerais (UFMG)Av. Alfredo Balena190Belo HorizonteMG30130-100Brazil

AIM:To evaluate the effect of β-blockade on angiotensins in the splanchnic and peripheral circulation of cirrhotic patients and also to compare hemodynamic parameters during liver transplantation according to propranolol pre-treatment or not. METHODS:Patients were allocated into two groups:outpatients with advanced liver disease(LD) and during liver transplantation(LT). Both groups were subdivided according to treatment with propranolol or not. Plasma was collected through peripheral venipuncture to determine plasma renin activity(PRA),Angiotensin(Ang) Ⅰ,Ang Ⅱ,and Ang-(1-7) levels by radioimmunoassay in LD group. During liver transplantation,hemodynamic parameters were determined and blood samples were obtained from the portal vein to measure renin angiotensin system(RAS) ***:PRA,Ang Ⅰ,Ang Ⅱ and Ang-(1-7) were signifi cantly lower in the portal vein and periphery in all subgroups treated with propranolol as compared to non-treated. The relationships between Ang-(1-7) and Ang Ⅰ levels and between Ang Ⅱ and Ang Ⅰ were significantly increased in LD group receiving propranolol. The ratio between Ang-(1-7) and Ang Ⅱ remained unchanged in splanchnic and peripheral circulation in patients under β-blockade,whereas the relationship between Ang Ⅱ and Ang Ⅰ was significantly increased in splanchnic circulation of LT patients treated with propranolol. During liver transplantation,cardiac output and index as well systemic vascular resistance and index were reduced in propranolol-treated subgroup. CONCLUSION:In LD group,propranolol treatment reduced RAS mediators,but did not change the ratio between Ang-(1-7) and Ang Ⅱ in splanchnic and peripheral circulation. Furthermore,the modification of hemodynamic parameters in propranolol treated patients was not associated with changes in the angiotensin ratio.

关键词： β-blockade Cirrhosis Renin angiotensinsystem Angiotensin-(1-7)

Acute Appendicitis after Liver Transplant: A Case Report and Review of the Literature

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Open Journal of Organ Transplant Surgery 2014年第4期4卷 29-32页

作者： Ronaldo de Oliveira Andrade Rodrigo da Silva Pires Raul évora Silva Felipe Pedreira Tavares de Mello Cláudia cristina Tavares de Sousa Samanta Teixeira Basto Eduardo de souza Martins Fernandes department of Surgery and Liver Transplant Hospital Adventista Silvestre Rio de Janeiro Brazil

Acute appendicitis is rare in the postoperative period of liver transplantation;only 23 cases were described in the literature to date, including late and immediate postoperative. Our case reports a patient who was presented with acute appendicitis in the immediate post-transplant and died in the subsequent postoperative period. The article reviews the available literature and all cases known until now, commenting on incidence, casual factors, symptoms, diagnostic and management.

关键词： Appendicitis Complications Early Postoperative Liver Transplantation

Discriminating Important Agronomic and Industrial Parameters of White Oat Cultivars Treated with Fungicide Based on SIMCA Algorithm

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Journal of Agricultural Science and Technology(B) 2017年第2期7卷 86-99页

作者： Virgilio Gavicho Uarrota Cileide Maria Medeiros Coelho Julhana cristina Sponchiado Clovis Arruda souza Laboratory of Crop Plants Department of Agronomy Santa Catarina State University Agroveterinary Science Center Av. Luizde Cam6es 2090 Zip Code 88520-000 Lages SC Brazil Laboratory of Seed Analysis Department of Agronomy Santa Catarina State University Agroveterinary Science Center Av. Luizde Cam~es 2090 Zip Code 88520-000 Lages SC Brazil

Selection of effective agronomic and industrial parameters of oat cultivars is a decisive step in oat breeding programs fordevelopment of new oat and elite cultivars. In this study, a new approach was utilized to distinguish the most informative agronomicand industrial parameters that are most affected with fungicide application in oat cultivars. Four subsequent field experiments from2007 to 2010 were conducted in completely randomized block design （CRBD） with split plots. Total nine oat cultivars with orwithout fungicide application were evaluated for plant height, sieve yield, grain yield, lodging index, weight of hectoliter andde-hulling index. Soft independent modeling of class analogy （SIMCA） was conducted as one-class and multi-classes models toidentify important variables that can be used to discriminate samples. Results showed that SIMCA was effective, and lodging index,de-hulling index, sieve yield, plant height and grain yield were most affected oat parameters. Therefore, SIMCA algorithm can beused to easily discriminate some agronomic and quality parameters of oats.

