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Kinetics of Al Evaporation from Liquid U-Al Alloys in Vacuum Induction Melting

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journal of Materials Science & Technology 2015年第4期31卷 423-426页

作者： Y.j.duan B.Chen Y.C.Ma K.Liu Materials for Special Environment Division Institute of Metal ResearchChinese Academy of Sciences

A research on kinetics of Al evaporation from liquid U—Al alloys was made in a vacuum induction melting（VIM） furnace at 1673—1843 *** evaporation rate of Al was found to be first order with respect to Al content in the *** overall mass transfer coefficient of Al was determined and it was found that the evaporation rate of Al increased with increasing *** apparent activation energy of Al evaporation at 1673-1843 K was 171.5 kj *** value of mass transfer coefficient of Al in the liquid phase was estimated to be 3.77 × 10-6,7.41×10-6,and 9.40 × 10-6m s-1at 1673,1753,and 1843 K,***,rate determining steps were discussed and it was concluded that the evaporation rate of Al is mainly controlled by liquid phase mass transfer.

关键词： Al evaporation Kinetics Liquid U-Al alloys Mass tr

Determination of Vapor Pressure of Liquid Copper by Carrier Gas Method

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journal of Materials Science & Technology 2013年第12期29卷 1209-1213页

作者： Y.j.duan B.Chen Y.C.Ma M.Gao K.Liu Institute of Metal Research Chinese Academy of Sciences

The relationship between the vapor pressure of liquid copper and the flow rate of carrier gas argon was discussed, when the carrier gas method was used to determine the vapor pressure of liquid copper at 1892 K. The proper argon flow rate range obtained was 150-500 mL/min and enough evidence was provided to verify the vapor pressure-flow rate of carrier gas relationship at the target temperature. Based on the proper flow rate range, the vapor pressure of liquid copper was measured at 1609-1892 K. The relationship of vapor pressure-temperature obtained by the method of regression analysis can be expressed as： In（p/Pa） = （25.470 -I- 0.903） - （39099.8 -4- 1574.5）/T, Further, the thermodynamic properties including the heat of vaporization and the Gibbs free energy of the Cu （I） = Cu （g） reaction were calculated by the vapor pressijre obtained over the temperature range covered.

关键词： Carrier gas method Liquid copper vapor pressure Thermodynamic property of copper

Analysis of the anelastic deformation of high-entropy Pd_(20)Pt_(20)Cu_(20)Ni_(20)P_(20) metallic glass under stress relaxation and recovery

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journal of Materials Science & Technology 2022年第12期107卷 82-91页

作者： Y.j.duan L.T.Zhang T.Wada H.Kato E.Pineda D.Crespo j.M.Pelletier j.C.Qiao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical UniversityXi’an 710072China Department of Physics Institute of Energy TechnologiesUniversitat Politècnica de CatalunyaBarcelona 08019Spain Institute for Materials Research Tohoku UniversitySendai 980-8577Japan Universitéde Lyon MATEISUMR CNRS5510Bat.B.PascalINSA-LyonF-69621 Villeurbanne CedexFrance

The anelastic deformation behavior of Pd_(20)Pt_(20)Cu_(20)Ni_(20)P_(20) high-entropy metallic glass was probed by monitoring the stress relaxation and recovery processes. The stress relaxation under consecutive strain steps can be described by the Kohlrausch-Williams-Watts(KWW) function. In addition, considering a hierarchy of relaxation processes related to the structural heterogeneity, a constitutive model is proposed in order to describe the whole process of stress relaxation and determine the contribution of different time scales. Moreover, a crossover from stochastic activation to percolation of flow defects with the ultimate strain can be observed during stress relaxation process. The anelastic recovery process after a strain step is studied as a function of the initial strain level and characterized by means of a direct spectrum analysis. The peaks in the recovery time-spectra revealed the evolution of flow defects in Pd_(20)Pt_(20)Cu_(20)Ni_(20)P_(20) high-entropy metallic glass. The understanding of the atomic free-volume zones effect and the anelastic deformation provides important insight into how atomic structural features affect the deformation behavior of high-entropy metallic glasses, and may provide a new avenue into the improvement of their mechanical properties.

