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Inte.national Journal of Organic Che.is.ry 2024年第1期14卷 20-31页

作者： dmitry e. Pugache. Ge.rgy V. Zatons.y Tatyana s. Kos.ryukova Anna G. s.ubina Nikolay V. Vas.lie. de.artme.t of Biological Microanalys.s FGUP State Research Institute of Biological Engineering Moscow Russia de.artme.t of The.re.ical a.d Applie. Che.is.ry State University of Education Mytishchi Russia

Ne. re.ge.ts.for immunofluore.ce.ce.analys.s.of carbazole.s.0}ie. containing fluorinate. β-dicarbonyl fragme.ts.a.d carboxylic s.bs.itue.t groups.s.0}arate. by s.ace.s.of diffe.e.t le.gths.from the.light-gathe.ing carbazole.s.affold have.be.n de.e.ope.. The.marke.s.in comple. with e.s.p>3+s.p> ions.pos.e.s.s.ability in the.aque.us.phas.0} inte.s.0}a.d prolonge. lumine.ce.ce.(τ 550 - 570 μs. with characte.is.ic e.is.ion maxima in the.re.ion of 615 nm a.d e.citation wave.e.gths.in the.re.ion of 380 - 390 nm, which dis.inguis.e. the. from mos. of the.analogs.us.0}. In the.s.udy of marke. conjugation with s.re.tavidin, a re.ge.t containing 4 - 5 e.ropium labe.ing comple.e. bas.0} on s.ace.-containing carbazole.te.rake.one.was.obtaine.. The.marke.-dope. s.licate.nanoparticle. e.hibit inte.s.0}a.d long-live. lumine.ce.ce.in the.characte.is.ic re.ion.

关键词： Fluore.ce.ce.Immunoas.ay Fluorinate. β-dike.one. Carbazole e.ropium Comple.e. s.re.tavidin Nanodis.e.s.ons

Nanomotion of bacte.ia to de.e.mine.me.abolic profile

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Nanote.hnology a.d Pre.is.on e.gine.ring 2024年第1期7卷 1-9页

作者： s.N.Ple.kova e.V.Lazare.ko N.A.Be.rukov R.N.Kriukov A.V.Boryakov M.e.dokukin s.I.s.rodin Re.e.rch Laboratory of s.anning Probe.Micros.opy Lobachevsky State University of Nizhny NovgorodNizhny Novgorod 603950Russia de.artme.t of Nanote.hnology a.d Biote.hnology Nizhny Novgorod State Technical University n.a.R.E.AlekseevNizhny Novgorod 603950Russia s.rov Phys.cs.a.d Te.hnology Ins.itute National Research Nuclear University MEPhISarov 607186Russia

In a.dition to the.r vis.ble.motion s.ch as.s.imming(e.g.,with the.he.p ofﬂage.la),bacte.ia can als. e.hibit nanomotion that is.de.e.table.only with highly s.1}s.tive.ins.rume.ts.a.d this.s.udy s.ows.that it is.pos.ible.to de.e.t bacte.ial nanomotion us.ng an AFM de.e.tion *** re.ults.s.ow that the.nanomotion characte.is.ics.de.e.d on the.bacte.ial s.rain,a.d that nanomotion can be.us.1} to s.1}s.1}the.me.abolic activity of bacte.ia be.aus.1}the.os.illations.are.s.1}s.tive.to the.food pre.e.e.ce. of the.bacte.ia a.d the.type.of s.rrounding me.ium.

关键词： Nanomotion Bacte.ia Cantile.e. Os.illation Atomic force.micros.opy Me.abolis.

Modulation of oxidative.damage.a.d ge.otoxicity of bios.nthe.ize. zinc oxide.nanoparticle. via s.pple.e.tation with modifie. cinnama.de.yde.loade. chitos.n nanoparticle. in mice

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Food s.ie.ce.a.d Human We.lne.s 2024年

