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Impact of H_(2)S on Hg^(0)capture performance over nitrogen-doped carbon microsphere sorbent:experimental and theoretical insights

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Frontiers of Chemical Science and Engineering 2024年第3期18卷 89-100页

作者： Guopei Zhang Xiaoyang Zhang Xiangwen Xing Xiangru Kong Lin Cui dong yong National Engineering Laboratory for Reducing Emissions from Coal Combustion Shandong UniversityJinan250061China Bingtuan Energy Development Institute Shihezi UniversityShihezi832000China

A nitrogen-doped carbon microsphere sorbent with a hierarchical porous structure was synthesized via aggregation-hydrothermal *** Hg^(0)adsorption performance of the nitrogen-doped carbon microsphere sorbent was tested and compared with that of the coconut shell activated carbon prepared in the *** effect of H_(2)S on Hg^(0)adsorption was also *** nitrogen-doped carbon microsphere sorbent exhibited superior mercury removal performance compared with that of coconut shell activated *** the absence of H_(2)S at a low temperature(≤100℃),the Hg^(0)removal efficiency of the nitrogen-doped carbon microsphere sorbent exceeded 90%.This value is significantly higher than that of coconut shell activated carbon,which is approximately 45%.H_(2)S significantly enhanced the Hg^(0)removal performance of the nitrogen-doped carbon microsphere sorbent at higher temperatures(100–180℃).The hierarchical porous structure facilitated the diffusion and adsorption of H_(2)S and Hg^(0),while the nitrogen-containing active sites significantly improved the adsorption and dissociation capabilities of H_(2)S,contributing to the generation of more active sulfur species on the surface of the nitrogen-doped carbon microsphere *** formation of active sulfur species and HgS on the sorbent surface was further confirmed using X-ray photoelectron spectroscopy and Hg^(0)temperature-programmed desorption *** functional theory was employed to elucidate the adsorption and transformation of Hg^(0)on the sorbent surface.H_(2)S adsorbed and dissociated on the sorbent surface,generating active sulfur species that reacted with gaseous Hg^(0)to form HgS.

关键词： nitrogen-doped carbon microsphere H_(2)S Hg^(0)removal adsorption mechanism

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A continuous and long-term in-situ stress measuring method based on fiber optic. Part I: Theory of inverse differential strain analysis

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Petroleum Science 2024年第2期21卷 1171-1189页

作者： Kun-Peng Zhang Mian Chen Chang-Jun Zhao Su Wang yong-dong Fan State Key Laboratory of Petroleum Resources and Prospecting China University of PetroleumBeijing102249China MOE Key Laboratory of Petroleum Engineering in China University of Petroleum Beijing102249China Beijing International Center for Gas Hydrate School of Earth and Space SciencesPeking UniversityBeijing100871China

A method for in-situ stress measurement via fiber optics was proposed. The method utilizes the relationship between rock mass elastic parameters and in-situ stress. The approach offers the advantage of long-term stress measurements with high spatial resolution and frequency, significantly enhancing the ability to measure in-situ stress. The sensing casing, spirally wrapped with fiber optic, is cemented into the formation to establish a formation sensing nerve. Injecting fluid into the casing generates strain disturbance, establishing the relationship between rock mass properties and treatment ***, an optimization algorithm is established to invert the elastic parameters of formation via fiber optic strains. In the first part of this paper series, we established the theoretical basis for the inverse differential strain analysis method for in-situ stress measurement, which was subsequently verified using an analytical model. This paper is the fundamental basis for the inverse differential strain analysis method.

关键词： In-situ stress Fiber optic Orthotropic elastic Differential evolution ABAQUS

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Machine learning for carbonate formation drilling: Mud loss prediction using seismic attributes and mud loss records

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Petroleum Science 2024年第2期21卷 1241-1256页

作者： Hui-Wen Pang Han-Qing Wang Yi-Tian Xiao Yan Jin Yun-Hu Lu yong-dong Fan Zhen Nie National Key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing102249China College of Science China University of Petroleum-BeijingBeijing102249China Petroleum Exploration and Production Research Institute SINOPECBeijing102206China College of Petroleum Engineering China University of Petroleum-BeijingBeijing102249China Research Institute of Petroleum Exploration and Development CNPCBeijing100083China