关键词： High-entropy metallic glass Stress relaxation Anelastic deformation Flow defects Free-volume zones

Dynamic mechanical relaxation behavior of Zr_(35)Hf_(17.5)Ti_(5.5)Al_(12.5)Co_(7.5)Ni_(12)Cu_(10)high entropy bulk metallic glass

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journal of Materials Science & Technology 2021年第24期83卷 248-255页

作者： L.T.Zhang Y.j.duan T.Wada H.Kato j.M.Pelletier D.Crespo E.Pineda j.C.Qiao School of Mechanics Civil Engineering and ArchitectureNorthwestern Polytechnical UniversityXi’an710072China Institute for Materials Research Tohoku UniversitySendai980-8577Japan Universitéde Lyon MATEISUMR CNRS5510Bat.B.PascalINSA-LyonF-69621Villeurbanne CedexFrance Department of Physics Barcelona Research Center in Multiscale Science and TechnologyInstitute of Energy TechnologiesUniversitat Politècnica de Catalunya08019BarcelonaSpain

Non-equiatomic high entropy bulk metallic glasses were reported recently and show unique mechanical and physical *** mechanical relaxation behavior of Zr_(35)Hf_(17.5)Ti_(5.5)Al_(12.5)Co_(7.5)Ni_(12)Cu_(10)high entropy bulk metallic glass was investigated by dynamic mechanical analysis(DMA)and the mechanical spectra could be well described by the quasi-point defects(QPD)*** to typical metallic glasses,the intensity of theβrelaxation of Zr_(35)Hf_(17.5)Ti_(5.5)Al_(12.5)Co_(7.5)Ni_(12)Cu_(10)high entropy bulk metallic glass is lower due to the sluggish *** the same time,the correlation factor is higher than that of conventional metallic glasses and this is ascribed to the high configuration *** parallel,physical aging below the glass transition temperature leads to a decrease of atomic mobility,caused by a decrease of the concentration of defects.

关键词： High entropy bulk metallic glass Mechanical relaxation Quasi-point defects Physical aging

Kinetics Study on Photocatalytic Degradation of Methyl Orange Catalyzed by Sea Urchin-Like Cu2O

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journal of Materials Science and Chemical Engineering 2016年第6期4卷 35-40页

作者： R. j. Gao T. Ding X. j. duan Institutes of Materials Science and Engineering Ocean University of China Qingdao China Zaozhuang Vocational College of Science and Technology Zaozhuang China

Sea urchin-like cuprous oxide with hollow glass microsphere as core was prepared using sodium sulfite as the reducing agent and sodium acetate-acetic acid as buffer solution in copper sulfate solution. Methyl orange was selected as degradation target for photocatalytic experiments. The photocatalytic activities were investigated by visible spectro- photometer. Photocatalytic kinetics parameters were studied by the Langmuir-Hinshelwood model and Arrhenius formula. It was observed that the sea urchin-like morphology dramatically improved the photocatalytic activity of cuprous oxide. The photo-degradation belongs to the first-order reaction and the maximum degradation rate could reach 94.37%. The activation energy and pre-exponential factor are 41.18 Kj·mol-1 and 1.07 × 106, respectively. After seven times recycling, the sample still showed high photo-catalytic efficiency and stability.

关键词： Cuprous Oxide Sea Urchin-Like Photo-Catalyst Reaction Kinetic Methyl Orange

Tumor necrosis factor-stimulated gene-6 ameliorates early brain injury after subarachnoid hemorrhage by suppressing NLRC4 inflammasome-mediated astrocyte pyroptosis

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Neural Regeneration Research 2024年第5期19卷 1064-1071页