作者： Mos.0} A.a.de.-wahhab Aziza A.e.-Ne.e.ty As.aa s.s.lman Ze.nab K.Hamza e.gy M.Akl s.he. e.Aly We.yi Kang de.artme.t of Food Toxicology & Contaminants. National Re.e.rch Ce.tre Dokki， Cairo， Egypt Ge.e.ic a.d Cytology de.artme.t， National Re.e.rch Ce.tre Dokki， Cairo， Egypt de.artme.t of Fats.a.d Oils. National Re.e.rch Ce.tre Dokki， Cairo， Egypt National R & d Ce.te. for e.ible.Fungus.Proce.s.ng Te.hnology， He.an Unive.s.ty Joint Inte.national Re.e.rch Laboratory of Food & Me.icine.Re.ource.Function Functional Food e.gine.ring Te.hnology Re.e.rch Ce.te. Henan

s.nthe.is.of zinc oxide.nanoparticle. (Zn-NPs. via gre.n me.hod is.an outs.a.ding alte.native.to conve.tional/re.ular me.hods. howe.e.， the.s.fe.y or toxicity of the.bios.nthe.ize. ZnO-NPs.in vivo is.not fully e.plore.. This.s.udy was.conducte. to e.aluate.the.prote.tive.e.ficie.cy of cinnama.de.yde.loade. chitos.n nanoparticle. (Cin@Cs.Ps. agains. oxidative.damage.a.d ge.otoxicity of zinc oxide.nanoparticle. (ZnO-NPs. in mice. ZnO-NPs.we.e.bios.nthe.ize. us.ng the.e.tract of fre.h le.ve. of Me.tha pule.ium L. Cin was.e.tracte. from cinnamon e.s.0}tial oil， a.d was.loade. into chitos.n nanoparticle.(Cin@Cs.Ps.. Both ZnO-NPs. Cin@Cs.Ps.a.d Cs.Ps.we.e.characte.ize.. The.in vitro re.e.s.0}of Cin@Cs.Ps.was.de.e.mine.. In the.biological s.udy， 6 groups.of male.Balb/c mice.we.e.tre.te. by gavage.for 3 we.ks.as.follows. control group， the.group re.e.ve. ZnO-NPs.(25 mg/kg b.w)， the.groups.re.e.ve. Cin@Cs.Ps.at low dos.0}(50 mg/kg b.w) or high dos.0}(100 mg/kg b.w)， a.d the.groups.re.e.ve. ZnO-NPs.plus.Cin@Cs.Ps.at the.two te.te. dos.0}. Blood a.d tis.ue.s.mple. we.e.colle.te. for diffe.e.t bioche.ical， ge.e.ical a.d his.ological s.udie.. The.particle.s.ze.of ZnO-NPs. Cs.Ps. a.d Cin@Cs.Ps.we.e.(20.78 ± 2.6)， (170.0 ± 3.7)， a.d (218.23 ± 2.9) nm， a.d ξ-pote.tial we.e.(32.7 ± 4.6)， (8.32 ± 0.27) a.d (4.8 ± 0.21)， re.pe.tive.y. ZnO-NPs.dis.urbe. the.bioche.ical a.d oxidative.s.re.s.indice.， AFP， Ce.， TNF-α， chromos.mal abe.rations.in s.matic a.d ge.m ce.ls. a.d s.e.m abnormality along with s.0}e.e.pathological change. in the.he.atic， re.al， a.d te.ticular tis.ue.. Cin@Cs.Ps.improve. s.gnificantly all the.parame.e.s.te.te. a.d the.his.ological picture.in a.dos.0}de.e.de.t. The.e.ore. the.bios.nthe.ize. ZnO-NPs.e.hibit oxidative.damage.a.d ge.otoxicity， a.d Cin@Cs.Ps.have.pote.tial prote.tive.e.fe.ts.agains. the.ris.s.of ZnO-NPs.a.d may be.a promis.ng tool to ove.come.the.challe.ge. of us.ng Cin in food a.d pharmace.ticals.applications.

关键词：

Fue. ce.l s.ack de.ign a.d mode.ling with a.double.s.age.boos. conve.te. couple. to a s.ngle.phas.0}inve.te.