关键词： Oat cultivars, SIMCA modeling, non-supervised techniques, fungicide application, growth, yield, principal componentanalysis, hierarchical cluster analysis, model classification.

Surgical Technique Used for Portal Vein Thrombosis when Thrombectomy Is Not Possible During Liver Transplantation

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Surgical Science 2011年第5期2卷 248-251页

作者： José Roberto Alves Ilka de Fátima Santana Ferreira Boin Anaísa Portes Ramos Catherine Puliti Hermida Reigada Nelson Caserta Adilson Roberto Cardoso cristina Arrivabene Caruy Elaine cristina Ataíde Jazon Romilson souza Almeida 不详

Portal vein thrombosis (PVT) was for a long time considered a barrier to liver transplantation. The aim of this study is to demonstrate the surgical technical options for portal vein reconstruction during liver transplantation in patients with PVT in which thrombectomy was not possible. Between September 1991 and March 2009, 420 liver transplanted patients were retrospectively analyzed, identifying 29 cases with PVT (6.9%). Preoperative diagnosis, preoperative risk factors, surgical technique options to treat various forms (grades) of PVT, postoperative recurrence and actuarial survival rates were studied. In three cases of PVT grade II and in one case PVT grade III the thrombectomy was insufficient, requiring some surgical technique options (13.79%). In two cases placement of iliac vein graft was performed, in one an anastomosis of the portal vein with collateral splenorenal vein and in the other with left gastric varicose. The actuarial survival rate for patients without PVT and patients with PVT and effective thrombectomy was 73.8% while those with PVT who needed some type of surgical option was 75%. Our results suggest that actuarial survival rates were similar among patients with PVT or PVT with effective thrombectomy when compared with PVT that required some surgical options.

关键词： Liver Transplantation Portal Vein Thrombosis Surgical Technique

Diversity of Filamentous Fungi of Area from Brazilian Caatinga and High-Level Tannase Production Using Mango (Mangifera indicaL.) and Surinam Cherry (Eugenia unifloraL.) Leaves under SSF

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Advances in Microbiology 2013年第8期3卷 52-60页

作者： Roberta Cruz Juliana Silva de Lima Julyana Cordoville Fonseca Maria José dos Santos Fernandes Débora Maria Massa Lima Gustavo Pereira Duda Keila Aparecida Moreira cristina Maria de souza Motta Academic Unit of Garanhuns Federal Rural University of Pernambuco Garanhuns Brazil department of Mycology Federal University of Pernambuco Recife Brazil

Tannase is a biotechnologically important enzyme that can be produced during fungal fermentation of organic matter. The Caatinga is an exclusive Brazilian ecosystem that has been largely unexplored by science, particularly its filamentous fungal diversity. This study evaluated the diversity of filamentous fungi in the Caatinga soils of Pernambuco, Brazil, and their potential for tannase production by solid-state fermentation (SSF) of mango (Mangifera indica L.) and Surinam cherry (Eugenia uniflora L.) leaves. A total of 4711 isolates were obtained, 2090 during the rainy seasonand 2621 during the dry season. The isolates belonged to 18 genera and 66 species, with Aspergillus and Penicillium having the highest species richness. The dry season had a higher diversity index. Aspergillus was the dominant genus, and A. flavus, A. sclerotiorum, and A. ochraceus the most abundant species. A representative of each species was tested for tannase production using dried mango and Surinam cherry leaves as substrates;the leaves contained 14.28 and 7.0 g/L tannin, respectively. Most fungal species produced tannase, but the highest yields were obtained when mango leaves were used as substrate for Penicillium restrictum (accession URM 6044), Aspergillus flavofurcatus (URM 6142), and A. stromatoides (URM 6609), which produced 104.16, 87.51, and 81.83 U/mL tannase, respectively. These yields exceeded previously published reports. Filamentous fungi from Caatinga soils have great potential for producing tannase by SSF, and low-cost mango leaves make excellent substrate.

关键词： Caatinga Filamentous Fungi Tannase Solid-State Fermentation Mangifera indicaL.