作者： Mingxiang Ding Lei jin Boyang Wei Wenping Cheng Wenchao Liu Xifeng Li Chuanzhi duan Neurosurgery Center Department of Cerebrovascular SurgeryThe National Key Clinical SpecialtyThe Engineering Technology Research Center of Education Ministry of China on Diagnosis and Treatment of Cerebrovascular DiseaseGuangdong Provincial Key Laboratory on Brain Function Repair and RegenerationThe Neurosurgery Institute of Guangdong ProvinceZhujiang HospitalSouthern Medical UniversityGuangzhouGuangdong ProvinceChina Department of Cerebrovascular Intervention Zhongshan City People’s HospitalZhongshanGuangdong ProvinceChina

Subarachnoid hemorrhage is associated with high morbidity and mortality and lacks effective *** is a crucial mechanism underlying early brain injury after subarachnoid *** studies have confirmed that tumor necrosis factor-stimulated gene-6(TSG-6)can exert a neuroprotective effect by suppressing oxidative stress and ***,no study to date has explored whether TSG-6 can alleviate pyroptosis in early brain injury after subarachnoid *** this study,a C57BL/6j mouse model of subarachnoid hemorrhage was established using the endovascular perforation *** results indicated that TSG-6 expression was predominantly detected in astrocytes,along with NLRC4 and gasdermin-D(GSDMD).The expression of NLRC4,GSDMD and its N-terminal domain(GSDMD-N),and cleaved caspase-1 was significantly enhanced after subarachnoid hemorrhage and accompanied by brain edema and neurological *** explore how TSG-6 affects pyroptosis during early brain injury after subarachnoid hemorrhage,recombinant human TSG-6 or a siRNA targeting TSG-6 was injected into the cerebral *** TSG-6 administration downregulated the expression of NLRC4 and pyroptosis-associated proteins and alleviated brain edema and neurological ***,TSG-6 knockdown further increased the expression of NLRC4,which was accompanied by more severe astrocyte *** summary,our study revealed that TSG-6 provides neuroprotection against early brain injury after subarachnoid hemorrhage by suppressing NLRC4 inflammasome activation-induced astrocyte pyroptosis.

关键词： astrocyte early brain injury inflammasome NLRC4 pyroptosis subarachnoid hemorrhage tumor necrosis factor-stimulated gene-6(TSG-6)

Measurement of the banana pseudo-stem phenotypic parameters based on ellipse model

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International journal of Agricultural and Biological Engineering 2022年第3期15卷 195-202页

作者： Yinlong jiang jieli duan Xing Xu Yunhe Ding Yang Li Zhou Yang College of Engineering South China Agricultural UniversityGuangzhou 510642China Guangdong Laboratory for Lingnan Modern Agriculture Guangzhou 510642China College of Electronic Engineering(College of Artificial Intelligence) South China Agricultural UniversityGuangzhou 510642China Guangdong Provincial Key Laboratory of Conservation and Precision Utilization of Characteristic Agricultural Resources in Mountainous Areas Jiaying UniversityMeizhou 514015GuangdongChina

The measurement of banana pseudo-stem phenotypic parameters is a critical way to evaluate the growth status of bananas,and it can provide essential data support for mechanized cultivation operations such as fertilization and pesticide *** studies mainly measure the diameter of banana pseudo-stem as its phenotypic *** banana pseudo-stem cross section was closer to an ellipse other than a standard circle,so the diameter parameter cannot adequately represent the phenotypic characteristics of the banana *** this study,an automatic measuring device for banana pseudo-stem phenotypic parameters was *** device,which integrates three different types of sensors:a laser ranging sensor,a rotary encoder,and a digital camera,were used to obtain the point cloud and image data of banana pseudo-stem.A K-means point clouds clustering algorithm based on Euclidean distance was *** point cloud of banana pseudo-stem was identified and extracted.A three-dimensional reconstruction algorithm based on the ellipse model was also *** three-dimensional contour of the pseudo-stem was calculated to obtain three types of phenotypic parameters:the long axis length,the short axis length,and the ***,a synchronous trigger image acquisition mechanism was used to take pictures of pseudo-stems during *** can be utilized for manual assessment of the growth status of the *** experimental results showed that the three banana phenotypic parameters had a high correlation with the manual measurement results,and R^(2)is always more significant than 0.95,the total average measurement error and relative error were only 6.16 mm and 4.38%,respectively,both are within the acceptable agronomy *** general,this method has good universality for plant stem detection,and the stem phenotypic parameters can be obtained by means of non-contact test,which is of great significance to the mechanized cultivation of the forest and f