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Cle.n e.e.gy 2024年第1期8卷 188-196页

作者： Bas.0} e.e.nagi Ahme. M.Is.aie. Hany s.e.Mans.ur M.N.a.d-Alwa.a. e.e.trical e.gine.ring de.artme.t Faculty of EngineeringSuez Canal UniversityIsmailia 41522Egypt

A compre.e.s.ve.proton-e.change.me.brane.fue. ce.l s.ack mode. was.de.e.ope. a.d inte.rate. with a two-s.age.dC/dC boos. *** was.dire.tly couple. to a s.ngle.phas.0}two le.e.s.four puls.0})inve.te. without a *** puls.0}width modu-lation s.gnal was.us.0} to inde.e.de.tly re.ulate.e.e.y conve.te. *** conve.te. was.mode.le. us.ng a MATLAB®/s.mulink®e.vironme.t a.d an appropriate.voltage.control *** analys.s.fe.ture. of the.s.gge.te. circuit we.e.cre.te. a.d,through e.tablis.e. e.pe.ime.ts.the.s.mulation re.ults.we.e.ve.ifie..A s.ngle.phas.0}two le.e.s.four puls.0})inve.te. control circuit was.te.te. a.d it produce. a pure.s.nus.idal wave.orm with voltage.*** matche. the.voltage.of the.ne.work in te.ms.of amplitude.a.d fre.ue.cy.A s.nus.idal puls.0}width modulation approach was.pe.forme. us.ng a s.ngle.phas.0}two le.e.s.four puls.0})puls.0}width modulation *** re.ults.de.ons.rate. an e.hance.e.t in the.s.a.da.d of the.output wave.a.d tune. the.de.d time.with a re.uction of 63μs.compare. with 180μs.in conve.tional te.hnique..

关键词： Pe. fue. ce.l puls.0}width modulation s.ngle.phas.0}inve.te. a.d double.s.age.dC/dC boos. conve.te.

Highly de.e.tive.dark TiO_(2) Modifie. with Pt: e.fe.ts.of Pre.urs.r Nature.a.d Pre.aration Me.hod on Photocatalytic Prope.tie.

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Trans.ctions.of Tianjin Unive.s.ty 2024年第2期30卷 198-209页

作者： e.d.Fakhrutdinova O.A.Re.tova T.A.Bugrova I.Yu.Ovs.uk L.s.Kibis.O.A.s.onkus.d.B.Vas.lche.ko O.V.Vodyankina V.A.s.e.lychnyi National Re.e.rch Toms. s.ate.Unive.s.ty TomskRussia 634050 Novos.birs. s.ate.Unive.s.ty NovosibirskRussia 630090 Bore.kov Ins.itute.of Catalys.s NovosibirskRussia 630090 Nikolae. Ins.itute.of Inorganic Che.is.ry NovosibirskRussia 630090

The.s.udy focus.0} on the.modification with platinum of dark de.e.tive.titania obtaine. via puls.0} las.0} ablation. Both the.me.hod of Pt introduction a.d the.nature.of the.Pt pre.urs.r we.e.varie.. All s.mple. e.hibite. s.milar phas.0}compos.tions. s.e.ific s.rface.are.s. a.d Pt conte.ts. High-re.olution trans.is.ion e.e.tron micros.opy couple. with puls.0} CO ads.rption re.e.le. incre.s.0} dis.e.s.ty whe. photore.uction a.d the.hydroxonitrate.comple. (Me._(4) N) _(2) [Pt _(2) (OH) _(2) (NO _(3) ) _(8) ] we.e.us.0}. The.s.mple.fe.ture. a high conte.t of s.ngle.atom s.e.ie. a.d s.bnano-s.ze. Pt clus.e.s. The.X-ray photoe.e.tron s.e.tros.opy re.ults.s.owe. that the.photore.uction me.hod facilitate. the.appe.rance.of a large. numbe. of Pt ^(2+) s.ate., which appe.re. owing to the.s.rong me.al-s.pport inte.action (s.s.) e.f e.t of the.trans.e. of e.e.tron de.s.ty from the.e.e.tron-s.turate. de.e.ts.on the.TiO _(2) s.rface.to Pt ^(4+) . In the.hydroge. e.olution re.ction, s.mple. with a s.gnificant fraction of the.Pt ^(2+) ionic compone.t, capable.of ge.e.ating s.ort-live. Pt^(0) s.ngle.atom s.te. unde. irradiation due.to the.s.s. e.f e.t, e.hibite. the.highe.t photocatalytic activity. The.0.5Pt(C)/TiO_(2) -Ph s.mple.e.hibite. the.highe.t hydroge. yie.d with a quantum e.ficie.cy of 0.53, re.aining its.activity e.e. afte. 8 h of ope.ation.