Due to the complexity and variability of carbonate formation leakage zones, lost circulation prediction and control is one of the major challenges of carbonate drilling. It raises well-control risks and production expenses. This research utilizes the H oilfield as an example, employs seismic features to analyze mud loss prediction, and produces a complete set of pre-drilling mud loss prediction solutions. Firstly, 16seismic attributes are calculated based on the post-stack seismic data, and the mud loss rate per unit footage is specified. The sample set is constructed by extracting each attribute from the seismic trace surrounding 15 typical wells, with a ratio of 8:2 between the training set and the test set. With the calibration results for mud loss rate per unit footage, the nonlinear mapping relationship between seismic attributes and mud loss rate per unit size is established using the mixed density network ***, the influence of the number of sub-Gausses and the uncertainty coefficient on the model's prediction is evaluated. Finally, the model is used in conjunction with downhole drilling conditions to assess the risk of mud loss in various layers and along the wellbore trajectory. The study demonstrates that the mean relative errors of the model for training data and test data are 6.9% and 7.5%, respectively, and that R2is 90% and 88%, respectively, for training data and test data. The accuracy and efficacy of mud loss prediction may be greatly enhanced by combining 16 seismic attributes with the mud loss rate per unit footage and applying machine learning methods. The mud loss prediction model based on the MDN model can not only predict the mud loss rate but also objectively evaluate the prediction based on the quality of the data and the model.

关键词： Lost circulation Risk prediction Machine learning Seismic attributes Mud loss records

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Examining the association between delay discounting,delay aversion and physical activity in Chinese adults with type-2 diabetes mellitus

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World Journal of Diabetes 2024年第4期15卷 675-685页

作者： yong-dong An Guo-Xia Ma Xing-Kui Cai Ying Yang Fang Wang Zhan-Lin Zhang Department of Endocrinology People's Hospital of Linxia Hui Autonomous PrefectureLinxia Hui Autonomous Prefecture 731100Gansu ProvinceChina Department of Gynecology People's Hospital of Linxia Hui Autonomous PrefectureLinxia Hui Autonomous Prefecture 731100Gansu ProvinceChina The First Clinical Medical College Lanzhou UniversityLanzhou 730013Gansu ProvinceChina Department of Internal Medicine People's Hospital of HezhengLinxia Hui Autonomous Prefecture 731200Gansu ProvinceChina Department of Geratology People's Hospital of Linxia Hui Autonomous PrefectureLinxia Hui Autonomous Prefecture 731100Gansu ProvinceChina Department of Medical People's Hospital of Linxia Hui Autonomous PrefectureLinxia Hui Autonomous Prefecture 731100Gansu ProvinceChina

BACKGROUND The role of physical activity in diabetes is critical,influencing this disease's development,man-agement,and overall *** China,22.3%of adults do not meet the minimum level of physical activity recommended by the World Health ***,it is imperative to identify the factors that contributing to lack of physical activity must be *** To investigate the relationship among delay discounting,delay aversion,glycated hemoglobin(HbA1c),and various levels of physical activity in Chinese adults diagnosed with type 2 diabetes mellitus(T2DM).METHODS In 2023,400 adults with T2DM were recruited from the People's Hospital of Linxia Hui Autonomous Prefecture of Gansu Province.A face-to-face questionnaire was used to gather demographic data and details on physical activity,delay discounting,and delay *** addition,HbA1c levels were measured in all 400 *** primary independent variables considered were delay discounting and delay *** outcome variables included HbA1c levels and different intensity levels of physical activity,including walking,moderate physical activity,and vigorous physical *** linear regression models were utilized to assess the relationship between delay discounting,delay aversion,and HbA1c levels,along with the intensity of different physical activity measured in met-hours per *** After controlling for the sample characteristics,delay discounting was negatively associated with moderate physical activity(β=-2.386,95%CI:-4.370 to-0.401).Meanwhile,delay aversion was negatively associated with the level of moderate physical activity(β=-3.527,95%CI:-5.578 to-1.476)in the multiple linear regression model,with statistically significant *** Elevated delay discounting and increased delay aversion correlated with reduced levels of moderate physical *** suggests that delay discounting and aversion may influence engagement in moderate physical activity.