关键词： multi-sensor fusion point cloud fitting phenotypic parameter extraction banana pseudo-stem ellipse model

Enhanced bifunctional oxygen electrochemical catalytic performance using La-doped CoFe_(2)O_(4)spinel supported by 3D-G for Zn-air batteries

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journal of Energy Chemistry 2024年第7期94卷 778-788页

作者： Yinggang Sun Tingwei Zhang Peng Sun jigang Wang Wenjie duan Yanqiong Zhuang Likai Wang Zhongfang Li School of Chemistry and Chemical Engineering Shandong University of TechnologyZibo 255049ShandongChina

The preparation of bifunctional catalysts for oxygen reduction(ORR)and oxygen evolution(OER)is crucial for Zn-air ***,we report a La doped CoFe_(2)O_(4) spinel catalyst supported on threedimensional graphene(3D-G),where La can facilitate electron transfer from Co to Fe,leading to increased electron cloud density in Fe and improved catalytic *** redshift of the G peak in the Raman spectra indicates the interaction between theπbond of 3D-G and d orbitals in La_(0.2)CoFe_(1.8)O_(4).La_(0.2)CoFe_(1.8)/3D-G exhibits superior ORR performance(E_(1/2)=0.86 V ***)and OER performance(E_(j=10)=1.55 V ***)to CoFe_(2)O_(4)/3D-G(E_(1/2)=0.831 V ***,E_(j=10)=1.603 V ***).Furthermore,it demonstrates excellent bifunctional oxygen catalytic performance while maintaining high power density and stability in liquid zinc-air batteries(ZABs)and flexible ZABs(F-ZABs).This work presents a viable strategy for utilizing rare earth element doped spinels to enhance oxygen catalyst and ZABs performance.

关键词： Zn-air batteries Electrocatalysts La_(0.2)CoFe_(1.8)/3D-G Electron pump Bifunctional oxygen catalytic performance

Cooperative Rate Splitting Transmit Design for Full-Duplex-Enabled Multiple Multicast Communication Systems

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工程与科学中的计算机建模(英文) 2024年第1期138卷 619-638页

作者： Siyi duan Mingsheng Wei Shidang Li Weiqiang Tan Bencheng Yu School of Physics and Electronic Engineering Jiangsu Normal UniversityXuzhou221116China School of Computer Science and Cyber Engineering Guangzhou UniversityGuangzhou510006China School of Information Engineering Xuzhou Vocational College of Industrial TechnologyXuzhou221140China

This paper examines the performance of Full-Duplex Cooperative Rate Splitting(FD-CRS)with Simultaneous Wireless Information and Power Transfer(SWIPT)support in Multiple Input Single Output(MISO)*** a Rate Splitting Multiple Access(RSMA)multicast system with two local users and one remote user,the common data stream contains the needs of all users,and all users can decode the common data ***,each user can receive some information that other users need,and local users with better channel conditions can use this information to further enhance the reception reliability and data rate of users with poor channel *** using Cell-Center-Users(CCUs)as a cooperative relay to assist the transmission of common data can improve the average system *** maximize the minimum achievable rate,we optimize the beamforming vector of Base Station(BS),the common streamsplitting vector,the cooperative distributed beamvector and the strong user transmission power under the power budget constraints of BS and relay devices and the service quality requirements constraints of *** the whole problem is not convex,we cannot solve it ***,we propose a low complexity algorithm based on Successive Convex Approximation(SCA)technology to find the optimal solution to the problemunder *** simulation results show that FD C-RSMA has better gain andmore powerful than FD C-NOMA,HD C-RSMA,RSMA and NOMA.

关键词： Full-duplex cooperative rate segmentation SWIPT RSMA power control