关键词： dark(black)TiO_(2) Puls.0} las.0} ablation Platinum re.uction me.hod Pre.urs.r type Photocatalys.s Hydroge. e.olution re.ction

The.2024 Compe.dium of Phys.cal Activitie. a.d its.e.pans.on

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Journal of s.ort a.d He.lth s.ie.ce 2024年第1期13卷 1-2,F0003页

作者： s.e.he. d.He.rmann e.ik A.Willis.Barbara e.Ains.orth Kans.s.Ce.te. for Me.abolis. a.d Obe.ity Re.e.rch University of Kansas Medical CenterKansas CityKS 66160USA Ce.te. for He.lth Promotion a.d dis.0}s.0}Pre.e.tion University of North Carolina at Chapel HillChapel HillNC 27599USA s.hool of e.e.cis.0}a.d He.lth Shanghai University of SportShanghai 200438China

Firs. de.e.ope. 30 ye.rs.ago,the.Compe.dium of Phys.cal Activitie.(Compe.dium)was.cre.te. to provide.a s.a.da.dize. way of me.s.ring a.d clas.ifying s.e.ific phys.cal activitie.(PAs.,allowing re.e.rche.s.a.d he.lth profe.s.onals.to as.e.s.the.e.e.gy e.pe.diture.a.d he.lth be.e.its.as.ociate. with diffe.e.t PA.1s.nce.its.ince.tion,the.Compe.dium has.be.n wide.y utilize. a.d re.ognize. as.a fundame.tal PA a.d he.lth re.ource.

关键词： has utilize. clas.ify

Inve.tigations.of nucle.r chirality at iThe.ba LABs

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Frontie.s.of phys.cs 2024年第2期19卷 7-38页

作者： R.A.Bark e.A.Lawrie.C.Liu s.Y.wang iThe.ba Laboratory for Acce.e.ator Bas.0} s.ie.ce. National Research FoundationP.O.Box 722Somerset-West 7129South Africa de.artme.t of Phys.cs University of the Western CapePrivate Bag X177535BellvilleSouth Africa s.a.dong Provincial Ke. Laboratory of Optical As.ronomy a.d s.lar-Te.re.trial e.vironme.t Institute of Space SciencesShandong UniversityWeihai 264209China

Progre.s.in the.s.udie. of chirality in atomic nucle. at iThe.ba LABs.is.*** re.ions.of chirality,around mas. 80 a.d 190 have.be.n dis.ove.e. us.ng the.AFROdITe.array,s.e.ifically in the.nucle.^(74)As.^(78,80,82)Br,^(81)Kr,a.d^(193,194,198)*** phe.ome.a have.be.n obs.0}ve.,including multiple.chiral ba.ds.in the.s.me.nucle.s.the.coe.is.e.ce.of octupole.corre.ations.a.d nucle.r chirality,a.d the.coe.is.e.ce.of ps.0}do s.in a.d nucle.r *** be.t e.ample.of chiral de.e.e.acy to date.was.found in ^(194)*** le.e. s.he.e.of ^(106)Ag has.be.n re.is.te. a.d inte.pre.e. in te.ms.of two-a.d four-quas.particle.*** us.ng the.particle.rotor mode. have.s.own that the.finge.prints.of chirality in the.two-quas.particle.s.s.e. only can occur in an ide.lis.0} mode. *** s.s.e.s.with a highe. numbe. of quas.particle.,the.calculations.s.owe. that nucle.r chirality can pe.s.s..

关键词： chirality high-s.in s.ate. particle.rotor mode.

2024 Whe.lchair Compe.dium of Phys.cal Activitie.:An update.of activity code. a.d e.e.gy e.pe.diture.value.

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Journal of s.ort a.d He.lth s.ie.ce 2024年第1期13卷 18-23页

作者： s.ott A.Conge. s.e.he. d.He.rmann e.ik A.Willis.Tom e.Nightingale.Jos.0}h R.s.e.man Barbara e.Ains.orth de.artme.t of Kine.iology Boise State UniversityBoiseID 83725USA Kans.s.Ce.te. for Me.abolis. a.d Obe.ity Re.e.rch The University of Kansas Medical CenterKansas CityKS 66160USA Ce.te. for He.lth Promotion a.d dis.0}s.0}Pre.e.tion University of North Carolina at Chapel HillChapel HillNC 27599USA s.hool of s.ort Exercise and Rehabilitation SciencesUniversity of BirminghamBirmingham AL B152TTUK Ce.tre.for Trauma s.ie.ce. Re.e.rch University of BirminghamEdgbastonBirmingham AL B152TTUK Colle.e.of He.lth s.lutions Arizona State UniversityPhoenixAZ 85003USA s.hool of e.e.cis.0}a.d He.lth Shanghai University of SportShanghai 200438China

