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岩石工程与环境保护

长江科学院院报 2009年第4期26卷 22-26页

作者：董学晟长江科学院科学技术委员会武汉430010

近年来,环境保护问题变得越来越紧迫,作为一种可再生能源,水力发电受到了极大的重视,但它却并不是一种绝对清洁的能源。不论是在施工期还是在运行期,水力发电工程都会给环境和生态条件施加一些负面的影响。施工中大量的土石方开挖完全... 详细信息

近年来,环境保护问题变得越来越紧迫,作为一种可再生能源,水力发电受到了极大的重视,但它却并不是一种绝对清洁的能源。不论是在施工期还是在运行期,水力发电工程都会给环境和生态条件施加一些负面的影响。施工中大量的土石方开挖完全毁坏了建设场地上的植被和土壤,导致大面积水土流失,增加了潜在的滑坡数量。在进行西南水电开发的规划和建设时,应当就区域内梯级电站建设对环境和生态条件的综合影响和长期影响进行详尽的研究和分析,并提出了几条减少土石方开挖的原则性建议。

关键词：岩石力学水力发电环境保护生态条件土石方开挖

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可分离连接器与套管装配后电场仿真分析

电工电气 2023年第3期 55-59页

作者：董雪生上海安亦极企业发展有限公司上海200090

为了研究可分离连接器与套管在不同配合尺寸下的电场分布特性并给出合理的结构设计方案及安装配合尺寸,调研了几种12 kV开关柜用可分离连接器及套管的典型结构,对不同配合尺寸及屏蔽方式下电场进行仿真分析。在此基础上,引入了放电概率... 详细信息

为了研究可分离连接器与套管在不同配合尺寸下的电场分布特性并给出合理的结构设计方案及安装配合尺寸,调研了几种12 kV开关柜用可分离连接器及套管的典型结构,对不同配合尺寸及屏蔽方式下电场进行仿真分析。在此基础上,引入了放电概率系数α,判断首先发生放电的位置。结果表明:配合尺寸和屏蔽方式对套管与可分离连接器安装配合后电场分布影响较大,在环氧树脂中埋入金属网作为屏蔽并减小屏蔽网端部距离套管锥度端部的尺寸,增加与套管配合的可分离连接器台阶尺寸,以及可分离连接器采用屏蔽层与绝缘层平齐的屏蔽方式,可以起到均匀电场的作用。

关键词：可分离连接器套管配合尺寸屏蔽方式

Small extracellular vesicles derived from human induced pluripotent stem cell-differentiated neural progenitor cells mitigate retinal ganglion cell degeneration in a mouse model of optic nerve injury

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Neural Regeneration Research 2025年第2期20卷 587-597页

作者： Tong Li Hui-Min Xing Hai-dong Qian Qiao Gao sheng-Lan Xu Hua Ma Zai-Long Chi State Key Laboratory of Ophthalmology Optometry and Visual ScienceEye HospitalWenzhou Medical UniversityWenzhouZhejiang ProvinceChina National Clinical Research Center for Ocular Diseases Eye HospitalWenzhou Medical UniversityWenzhouZhejiang ProvinceChina

Several studies have found that transplantation of neural progenitor cells(NPCs)promotes the survival of injured ***,a poor integration rate and high risk of tumorigenicity after cell transplantation limits their clinical *** extracellular vesicles(sEVs)contain bioactive molecules for neuronal protection and *** studies have shown that stem/progenitor cell-derived sEVs can promote neuronal survival and recovery of neurological function in neurodegenerative eye diseases and other eye *** this study,we intravitreally transplanted sEVs derived from human induced pluripotent stem cells(hiPSCs)and hiPSCs-differentiated NPCs(hiPSC-NPC)in a mouse model of optic nerve *** results show that these intravitreally injected sEVs were ingested by retinal cells,especially those localized in the ganglion cell *** with hiPSC-NPC-derived sEVs mitigated optic nerve crush-induced retinal ganglion cell degeneration,and regulated the retinal microenvironment by inhibiting excessive activation of *** analysis further revealed that hiPSC-NPC derived sEVs transported neuroprotective and anti-inflammatory miRNA cargos to target cells,which had protective effects on RGCs after optic nerve *** findings suggest that sEVs derived from hiPSC-NPC are a promising cell-free therapeutic strategy for optic neuropathy.

