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Phenotypic, Cytological and Molecular (AFLP) Analyses of the Cotton Synthetic Allohexaploid Hybrid (G. hirsutum×G. longicalyx)²

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Open Journal of Genetics 2020年第2期10卷 35-49页

作者： n’guessan Olivier konan Jean-Marie Jacquemin Jean-Pierre Baudoin Guy Mergeai Laboratory of Crop Improvement Agroforestry Unit Jean Lorougnon Guédé University Daloa C&#244 te D’Ivoire Laboratory of Tropical Agroecology Gembloux Agro-Bio Tech Liège University Gembloux Belgium Department of Life Sciences Bioengineering Unit Walloon Agricultural Research Centre (CrAw) Gembloux Belgium

The wild cotton diploid species (2n = 2x = 26) are important sources of useful traits such as high fiber quality, resistance to biotic and abiotic stresses etc., which can be introgressed into the cultivated tetraploid cotton Gossypium hirsutum L (2n = 4x = 52), for its genetic improvement. The African wild diploid species G. longicalyx Hutchinson and Lee could be used as donor of the desirable traits of fiber fineness and resistance to reniform nematode. However, hybridization of wild diploid species and cultivated tetraploid cotton encounters a sterility problem of the triploid (2n = 3x = 59), mainly due to ploidy. The restoration of the fertility can be done by creating an allohexaploid (2n = 6x = 78) through the doubling with colchicine of the sterile triploid chromosomes. With this method, a synthetic allohexaploid hybrid (G. hirsutum × G. longicalyx)2 has been obtained. This genotype was studied using phenotypic, cytological and molecular (AFLP) analyses in order to confirm its hybridity and its caryotype, and also to verify the expression of the desirable traits coming from G. longicalyx. The studied genotype showed a quite good level of pollen fertility (83%), and apart from larger seeds and some minor seedling anomalies, most of its morphological characteristics were intermediate between the two parental species. It had 78 chromosomes, proving its hexaploid status. Molecular analysis revealed 136 AFLP loci in this hexaploid, all from G. hirsutum and G. longicalyx, demonstrating its hybrid status. In addition, the hexaploid exhibited the useful traits of G. longicalyx with regard to its remarkable fiber fineness and its high resistance to the reniform nematode. This allohexaploid hybrid constitutes an interesting agronomic material, which can be used as a bridge for the transfer of useful agronomic traits from wild species to varieties of G. hirsutum.

关键词： Gossypium spp Hexaploid Hybrid Chromosomes AFLP Marker Plant Breeding

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Monitoring Forest Recovery in Protected Forests of northern Côte d’Ivoire Using Landsat Imagery and Intensity Change Analysis

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Advances in Remote Sensing 2022年第2期11卷 17-37页

作者： n’guessan Simon Andon Avy Stéphane koffi Farid Traoré Patrick n’Gatta Department of Geography Université Peleforo GON COULIBALY Korhogo C&ocirc te d’Ivoire Department of Geosciences Université Peleforo GON COULIBALY Korhogo C&ocirc te d’Ivoire Institut de l’Environnement et de Recherches Agricoles Ouagadougou Burkina Faso

In this paper, the initiatives of reforestation of the national forests of the north of the Côte d’Ivoire were examined using geomatics and the analysis of change of intensity by taking the case of the protected Forest of Badénou (PFB). A spatial analysis based on multi-spectral and multi-temporal Landsat imagery was carried out to assess land cover changes in the (PFB) over the past two decades and determine whether patterns of change in terms of the intensity of gains/losses of each of the land cover classes were active or dormant between the period before (2000-2013) and after (2013-2019) the reforestation initiative. Five main classes were identified: forest (dry deciduous and gallery forests), tree savannah, shrub/grassy savannah (including agricultural lands), bare lands (bare soils and degraded land areas), and water course. All classes were satisfactorily classified, with an excellent producer’s and user’s and overall accuracies and very good Kappa coefficients. The results showed that between 2000 and 2019, the forest cover in the PFB increased from 7778 ha to 5054 ha, a decrease was marked between 2000 and 2013 of approximately 60% compared to its size in 2000, while a slight increase between 2013 and 2019 (4645 ha to 5054 ha) i.e. around 9%) certainly due to the reforestation since 2016. As for the annual intensities of change for each class in both study periods, changes (gain or loss) in forest and tree savanna were relatively dormant after reforestation, while annual bare land gain was relatively active and marked, indicating that degradation of forests remains a threat to the sustainability of the PFB. Forest degradation has occurred mainly in the eastern parts of the PFB, while the central parts have regained more tree cover. These results can help identify conservation and restoration priorities and improve the overall management of the PFB.