Where Are the Bromeliads? A Study on Different Trails in the Ecological Reserve of Guapiaçu, RJ

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Agricultural Sciences 2023年第2期14卷 196-201页

作者： Johnatan Jair de Paula Marchiori Vinicius de souza Oliveira Gilcéa Teixeira Fontana Boone Luan Luciano dos Santos Pereira Natália cristina Barbosa Moura Ana Beatriz Mamedes Piffer Anderson Mathias Holtz Lusiane de Sousa Ferreira Raquel Cetto Sampaio Federal Rural University of Rio de Janeiro Seropédica Brazil Center for Agricultural Sciences and Engineering Federal University of Espírito Santo Alegre Brazil Campus Itapina Federal Institute of Espírito Santo Colatina Brazil State University Paulista “Júlio de Mesquita Filho” Botucatu Brazil

Bromeliaceae are important in ecological restoration, showing easy adaptation to different environments, and constantly interacting with each other through ecological relationships, whose effects may or may not benefit the species involved. The hypothesis tested whether the population density of Hohenbergia augusta is higher in areas at a more advanced successional stage (brown trail), since the species is typical of more structured forest environments, occurring especially in the lower strata of the forest. Six plots of 10 meters (6 × 10 m) were installed, parallel to the brown and yellow trails, and with a distance of 5 m from the edge. Plots were allocated alternately between the two sides of the trail, 10 meters apart from each other when on the same side. In each plot, all H. augusta (Vell.) E. Morren bromeliads were sampled, without a minimum inclusion criterion, provided they were epiphytic phorophytes. The logarithm of the value was used for data normalization and later, the data were tested in a student’s t-test. The study pointed out that the highest population density of H. augusta occurred in the brown trail because the area is in a more advanced successional stage.

关键词： Bromeliads Atlantic Forest Ecological Restoration

Adjustment of Mathematical Equations to determine the Area Leaf of Cordia myxaL.

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Agricultural Sciences 2020年第7期11卷 609-616页

作者： Michelle Teixeira Araujo ellen Maurício Faria Gabriel Linhares Cunha Paloma de Moraes Nunes Vinicius de souza Oliveira Karina Tiemi Hassuda dos Santos Omar Schmildt Antelmo Ralph Falqueto Mônica Maria Pereira Tognella Edilson Romais Schmildt Center North of Espírito Santo Federal University of Espírito Santo S&#227 o Mateus Espírito Santo Brazil Center for Agricultural Sciences and Engineering Federal University of Espírito Santo Alegre Espírito Santo Brazil

The objective of this study was to obtain mathematical equations through the leaf dimensions to estimate the area leaf of Cordia myxa L. 392 leaves of plants were collected, located in the municipality of São Mateus, North of the State of Espírito Santo, Brazil, 300 of which were used to adjust the equations and 92 for validation. Of all the leaves, the largest length (L) and maximum width (W) were measured, product of multiplying the length with the width (LW) and the real leaf area (RLA). Models equation first degree linear, quadratic and power were fitted, where RLA was the dependent variable as a function of L, W and LW as an independent variable. All equations were validated according to appropriate criterion. Thus, the power model ELA = 0.84(LW)0.9749, based on the product of multiplication of length with width (LW) is the most suitable for estimating the leaf area of Cordia myxa L.

关键词： Non-destructive Method Validated Modeling

Chemical Composition and Allelopathic Activity of Parthenium hysterophorusand Ambrosia polystachyaWeeds Essential Oils

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American Journal of Plant Sciences 2014年第9期5卷 1248-1257页

作者： Cíntia Alvarenga S. F. de Miranda Maria das G. Cardoso Maria Laene M. de Carvalho Ana cristina S. Figueiredo David L. Nelson Christiane M. de Oliveira Marcos de S. Gomes Juliana de Andrade Josefina A. de souza Luiz R. Marques de Albuquerque department of Agricuture Federal University of Lavras Lavras Brazil department of Chemistry Federal University of Lavras Lavras Brazil Federal University of the Jequitinhonha and Mucuri Valleys Diamantina Brazil Universidade de Lisboa Faculdade de Ciências de Lis-boa DBV Instituto de Biotecnologia e Bioengenharia Centro de Biotecnologia Vegetal C2 Campo Grande Lisboa Portugal

The volatile constituents of the essential oils from leaves from the weed plants Parthenium hysterophorus and Ambrosia polystachya were identified and quantified by GLC-MS and GLC. Allelopathic activities were determined by methods that evaluated the volatile effects and the direct application of these essential oils on the seed germination and seedling vigor of lettuce. We identified 27 compounds in the essential oil from P. hysterophorus, and the main constituents were germacrene-D (35.9%), trans-β-ocimene (8.5%) and β-myrcene (7.6%). In the essential oil from A. polystachya, 40 constituents were identified and the principal compounds were germacrene-D (29.3%), trans-β-ocimene (13.6%) and β-caryophyllene (9.8%). In both methods, the essential oil from A. polystachya presented a greater potential for reducing seed germination and seedling vigor in lettuce than the essential oil from P. hysterophorus, and this activity might be attributed to its higher content of monoterpenes.

关键词： Volatile Oils Allelopathy Asteraceae