关键词： exosome miRNA neural progenitor cell neurodegeneration neuroinflammation neuroprotection optic nerve crush optic neuropathy retinal ganglion cell small extracellular vesicles

Facile synthesis of the dodecahydridododecaborate (B12H122-) from borane Lewis base adducts

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Science China Chemistry 2025年

作者： Yi Jing Xin-Ran Liu Xing-Hua Wang Hui Han Sha-Sha Liang Xi-Meng Chen dong-Hui Wei Lai-sheng Wang xue-Nian Chen College of Chemistry Zhengzhou University School of Chemistry and Chemical Engineering Henan Key Laboratory of Boron Chemistry and Advanced MaterialsHenan Normal University Department of Chemistry Brown University

Polyhedral boranes are a class of well-known boron molecular clusters widely used in energy,chemistry,medicine,and materials science because of their unique physical and chemical *** efforts have been made in the past decades to find more effective synthetic methods for this important class of boron ***,existing synthetic methods suffer from low efficiency and low ***,we report a facile one-pot synthesis of[（CH3）3S]2B12H12with moderate yields at mild *** mechanisms for the multi-step chemoselective synthesis of B12H122-without other by-products are elucidated based on theoretical results and our previous *** Lewis base used in B–H bond condensation reaction,which acts as a hydrogen or to balance the newly generated polyhedral borane charges,is proposed and studied in *** current study has led to a more effective and selective synthetic method for B12H122-and has also implicated the syntheses of other new polyhedral boranes.

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Plasmonic tandem heterojunctions enable high-efficiency charge transfer for broad spectrum photocatalytic hydrogen production

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Journal of Energy Chemistry 2025年第1期100卷 710-720页

作者： Wenxuan Chen Xiu-Qing Qiao Guo Hui Bojing Sun dongfang Hou Meidi Wang xueqian Wu Tao Wu dong-sheng Li College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University Hubei Three Gorges Laboratory College of Chemistry and Materials Science and Guangdong Provincial Key Laboratory of Supramolecular Coordination Chemistry Jinan University

Rational engineering of semiconductor photocatalysts for efficient hydrogen production is of great significance but still challenging,primarily due to the limitations in charge transfer ***,a fascinating plasmonic tandem heterojunction with the hc-CdS/Mo2C@C heterostructure is aimfully prepared for effectively promoting the charge separation kinetics of the CdS photocatalyst via the synergistic strategy of phase junction,Schottky junction,and photothermal *** difference in atomic configuration between cubic-CdS （c-CdS） and hexagonal-CdS （h-CdS） leads to effective charge separation through a typical Ⅱ charge transfer mechanism,and plasmonic Schottky junction further extracts the electrons in the hc-CdS phase junction to realize gradient charge ***,the photothermal effect of Mo2C@C helps to expand the light absorption,accelerate charge transfer kinetics,and reduce the hydrogen evolution energy *** carbon layer provides a fast channel for charge transfer and protects the photocatalyst from *** a result,the optimized hc-CMC photocatalyst exhibits a significantly high photocatalytic H2production activity of 28.63 mmol/g/h and apparent quantum efficiency of 61.8%,surpassing most of the reported *** study provides a feasible strategy to enhance the charge transfer kinetics and photocatalytic activity of CdS by constructing plasmonic tandem heterogeneous junctions.

关键词： Cadmium sulfide

Enhanced subacute ischemic stroke treatment via multistage drug delivery system design for combination therapy

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Science China Chemistry 2025年

作者： Xihan Xu Juan-Juan Li Jiamin Li Hui-Yan Zhang Yilin Qi Bing-Sen Shi Tianqi Li Shan-Shan Su Weitao Zhao Chang Chen Zhongying Gong Huiyu Liu Ke-Rang Wang dong-sheng Guo xue xue State Key Laboratory of Medicinal Chemical Biology College of Pharmacy Nankai University College of Chemistry State Key Laboratory of Elemento-Organic Chemistry Key Laboratory of Functional Polymer Materials (Ministry of Education) Frontiers Science Center for New Organic Matter Collaborative Innovation Center of Chemical Science and EngineeringNankai University College of Chemistry and Materials Science State Key Laboratory of New Pharmaceutical Preparations and Excipients Key Laboratory of Medicinal Chemistry and Molecular Diagnosis (Ministry of Education) Key Laboratory of Chemical Biology of Hebei Province Hebei Research Center of the Basic Discipline of Synthetic Chemistry Hebei University Department of Neurology Tianjin First Central Hospital School of Medicine Nankai University Beijing Advanced Innovation Center for Soft Matter Science and Engineering State Key Laboratory of Organic-Inorganic Composites Beijing Laboratory of Biomedical Materials Bionanomaterials & Translational Engineering Laboratory Beijing Key Laboratory of BioprocessBeijing University of Chemical Technology

The management of acute ischemic stroke remains challenging due to its abrupt onset and the narrow treatment window,resulting in high rates of disability and *** therapy for neuroprotection and neurorepair strategies provided new hopes for subacute stroke *** we designed a multistage nanodelivery system that matches the unique microenvironment of the subacute phase of stroke,which utilizes calixarene as a building block to effectively load the neuroprotective drug *** calixarene is designed with glycosidic linkages targeting the glucose transporter 1 (GLUT1)on the blood-brain barrier (BBB) and azo bonds that are responsive to hypoxic ***,the decomposed calixarene molecules themselves possess intrinsic bio-activation to modulate inflammatory responses,achieving a multistage therapeutic approach that transitions from targeting to release and finally to *** approach combines anti-inflammation and neuroprotection,providing a multi-level treatment *** system was validated in a rat model of permanent middle cerebral artery occlusion (pMCAO),demonstrating that intravenous administration of the nanodelivery system repairs brain damage and improves motor function 24 h post-pMCAO *** work offers a precise and integrative strategy for stroke patients missing the acute therapy window to improve functional recovery and enhance the effect of comprehensive treatment.