关键词： Type 2 diabetes mellitus Delay discounting Delay aversion Physical activity

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Appendicitis combined with Meckel’s diverticulum obstruction, perforation, and inflammation in children: Three case reports

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World Journal of Clinical Cases 2024年第4期12卷 865-871页

作者： Yi-Meng Sun Wang Xin Yu-Fang Liu Zhe-Ming Guan Hao-Wen Du Ning-Ning Sun yong-dong Liu School of Clinical Medicine Weifang Medical UniversityWeifang 261000Shandong ProvinceChina Department of Pediatric Surgery Weifang People’s HospitalWeifang 261000Shandong ProvinceChina Department of Burn Surgery Weifang People’s HospitalWeifang 261000Shandong ProvinceChina

BACKGROUND Meckel’s diverticulum is a common congenital malformation of the small intestine,with the three most common complications being obstruction,per-foration,and *** date,only a few cases have been reported *** children,the clinical symptoms are similar to *** most of the imaging features are nonspecific,the preoperative diagnosis is not *** addition,the clinical characteristics are highly similar to pediatric acute appendicitis,thus special attention is necessary to distinguish Meckel’s diver-ticulum from pediatric *** with poor disease control should undergo laparoscopic exploration to avoid serious complications,including intestinal necrosis,intestinal perforation and gastrointestinal *** SUMMARY This report presents three cases of appendicitis in children combined with intestinal obstruction,which was caused by fibrous bands(ligaments)arising from the top part of Meckel's diverticulum,diverticular perforation,and diver-ticular *** three patients,aged 11-12 years,had acute appendicitis as their initial clinical *** were treated by laparoscopic surgery with a favorable outcome.A complete dataset including clinical presentation,dia-gnostic imaging,surgical information,and histopathologic findings was also *** Preoperative diagnosis of Meckel’s diverticulum and its complications is challenging because its clinical signs and complications are similar to those of appendicitis in *** combined with laparotomy is useful for diagnosis and treatment.

关键词： Meckel’s diverticulum Complications Intestinal obstruction Perforation Appendicitis in children Mesodiverticular band Ligament Diverticular disease Case report

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南北向资金流动与中国股票市场的动态关联分析

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系统工程 2024年第2期42卷 141-150页

作者：湛东曈董希勇北京师范大学系统科学学院北京100875 山西大学经济与管理学院山西太原030006

沪港通和深港通是中国金融市场迈向国际化的一项重大创新政策。沪港通和深港通运行至今,北向资金和南向资金逐渐成为投资者的重点关注对象,特别是北向资金的动向往往被看成是市场行情好坏的风向标。本文使用ARMA-cDCC-FIGARCH模型,探究... 详细信息

沪港通和深港通是中国金融市场迈向国际化的一项重大创新政策。沪港通和深港通运行至今,北向资金和南向资金逐渐成为投资者的重点关注对象,特别是北向资金的动向往往被看成是市场行情好坏的风向标。本文使用ARMA-cDCC-FIGARCH模型,探究北向及南向资金流动和上证指数、深证成指与恒生指数间的动态联动性。研究表明,北向资金流动和深证成指涨跌的相关性最强,北向资金流动和上证指数涨跌的相关性次之,而南向资金流动和恒生指数涨跌的相关性最弱。其中,北向资金和内地两个市场间的相关系数波动较小,而南向资金和恒生指数间的相关系数波动幅度较大。并且,三个股票市场和南北向资金流动均存在长期记忆性特征。研究结果对于维护国家金融体系稳定,制定针对性的监管政策,以及促进资本市场发展具有重要的现实意义。

关键词：股票市场南北向资金动态关联 ARMA-cDCC-FIGARCH模型

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金沙江向家坝水电站下游河道2020年淤积成因分析

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泥沙研究 2024年第1期49卷 45-50页

作者：杜泽东秦蕾蕾董先勇中国三峡建工(集团)有限公司四川成都610041

向家坝下游河道泥沙冲淤变化对岸坡稳定及通航具有重要影响,向家坝水电站运行后坝下游河床一直呈冲刷状态,但2020年首次出现淤积。采用输沙法和断面法计算向家坝出库沙量和下游河段泥沙冲淤量,结合气象、水动力及实勘资料,分析向家坝下... 详细信息

向家坝下游河道泥沙冲淤变化对岸坡稳定及通航具有重要影响,向家坝水电站运行后坝下游河床一直呈冲刷状态,但2020年首次出现淤积。采用输沙法和断面法计算向家坝出库沙量和下游河段泥沙冲淤量,结合气象、水动力及实勘资料,分析向家坝下游2020年淤积成因。研究结果表明:向家坝蓄水后出库年径流量变化不大,出库沙量受上游电站拦沙作用大幅减少,但2020年向家坝下游支流降雨偏丰,支流输沙量大幅增加,产生区域强输沙过程;该年下游各控制站最高水位较历史平均水位均偏高,汛期比降变化不大,水流挟沙能力不足以输送显著增多的泥沙;加上采砂减少和采砂造成的下切幅度较大部位发生回淤。这些原因导致2020年向家坝下游河道产生淤积。