关键词： Forest Degradation Reforestation Forest Cover Monitoring Intensity Change Analysis Desertification

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Hydrogen Bonds Sites of Amylose or Amylopectin from Starch at the OnIOn Level (B3LYP/6-311++G [d, p]: AM1)

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Computational Chemistry 2021年第1期9卷 85-96页

作者： Ablé Anoh Valentin n’guessan Boka Robert Bamba El Hadji Sawaliho Laboratoire de Constitution et de Réaction de la Matière UFR SSMT Université Félix Houphou&#235t-Boigny Abidjan C&#244te d’Ivoire

The research aims to help reduce the enormous post-harvest losses of rice or bananas in Cote d’Ivoire. It focuses on the breakdown mechanism of their starch. This process contributes to their decay. This study wants to elucidate it;to do this, it analyzes the tetra or penta saccharide reactions with the water or dioxide carbon. It calculates the geometric, energetic and spectroscopic parameters at the OnIOM level (B3LYP/6-311++G [d, p]: AM1). These quantities allow establishing that oxygen represents the privileged hydrogen bond (HB) site for amylose with four or five D-glucose building blocks. They suggest and are respectively those of amylopectin when the latter consists of four and five D-glucose synthons. They prove that amylose deteriorates before it;the degradation of starch begins with its alteration into disaccharides. It continues with that of amylopectin into tri or tetra-saccharides with four or five building blocks.

关键词： Hydrogen Bonds Glucose Amylose Amylopectin

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The Oryzenin’s Effect on Di, Tri and Quadri-Saccharide Degradation. An Investigation by a Mixed Method: OnIOM (DFT/B3LYP/6 - 31 + G(d, p): AM1)

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Computational Chemistry 2022年第2期10卷 97-119页

作者： n’guessan Boka Robert Bamba El Hadji Sawaliho koffi kouassi Alain Laboratoire de Constitution et de Réaction de la Matière UFR SSMT Université Félix Houphou&#235 t-Boigny Abidjan C&#244 te d’Ivoire

The paddy rice degradation remains a concern for research;the chemical phenomena underlying this process persists unknown. This research aims to identify the mechanism of starch degradation. It determines the nature of the reactions between two, three and four synthons of amylose with oryzenin using theoretical methods. The OnIOM (DFT/B3LYP/6 - 31 + G(d, p): AM1) level of theory is performed on four monomers and eight complexes. Frequencies make it possible to obtain energy and spectroscopic quantities. Calculations after geometry optimization. Following this, a “single point” allows exploiting the “natural Bond Orbital (nBO)” analysis. The first three parameters suggest that the main interactions between oryzenin and amylose arise through O29-H30…O46 hydrogen bonds (HB). Furthermore, this result posits that the length of the amylose doesn’t influence this reaction. The nBO analysis shows that this component of starch degrades first at the end of the chain to produce monosaccharides;it can also alter in the middle of the chain to give disaccharides.