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Modeling tactile perceived intensity for vibration from a coin eccentric rotating mass motor

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Science China Technological Sciences 2025年

作者： Yun FANG Jingchen HUANG Yujun WU Jiaqi dong Weichao GUO Xinjun sheng State Key Laboratory of Mechanical System and Vibration School of Mechanical Engineering Shanghai Jiao Tong University Meta Robotics Institute Shanghai Jiao Tong University

Establishing the relationship between vibrotactile parameters and perceived intensity（PI） is of great significance in the regulation of desired sensations, which contribute to haptic interfaces in practical applications. Coin eccentric rotating mass（ERM） motors are routinely utilized due to their lightweight design and efficient ability to evoke strong tactile sensations. By adjusting input voltages, ERMs can yield different stimuli, but the effects of their physical properties on PI remain ***, we developed the physical model of the ERM-skin system and optimized the parameters affecting PI. Moreover, the relationship between stimulus and perception was derived based on Fechner?s law. Three experiments were conducted on fifteen subjects（ten males and five females, aged 24.40 ± 2.87 years） to identify the vibration parameters and corresponding PI to verify the proposed PI model. ERMs in this study were attached to phantom skin/forearm with slim adhesive tape to minimize the interference. Experiment 1 performed vibration calibration with ERM attached to the skin phantom to simulate the actual configuration. Then, the relative and absolute PI of subjects on specific stimuli were acquired in Experiments 2 and *** fitting reliability of the proposed PI model was evaluated on fifteen subjects with R2of 0.73 ± 0.07 and root mean squared error（RMSE） of 1.35 ± 0.28. Overall, the proposed PI model established the quantitative relationship between stimulus parameters（vibration parameters and physical parameters） and subjective PI, which provided theoretical support for ERM optimization and vibrotactile modulation.

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红壤区不同生态模式的“土壤水库”特征及其防洪减灾效能

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土壤学报 2003年第5期40卷 656-664页

作者：于东升史学正中国科学院南京土壤研究所南京210008

本文在江西红壤区选择 5种具有代表性的红壤生态利用模式 :稀疏林生态 (Ⅰ )、林草生态(Ⅱ )、草灌生态 (Ⅲ )、经果生态 (Ⅳ )、农田生态 (Ⅴ )和对照模式侵蚀裸地 (Ⅵ ) ,利用人工模拟降雨仪研究和分析了不同生态模式“土壤水库”调... 详细信息

本文在江西红壤区选择 5种具有代表性的红壤生态利用模式 :稀疏林生态 (Ⅰ )、林草生态(Ⅱ )、草灌生态 (Ⅲ )、经果生态 (Ⅳ )、农田生态 (Ⅴ )和对照模式侵蚀裸地 (Ⅵ ) ,利用人工模拟降雨仪研究和分析了不同生态模式“土壤水库”调节雨水的特征及其防洪减灾效能。结果表明 ,红壤区土壤入水通道受阻是“土壤水库”发挥防洪减灾效能的主要障碍因子 ;人工草灌生态模式 (Ⅲ )的防洪减灾效能最好 ;经果生态模式 (Ⅳ )不但具有较高的防洪减沙效能 ,而且具有较高的经济效益 ,是该区首选模式。

关键词：红壤区生态模式 “土壤水库” 特征特性防洪减灾效能

基于PLS-红外光谱的汽油辛烷值测定方法研究

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化学研究与应用 2021年第5期33卷 863-867页

作者：丁怡曼薛晓康范宾董学胜舒耀皋上海化工研究院有限公司上海200062 上海化学品公共安全工程技术中心上海200062

辛烷值是反映汽油抗爆性的重要指标,现有的辛烷值测试方法具有分析周期长、测试成本高等缺点。本文以红外光谱法结合偏最小二乘法(PLS)建立了汽油辛烷值快速测定方法。实验采集了113个汽油样品的光谱数据,以研究法辛烷值(RON)测得的实... 详细信息

辛烷值是反映汽油抗爆性的重要指标,现有的辛烷值测试方法具有分析周期长、测试成本高等缺点。本文以红外光谱法结合偏最小二乘法(PLS)建立了汽油辛烷值快速测定方法。实验采集了113个汽油样品的光谱数据,以研究法辛烷值(RON)测得的实际辛烷值为参数,建立了预测汽油辛烷值的PLS模型。结果表明:20个预测集的相关系数Rp^(2)为1.0184,预测均方根误差RMSEP为0.4639。说明此方法对汽油辛烷值具有较好的预测效果,且操作简单、分析速度快,具有一定的可行性。

关键词：汽油辛烷值红外光谱偏最小二乘法