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Oxidation of chalcopyrite in air-equilibrated acidic solution: Inhibition with phenacyl derivatives

Transactions of Nonferrous Metals Society of China 2020年第7期30卷 1928-1942页

作者： Paul CHIRITA Madalina IDUINEA Laura GSARBU Lucian MBIRSA Mihaela BAIBARAC Florinel SAVA elena matei Department of Chemistry University of CraiovaCalea Bucuresti 107I200478CraiovaRomania Department of Chemistry Physics and Environment"Dunarea de Jos"University of Galati111 Domneasca StreetGalati 800201Romania Department of Chemistry "Al.I.Cuza"University of Iasi11 Carol I Blv.Iasi 700506Romania Lab.Optical Processes in Nanostructured Materials National Institute of Materials PhysicsP.O.Box MG-7BucharestR077125Romania

The effects of 4-(2-hydroxyphenyl)-2-(morpholin-4-yl)-1,3-thiazole(Pr02), 1-(3,5-dibromo-2-hydroxyphenyl)-1-oxoethan-2-yl-N,N-diethyldithiocarbamate(Pr04) and 1-(5-bromo-2-hydroxy-3-methylphenyl)-1-oxoethan-2-yl-Oethyl xanthate(Pr06) on the aqueous oxidation of chalcopyrite(CuFeS2) in air-equilibrated solution at a temperature of 25 ℃ and a pH of 2.5 were studied. The effects were investigated by using potentiodynamic polarization, electrochemical impedance spectroscopy(EIS), scanning electron microscopy coupled with energy dispersive X-ray(SEM/EDX) analysis, aqueous batch experiments, Fourier transform infrared(FTIR) spectroscopy, Raman scattering and quantum chemical calculations. It is found that the anodic current densities decrease in the order of EtOH > Pr02 > Pr04 > Pr06. These results, along with those of the EIS measurements, show that Pr02, Pr04 and Pr06 are effective anodic inhibitors of chalcopyrite aqueous oxidation. Both Raman scattering and FTIR spectroscopy indicate that the elemental sulfur, polysulfide and ferric oxyhydroxides that form on the surface of the mineral are not responsible when it comes to the aqueous oxidation inhibition of chalcopyrite. Quantum chemical calculations show that the adsorption of the tested compounds on the chalcopyrite surface is energetically favorable and so, it can explain the inhibiting effects that were observed.

关键词： chalcopyrite oxidation phenacyl derivatives inhibition potentiodynamic polarization quantum chemical calculation

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Short-term effects of cleaning-respacing in a silver fir-dominated stand in Romania

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Journal of Forestry Research 2018年第6期29卷 1591-1599页

作者： Valeriu-Norocel Nicolescu Cornelia Hernea Diana-Cristina Simon3 matei-Nicolae Ciolan Monica-elena Barti Hendrik Schubert Edina Borbely Faculty of Silviculture and Forest Engineering Transylvania University of Brasov.irul Beethoven 1500123 BrasovRomania Faculty of Horticulture and Forestry Banat’s University of Agricultural Sciences and Veterinary Medicine“King Michael I of Romania”from Timi.oaraCalea Aradului 119300645 Timi.oaraRomania Barzava Forest District 317030 BarzavaAradRomania LIGNUM Forest District 605300 DarmanestiBacauRomania

This paper discusses the early silviculture of silver fir(Abies alba Mill.), a major softwood in Romania covering more than 294,000 ha. Three research plots(DRP1, DRP2 and DRP3) were established in a 25-year-old silver fir-dominated stand in May 2012. In DRP1 and DRP2, heavy cleaning-respacing were carried out while DRP3 was kept as a control. After the treatments in 2012,the plots had stocking between 1470 trees ha-1(DRP2) and10,030 trees ha-1(DRP3), basal areas between11.8 m2ha-1(DRP2) and 31.6 m2ha-1(DRP3). The average diameters were between 5.7 cm(DRP3) and 9.6 cm(DRP2). Measurements in September 2016 confirmed the rapid response of silver fir to *** best results in average diameter increments and basal area between 2012 and 2016 were in DRP2: 3.7 cm(36.4%) and 7.7 m2ha-1(85.0%) respectively. The largest diameter trees in 2012 were the best growers, and a strong linear correlation between the initial diameter of the remaining trees and their increment was established. Natural dieback of trees occurred only in DRP3(8.6%). The selection of crop trees based on the vigour, quality, and spacing criteria during cleaning-respacing was possible as individuals stood out in terms of vigour and early diameter growth. An issue encountered in DRP1 and DRP2 was the occurrence of epicormic shoots, especially on less vigorous individuals with small crowns. However, four years after cleaning-respacing, these branches are small and do not significantly affect the wood quality.

关键词： Abies alba Tending operations Stocking Basal area Increment

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