关键词： Paddy Rice Oryzenin Amyloidosis Hydrogen Bond

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Mapping and Petro-Structural Study of northern komborodougou Formations, in korhogo Gold District: A Substantial Contribution to the Discovery of a Potential Gold Mineralization in Birimian Greenstone Belts

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International Journal of Geosciences 2022年第10期13卷 855-874页

作者： Houssou n’guessan nestor Allialy Marc Ephrem Adingra Martial Pohn koffi Pria koffi kossonou Jean-Marie koffi n’guessan Martial Ahossi Loba Gbriga Franck Cyrille UFHB University of Felix Houphou&#235 t-Boigny Abidjan UFR Earth Sciences and Mineral Resources Abidjan C&#244 te d’Ivoire UJLoG University of Jean Lorougnon Guede Daloa C&#244 te d’Ivoire CAREM Sarl Abidjan C&#244 te d’Ivoire

The Gold District of korhogo, in the northern region of C?te d’Ivoire, holds enormous potential for gold mineralizations, some of which are under exploration phase and others in exploitation phase (example of Tongon Gold Mine). Dormant since 1998, Mapping Services of most of the West African countries hardly provide geological maps at the scales of: 1/200,000, 1/50,000 and 1/25,000. This situation of unavailability of detailed geological maps does not help mining operators in the selection of prolific areas and also in the interpretation of in soil geochem anomies or gold mineralizations. Consequently, during the years 2020 and 2021, we have undertaken a campaign of geological mapping and petro-structural study of the northern sector of komborodougou, located in the southern extension of Banfora Birimian Belt. This work, which allowed the realization of a geological map at 1/20,000 scale, reveals that: the mapped area includes three (3) major lithological units: 1) a volcano-sedimentary unit made up of metasediments (metaarenites, metasiltites and metaflyschs) and metavolcanites (metabasalts), which are metamorphosed and outcrop in the form of schists;2) a metaplutonic and intrusive unit composed on the one hand of quartz-diorites and metagabbros, and on the other hand of granites and granodiorites;3) and finally, a unit of dikes formed by microgranites, microgabbros, aplites and quartzites. The volcano-sedimentary complex is affected by a regional fold with an axis subparallel to the regional tectonic grain and an S1 schistosity oriented nE-SW to nnE-SSW with steep dips (>60o), except for those of the metaflyschs which are weak (o);a regional nW-SE compression would be at the origin of the setting of this schistosity. The volcano-sediment and metaplutonite complex is crossed in a nnE-SSW direction by a senetral shear-zone or main shear-zone and secondary shear-zones oriented sometimes nE-SW or n-S. These shear-zones are intersected by more or less dextral or senest

关键词： Geological Mapping Petro-Structural Gold Mineralization komborodougou Côte d’Ivoire

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nBO Population Analysis and Electronic Calculation of Four Azopyridine Ruthenium Complexes by DFT Method

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Computational Chemistry 2017年第1期5卷 51-64页

作者： n’guessan ko.ako. nobel Kafoumba Bamba Ouattara Wawohinlin Patrice nahossé Ziao Laboratoire de Thermodynamique et de Physico-Chimie du Milieu UFR-SFA Université Nangui Abrogoua Abidjan C&ocirc te d’Ivoire

The molecular structure, the natural Bond orbital (nBO) and the Time Dependent-DFT of both isomers cis or γ-Cl and trans or δ-Cl of RuCl2(L)2, where L stands respectively for 2-phenylazopyridine (Azpy), 2,4-dimethyl-6-[phenylazo]pyridine (Dazpy), 2-[(3,5-dimethylphenyl)azopyridine] (Mazpy) and 2-pyridylazonaphtol (nazpy) were calculated with DFT method at B3LYP/LAnL2DZ level. The prediction of the frontier orbitals (Highest Occupied Molecular Orbital or HOMO and Lowest Unoccupied Molecular Orbital or LUMO) shows that the most active complexes suitable for electronic reactions are admitted to be the trans isomers. Moreover, δ-RuCl2 (Azpy)2 is discovered to react more actively as photo-sensitizer since its energy gap is the minimum. Besides, electronic structures of all complexes through nBO calculation indicate that Ru-n bonds are made of delocalization of occupancies from lone pair orbital of n atoms to the ruthenium. Moreover, Ru was assumed to have almost the same charge regardless the structure of the azopyridine ligands in the complex indicating that the ligands provide only a steric effect that is responsible for the ruthenium’s selectivity. Concerning the transition state, nBO analysis also highlights that the transition LP(Ru) π*(n1-n2) does correspond to t2g?π*(L). This transition is assumed to correspond to Metal to Ligand Charge Transfer (MLCT) that is responsible for the photo-sensitiveness of the metallic complex. Besides, TDDFT calculation of complexes showed that δ-RuCl2(nazpy)2 displays the largest band during the absorption. For that reason, it is admitted to be the best photosensitizer due to a large system of conjugation provided by nazpy ligand.