关键词：向家坝水电站泥沙冲淤水面比降水动力条件河道采砂

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V型三能级金刚石氮空位色心电磁诱导透明体系中孤子的存取

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物理学报 2024年第10期73卷 307-314页

作者：谭聪王登龙董耀勇丁建文湘潭大学物理与光电工程学院湘潭411105 广东工业大学机电工程学院广州510006

本文先构建一束弱探测场和一束强控制场所形成的V型三能级金刚石氮空位(NV)色心电磁诱导透明(EIT)模型,随后研究探测场在体系的线性吸收和非线性传播特性.结果表明,一旦开启强控制场,体系就会呈现出EIT窗口,且透明窗口的宽度随着控制场... 详细信息

本文先构建一束弱探测场和一束强控制场所形成的V型三能级金刚石氮空位(NV)色心电磁诱导透明(EIT)模型,随后研究探测场在体系的线性吸收和非线性传播特性.结果表明,一旦开启强控制场,体系就会呈现出EIT窗口,且透明窗口的宽度随着控制场磁感应强度的增加而变宽.在非线性情况下,探测场能形成稳定传播的孤子,且可通过开启和关闭控制场的磁场实现孤子的存储和读取,可以有效地克服冷原子介质和量子点介质孤子存取的缺陷.值得一提的是,体系所存取孤子的振幅还可以通过控制场的磁感应强度来进行调节.

关键词：金刚石氮空位色心孤子的存储与读取电磁诱导透明

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高温烟气热解废轮胎过程中痕量金属Cu、Pb的迁移特性分析

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化工进展 2024年第3期43卷 1606-1613页

作者：张鑫汤吉昀陈娟宋占龙董勇姚洪山东大学能源与动力工程学院山东济南250061 昌吉学院能源与控制工程学院新疆昌吉831100 华中科技大学能源与动力工程学院煤燃烧与低碳利用全国重点实验室湖北武汉430000

废轮胎(WT)作为一种常见固废,不合理的处置会对环境造成较大污染。本文采用燃煤高温烟气对WT进行热解,重点研究了热解过程中重金属Cu和Pb的释放特性,以及不同金属氧化物(CaO、MgO、Al_(2)O_(3)、Fe_(2)O_(3))对两种重金属的控制效果,此... 详细信息

废轮胎(WT)作为一种常见固废,不合理的处置会对环境造成较大污染。本文采用燃煤高温烟气对WT进行热解,重点研究了热解过程中重金属Cu和Pb的释放特性,以及不同金属氧化物(CaO、MgO、Al_(2)O_(3)、Fe_(2)O_(3))对两种重金属的控制效果,此外还研究了添加聚氯乙烯(PVC)对两种重金属迁移释放的影响。结果表明,当热解时间为10min时,两种元素已经基本释放完全。高温促进了Cu的富集,而低温反而促进了Cu的释放。对Pb元素而言,随着温度的升高,其释放量不断增加,展现出明显的线性规律。当WT添加金属氧化物热解时,MgO促进了Cu的富集,而Al_(2)O_(3)促进了Pb的富集。当WT添加PVC热解时,低温促进了Cu的富集,而高温促进了Cu的释放。但不论温度的高低,PVC的添加使得Pb几乎完全释放。此时,添加Fe_(2)O_(3)对两种重金属的释放均起到了抑制作用。

关键词：废轮胎热解高温烟气铜铅

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广电工程中的虚拟数字人技术应用

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电视技术 2024年第4期48卷 210-213页

作者：董永山东科视文化产业有限公司山东济南250000

随着科技的飞速发展,虚拟数字人技术已逐步应用于广电工程领域,开启了电视广播内容制作和传播的新纪元。以广电工程中虚拟数字人技术应用为研究对象,分析虚拟数字人技术与广电工程需求间的深度适配关系,深入探讨虚拟数字人技术在广电工... 详细信息

随着科技的飞速发展,虚拟数字人技术已逐步应用于广电工程领域,开启了电视广播内容制作和传播的新纪元。以广电工程中虚拟数字人技术应用为研究对象,分析虚拟数字人技术与广电工程需求间的深度适配关系,深入探讨虚拟数字人技术在广电工程应用中的关键实施策略和技术手段,为广电行业的创新发展提供前瞻性的理论依据和技术方案。

关键词：虚拟数字人技术广电工程实时交互设计

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