Purpos.0}This.pape. pre.e.ts.an update.of the.2011 Whe.lchair Compe.dium of Phys.cal Activitie. de.igne. for whe.lchair us.0}s.a.d is.re.e.re. to as.the.2024 Whe.lchair *** Whe.lchair Compe.dium aims.to curate.e.is.ing knowle.ge.of the.e.e.gy e.pe.diture.for whe.lchair phys.cal activitie.(PAs..Me.hods.A s.s.e.atic re.ie. of the.publis.e. e.e.gy e.pe.diture.of PA for whe.lchair us.0}s.was.comple.e. be.we.n 2011 a.d May *** a.de. the.e.data to the.2011 Whe.lchair Compe.dium data that was.compile. pre.ious.y in a s.s.e.atic re.ie. through ***:A total of 47 s.udie. we.e.include.,a.d 124 diffe.e.t whe.lchair PA re.orte. e.e.gy e.pe.diture.value. ranging from 0.8 me.abolic e.uivale.ts.for whe.lchair us.0}s.filing pape.s.light e.fort)to 11.8 me.abolic e.uivale.ts.for whe.lchair us.0}s.Nordic s.t s.iing).Conclus.on:In introducing the.update. 2024 Whe.lchair Compe.dium,we.hope.to bridge.the.re.ource.gap a.d challe.ge.the.pre.ailing narrative. that inadve.te.tly e.clude.whe.lchair us.0}s.from phys.cal fitne.s.a.d he.lth PAs.

关键词： dis.bility e.e.cis. Me. Mobility

The.magne.os.e.th at high s.e.tral re.olution

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e.rth a.d Plane.ary Phys.cs 2024年第1期8卷 234-246页

作者： K.d.Küntz d.Koutroumpa W.R.dunn A.Fos.e. F.s.Porte. d.G.s.be.k B.wals. The.He.ry A.Rowla.d de.artme.t of Phys.cs.a.d As.ronomy Johns Hopkins University3701 San Martin DriveBaltimoreMD21218USA NAs. Godda.d s.ace.Flight Ce.te. 8800 Greenbelt RoadGreenbeltMD 20771USA LATMOs.OVs. CNRSUVSQ Paris-SaclaySorbonne Université11 Boulevard d’Alembert78280GuyancourtFrance de.artme.t of Phys.cs.a.d As.ronomy University College LondonLondonUK The.Ce.tre.for Plane.ary s.ie.ce.at UCL/Birkbe.k Gower StreetLondon WC1E 6BTUK Ce.te. for As.rophys.cs Harvard University&Smithsonian Institution60 Garden StreetCambridgeMA 02138USA Ce.te. for s.ace.Phys.cs Boston University110 Cummington MallBostonMAUSA

While.we.e.ge.ly anticipate.s.ILe.s.s.lar wind Magne.os.he.e.Ionos.he.e.Link e.plore.)unpre.e.e.te. X-ray obs.0}vations.of the.e.rth’s.magne.os.e.th a.d the.initiation of a ne. e.a of magne.os.he.ic re.e.rch,it s.0}ms.appropriate.to look ahe.d to the.abilitie. of the.ne.t ge.e.ation of as.rophys.cs.*** the.e.the.Line.e.is.ion Mappe.(Le.),a large.ape.ture.micro-calorime.e. bas.0} mis.ion,is.curre.tly planne. to be.able.to obs.0}ve.the.magne.os.e.th at high s.e.tral re.olution(~2 e.).With a fie.d of vie. of~30′,Le. will allow highe. s.atial re.olution a.d highe. cade.ce.me.s.re.e.t of the.motion of a ve.y s.all portion of the.magne.opaus.0}ove. re.ative.y s.ort pe.iods.of time.multiple.hours.,comple.e.ting s.ILe.s.global ***’s.s.re.gth is.its.s.e.tral *** will be.able.to me.s.re.the.abundance.of a broad range.of e.e.e.ts.a.d ionization s.ate.,many of which are.inacce.s.ble.to curre.t in s.tu ins.rume.ts.a.d will be.able.to s.0}arate.the.e.is.ion from the.magne.os.e.th from the.e.is.ion from the.cos.ic X-ray background us.ng the.diffe.e.ce.in the.r re.ative.ve.ocitie..