关键词： natural Bond Orbital (nBO) HOMO LUMO Azopyridine Ligand MLCT LLCT

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Theoretical and Electrochemical Characterization of δ-RuCl₂(nazpy)₂: Application to Oxidation of D-Glucose

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American Journal of Analytical Chemistry 2016年第1期7卷 57-66页

作者： Wawohinlin Patrice Ouattara Kafoumba Bamba nahossé Ziao ko.ako. nobel n’guessan Laboratoire de Thermodynamique et de Physico-Chimie du Milieu UFR-SFA Université Nangui-Abrogoua Abidjan Cote d’Ivoire

The heterogenized δ-RuCl2(nazpy)2 deposited on carbon toray (CT) was studied for the first time as electrochemical catalyst. Before, it was characterized by visible-ultraviolet spectra and theoretically by TDDFT method at B3LYP/Lanl2DZ level. It displayed an MLCT t2geg → π* transition where t2geg due to the structure of nazpy that considerably reduces energy between d AOs of Ru represents the HOMO of the complex and π* is identified as the LUMO. Electrochemistry study shows two redox ranges in both negative and positive sides of the potential. The positive side that corresponds to the couple RuIV/RuIII of catalyst appears to be active for oxidation of D-glucose in carbonate buffer with a high turnover. Therefore, Keto-2-gluconic and gluconic acids were the two main products obtained with respectively 80% and 17.6% of selectivity. Moreover, a small amount of tartaric and glycol acids coming from the c-c bond cleavage due to non-protection of the anomeric carbon of D-glucose were also observed.

关键词： DFT Calculation HOMO-LUMO Analysis nBO Electrochemistry Ruthenium Complex D-Glucose

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Petro-Geochemistry Contraints of Côte d’Ivoire north-East Plutonites: Implications for Eoeburnean Magmatism of Baoulé-Mossi Domain (Southern of West African Craton)

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Journal of Geoscience and Environment Protection 2022年第9期10卷 185-206页

作者： Brice Roland kouassi Marc Ephrem Allialy n’guessan Houssou nestor kouadio David koffi UFR-Biological Sciences Geosciences Department Peleforo Gon Coulibaly University Korhogo C&#244 te d’Ivoire Laboratory of Geology Mineral and Energy Resources/Training and Research Unit in Earth Sciences and Mineral Resources Félix Houphou&#235 t-Boigny University Abidjan C&#244 te d’Ivoire

Plutonites are part of the set of crystallines compose the Precambrian basement. Their study is capital because it allows participating in the debates on the geodynamic evolution of the West African craton. This study concerns granitoids and dioritoids of the north-East of Côte d’Ivoire located in the Man-Leo ridge structured by Eoeburnean magmatism. The petrographic and geochemistry constraints make it possible to say that these rock formations have evolved by the process of fractional crystallization. They have a hybrid origin (mantle and crust), metaluminous to peraluminous highlighted by geochemistry. Concerning the geotectonic context, these plutonites of the Baoulé-Mossi domain are emplacement in a context of subduction more precisely in a context of volcanic arc.