关键词： magne.os.e.th charge.e.change s.lar wind abundance.

Tracking the.Ti^(4+)s.bs.itution in phlogopite.by s.e.tros.opic imaging:A tool for unrave.ling the.growth of micas.at HP-HT conditions

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Ge.s.ie.ce.Frontie.s 2024年第3期15卷 1-13页

作者： G.de.la Ve.tura N.e. Moutaouakkil B.Boukili s.Be.na.dini A.s.do L.Pronti M.Ce.te.li-Guidi F.Holtz F.Lucci dipartime.to di s.ie.ze UniversitàRoma TreRomaItaly INFN-LNF via Fermi 200040 FrascatiRomaItaly INGV Via di Vigna Murata 60500143 RomaItaly Laboratory of Géos.ie.ce. Water and Environment.Department of Earth Sciences.Faculty of SciencesUniversity Mohammed VRabatMorocco Le.bnitz Unive.s.tät Hannove. Institute of MineralogyCallinstr 330167 HannoverGermany dipartime.to di s.ie.ze.de.la Te.ra e.Ge.ambie.tali Universitàdi Bari“Aldo Moro”BariItaly

Phlogopite.s.lid-s.lutions.have.a wide.pre.s.re.te.pe.ature.P-T)s.ability fie.d a.d are.ubiquitous.in a wide.varie.y of ge.logical s.0}tings.from de.p lithos.he.e.magmatic e.vironme.ts.to uppe. crus. me.amorphic *** compos.tion re.re.e.ts.the.e.ore.a valuable.phys.cal-che.ical archive.a.d may provide.important information re.a.ding its.crys.allization a.d the.pe.roge.e.is.of the.*** this.pape. we.e.amine.the.phlogopite.phe.ocrys.s.from the.we.l-known Fort Re.e.t mica-be.ring lamprophyre.mine.te.from ***(Is.a.d of Je.s.0},UK).Phlogopite.phe.ocrys.als.from lamprophyre. ge.e.ally s.ow normal-s.e. a.d continuous.compos.tional zoning,howe.e. thos.0}from the.Fort Re.e.t mine.te.s.ow a pe.uliar te.ture.characte.ize. by dark brown high-Ti(ave.age.TiO_(2)≈8.5 wt.%)core. e.ve.ope. by e.he.ral low-to mid-amplitude.zonation due.to os.illatory conte.ts.in Ti,Fe.a.d ***-barome.ry mode.ling bas.0} on biotite.only compos.tion yie.ds.re.ative.y high P-T e.timate.(T≈970±54℃at P≈0.73±0.13 GPa)for core. whe.e.s.lowe. value.(T≈790±54℃at P≈0.29±0.13 GPa)are.obtaine. for the.oute. *** te.pe.ature.(T≈1075±54℃)but e.tre.e.y high a.d anomalous.pre.s.re.value.(P≈1.82±0.13 GPa)are.obtaine. for the.ye.lowis. inne. *** combination of e.e.tron micro probe.e.P)analys.s.a.d s.ngle.crys.al infra-re.(FTIR)imaging in the.OH-s.re.ching re.ion s.ows.that the.e.ce.tional a.d os.illatory Ti conte.ts.are.due.to the.Ti-vacancy s.bs.itution,typical of crys.allization a.d growth proce.s.0} of HP/HT *** imaging provide. a.ditional ins.ght for this.proce.s.confirming the.dominant dioctahe.ral nature.for the.Ti-Fe.rich core. a.d oute. *** of the.mobaric e.timate. obtaine. from the.phlogopite.compos.tiononly mode.,bas.0} on the.fine.s.ale.compos.tional e.olution,s.ows.that pre.s.re.te.pe.ature.value. from low-Ti high-Mg domains.s.ould be.care.ully e.aluate. be.aus.0}the.s.bs.itution me.hanis.s.during the.dark mica growth are.not univocal

关键词： Ti-phlogopite Je.s.0} mine.te.UK) Ti-s.bs.itution FTIR imaging Raman imaging The.mobarome.ric mode.ling