关键词： Plutonites Contraints Magmatism Source Geotectonics Côte d’Ivoire West African Craton

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Molecular Structure, Electronic Structure, Properties and Analyses of Five Azopyridine Ruthenium Complexes α-Cl, β-Cl, γ-Cl, δ-Cl and ε-Cl of RuCl2(4,6-Dimethyl-Phenylazopyridine)2as Potential Cancer Drugs: DFT and TD-DFT Investigations

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Computational Chemistry 2018年第3期6卷 27-46页

作者： nobel ko.ako. n’guessan Kafoumba Bamba Ouattara Wawohinlin Patrice nahosséZiao Laboratoire de Thermodynamique et Physico-Chimie du Milieu UniversitéNangui AbrogouaAbidjanC&ocirc te d’Ivoire

Ground state geometries, natural bond orbital (nBO), analysis of frontier molecular orbitals (FMOs), analysis and spectral (RMn and UV-Visible) properties of five azopyridine ruthenium (II) complexes α-Cl, β-Cl, γ-Cl, δ-Cl and ε-Cl of RuCl2(Dazpy)2 have been theoretically studied by the Density Functional Theory (DFT) and Time-Dependent Density Functional Theory (TD-DFT) methods using two basis sets: Lanl2DZ and a generic basis set in gas or in chloroform solvent. Dazpy stands for 4,6-dimethyl-phenylazopyridine. Optimized geometry shows that, except β-Cl, all the other four isomers α-Cl, γ-Cl, δ-Cl and ε-Cl are C2 symmetrical. Otherwise, a good agreement was found between experimental and the calculated geometry and nMR data. Moreover, Lanl2DZ effective core potential basis set provides good chemical shifts and geometric properties. Furthermore, the prediction of the frontier orbitals (Highest Occupied Molecular Orbital or HOMO and Lowest Unoc-cupied Molecular Orbital or LUMO) shows that the most active isomer suita-ble for electronic reactions is admitted to be δ-Cl. Besides, the nBO analysis indicates that the Ru-n is formed by the electron delocalization of lone pair atomic orbital of n2 and npy to Ru. Also, the strongest interactions between LP(n) with LP*(Ru) and LP(Cl) with LP*(Ru) stabilize the molecular struc-ture. In addition, nBO shows that the five d orbitals of Ru in the complex are organized so that there is no order of priority from one complex to another. Therefore, the transition LP(Ru) → π*(n1 = n2) corresponding to Metal to Li-gand Charge Transfer (MLCT) is in reality no more than d → π*. Besides, TDDFT prediction in chloroform solvent reveals that all the five isomerics complexes absorb in the visible region as well as efficient photosensitizers. What’s more, δ-RuCl2(dazpy)2 can potentially act as the excellent sensitizer with a large band of absorption in visible region and a small excited energy. This study can help design and find out the abili

关键词： Azopyridine DFT nBO Pseudo-Potential Ru(II) Complexes

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Events Sourcing and Command Query Responsibility Segregation Based Fast Data Architecture

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Open Journal of Applied Sciences 2023年第2期13卷 198-206页

作者： Gérard Behou n’guessan Odilon Yapo Achiepo Jérôme Diako Research and Digital Expertise Unit (UREn) Virtual University of C&#244te d’Ivoire (UVCI) Abidjan Ivory Coast Lastic ESATIC Abidjan Ivory Coast

With the advent of Big Data, the fields of Statistics and Computer Science coexist in current information systems. In addition to this, technological advances in embedded systems, in particular Internet of Things technologies, make it possible to develop real-time applications. These technological developments are disrupting Software Engineering because the use of large amounts of real-time data requires advanced thinking in terms of software architecture. The purpose of this article is to propose an architecture unifying not only Software Engineering and Big Data activities, but also batch and streaming architectures for the exploitation of massive data. This architecture has the advantage of making possible the development of applications and digital services exploiting very large volumes of data in real time;both for management needs and for analytical purposes. This architecture was tested on COVID-19 data as part of the development of an application for real-time monitoring of the evolution of the pandemic in Côte d’Ivoire using PostgreSQL, ELasticsearch, Kafka, Kafka Connect, niFi, Spark, node-Red and MoleculerJS to operationalize the architecture.

关键词： Architecture Software Engineering Big Data Data Engineering Real Time

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